CN109370347A - A kind of anion artificial granite paint and preparation method thereof - Google Patents

A kind of anion artificial granite paint and preparation method thereof Download PDF

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Publication number
CN109370347A
CN109370347A CN201811136259.3A CN201811136259A CN109370347A CN 109370347 A CN109370347 A CN 109370347A CN 201811136259 A CN201811136259 A CN 201811136259A CN 109370347 A CN109370347 A CN 109370347A
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China
Prior art keywords
component
agent
anion
deionized water
acrylic emulsion
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CN201811136259.3A
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Inventor
吴玉良
郭云建
胡中源
董立志
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Hebei Chenyang Industry and Trade Group Co Ltd
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Hebei Chenyang Industry and Trade Group Co Ltd
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Priority to CN201811136259.3A priority Critical patent/CN109370347A/en
Publication of CN109370347A publication Critical patent/CN109370347A/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04—Homopolymers or copolymers of monomers containing silicon
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/48—Stabilisers against degradation by oxygen, light or heat
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The present invention provides a kind of anion artificial granite paint and preparation method thereof, including ingredient are as follows: component A: deionized water, carboxymethyl cellulose, waterproofing agent of organosilicon, defoaming agent, fungicide, PH regulator, antifreezing agent, coalescing agent, titanium dioxide, kaolin, anionic additive, water-base resin, protective glue, diamond dust；B component: deionized water, bentonite；C component: water-base resin, auxiliary agent, alkali swollen thickener.Anion granite paint of the present invention, by adding anionic additive, when being acted synergistically using specific anionic additive and specific dosage of the present invention, specific component, can keep anion-generating capacity not less than 1000/(Scm2), and it can effectively neutralize the substances such as dust, bacterium, virus in air, it is allowed to, to achieve the purpose that purify air.

Description

A kind of anion artificial granite paint and preparation method thereof
Technical field
The invention belongs to paint fields, and in particular to a kind of anion artificial granite paint and preparation method thereof.
Background technique
Anion is referred to as the vitamin in air.When people stroll by the sea, waterfall and when forest, can feel that breathing is relaxed Freely, relaxing, one of them most important reason is exactly anion rich in air.And air environment is deteriorated mainly It is since positive and negative ion concentration contains pernicious gas and smog, dust, virus, bacterium etc. than unbalance in air in air.And On the one hand adjustable positive and negative ion concentration ratio, another aspect can play the role of purifying air anion again, and anion can make The invisible drift dirt of micron order in air forms micel by negative ions attraction, collision and sinks to landing, and anion It is reverse to make bacterio protein two-stage, and makes bacterial viability decline or lethal.The characteristics of anion fine-purification air is to go out Speed living is fast, and inactivation ratio is high, has deactivation to the microorganism of air, article surface, bacterium, virus.
Strength of character intension of the artificial granite paint rich in natural granite, the noble grade of quite aobvious granite are traditional natural true The novel upgrading kind of mineral varnish.The big-pattern, big idea, good-looking, secured after spraying and decorating, effect exactly likes the abundant matter of stone material Sense, gives dignified, rough, atmosphere the visual enjoyment as natural granite.Due to artificial granite paint artistic effect abundant, Favor increasingly by most of realtors, artificial granite paint are widely used in external wall elevation and interior wall background effect In coating.
However, existing artificial granite paint is the physical property and application property for laying particular emphasis on product on the market, not to imitative The air cleaning performance of granite paint is studied.
Summary of the invention
In order to solve the technical problem in above-mentioned background technique, the present invention provides a kind of anion artificial granite paint, including A Component, B component and C component, the addition mass ratio of the component A, B component and C component are 5:3:2；Wherein,
In the component A, in terms of the mass percent of component A, including following component: deionized water 20~21%, carboxylic first Base cellulose 3%, waterproofing agent of organosilicon 1~1.5%, defoaming agent 0.5%, fungicide 0.4%, PH regulator 0.1%, antifreezing agent 1%, coalescing agent 1%, titanium dioxide 2%, kaolin 10~12%, anionic additive 3~5%, high-elastic pure-acrylic emulsion 0~ 5%, styrene-acrylic emulsion 13~20%, the protective glue S482 2.5~3% of Lockwood, diamond dust 32~35%；The above material is mixed It closes and white anion base paint is uniformly made；
In the B component, in terms of the mass percent of B component, including following component: deionized water 94.5%, bentonite 5.5%, the two mixes obtained mixed liquid B component；
In the C component, in terms of the mass percent of C component, including following component: deionized water 0~9%, the third cream of silicon Liquid 80~88%, auxiliary agent 8~10%, alkali swollen thickener 2~3%, three mix obtained lotion phase C component.
Further, it is 0.3g/cm that the carboxymethyl cellulose, which is Langfang Venus Chemical Co., Ltd. density,3Carboxymethyl Cellulose；The waterproofing agent of organosilicon is Nanxiong ancient cooking vessel into the solid containing the organic silicon water-proofing for being 40wt% of new material Science and Technology Ltd. Agent；The defoaming agent is one or both of mineral oils, organic silicon, mineral oils；The fungicide is that Jinan moral is blue The DL-T201 of Chemical Co., Ltd.；The PH regulator is 2-amino-2-methyl-1-propanol；The antifreezing agent is methyl second two Alcohol antifreezing agent；The coalescing agent is 12 coalescing agent of alcohol ester；The titanium dioxide is the CHR-500 golden red of the happy roc chemical industry in Langfang Stone titanium dioxide；The kaolin is the JYCK-95 of Jin Yu calcined kaolin Chemical Co., Ltd.；The high-elastic pure-acrylic emulsion is bar The DC420V styrene-acrylic emulsion that the high-elastic pure-acrylic emulsion of the RS-9689AS of De Fu Industrial Co., Ltd. and the styrene-acrylic emulsion are DOW；Institute State the 80-120 mesh diamond dust that diamond dust is Zhengzhou City Hai Xu abrasive material Co., Ltd.
Further, the anionic additive is the day that Beijing Health-care Science & Technology Co., Ltd.'s solid content is 50% Refreshing board anionic additive.
Further, the bentonite is that Anji County, Zhejiang Province sky dragon organobentonite Co., Ltd ST-B bentonite thickens rheology Agent.
Further, in the C component, silicone acrylic emulsion is Ahmedabad richness RS-996AD soap-free polymerization silicone acrylic emulsion.
Further, the alkali swollen thickener is the TT-935 hydrophobically modified alkali-soluble emulsion type thickener of DOW.
Further, in the C component, auxiliary agent is defoaming agent, pH stabilizer, antifreezing agent and coalescing agent, wherein described Defoaming agent is Nuo Pu section SN1360, and the PH stabilizer is AMP-95；The antifreezing agent is Propylene Glycol antifreezing agent；It is described at Film auxiliary agent is 2,2,4- trimethyl -1,3- pentanediol mono isobutyrate.
Further, the present invention also provides the preparation methods of the anion artificial granite paint, comprising the following steps:
S1. it first prepares component A: deionized water being first added in dispersion tank, is slowly added to carboxylic under 300-500rpm revolving speed Methylcellulose stirs 2 minutes, sequentially adds waterproofing agent of organosilicon, defoaming agent, fungicide, PH regulator, antifreezing agent, film forming Then auxiliary agent, titanium dioxide, kaolin, anionic additive sequentially add high speed dispersion 25 minutes under 1000-1200rpm revolving speed Water-base resin, protective glue, diamond dust had both obtained component A white anion base paint；It requires followed by according to toning by base paint It is divided into several pieces to mix colours respectively；
S2.B component the preparation method is as follows: first deionized water is added in dispersion tank, under 300-500rpm revolving speed delay Slow that ST-B bentonite thickener rheology agent is added and steps up revolving speed to 1000rpm, high speed dispersion 30 minutes is to being completely dissolved both Obtain protective glue；
S3.C component the preparation method is as follows: sequentially add deionized water, water-base resin, auxiliary agent in dispersion tank, adjust Viscosity to 60-70ku both lotion phase；
S4. various colors and various granular sizes are made after mixing component A, B component in above-mentioned steps as requested Particle color spot；
S5. material shear-mixed made from step S3, S4 is uniform, viscosity is adjusted to 65-75KU, that is, forms different colours The equally distributed anion artificial granite paint of grain.
The invention has the following advantages over the prior art:
(1) anion granite paint of the present invention is added by adding anionic additive using specific anion When agent and specific dosage of the present invention, specific component act synergistically, can keep anion-generating capacity not less than 6000/ cm3, and the substances such as dust, bacterium, virus in air can be effectively neutralized, it is allowed to, to achieve the purpose that purify air.
(2) anion granite paint of the present invention, since diamond dust is logical with raw materials such as quartz sand, petroleum coke, sawdusts Resistance furnace pyrolytic semlting is crossed to form, chemical property stablize, the more conducively storage and transport of anion artificial granite paint, product it is resistance to It is more excellent to wait performance.
Specific embodiment
The present invention is further illustrated below by preferred embodiment of the invention, it should be noted that following examples are only Illustration purpose is not intended to limit the present invention.
In the present invention, indicate that the unit of material content is based on mass percent meter, unit is kilogram, unless in addition saying It is bright.In addition, the measuring method about technical indicator of the invention is in the art using standard method, for details, reference can be made to newest National standard, unless otherwise stated.In addition, such as the specific producer of other raw material use in the present invention and model Under:
The carboxymethyl cellulose is that Langfang Venus Chemical Co., Ltd. density is 0.3g/cm3Carboxymethyl cellulose；
The waterproofing agent of organosilicon is Nanxiong ancient cooking vessel into the solid anti-containing the organosilicon for being 40wt% of new material Science and Technology Ltd. Aqua；
The defoaming agent is one or both of mineral oils, organic silicon, mineral oils；
The fungicide is the DL-T201 of Jinan De Lan Chemical Co., Ltd.；
The PH regulator is 2-amino-2-methyl-1-propanol；
The antifreezing agent is Propylene Glycol antifreezing agent；
The coalescing agent is 12 coalescing agent of alcohol ester；
The titanium dioxide is the CHR-500 rutile titanium white powder of the happy roc chemical industry in Langfang；
The kaolin is the JYCK-95 of Jin Yu calcined kaolin Chemical Co., Ltd.；The high-elastic pure-acrylic emulsion is bar The DC420V styrene-acrylic emulsion that the high-elastic pure-acrylic emulsion of the RS-9689AS of De Fu Industrial Co., Ltd. and the styrene-acrylic emulsion are DOW；
The diamond dust is the 80-120 mesh diamond dust of Zhengzhou City Hai Xu abrasive material Co., Ltd；
The anionic additive be Beijing Health-care Science & Technology Co., Ltd.'s solid content be 50% day feel well board bear from Sub- additive；
The bentonite is the ST-B bentonite thickener rheology agent of Anji County, Zhejiang Province sky dragon organobentonite Co., Ltd；
In the C component, the silicone acrylic emulsion is Ahmedabad richness RS-996AD soap-free polymerization silicone acrylic emulsion, and auxiliary agent is defoaming Agent, pH stabilizer, antifreezing agent and coalescing agent, wherein the defoaming agent is Nuo Pu section SN1360, the PH stabilizer is AMP- 95；The antifreezing agent is Propylene Glycol antifreezing agent；The coalescing agent is 2,2,4- trimethyl -1,3- pentanediol list isobutyric acid Ester；
The alkali swollen thickener is the TT-935 hydrophobically modified alkali-soluble emulsion type thickener of DOW.
Embodiment 1
The paint of anion granite described in the present embodiment, including component A, B component and C component, the component A, B component and The addition mass ratio of C component is 5:3:2；Wherein,
In the component A, in terms of the mass percent of component A, including following component: component A: deionized water 21%, carboxylic Methylcellulose 3%, waterproofing agent of organosilicon 1.5%, defoaming agent 0.5%, fungicide 0.4%, PH regulator 0.1%, antifreezing agent 1%, coalescing agent 1%, titanium dioxide 2%, kaolin 10%, anionic additive 5%, high-elastic pure-acrylic emulsion 5%, styrene-acrylic emulsion 15%, protective glue 2.5%, diamond dust 32%；The above material, which is uniformly mixed, is made white anion base paint；
In the B component, in terms of the mass percent of B component, including following component: deionized water 94.5%, bentonite 5.5%, the two mixes obtained protective glue；
In the C component, in terms of the mass percent of C component, including following component: silicone acrylic emulsion 88%, auxiliary agent 10%, Alkali swollen thickener 2%, three mix obtained lotion phase.
The new product manufacturing method are as follows:
S1.A component: being first added deionized water in dispersion tank, and carboxymethyl fibre is slowly added under 300-500rpm revolving speed Dimension element stirring 2 minutes, sequentially add waterproofing agent of organosilicon, defoaming agent, fungicide, PH regulator, antifreezing agent, coalescing agent, Then titanium dioxide, kaolin, anionic additive sequentially add aqueous high speed dispersion 25 minutes under 1000-1200rpm revolving speed Resin, protective glue, diamond dust had both obtained component A white anion base paint；It requires for base paint to be divided into followed by according to toning Several pieces are mixed colours respectively；
S2.B component: deionized water is first added in dispersion tank, ST-B swelling is slowly added under 300-500rpm revolving speed Native thickener rheology agent bentonite simultaneously steps up revolving speed to 1000rpm, and high speed dispersion 30 minutes was both protected to being completely dissolved Glue.
S3.C component: sequentially adding deionized water, water-base resin, auxiliary agent in dispersion tank, adjusts viscosity to 60-70ku both Obtain lotion phase.
S4. anion base paint white in above-mentioned steps is divided into after several pieces are mixed colours respectively and is added in B component (color Modulation effect be that the template provided according to client determines), the ratio of component A and B component is 5:3；It is then turned on dispersion Machine, revolving speed are adjusted to 300-500rpm and stir 2 minutes to get (size of particle is according to sample to the particle color spot of various granular sizes Depending on plate effect)；
S5. material shear-mixed made from step S3, S4 is uniform, viscosity is adjusted to 65-75KU, that is, forms different colours The equally distributed anion artificial granite paint of grain.
Embodiment 2
The raw material of the present embodiment are as follows:
The paint of anion granite described in the present embodiment, including component A, B component and C component, the component A, B component and The addition mass ratio of C component is 5:3:2；Wherein,
In the component A, in terms of the mass percent of component A, including following component: deionized water 20%, carboxymethyl are fine Dimension element 3%, waterproofing agent of organosilicon 1.0%, defoaming agent 0.5%, fungicide 0.4%, PH regulator 0.1%, antifreezing agent 1%, at Film auxiliary agent 1%, titanium dioxide 2%, kaolin 10%, anionic additive 5%, high-elastic pure-acrylic emulsion 5%, styrene-acrylic emulsion 13%, Protective glue 3.0%, diamond dust 35%；The above material, which is uniformly mixed, is made white anion base paint；
In the B component, in terms of the mass percent of B component, including following component: deionized water 94.5%, bentonite 5.5%, the two mixes obtained protective glue；
In C component described in C, in terms of the mass percent of C component, including following component: deionized water 9%, silicone acrylic emulsion 80%, auxiliary agent 8%, alkali swollen thickener 3%, three mix obtained lotion phase.
The new product manufacturing method are as follows:
S1.A component: being first added deionized water in dispersion tank, and carboxymethyl fibre is slowly added under 300-500rpm revolving speed Dimension element stirring 2 minutes, sequentially add waterproofing agent of organosilicon, defoaming agent, fungicide, PH regulator, antifreezing agent, coalescing agent, Then titanium dioxide, kaolin, anionic additive sequentially add aqueous high speed dispersion 25 minutes under 1000-1200rpm revolving speed Resin, protective glue, diamond dust had both obtained component A white anion base paint；It requires for base paint to be divided into followed by according to toning Several pieces are mixed colours respectively；
S2.B component: deionized water is first added in dispersion tank, ST-B swelling is slowly added under 300-500rpm revolving speed Native thickener rheology agent simultaneously steps up revolving speed to 1000rpm, and high speed dispersion 30 minutes both obtains protective glue to being completely dissolved.
S3.C component: sequentially adding deionized water, water-base resin, auxiliary agent in dispersion tank, adjusts viscosity to 60-70ku both Obtain lotion phase.
S4. proportionally various colors and various is made after ratio requirement mixes in component A, B component in above-mentioned steps The particle color spot of grain size；
S5. will expect to require shear-mixed uniform according to the proportion made from step S3, S4, adjustment viscosity to 65-75KU, i.e. shape At the equally distributed anion artificial granite paint of different colours particle.
Embodiment 3
The paint of anion granite described in the present embodiment, including component A, B component and C component, the component A, B component and The addition mass ratio of C component is 5:3:2；Wherein,
In the component A, in terms of the mass percent of component A, including following component: deionized water 21%, carboxymethyl are fine Dimension element 3%, waterproofing agent of organosilicon 1.5%, defoaming agent 0.5%, fungicide 0.4%, PH regulator 0.1%, antifreezing agent 1%, at Film auxiliary agent 1%, titanium dioxide 2%, kaolin 12%, anionic additive 3%, styrene-acrylic emulsion 20%, protective glue 2.5%, Buddha's warrior attendant Sand 32%；The above material, which is uniformly mixed, is made white anion base paint；
In the B component, in terms of the mass percent of B component, including following component: deionized water 94.5%, bentonite 5.5%, the two mixes obtained protective glue；
In the C component, in terms of the mass percent of C component, including following component: deionized water 5%, silicone acrylic emulsion 85%, auxiliary agent 7.5%, alkali swollen thickener 2.5%, three mix obtained lotion phase.
The new product manufacturing method are as follows:
S1.A component: being first added deionized water in dispersion tank, and carboxymethyl fibre is slowly added under 300-500rpm revolving speed Dimension element stirring 2 minutes, sequentially add waterproofing agent of organosilicon, defoaming agent, fungicide, PH regulator, antifreezing agent, coalescing agent, Then titanium dioxide, kaolin, anionic additive sequentially add aqueous high speed dispersion 25 minutes under 1000-1200rpm revolving speed Resin, protective glue, diamond dust had both obtained component A white anion base paint；It requires for base paint to be divided into followed by according to toning Several pieces are mixed colours respectively；
S2.B component: deionized water is first added in dispersion tank, ST-B swelling is slowly added under 300-500rpm revolving speed Native thickener rheology agent simultaneously steps up revolving speed to 1000rpm, and high speed dispersion 30 minutes both obtains protective glue to being completely dissolved.
S3.C component: sequentially adding deionized water, water-base resin, auxiliary agent in dispersion tank, adjusts viscosity to 60-70ku both Obtain lotion phase.
S4. various colors is made after component A, B component in above-mentioned steps being required mixing according to the proportion and various particles are big Small particle color spot；
S5. material shear-mixed made from step S3, S4 is uniform, viscosity is adjusted to 65-75KU, that is, forms different colours The equally distributed anion artificial granite paint of grain.
Embodiment 4
Including component A, B component and C component, the addition mass ratio of the component A, B component and C component is 5:3:2；Its In,
In the component A, in terms of the mass percent of component A, including following component: deionized water 21%, carboxymethyl are fine Dimension element 3%, waterproofing agent of organosilicon 1.5%, defoaming agent 0.5%, fungicide 0.4%, PH regulator 0.1%, antifreezing agent 1%, at Film auxiliary agent 1%, kaolin 9%, anionic additive 4%, high-elastic pure-acrylic emulsion 5%, styrene-acrylic emulsion 12%, is protected titanium dioxide 3% Protect glue 2.5%, diamond dust 35%；The above material, which is uniformly mixed, is made white anion base paint；
In the B component, in terms of the mass percent of B component, including following component: deionized water 94.5%, bentonite 5.5%, the two mixes obtained protective glue；
In the C component, in terms of the mass percent of C component, including following component: silicone acrylic emulsion 88%, auxiliary agent 10%, Alkali swollen thickener 2%, three mix obtained lotion phase.
The new product manufacturing method are as follows:
S1.A component: being first added deionized water in dispersion tank, and carboxymethyl fibre is slowly added under 300-500rpm revolving speed Dimension element stirring 2 minutes, sequentially add waterproofing agent of organosilicon, defoaming agent, fungicide, PH regulator, antifreezing agent, coalescing agent, Then titanium dioxide, kaolin, anionic additive sequentially add aqueous high speed dispersion 25 minutes under 1000-1200rpm revolving speed Resin, protective glue, diamond dust had both obtained component A white anion base paint；It requires for base paint to be divided into followed by according to toning Several pieces are mixed colours respectively；
S2.B component: deionized water is first added in dispersion tank, ST-B swelling is slowly added under 300-500rpm revolving speed Native thickener rheology agent simultaneously steps up revolving speed to 1000rpm, and high speed dispersion 30 minutes both obtains protective glue to being completely dissolved.
S3.C component: sequentially adding deionized water, water-base resin, auxiliary agent in dispersion tank, adjusts viscosity to 60-70ku both Obtain lotion phase.
S4. various colors is made after component A, B component in above-mentioned steps being required mixing according to the proportion and various particles are big Small particle color spot；
S5. material shear-mixed made from step S3, S4 is uniform, viscosity is adjusted to 65-75KU, that is, forms different colours The equally distributed anion artificial granite paint of grain.
Embodiment 5
This comparative example includes component A, B component and C component, and the addition mass ratio of the component A, B component and C component is 5: 3:2；Wherein,
In the component A, in terms of the mass percent of component A, including following component: deionized water 23%, carboxymethyl are fine Dimension element 3.5%, waterproofing agent of organosilicon 1%, defoaming agent 0.5%, fungicide 0.4%, PH regulator 0.1%, antifreezing agent 1%, at Film auxiliary agent 1%, titanium dioxide 2%, kaolin 10%, high-elastic pure-acrylic emulsion 5%, styrene-acrylic emulsion 15%, protective glue 2.5%, snowflake White sand 35%；The above material, which is uniformly mixed, is made white anion base paint；
In the B component, in terms of the mass percent of B component, including following component: deionized water 95%, bentonite 5%, the two mixes obtained protective glue；
In the C component, in terms of the mass percent of C component, including following component:: deionized water 10%, silicone acrylic emulsion 80%, auxiliary agent 8%, alkali swollen thickener 2%, three mix obtained lotion phase.
The Manufacturing Method of Products are as follows:
S1.A component: being first added deionized water in dispersion tank, and carboxymethyl fibre is slowly added under 300-500rpm revolving speed Dimension element stirring 2 minutes, sequentially add waterproofing agent of organosilicon, defoaming agent, fungicide, PH regulator, antifreezing agent, coalescing agent, Then titanium dioxide, kaolin sequentially add water-base resin, protective glue, snow high speed dispersion 25 minutes under 1000-1200rpm revolving speed Grey sand had both obtained component A white anion base paint；It is adjusted respectively followed by base paint is divided into several pieces according to toning requirement Color；
S2.B component: deionized water is first added in dispersion tank, ST-B swelling is slowly added under 300-500rpm revolving speed Native thickener rheology agent soil simultaneously steps up revolving speed to 1000rpm, and high speed dispersion 30 minutes both obtains protective glue to being completely dissolved.
S3.C component: sequentially adding deionized water, water-base resin, auxiliary agent in dispersion tank, adjusts viscosity to 60-70ku both Obtain lotion phase.
S4. various colors and various granular sizes are made after mixing component A, B component in above-mentioned steps as requested Particle color spot；
S5. material shear-mixed made from step S3., S4. is uniform, viscosity is adjusted to 65-75KU, that is, forms different colours The equally distributed anion artificial granite paint of particle.
The prevailing quality technical indicator such as following table (table 1) of the resulting anion artificial granite paint of embodiment 1:
Table 1
The prevailing quality technical indicator such as following table (table 2) of the resulting anion artificial granite paint of embodiment 2:
Table 2
The prevailing quality technical indicator such as following table (table 3) of the resulting anion artificial granite paint of embodiment 3:
Table 3:
The prevailing quality technical indicator of the resulting anion artificial granite paint of embodiment 4 is as follows:
Table 4:
The prevailing quality technical indicator of the resulting anion artificial granite paint of embodiment 5 is as follows:
Obviously, the above embodiments are merely examples for clarifying the description, and does not limit the embodiments.It is right For those of ordinary skill in the art, can also make on the basis of the above description it is other it is various forms of variation or It changes.There is no necessity and possibility to exhaust all the enbodiments, and it is extended from this it is obvious variation or It changes among still in the invention scope of protection of the claims.

Claims (8)

1. a kind of anion artificial granite paint, which is characterized in that including component A, B component and C component, the component A, B component Addition mass ratio with C component is 5:3:2；Wherein,
In the component A, in terms of the mass percent of component A, including following component: deionized water 20~21%, carboxymethyl are fine Dimension element 3%, waterproofing agent of organosilicon 1~1.5%, defoaming agent 0.5%, fungicide 0.4%, PH regulator 0.1%, antifreezing agent 1%, Coalescing agent 1%, titanium dioxide 2%, kaolin 10~12%, anionic additive 3~5%, high-elastic pure-acrylic emulsion 0~5%, benzene Acrylic emulsion 13~20%, the protective glue S482 2.5~3% of Lockwood, diamond dust 32~35%；The above material is uniformly mixed White anion base paint is made；
In the B component, in terms of the mass percent of B component, including following component: deionized water 94.5%, bentonite 5.5%, the two mixes obtained mixed liquor；
In the C component, in terms of the mass percent of C component, including following component: deionized water 0~9%, silicone acrylic emulsion 80 ~88%, auxiliary agent 8~10%, alkali swollen thickener 2~3%, three mix obtained lotion phase C component.
2. anion artificial granite paint according to claim 1, which is characterized in that the carboxymethyl cellulose is Langfang Venus Chemical Co., Ltd.'s density is 0.3g/cm3Carboxymethyl cellulose；The waterproofing agent of organosilicon is Nanxiong ancient cooking vessel into new material science and technology The solid waterproofing agent of organosilicon containing for 40wt% of Co., Ltd；The defoaming agent is mineral oils, in organic silicon, mineral oils One or two；The fungicide is the DL-T201 of Jinan De Lan Chemical Co., Ltd.；The PH regulator is 2- amino- 2- methyl-1-propyl alcohol；The antifreezing agent is Propylene Glycol antifreezing agent；The coalescing agent is 12 coalescing agent of alcohol ester；Institute State the CHR-500 rutile titanium white powder that titanium dioxide is the happy roc chemical industry in Langfang；The kaolin is that golden space calcined kaolin chemical industry has The JYCK-95 of limit company；The high-elastic pure-acrylic emulsion be Ahmedabad richness Industrial Co., Ltd. the high-elastic pure-acrylic emulsion of RS-9689AS and The styrene-acrylic emulsion is the DC420V styrene-acrylic emulsion of DOW；The diamond dust is the 80-120 of Zhengzhou City Hai Xu abrasive material Co., Ltd Mesh diamond dust.
3. anion artificial granite paint according to claim 2, which is characterized in that the anionic additive is Beijing day The refreshing board anionic additive in the day that rock health Science and Technology Ltd.'s solid content is 50%.
4. -3 any anion artificial granite paint according to claim 1, it is characterised in that: the bentonite is Anji County, Zhejiang Province The ST-B bentonite thickener rheology agent of sky dragon organobentonite Co., Ltd.
5. -4 any anion artificial granite paint according to claim 1, it is characterised in that: in the C component, the silicon third Lotion is Ahmedabad richness RS-996AD soap-free polymerization silicone acrylic emulsion.
6. any a kind of anion artificial granite paint according to claim 1~5, it is characterised in that: the swollen increasing of alkali soluble The thick dose of TT-935 hydrophobically modified alkali-soluble emulsion type thickener for DOW.
7. any anion artificial granite paint according to claim 1~5, it is characterised in that: in the C component, auxiliary agent is Defoaming agent, pH stabilizer, antifreezing agent and coalescing agent, wherein the defoaming agent is Nuo Pu section SN1360, the PH stabilizer is AMP-95；The antifreezing agent is Propylene Glycol antifreezing agent；The coalescing agent is 2,2,4- trimethyl -1,3- pentanediol Dan Yi Butyrate.
8. the preparation method of any anion artificial granite paint of claim 1-7, it is characterised in that the following steps are included:
S1. it first prepares component A: deionized water being first added in dispersion tank, is slowly added to carboxymethyl under 300-500rpm revolving speed Cellulose stirs 2 minutes, sequentially adds waterproofing agent of organosilicon, defoaming agent, fungicide, PH regulator, antifreezing agent, film forming and helps Then agent, titanium dioxide, kaolin, anionic additive sequentially add water high speed dispersion 25 minutes under 1000-1200rpm revolving speed Property resin, protective glue, diamond dust had both obtained component A white anion base paint；It requires followed by according to toning by base paint point It mixes colours respectively at several pieces；
S2.B component the preparation method is as follows: first deionized water is added in dispersion tank, under 300-500rpm revolving speed slowly plus Enter ST-B bentonite thickener rheology agent and step up revolving speed to 1000rpm, high speed dispersion 30 minutes was both obtained to being completely dissolved Mixed liquor；
S3.C component the preparation method is as follows: sequentially add deionized water, water-base resin, auxiliary agent in dispersion tank, adjust viscosity Lotion phase is both obtained to 60-70ku；
S4. the particle of various colors and various granular sizes is made after mixing component A, B component in above-mentioned steps as requested Color spot；
S5. material shear-mixed made from step S3, S4 is uniform, viscosity is adjusted to 65-75KU, that is, it is equal to form different colours particle The anion artificial granite paint of even distribution.
CN201811136259.3A 2018-09-28 2018-09-28 A kind of anion artificial granite paint and preparation method thereof Pending CN109370347A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110484075A (en) * 2019-07-30 2019-11-22 安徽富瑞雪化工科技股份有限公司 A kind of aqueous camouflage color paint and preparation method thereof and application method
CN111748250A (en) * 2019-03-28 2020-10-09 河北晨阳工贸集团有限公司 Anion sand-in-water multicolor paint and preparation method thereof
CN112892389A (en) * 2021-01-20 2021-06-04 富思特新材料科技发展股份有限公司 Toning method of granite-like multicolor paint

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105238196A (en) * 2015-10-29 2016-01-13 江门市蓬江区慧邦涂料有限公司 Water-in-water granite-imitated coating and preparation method thereof
CN107118645A (en) * 2017-06-08 2017-09-01 广东东艺宝建材有限公司 A kind of waterproof artificial granite speckle multicolor finish and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105238196A (en) * 2015-10-29 2016-01-13 江门市蓬江区慧邦涂料有限公司 Water-in-water granite-imitated coating and preparation method thereof
CN107118645A (en) * 2017-06-08 2017-09-01 广东东艺宝建材有限公司 A kind of waterproof artificial granite speckle multicolor finish and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111748250A (en) * 2019-03-28 2020-10-09 河北晨阳工贸集团有限公司 Anion sand-in-water multicolor paint and preparation method thereof
CN110484075A (en) * 2019-07-30 2019-11-22 安徽富瑞雪化工科技股份有限公司 A kind of aqueous camouflage color paint and preparation method thereof and application method
CN112892389A (en) * 2021-01-20 2021-06-04 富思特新材料科技发展股份有限公司 Toning method of granite-like multicolor paint

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