CN106883752A - A kind of full effect unification interior wall coating and preparation method thereof - Google Patents
A kind of full effect unification interior wall coating and preparation method thereof Download PDFInfo
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- CN106883752A CN106883752A CN201710040846.1A CN201710040846A CN106883752A CN 106883752 A CN106883752 A CN 106883752A CN 201710040846 A CN201710040846 A CN 201710040846A CN 106883752 A CN106883752 A CN 106883752A
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- interior wall
- wall coating
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1668—Vinyl-type polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1675—Polyorganosiloxane-containing compositions
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention belongs to water paint field, and in particular to a kind of full effect unification interior wall coating and preparation method thereof.The full effect unification interior wall coating of one kind that the present invention is provided, with water as solvent, by styrene-acrylic emulsion, organic silicon emulsion, nano-powder, diatom ooze, anionic additive, color stuffing and various aqueous paint additives by accurate proportioning, is prepared under rigid process conditions.The outstanding feature that there is the full effect unification interior wall coating the comprehensive efficiency such as adsorption-decomposition function formaldehyde, sustained release negative oxygen ion, superpower anti-pollution characteristic to integrate, can create health, environmental protection, a livable indoor environment for user.
Description
Technical field
The invention belongs to water paint field, and in particular to a kind of full effect unification interior wall coating and preparation method thereof.
Background technology
With the progress of economic society, people increasingly pay attention to and thirst for health, environmental protection.But instantly at country
In specific developing stage, atmosphere quality is not good enough, and by long-term existence.People cannot temporarily improve outdoor big compression ring
In the case of border, will more take notice of for the quality that the most of the time in all one's life will be in indoor air environment therein.First, people
The formaldehyde for being produced by indoor fitment material for family always etc. perplex, it is eager to want to eliminate this class harmful substance;Secondly, rich in sky
The environment of gas anion, to the healthy highly beneficial of people, is also that people yearn for always.Therefore, health environment-friendly with decompose first
Aldehyde purify air, the feature interior wall coating of releasing negative oxygen ion just arise at the historic moment, and more and more popular with consumers.
Patent document (application number 201110123361.1) discloses a kind of Novel anti-formaldehyde smell-clearing full-effective water-based inner wall and applies
Material and preparation method thereof;It is difunctional except first that patent document (application number 201310459167.X) discloses a kind of adsorbable, decomposition
Coating of aldehyde and preparation method thereof;Patent document (application number 201210442969.5) discloses a kind of multifunctional ecological anion
Coating and preparation method thereof.
Possess the interior wall coating of the above-mentioned effect room atmosphere environment good for people create.But go out from practical standpoint
Hair, due to the long-term activity indoors of people, wall has the possibility of contamination unavoidably, and possesses the interior wall coating of obvious anti-pollution characteristic
Existing market is also very rarely seen.So, as the water paint of interior wall, assign its superpower anti-pollution characteristic and also just seem and very must
Will.And above-mentioned patent document there is no the anti-pollution characteristic for taking into account interior wall coating.
For case above, decomposing formaldehyde purify air, the function of releasing negative oxygen ion and superpower resistant technology are mutually tied
Close, study a kind of interior wall coating rolled into one with adsorption-decomposition function formaldehyde, sustained release negative oxygen ion, superpower anti-pollution characteristic just
It is significant.
The content of the invention
There is adsorption-decomposition function formaldehyde, sustained release negative oxygen ion, superpower anti-pollution characteristic it is an object of the invention to provide one kind
Interior wall coating integrated etc. comprehensive efficiency and preparation method thereof.
The full effect unification interior wall coating of one kind that the present invention is provided, is made up of the raw material of following mass ratio:
Dispersant 0.2% ~ 2.0%, wetting agent 0.02% ~ 0.50%, hydroxyethyl cellulose 0.05% ~ 0.50%, defoamer 0.1% ~ 1.0
%, pH adjusting agent 0.02% ~ 0.40%, antifreezing agent 0.2% ~ 3.0%, titanium dioxide 5% ~ 50%, powdered whiting 3% ~ 30%, nanometer two
Titanium oxide 0.2% ~ 3.0%, nanometer titanium phosphate 0.2% ~ 2.5%, nano phase ag_2 o 0.1% ~ 2.5%, diatomite 1% ~ 20%, anion add
Plus agent 0.2% ~ 2.0%, organic silicon emulsion 5% ~ 40%, styrene-acrylic emulsion 5% ~ 40%, preservative 0.1% ~ 1.0%, coalescents 0.5% ~
4.0%th, thickener 0.1% ~ 1.0%, remaining is water, and above each component percentage sum is 100%.
The dispersant is ammonium salt dispersant;The pH adjusting agent is AMP-95;The antifreezing agent is propane diols;Described two
Titanium oxide is rutile-type, and content of titanium dioxide is more than 96%;The active ingredient of the anionic additive is tourmaline.
This it is full effect unification interior wall coating step of preparation process be:
(1), premixing:Most of water in adding institute's water requirement in dispersion cylinder, sequentially adds the dispersion of above-mentioned mass ratio
Agent, wetting agent, moderate-speed mixer are slowly added to the hydroxyethyl cellulose of above-mentioned mass ratio, after it is completely dissolved, add above-mentioned
The defoamer of mass ratio, pH adjusting agent, antifreezing agent;
(2), grinding distribution:Sequentially add titanium dioxide, powdered whiting, nano titanium oxide, the nanometer phosphorus of above-mentioned mass ratio
Sour titanium, nano phase ag_2 o, diatomite, anionic additive, high-speed stirred are disperseed 40 ~ 50 minutes;
(3), paint:Dispersing speed is reduced to sequentially add the organic silicon emulsion of above-mentioned mass ratio, styrene-acrylic emulsion, preservative, disappear
Infusion, coalescents, middle low speed disperse half an hour, and appropriate thickener is added according to dope viscosity requirement, supply remaining water, in
Speed dispersion 5 minutes, stirring at low speed catches up with bubble 5 minutes, is then filtrated to get finished product.
The full effect unification interior wall coating that the present invention is provided has the characteristics that:
(1)Solvent is done with water, with extremely low VOC, itself is nontoxic, does not detect free formaldehyde, belongs to environmental labelling product;
(2)Adsorbed by harmful substances such as diatomite PARA FORMALDEHYDE PRILLS(91,95)s, in nano titanium oxide, nanometer titanium phosphate, nano oxidized
The harmful substances such as the formaldehyde that efficient-decomposition is adsorbed by film under the synergy of silver, toxic air in clean room is eliminated to human body
Injury;
(3)Anionic additive can constant releasing negative oxygen ion, provide stabilization spirit for people, enhance metabolism and
Blood circulation, set up, maintain the health-care efficacies such as health;
(4)Because having used high performance organic silicon emulsion, make coating that there is superpower anti-pollution characteristic, high greasiness removal rate,
Most spots can be removed, is that people create bright and new beautiful Easy Living Envi-ronment.
Specific embodiment:
A part of specific embodiment is set forth below, and the present invention will be described, it is necessary to it is pointed out here that be specific examples below
It is served only for that the invention will be further described, does not represent limiting the scope of the invention.Other people make according to the present invention
Some it is nonessential modification and adjustment still fall within protection scope of the present invention.
Recipe ingredient mass ratio according to table 1 prepares raw material and implements.
1 three Example formulations constituent mass ratios of table
Material name | The constituent mass ratio of embodiment 1/% | The constituent mass ratio of embodiment 2/% | The constituent mass ratio of embodiment 3/% |
Water | 20 | 18 | 22 |
Dispersant | 1 | 0.8 | 1.2 |
Wetting agent | 0.1 | 0.2 | 0.05 |
Hydroxyethyl cellulose | 0.3 | 0.2 | 0.4 |
Defoamer | 0.2 | 0.1 | 0.3 |
PH adjusting agent | 0.2 | 0.3 | 0.1 |
Antifreezing agent | 1.3 | 1.1 | 1.5 |
Titanium dioxide | 15 | 14 | 16 |
Powdered whiting | 9 | 8 | 10 |
Nano titanium oxide | 0.4 | 0.6 | 0.7 |
Nanometer titanium phosphate | 0.6 | 0.5 | 0.7 |
Nano phase ag_2 o | 0.6 | 0.5 | 0.2 |
Diatomite | 4 | 4.5 | 3.5 |
Anionic additive | 1 | 1.4 | 0.7 |
Organic silicon emulsion | 20 | 22 | 18 |
Styrene-acrylic emulsion | 20 | 22 | 18 |
Preservative | 0.2 | 0.3 | 0.1 |
Defoamer | 0.2 | 0.3 | 0.15 |
Coalescents | 1.6 | 1.2 | 1.8 |
Thickener | 0.5 | 0.4 | 0.6 |
Water | 3.8 | 3.6 | 4 |
Embodiment 1
According to the constituent mass of embodiment 1 in table 1 than configuration raw material, prepared in full effect unification of the invention according to following processing step
Wall coating:
(1), premixing:Water is added in dispersion cylinder, dispersant, wetting agent is sequentially added, moderate-speed mixer is slowly added to hydroxyl second
Base cellulose, after it is completely dissolved, adds defoamer, pH adjusting agent, antifreezing agent;
(2), grinding distribution:Sequentially add titanium dioxide, powdered whiting, nano titanium oxide, nanometer titanium phosphate, nano oxidized
Silver, diatomite, anionic additive, high-speed stirred are disperseed 40 ~ 50 minutes;
(3), paint:Reduction dispersing speed sequentially adds organic silicon emulsion, styrene-acrylic emulsion, preservative, defoamer, film forming and helps
Agent, middle low speed disperses half an hour, and thickener is added according to dope viscosity requirement, adds water, and middling speed is disperseed 5 minutes, and stirring at low speed is caught up with
Bubble 5 minutes, is then filtrated to get finished product.
Embodiment 2, the configuration of the raw material of embodiment 3, than implementing, are prepared according to the constituent mass of embodiment 2, embodiment 3 in table 1
Processing step is with reference to embodiment 1.
Full effect unification interior wall coating obtained by above-described embodiment is pressed《Resin latex dope》(GB/T
Standard 9756-2009) is tested, and gained assay is shown in Table 2, as shown in Table 2 full effect unification disclosed by the invention
The interior wall coating grade that is at the top of one's class is other.
Table 2 is pressed《Resin latex dope》(GB/T 9756-2009) standard is tested acquired results
Full effect unification interior wall coating obtained by above-described embodiment is pressed《Environmental labelling product technical requirements water paint》(HJ
Standard 2537-2014) is tested, and gained assay is shown in Table 3, as shown in Table 3 full effect unification interior wall disclosed by the invention
Coating complies fully with the requirement of environmental mark water paint product technology.
Table 3 is pressed《Environmental labelling product technical requirements water paint》(HJ 2537-2014) standard is tied obtained by testing
Really
Because《Environmental labelling product technical requirements water paint》(HJ 2537-2014) compares《Indoor decorating and refurnishing materials interior wall
Limits of harmful substances in coating》(GB 18582-2008) is required more strictly, and full effect unification interior wall coating disclosed by the invention is complete
It is complete to meet the requirement of environmental mark water paint product technology, so being also fully consistent with《In indoor decorating and refurnishing materials interior wall coating
Limits of harmful substances》(GB 18582-2008) is required, is the health environment protection interior wall coating of consumer's interior decoration.
Full effect unification interior wall coating obtained by above-described embodiment is pressed《Function of purifying indoor air coating material purification property
Energy》The standard of (JC/T 1074-2008) is tested, and wherein the test value of purifying formaldehyde efficiency is much larger than standard value 75, first
The test value of aldehyde clean-up effect persistence is much larger than standard value 60%, meets《Function of purifying indoor air coating material purification property
Energy》The requirement of " 1 class material " in (JC/T 1074-2008) standard.
Full effect unification interior wall coating obtained by above-described embodiment is pressed《Anion function coating》(HG/T4109-2009)
The method that standard is provided, carries out negative aeroion and induces measurement examination, and acquired results are all more than 1000/(s cm2), and
Its radioactivity limitation is complied fully with《Radioactive material radionuclides limitation》The regulation of (GB 6566-2001) A class finishing materials will
Ask, it is unrestricted using scope.
Full effect unification interior wall coating obtained by above-described embodiment is pressed《Test method for dirt resistance of film of architectural coatings and paint》
" interior wall coating coating stain resistance test method " in (GB/T 9780-2013) partly tests, the various embodiments described above institute
Obtained full effect unification interior wall coating coating is to vinegar, black tea, blue-black ink, water-soluble melanin, spirit black pigment, vaseline
The removal ability of six kinds of spots of carbon black mixt is 10 grades, represents highest greasiness removal rate, illustrates that the overwhelming majority can be removed
Spot.
Claims (3)
1. a kind of full effect unifies interior wall coating, it is characterised in that be made up of the raw material of following mass ratio:
Dispersant 0.2% ~ 2.0%, wetting agent 0.02% ~ 0.50%, hydroxyethyl cellulose 0.05% ~ 0.50%, defoamer 0.1% ~ 1.0
%, pH adjusting agent 0.02% ~ 0.40%, antifreezing agent 0.2% ~ 3.0%, titanium dioxide 5% ~ 50%, powdered whiting 3% ~ 30%, nanometer two
Titanium oxide 0.2% ~ 3.0%, nanometer titanium phosphate 0.2% ~ 2.5%, nano phase ag_2 o 0.1% ~ 2.5%, diatomite 1% ~ 20%, anion add
Plus agent 0.2% ~ 2.0%, organic silicon emulsion 5% ~ 40%, styrene-acrylic emulsion 5% ~ 40%, preservative 0.1% ~ 1.0%, coalescents 0.5% ~
4.0%th, thickener 0.1% ~ 1.0%, remaining is water, and above each component percentage sum is 100%.
2. a kind of full effect according to claim 1 unifies interior wall coating, it is characterised in that:The dispersant disperses for ammonium salt
Agent;The pH adjusting agent is AMP-95;The antifreezing agent is propane diols;The titanium dioxide is rutile-type, and titanium dioxide contains
Amount is more than 96%;The active ingredient of the anionic additive is tourmaline.
3. a kind of full effect unification interior wall coating according to claim 1, it is characterised in that preparation method processing step is:
(1), premixing:Most of water in adding institute's water requirement in dispersion cylinder, sequentially adds the dispersion of above-mentioned mass ratio
Agent, wetting agent, moderate-speed mixer are slowly added to the hydroxyethyl cellulose of above-mentioned mass ratio, after it is completely dissolved, add above-mentioned
The defoamer of mass ratio, pH adjusting agent, antifreezing agent;
(2), grinding distribution:Sequentially add titanium dioxide, powdered whiting, nano titanium oxide, the nanometer phosphorus of above-mentioned mass ratio
Sour titanium, nano phase ag_2 o, diatomite, anionic additive, high-speed stirred are disperseed 40 ~ 50 minutes;
(3), paint:Dispersing speed is reduced to sequentially add the organic silicon emulsion of above-mentioned mass ratio, styrene-acrylic emulsion, preservative, disappear
Infusion, coalescents, middle low speed disperse half an hour, and appropriate thickener is added according to dope viscosity requirement, supply remaining water, in
Speed dispersion 5 minutes, stirring at low speed catches up with bubble 5 minutes, is then filtrated to get finished product.
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109705640A (en) * | 2018-11-29 | 2019-05-03 | 安徽开林新材料股份有限公司 | A kind of dope for inner wall of architecture |
CN110041829A (en) * | 2019-03-27 | 2019-07-23 | 河北晨阳工贸集团有限公司 | A kind of environmentally friendly plant base interior wall sealing wax and preparation method thereof |
CN110283504A (en) * | 2019-06-24 | 2019-09-27 | 赵雪亮 | A kind of sealing wax and preparation method thereof that anti-adhesive sticker is pasted |
CN111534218A (en) * | 2020-04-29 | 2020-08-14 | 湖北中科博策新材料科技有限公司 | Stain-resistant water paint and production process thereof |
CN112339630A (en) * | 2019-08-08 | 2021-02-09 | 于成贵 | Automobile cushion capable of releasing negative oxygen ions and application of liquid negative oxygen ions |
CN113402931A (en) * | 2021-06-30 | 2021-09-17 | 河北晨阳工贸集团有限公司 | Indoor coating capable of degrading benzene series and preparation method thereof |
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CN103602187A (en) * | 2013-11-11 | 2014-02-26 | 苏州市姑苏新型建材有限公司 | Method for preparing interior wall coating material for absorbing and decomposing formaldehyde |
CN104530848A (en) * | 2015-01-06 | 2015-04-22 | 季红军 | Preparation method of building coating with formaldehyde scavenging function |
CN104804567A (en) * | 2015-05-12 | 2015-07-29 | 重庆市品胜涂料有限公司 | High-grade interior wall paint and preparation method thereof |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109705640A (en) * | 2018-11-29 | 2019-05-03 | 安徽开林新材料股份有限公司 | A kind of dope for inner wall of architecture |
CN110041829A (en) * | 2019-03-27 | 2019-07-23 | 河北晨阳工贸集团有限公司 | A kind of environmentally friendly plant base interior wall sealing wax and preparation method thereof |
CN110283504A (en) * | 2019-06-24 | 2019-09-27 | 赵雪亮 | A kind of sealing wax and preparation method thereof that anti-adhesive sticker is pasted |
CN112339630A (en) * | 2019-08-08 | 2021-02-09 | 于成贵 | Automobile cushion capable of releasing negative oxygen ions and application of liquid negative oxygen ions |
CN111534218A (en) * | 2020-04-29 | 2020-08-14 | 湖北中科博策新材料科技有限公司 | Stain-resistant water paint and production process thereof |
CN113402931A (en) * | 2021-06-30 | 2021-09-17 | 河北晨阳工贸集团有限公司 | Indoor coating capable of degrading benzene series and preparation method thereof |
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Application publication date: 20170623 |