CN109135358A - A kind of aqueous inorganic mildew resistant paint and preparation method thereof - Google Patents
A kind of aqueous inorganic mildew resistant paint and preparation method thereof Download PDFInfo
- Publication number
- CN109135358A CN109135358A CN201810831756.9A CN201810831756A CN109135358A CN 109135358 A CN109135358 A CN 109135358A CN 201810831756 A CN201810831756 A CN 201810831756A CN 109135358 A CN109135358 A CN 109135358A
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- CN
- China
- Prior art keywords
- nano
- resistant paint
- aqueous inorganic
- mildew resistant
- titanium dioxide
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
Abstract
The invention belongs to paint fields, more particularly to a kind of aqueous inorganic, Diamond Search mildew resistant paint, the raw material including following mass percent: nano silicate 0-30%, nano-titanium dioxide 0-10%, rutile type titanium white 0-50%, nano silver 0-10%, nano zine oxide 0-5% and fumed silica 0-5%.Preparation method, which includes: ingredient, prepare thick mixture, plus nano material is stirred to 40 μm or less, the nano silicate that adds surplus makes to be uniformly dispersed, grinds fineness is made to reach 5 μm hereinafter, to obtain the final product.Aqueous inorganic mildew resistant paint of the present invention is free of VOC, and anti-microbial property reaches 99.5%, and the enduring quality of antibacterial reaches 98%, belongs to new inorganic material.
Description
Technical field
The invention belongs to paint fields more particularly to a kind of aqueous inorganic, Diamond Search mildew resistant paint and preparation method thereof.
Background technique
Coating is to be coated in the body surface protected or decorated, and can form the continuous of firm attachment with coated article
Film addition or does not add pigment, filler usually based on resin or oil or lotion, adds corresponding additive, with organic molten
The thick liquid that agent or water are formulated.Coating used at present is mostly viscous with high molecular materials such as water-soluble or aqueous emulsions
Tie agent or be main film forming matter, used in thickener be the water-soluble substances such as cellulose family or polyacrylate, these
It is all the objective condition of mould breeding, especially in summer, in the environment of certain temperature and humidity, coating products are easily sent out very much
Mould, blackening cannot use.
The presence of mould not only results in the cracking of coating and falls off, and gives out distinctive stink, containing a large amount of
VOC.With the development and improvement of living standard of modern economy, people increasingly focus on the feature of environmental protection, the health of coating, because
This, it would be highly desirable to develop a kind of inorganic, aqueous, Diamond Search mildew resistant paint.
Summary of the invention
In order to solve the shortcomings of the prior art, applicant passes through a large amount of verification experimental verification, provides a kind of aqueous inorganic
Mildew resistant paint, and disclose preparation method.
In order to achieve the above object, the invention is realized by the following technical scheme:
A kind of aqueous inorganic mildew resistant paint is designed, the raw material including following mass percent: nano silicate 0-30%, nanometer two
Titanium oxide 0-10%, rutile type titanium white 0-50%, nano silver 0-10%, nano zine oxide 0-5% and fumed silica 0-5%.
Preferably, the aqueous inorganic mildew resistant paint, the raw material including following mass percent: nano silicate 20-
30%, nano-titanium dioxide 1-6%, rutile type titanium white 20-35%, nano silver 1-8%, nano zine oxide 1-3% and gas phase dioxy
SiClx 3-5%.
Preferably, the aqueous inorganic mildew resistant paint, is made of the raw material of following mass percent: nano silicate 30%,
Rutile type titanium white 30%, nano-titanium dioxide 6%, nano silver 1%, fumed silica 3%, nano zine oxide 1% and deionization
Water 29%.
Preferably, the aqueous inorganic mildew resistant paint, is made of the raw material of following mass percent: nano silicate 30%,
Rutile type titanium white 20%, nano-titanium dioxide 1%, nano silver 6%, fumed silica 3%, nano zine oxide 1% and deionization
Water 39%.
Preferably, the aqueous inorganic mildew resistant paint, is made of the raw material of following mass percent: nano silicate 20%,
Nano-titanium dioxide 6%, rutile type titanium white 35%, nano silver 8%, nano zine oxide 3%, fumed silica 5% and deionization
Water 23%.
The preferred model JL801 of the nano silver.
The preferred model of the nano-titanium dioxide wins wound AEROXIDE TiO2 P25。
The preferred model LANXESS of the nano zine oxide.
The preferred model R706 of the titanium dioxide.
The preferred model watt gram H18 of the fumed silica.
The invention also discloses the preparation methods of the aqueous inorganic mildew resistant paint, include the following steps:
1) raw material is equipped with according to the mass percent；
2) deionized water, the nano silicate of outfit amount 10%, fumed silica and rutile type titanium are sequentially added in a reservoir
White powder, addition while, are mixed, and keep 120min after the addition, obtain thick mixture；
3) nano silver, nano zine oxide and nano-titanium dioxide are sequentially added into the resulting thick mixture of step 2, into
Row stirring, until the fineness of mixture reaches 40 μm or less；
4) nano silicate that surplus is added into the resulting mixture of step 3), is sufficiently stirred and is uniformly dispersed；
5) the resulting mixture of step 4) is ground, fineness is made to reach 5 μm hereinafter, to obtain the final product.
Compared with prior art, the invention has the following advantages:
Aqueous inorganic mildew resistant paint of the present invention is free of VOC, and anti-microbial property reaches 99.5%, and the enduring quality of antibacterial reaches 98%, belongs to
In new inorganic material.
Specific embodiment
Technical solution of the present invention is described further below in conjunction with specific embodiment.Original used in following embodiment
Material, is then commercially available unless otherwise instructed: the model JL801 of the nano silver, and the model of the nano-titanium dioxide is won
Create AEROXIDE TiO2P25, the model LANXESS of the nano zine oxide, the model R706 of the titanium dioxide are described
The model watt gram H18 of fumed silica, method therefor are unless otherwise instructed conventional method.
Embodiment 1
A kind of aqueous inorganic mildew resistant paint, is made of the raw material of following mass percent: nano silicate 30%, rutile type titanium
White powder 30%, nano-titanium dioxide 6%, nano silver 1%, fumed silica 3%, nano zine oxide 1% and deionized water 29%.
Gained coating is detected, Anti-mildew capability (HG/T3950) 99.9%, antifungi endurance quality (HG/T3950)
99.1%。
Embodiment 2
A kind of aqueous inorganic mildew resistant paint, is made of the raw material of following mass percent: nano silicate 30%, rutile type titanium
White powder 20%, nano-titanium dioxide 1%, nano silver 6%, fumed silica 3%, nano zine oxide 1% and deionized water 39%.
Gained coating is detected, Anti-mildew capability (HG/T3950) 99.8%, antifungi endurance quality (HG/T3950)
98.9%。
Embodiment 3
A kind of aqueous inorganic mildew resistant paint, is made of the raw material of following mass percent: nano silicate 20%, nanometer titanium dioxide
Titanium 6%, rutile type titanium white 35%, nano silver 8%, nano zine oxide 3%, fumed silica 5% and deionized water 23%.
Gained coating is detected, Anti-mildew capability (HG/T3950) 99.8%, antifungi endurance quality (HG/T3950)
99.0%。
Embodiment 4
A kind of aqueous inorganic mildew resistant paint, is made of the raw material of following mass percent: nano silicate 25%, nanometer titanium dioxide
Titanium 3.5%, rutile type titanium white 27.5%, nano silver 4.5%, nano zine oxide 2%, fumed silica 4%, remaining for go from
Sub- water.
Gained coating is detected, Anti-mildew capability (HG/T3950) 99.6%, antifungi endurance quality (HG/T3950)
98.5%。
Embodiment 5
A kind of aqueous inorganic mildew resistant paint, is made of the raw material of following mass percent: nano silicate 30%, nanometer titanium dioxide
Titanium 10%, rutile type titanium white 20%, nano silver 10%, nano zine oxide 5%, fumed silica 5%, remaining is deionized water.
Gained coating is detected, Anti-mildew capability (HG/T3950) 99.5%, antifungi endurance quality (HG/T3950)
98.0%。
Embodiment 6
The preparation method of aqueous inorganic mildew resistant paint, includes the following steps: described in embodiment 1-5
1) raw material is equipped with according to the mass percent；
2) water, the nano silicate of outfit amount 10%, fumed silica and rutile titanium dioxide are sequentially added in a reservoir
Powder, addition while, are mixed, and keep 120min after the addition, obtain thick mixture；
3) nano silver, nano zine oxide and nano-titanium dioxide are sequentially added into the resulting thick mixture of step 2, into
Row stirring, until the fineness of mixture reaches 40 μm or less；
4) nano silicate that surplus is added into the resulting mixture of step 3), is sufficiently stirred and is uniformly dispersed；
5) the resulting mixture of step 4) is ground, fineness is made to reach 5 μm hereinafter, to obtain the final product.
The invention is not limited to above-mentioned specific embodiment, those skilled in the art can also make a variety of variations accordingly,
But it is any all to cover within the scope of the claims with equivalent or similar variation of the invention.
Claims (7)
1. a kind of aqueous inorganic mildew resistant paint, which is characterized in that the raw material including following mass percent: nano silicate 0-
30%, nano-titanium dioxide 0-10%, rutile type titanium white 0-50%, nano silver 0-10%, nano zine oxide 0-5% and gas phase two
Silica 0-5%.
2. aqueous inorganic mildew resistant paint according to claim 1, which is characterized in that the original including following mass percent
Material: nano silicate 20-30%, nano-titanium dioxide 1-6%, rutile type titanium white 20-35%, nano silver 1-8%, nano oxidized
Zinc 1-3% and fumed silica 3-5%.
3. aqueous inorganic mildew resistant paint according to claim 2, which is characterized in that by the raw material group of following mass percent
At: nano silicate 30%, nano-titanium dioxide 6%, nano silver 1%, fumed silica 3%, is received rutile type titanium white 30%
Rice zinc oxide 1% and deionized water 29%.
4. aqueous inorganic mildew resistant paint according to claim 2, which is characterized in that by the raw material group of following mass percent
At: nano silicate 30%, nano-titanium dioxide 1%, nano silver 6%, fumed silica 3%, is received rutile type titanium white 20%
Rice zinc oxide 1% and deionized water 39%.
5. aqueous inorganic mildew resistant paint according to claim 2, which is characterized in that by the raw material group of following mass percent
At: nano silicate 20%, nano-titanium dioxide 6%, rutile type titanium white 35%, nano silver 8%, nano zine oxide 3%, gas phase
Silica 5% and deionized water 23%.
6. aqueous inorganic mildew resistant paint according to claim 1, it is characterised in that: the model JL801 of the nano silver,
The model of the nano-titanium dioxide wins wound AEROXIDE TiO2P25, the model LANXESS of the nano zine oxide,
The model R706 of the titanium dioxide, the model watt gram H18 of the fumed silica.
7. the preparation method of any one of the claim 1-6 aqueous inorganic mildew resistant paint, includes the following steps:
1) raw material is equipped with according to the mass percent；
2) deionized water, the nano silicate of outfit amount 10%, fumed silica and rutile type titanium are sequentially added in a reservoir
White powder, addition while, are mixed, and are kept stirring 120min after the addition, obtain thick mixture；
3) nano silver, nano zine oxide and nano-titanium dioxide are sequentially added into the resulting thick mixture of step 2, into
Row stirring, until the fineness of mixture reaches 40 μm or less；
4) nano silicate that surplus is added into the resulting mixture of step 3), is sufficiently stirred and is uniformly dispersed；
5) the resulting mixture of step 4) is ground, fineness is made to reach 5 μm hereinafter, to obtain the final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810831756.9A CN109135358A (en) | 2018-07-26 | 2018-07-26 | A kind of aqueous inorganic mildew resistant paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810831756.9A CN109135358A (en) | 2018-07-26 | 2018-07-26 | A kind of aqueous inorganic mildew resistant paint and preparation method thereof |
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| Publication Number | Publication Date |
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| CN109135358A true CN109135358A (en) | 2019-01-04 |
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| CN201810831756.9A Pending CN109135358A (en) | 2018-07-26 | 2018-07-26 | A kind of aqueous inorganic mildew resistant paint and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111480659A (en) * | 2020-04-15 | 2020-08-04 | 福建省宇诚环保科技有限公司 | Bactericidal mildew inhibitor and preparation method and application thereof |
| CN112940547A (en) * | 2021-04-06 | 2021-06-11 | 江苏旌翔建材科技有限公司 | Inorganic mildew-resistant coating |
| CN114045057A (en) * | 2021-11-19 | 2022-02-15 | 广东迪奥应用材料科技有限公司 | Inorganic coating with air purification and antibacterial functions and preparation method thereof |
| CN114702846A (en) * | 2022-04-24 | 2022-07-05 | 杭州意能电力技术有限公司 | Water-based antibacterial coating and preparation method and application thereof |
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| CN102585632A (en) * | 2012-01-16 | 2012-07-18 | 黑龙江省玉琦装饰涂料有限公司 | Special antibacterial paint for hospital and preparation method of special antibacterial paint |
| CN104387816A (en) * | 2014-11-28 | 2015-03-04 | 佛山市南海万磊建筑涂料有限公司 | Multifunctional inorganic diatom ooze coating and preparation method thereof |
| CN106987160A (en) * | 2017-05-19 | 2017-07-28 | 重庆中鼎三正科技有限公司 | Photocatalysis material of titanium dioxide preparation method for purification |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111480659A (en) * | 2020-04-15 | 2020-08-04 | 福建省宇诚环保科技有限公司 | Bactericidal mildew inhibitor and preparation method and application thereof |
| CN112940547A (en) * | 2021-04-06 | 2021-06-11 | 江苏旌翔建材科技有限公司 | Inorganic mildew-resistant coating |
| CN114045057A (en) * | 2021-11-19 | 2022-02-15 | 广东迪奥应用材料科技有限公司 | Inorganic coating with air purification and antibacterial functions and preparation method thereof |
| CN114702846A (en) * | 2022-04-24 | 2022-07-05 | 杭州意能电力技术有限公司 | Water-based antibacterial coating and preparation method and application thereof |
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| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190104 |
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| RJ01 | Rejection of invention patent application after publication |