CN113969087A - Nano negative ion interior wall latex paint and preparation method thereof - Google Patents
Nano negative ion interior wall latex paint and preparation method thereof Download PDFInfo
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- CN113969087A CN113969087A CN202111182756.9A CN202111182756A CN113969087A CN 113969087 A CN113969087 A CN 113969087A CN 202111182756 A CN202111182756 A CN 202111182756A CN 113969087 A CN113969087 A CN 113969087A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
- C09D5/025—Preservatives, e.g. antimicrobial agents
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- Engineering & Computer Science (AREA)
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Abstract
The invention relates to the technical field of building interior wall decoration materials, in particular to a nano negative ion interior wall latex paint which comprises, by weight, 20-50 parts of synthetic resin emulsion, 10-25 parts of filler, 0.5-10 parts of natural mineral composite nano negative ion powder, 1-2 parts of preservative, 40-60 parts of pigment and filler, 1.5-4.5 parts of hydroxyethyl cellulose, 20-50 parts of first auxiliary agent, 70-100 parts of second auxiliary agent and 80-120 parts of water, wherein the natural mineral composite nano negative ion powder is composed of one or more of nano tourmaline, nano opal and nano qibingshi. The invention avoids radiation and pollution caused by the addition of heavy metals, and the natural minerals have rich reserves, are environment-friendly and low in cost, and are beneficial to application and development; in addition, by adding proper materials and auxiliaries, the capability of the nano negative ion interior wall latex paint for releasing negative ions can be improved, and the air freshening effect of the nano negative ion interior wall latex paint is enhanced.
Description
Technical Field
The invention relates to the technical field of building interior wall decoration materials, in particular to nano negative ion interior wall latex paint and a preparation method thereof.
Background
In modern families and office buildings, a large amount of organic materials are used for decoration and fitment, the organic materials contain various chemical substances and volatile organic pollutants (VOC for short) to different degrees, formaldehyde, toluene and the like are continuously emitted in the using process to pollute indoor air, and all the pollutants seriously harm the physical and mental health of human beings.
The anion product has the advantages of delaying senility, promoting blood circulation and metabolism, improving sleep effect, enhancing immunity, freshening air and the like by releasing anions, so the anions enjoy the names of 'vitamin oxygen', 'air vitamin', 'longevity element', 'air vitamin' and the like in the medical field. The interior wall negative ion environment-friendly latex paint is a new, advanced and multifunctional environment-friendly functional material, is refined by a negative ion technology and adopting better materials, can continuously release negative ions, dispels indoor harmful gas, peculiar smell, bacteria in the air and the like, and has good effect of purifying indoor air; meanwhile, the paint film has good stain resistance, scrubbing resistance, carbonization resistance, mildew resistance and algae resistance, and has aromatic and pleasant smell and bright and colorful color.
However, the effect of the interior wall anion environment-friendly latex paint in the current market is unsatisfactory, the ability of releasing anions is required to be further improved, and most interior wall anion environment-friendly latex paints researched at present contain heavy metals with high content, which not only can generate radiation and pollution, but also can increase the cost, and the development and application of the interior wall anion environment-friendly latex paint are limited to a certain extent.
Disclosure of Invention
Aiming at the problems in the prior art, the invention aims to provide the nano negative ion interior wall latex paint which is less in addition amount, good in functionality, low in cost and environment-friendly. In order to realize the purpose of the invention, the following technical scheme is adopted:
a nano negative ion latex paint for interior walls comprises, by weight, 20-50 parts of synthetic resin emulsion, 10-25 parts of filler, 0.5-10 parts of natural mineral composite nano negative ion powder, 1-2 parts of preservative, 40-60 parts of pigment filler, 1.5-4.5 parts of hydroxyethyl cellulose, 20-50 parts of first aid, 70-100 parts of second aid and 80-120 parts of water, wherein the natural mineral composite nano negative ion powder is composed of one or more of nano tourmaline, nano opal and nano qibingshi.
Preferably, the filler is one or more of light calcium carbonate, heavy calcium carbonate and talcum powder.
Preferably, the preservative is a nitrogen-containing heterocyclic compound.
Preferably, the pigment filler is one of titanium dioxide or lithopone.
Preferably, the first auxiliary agent comprises, by weight, 1-3 parts of a pH regulator, 2-5 parts of a dispersant A, 15-35 parts of ethylene glycol, 1-3 parts of a wetting dispersant and 1-4 parts of a defoaming agent A.
Preferably, the pH regulator is organic amine, the dispersant A is polyacrylate, the wetting dispersant is a foam-inhibiting nonionic wetting agent, and the defoamer A is a mixture of aliphatic hydrocarbon and an emulsifier.
Preferably, the second auxiliary agent comprises, by weight, dispersant B1-3 parts, defoamer B2-3 parts, film-forming agent 2-7 parts, thickener 5-7 parts, and elastic emulsion 60-80 parts.
Preferably, the dispersant B is polymaleate, the defoamer B is a mixture of petroleum derivatives and special auxiliaries, the film forming agent is pentanediol monoisobutyrate, the thickener is hydrophobic modified polyurethane, and the elastic emulsion is pure acrylate elastic emulsion.
In order to achieve the purpose, the invention also provides a preparation method of the nano negative ion interior wall latex paint, which comprises the following steps:
(1) preparing natural mineral composite nano anion powder: weighing one or more of a certain amount of nano tourmaline, nano opal and nano mirabilite according to the weight parts, mixing and placing in a grinding machine for grinding to obtain natural mineral composite nano anion powder with the granularity of 30-80 nm;
(2) high-speed mixing: weighing a certain amount of the obtained natural mineral composite nano anion powder in parts by weight into a reaction kettle, adding synthetic resin emulsion, filler, preservative, pigment and filler, hydroxyethyl cellulose and a proper amount of water, adjusting the rotating speed to 800 plus materials at 1500r/min, adding a first auxiliary agent while stirring, and dispersing for a certain time;
(3) low-speed film forming: adjusting the rotating speed of the reaction kettle to 200-.
Preferably, the dispersing time is 2-4h, and the stirring temperature is 50-70 ℃.
Compared with the prior art, the invention has the beneficial effects that: according to the nano negative ion interior wall latex paint, the natural mineral composite nano negative ion powder is added, so that radiation and pollution caused by addition of heavy metals are avoided, and the natural mineral is rich in reserves, environment-friendly and low in cost, and is beneficial to application and development; in addition, by adding proper materials and auxiliaries, the capability of the nano negative ion interior wall latex paint for releasing negative ions can be improved, and the air freshening effect of the nano negative ion interior wall latex paint is enhanced.
Drawings
FIG. 1 is a flow chart of a method for preparing a nano negative ion interior wall latex paint of the present invention;
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Detailed description of the preferred embodiment 1
In this embodiment, the specific formulation is:
wherein, the natural mineral composite nano anion powder is composed of nano tourmaline and nano opal, the filler is light calcium carbonate, the preservative is a nitrogen-containing heterocyclic compound, and the pigment filler is titanium dioxide.
The first auxiliary agent comprises, by weight, 1 part of a pH regulator, 2 parts of a dispersant A, 15 parts of ethylene glycol, 1 part of a wetting dispersant and 1 parts of a defoaming agent A, wherein the pH regulator is organic amine, the dispersant A is polyacrylate, the wetting dispersant is a foam-suppressing nonionic wetting agent, and the defoaming agent A is a mixture of aliphatic hydrocarbon and an emulsifier.
The second auxiliary agent comprises, by weight, dispersant B1 parts, defoamer B2 parts, film forming agent 2 parts, thickening agent 5 parts and elastic emulsion 60 parts, wherein the dispersant B is polymaleate, the defoamer B is a mixture of petroleum derivatives and special auxiliary agents, the film forming agent is pentanediol monoisobutyrate, the thickening agent is hydrophobic modified polyurethane, and the elastic emulsion is pure acrylate elastic emulsion.
FIG. 1 is a flow chart of a method for preparing a nano negative ion interior wall latex paint, the specific preparation method of the embodiment is as follows:
step S1: preparing natural mineral composite nano anion powder: weighing a certain amount of nano tourmaline and nano opal according to the weight parts, mixing and grinding in a grinder to obtain natural mineral composite nano anion powder with the granularity of 30 nm;
step S2: high-speed mixing: weighing a certain amount of the obtained natural mineral composite nano anion powder in parts by weight into a reaction kettle, adding synthetic resin emulsion, filler, preservative, pigment and filler, hydroxyethyl cellulose and a proper amount of water, adjusting the rotating speed to 800r/min, adding a first auxiliary agent while stirring, and dispersing for 2 hours;
step S3: low-speed film forming: adjusting the rotating speed of the reaction kettle to 200r/min, dropwise adding a second auxiliary agent at 50 ℃ to obtain the nano negative ion interior wall latex paint, and detecting the correlation performance.
Specific example 2
In this embodiment, the specific formulation is:
the natural mineral composite nano negative ion powder is prepared from nano opal and nano travertine, a filler is a mixture of light calcium carbonate and heavy calcium carbonate, a preservative is a nitrogen-containing heterocyclic compound, and a pigment filler is lithopone.
The first auxiliary agent comprises, by weight, 3 parts of a pH regulator, 5 parts of a dispersant A, 35 parts of ethylene glycol, 3 parts of a wetting dispersant and 4 parts of a defoaming agent, wherein the pH regulator is organic amine, the dispersant A is polyacrylate, the wetting dispersant is a foam-inhibiting nonionic wetting agent, and the defoaming agent A is a mixture of aliphatic hydrocarbon and an emulsifier.
The second auxiliary agent comprises, by weight, dispersant B3 parts, defoamer B3 parts, film forming agent 7 parts, thickening agent 7 parts and elastic emulsion 80 parts, wherein the dispersant B is polymaleate, the defoamer B is a mixture of petroleum derivatives and special auxiliary agents, the film forming agent is pentanediol monoisobutyrate, the thickening agent is hydrophobic modified polyurethane, and the elastic emulsion is pure acrylate elastic emulsion.
FIG. 1 is a flow chart of a method for preparing a nano negative ion interior wall latex paint, the specific preparation method of the embodiment is as follows:
step S1: preparing natural mineral composite nano anion powder: weighing a certain amount of nano opal and nano mirabilite according to the parts by weight, mixing, placing in a grinder, and grinding to obtain natural mineral composite nano anion powder with the granularity of 80 nm;
step S2: high-speed mixing: weighing a certain amount of the obtained natural mineral composite nano anion powder in parts by weight into a reaction kettle, adding synthetic resin emulsion, filler, preservative, pigment and filler, hydroxyethyl cellulose and a proper amount of water, adjusting the rotating speed to 1500r/min, adding a first auxiliary agent while stirring, and dispersing for 4 hours;
step S3: low-speed film forming: adjusting the rotating speed of the reaction kettle to 400r/min, dropwise adding a second auxiliary agent at 70 ℃ to obtain the nano negative ion interior wall latex paint, and detecting the correlation performance.
Specific example 3
In this embodiment, the specific formulation is:
wherein, the natural mineral composite nanometer anion powder consists of nanometer tourmaline and nanometer qibingshi, the filler is talcum powder, the preservative is nitrogen-containing heterocyclic compound, and the pigment filler is titanium dioxide.
The first auxiliary agent comprises, by weight, 2 parts of a pH regulator, 3 parts of a dispersant A, 25 parts of ethylene glycol, 2 parts of a wetting dispersant and 2 parts of a defoaming agent, wherein the pH regulator is organic amine, the dispersant A is polyacrylate, the wetting dispersant is a foam-inhibiting nonionic wetting agent, and the defoaming agent A is a mixture of aliphatic hydrocarbon and an emulsifier.
The second auxiliary agent comprises, by weight, dispersant B2 parts, defoamer B2 parts, film forming agent 5 parts, thickening agent 6 parts and elastic emulsion 70 parts, wherein the dispersant B is polymaleate, the defoamer B is a mixture of petroleum derivatives and special auxiliary agents, the film forming agent is pentanediol monoisobutyrate, the thickening agent is hydrophobic modified polyurethane, and the elastic emulsion is pure acrylate elastic emulsion.
FIG. 1 is a flow chart of a method for preparing a nano negative ion interior wall latex paint, the specific preparation method of the embodiment is as follows:
step S1: preparing natural mineral composite nano anion powder: weighing a certain amount of nano tourmaline and nano mirabilite according to the weight parts, mixing and placing in a grinding machine for grinding to obtain natural mineral composite nano anion powder with the granularity of 50 nm;
step S2: high-speed mixing: weighing a certain amount of the obtained natural mineral composite nano anion powder in parts by weight into a reaction kettle, adding synthetic resin emulsion, filler, preservative, pigment and filler, hydroxyethyl cellulose and a proper amount of water, adjusting the rotating speed to 1200r/min, adding a first auxiliary agent while stirring, and dispersing for 3 hours;
step S3: low-speed film forming: adjusting the rotating speed of the reaction kettle to 300r/min, dropwise adding a second auxiliary agent at 60 ℃ to obtain the nano negative ion interior wall latex paint, and detecting the correlation performance, wherein the result is as follows:
TABLE 1 results of testing the properties of the examples
It can be seen from the above embodiments of the invention that the nano negative ion interior wall latex paint avoids radiation and pollution caused by the addition of heavy metals by adding the natural mineral composite nano negative ion powder, and the natural mineral has rich reserves, is environment-friendly, has low cost, and is beneficial to application and development; in addition, by adding proper materials and auxiliaries, the capability of the nano negative ion interior wall latex paint for releasing negative ions can be improved, and the air freshening effect of the nano negative ion interior wall latex paint is enhanced.
The above description is only for the specific embodiments of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art can understand that the changes or modifications within the technical scope of the present invention are included in the scope of the present invention, and therefore, the scope of the present invention should be subject to the protection scope of the claims.
Claims (10)
1. A nano negative ion interior wall latex paint is characterized in that: the composite nano-anion powder comprises, by weight, 20-50 parts of synthetic resin emulsion, 10-25 parts of filler, 0.5-10 parts of natural mineral composite nano-anion powder, 1-2 parts of preservative, 40-60 parts of pigment and filler, 1.5-4.5 parts of hydroxyethyl cellulose, 20-50 parts of first aid, 70-100 parts of second aid and 80-120 parts of water, wherein the natural mineral composite nano-anion powder is composed of one or more of nano tourmaline, nano opal and nano qibingshi.
2. The nano negative ion interior wall latex paint according to claim 1, characterized in that: the filler is one or more of light calcium carbonate, heavy calcium carbonate and talcum powder.
3. The nano negative ion interior wall latex paint according to claim 1, characterized in that: the preservative is a nitrogen-containing heterocyclic compound.
4. The nano negative ion interior wall latex paint according to claim 1, characterized in that: the pigment filler is one of titanium dioxide or lithopone.
5. The nano negative ion interior wall latex paint according to claim 1, characterized in that: the first auxiliary agent comprises, by weight, 1-3 parts of a pH regulator, 2-5 parts of a dispersant A, 15-35 parts of ethylene glycol, 1-3 parts of a wetting dispersant and 1-4 parts of a defoaming agent A.
6. The nano negative ion interior wall latex paint according to claim 5, characterized in that: the pH regulator is organic amine, the dispersant A is polyacrylate, the wetting dispersant is a foam-inhibiting non-ionic wetting agent, and the defoamer A is a mixture of aliphatic hydrocarbon and an emulsifier.
7. The nano negative ion interior wall latex paint according to claim 1, characterized in that: the second auxiliary agent comprises, by weight, 1-3 parts of a dispersing agent B, 2-3 parts of a defoaming agent B, 2-7 parts of a film forming agent, 5-7 parts of a thickening agent and 60-80 parts of an elastic emulsion.
8. The nano negative ion interior wall latex paint according to claim 7, characterized in that: the dispersing agent B is polymaleate, the defoaming agent B is a mixture of a petroleum derivative and a special auxiliary agent, the film forming agent is pentanediol monoisobutyrate, the thickening agent is hydrophobic modified polyurethane, and the elastic emulsion is pure acrylate elastic emulsion.
9. A preparation method of nano negative ion interior wall latex paint is characterized by comprising the following steps: the method comprises the following steps:
(1) preparing natural mineral composite nano anion powder: weighing one or more of a certain amount of nano tourmaline, nano opal and nano mirabilite according to the weight parts, mixing and placing in a grinding machine for grinding to obtain natural mineral composite nano anion powder with the granularity of 30-80 nm;
(2) high-speed mixing: weighing a certain amount of the obtained natural mineral composite nano anion powder in parts by weight into a reaction kettle, adding synthetic resin emulsion, filler, preservative, pigment and filler, hydroxyethyl cellulose and a proper amount of water, adjusting the rotating speed to 800 plus materials at 1500r/min, adding a first auxiliary agent while stirring, and dispersing for a certain time;
(3) low-speed film forming: adjusting the rotating speed of the reaction kettle to 200-.
10. The method for preparing the nano negative ion interior wall latex paint according to claim 9, wherein the method comprises the following steps: the dispersing time is 2-4h, and the stirring temperature is 50-70 ℃.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114621642A (en) * | 2022-03-08 | 2022-06-14 | 广西印建奇新型建筑材料有限公司 | Odor-removing full-effect interior wall paint and preparation method thereof |
| CN115260854A (en) * | 2022-08-30 | 2022-11-01 | 广东立时涂料科技有限公司 | Thick paste plastic artistic coating with negative ions and preparation method thereof |
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| CN1673294A (en) * | 2004-12-16 | 2005-09-28 | 许绍凰 | Nanometer nagative ion inner wall latex paint |
| CN105153830A (en) * | 2015-10-28 | 2015-12-16 | 漳州三德利油漆涂料有限公司 | Nanometer-anion functional interior-wall latex paint and preparing method thereof |
| CN107057487A (en) * | 2017-05-06 | 2017-08-18 | 西安宜新环境科技有限公司 | A kind of energy is efficiently and safety produces the light spoke interior wall coating and its preparation technology of anion |
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| CN107892859A (en) * | 2017-11-23 | 2018-04-10 | 广东华兹卜新材料科技有限公司 | A kind of nano-negative ion water-based interior paint and preparation method thereof |
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2021
- 2021-10-11 CN CN202111182756.9A patent/CN113969087A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1673294A (en) * | 2004-12-16 | 2005-09-28 | 许绍凰 | Nanometer nagative ion inner wall latex paint |
| CN105153830A (en) * | 2015-10-28 | 2015-12-16 | 漳州三德利油漆涂料有限公司 | Nanometer-anion functional interior-wall latex paint and preparing method thereof |
| CN107057487A (en) * | 2017-05-06 | 2017-08-18 | 西安宜新环境科技有限公司 | A kind of energy is efficiently and safety produces the light spoke interior wall coating and its preparation technology of anion |
| CN107325625A (en) * | 2017-08-16 | 2017-11-07 | 河北卓达建材研究院有限公司 | A kind of negative ion powder and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN114621642A (en) * | 2022-03-08 | 2022-06-14 | 广西印建奇新型建筑材料有限公司 | Odor-removing full-effect interior wall paint and preparation method thereof |
| CN115260854A (en) * | 2022-08-30 | 2022-11-01 | 广东立时涂料科技有限公司 | Thick paste plastic artistic coating with negative ions and preparation method thereof |
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Application publication date: 20220125 |