KR20090095356A - Composition for environment-friendly functional paint using volcanic stone - Google Patents

Composition for environment-friendly functional paint using volcanic stone Download PDF

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KR20090095356A
KR20090095356A KR1020080020644A KR20080020644A KR20090095356A KR 20090095356 A KR20090095356 A KR 20090095356A KR 1020080020644 A KR1020080020644 A KR 1020080020644A KR 20080020644 A KR20080020644 A KR 20080020644A KR 20090095356 A KR20090095356 A KR 20090095356A
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weight
volcanic stone
paint
composition
mesh
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KR1020080020644A
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KR101033205B1 (en
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방지혜
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(주)볼케닉스
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paints Or Removers (AREA)

Abstract

An environmentally friendly functional paint composition is provided to generate no volatile organic compound or smell, and to obtain mothproof, antibiotic and antifungal functions and humidify control function. An environmentally friendly functional paint composition comprises 20-60 weight% of a paint component; 10-30 weight% of a volcanic stone extract; and 20-60 weight% of a volcanic stone powder having a size of 50-350 mesh. The paint component comprises 20-25 weight% of titanium oxide; 24-28 weight% of silicate; 12-16 weight% of a vinyl acrylic resin; and 35-40 weight% of other materials comprising water, a surfactant and a defoamer. The volcanic stone extract is obtained by mixing a volcanic stone powder having a size of 320-370 mesh and a volcanic stone ore having a size of 1-2 cm in a ratio of 50:50, mixing the mixture with water in a ratio of 40:60, and extracting the mixture.

Description

화산석을 이용한 친환경 기능성 페인트 및 미장 도료용 조성물{COMPOSITION FOR ENVIRONMENT-FRIENDLY FUNCTIONAL PAINT USING VOLCANIC STONE}Eco-friendly functional paint and plaster coating composition using volcanic stone {COMPOSITION FOR ENVIRONMENT-FRIENDLY FUNCTIONAL PAINT USING VOLCANIC STONE}

본 발명은 화산석을 이용한 친환경 기능성 페인트 및 미장 도료용 조성물에 관한 것으로서, 보다 상세하게는 휘발성 유기 화합물이 전혀 없으며, 냄새가 없고, 방충, 항균 및 항 곰팡이 기능을 갖는 기능성 페인트 및 미장 도료용 조성물에 관한 것이다.The present invention relates to a composition for eco-friendly functional paint and plaster coating using volcanic stone, and more particularly, to a functional paint and plaster coating composition having no volatile organic compounds, no smell, and having insect repellent, antibacterial and anti-fungal functions. It is about.

일반적으로 페인트 및 미장 도료(이하 통칭하여 페인트라함)는 유동성의 물질로 물체의 표면에 넓게 도포되어 얇은 층을 형성하고 시간의 경과에 따라 건조, 경화하면서 연속적인 피막의 상태를 이룬다음 물체 표면에 부착되어 물체 표면을 보호하고 겉모양이나 형상의 변화 등 미장의 기능을 갖도록 한 것이다. In general, paints and plasters (hereinafter referred to as paints) are flowable materials that are widely applied to the surface of an object to form a thin layer, which is dried and cured over time to form a continuous film and then onto the surface of the object. It is attached to protect the surface of the object and to have the function of plastering, such as change of appearance and shape.

그러나, 일반적으로 사용되는 페인트의 경우에는 별다른 기능없이 인체와의 친화성이 적은 소재로서 색상만을 맞추는 형태이기 때문에 습기가 많은 여름철 등에는 곰팡이나 미생물 또는 각종 세균의 번식에 제대로 대응하지 못하고 있다.However, in the case of the paint used in general, it is a material having a small affinity with a human body without any special function, and only a color is matched, so it does not properly cope with the growth of molds, microorganisms or various bacteria in a humid summer.

한편, 시멘트 및 콘크리트 건축물 내에서 생활하는 사람들은 직접 또는 간접적으로 시멘트 독성에 의해 건강상의 문제가 제기되고 있다. 이렇게 콘크리트로부 터 발생하는 악취와 유해성분은 구조물 내로 그대로 배출되고 페인트를 도포하는 경우 페인트로 인해 구조물이 보호되고 미관이 증대되며 단열성이 증가하는 효과가 있기는 하나 악취와 유해성분이 저감되거나 차단되지는 않는다. On the other hand, people living in cement and concrete buildings have raised health problems directly or indirectly by cement toxicity. Odor and harmful components generated from concrete are discharged into the structure as it is, and when paint is applied, the structure protects the structure, increases aesthetics and increases insulation, but it does not reduce or block odors and harmful components. Does not.

따라서, 최근에는 상기와 같은 통상적인 페인트의 사용에 따른 문제를 해소하고 다양한 기능성을 부여하기 위하여 페인트에 황토, 숯 및 맥반석 등과 같은 재료를 이용한 페인트들이 개발되어 실내 마감재로서 활용이 되고 있으나 항균, 항곰팡이 또는 음이온 방출이나 실내의 공기 정화력 등 인체의 건강 증진에 도움을 주는 요소의 기능성이 미약하여 실질적인 도움이 되지 않고 있는 실정이다. Therefore, recently, paints using materials such as ocher, charcoal and elvan have been developed to solve the problems caused by the use of conventional paints and to impart various functionalities. The fact that it does not help practically due to the weak functionality of the elements that help to promote the health of the human body, such as the release of mold or negative ions or air purification of the room.

따라서, 본 발명은 상기와 같은 문제점을 해결하고자 발명된 것으로서, 화산석을 적절한 방법으로 처리하여 주원료로 사용하므로서 휘발성 유기 화합물이 전혀 없으며, 냄새가 없고, 방충, 항균 및 항 곰팡이 기능을 갖는 기능성 페인트용 조성물을 제공하는데 목적이 있다. Therefore, the present invention has been invented to solve the above problems, there is no volatile organic compound, no smell, insect repellent, antibacterial and anti-fungal functional paint for treating by using volcanic stone as a main raw material by appropriate methods It is an object to provide a composition.

상기와 같은 목적을 달성하기 위하여 본 발명은, 화산석을 이용한 친환경 기능성 페인트용 조성물에 있어서, In order to achieve the above object, the present invention, in the composition for environmentally friendly functional paint using volcanic stone,

티타늄 옥사이드 20-25중량%, 실리케이트 24-28 중량%, 비닐 아크릴 수지 12-16 중량% 및 기타 물, 계면활성제, 디포머 35-40 중량%로 이루어진 도료 성분 20-60 중량%;20-60% by weight of the paint component consisting of 20-25% by weight of titanium oxide, 24-28% by weight of silicate, 12-16% by weight of vinyl acrylic resin and 35-40% by weight of other water, surfactants, and deformers;

320-370 메쉬의 화산석 분말과 1-2㎝ 화산석 원석을 50:50으로 배합하고 물과 40:60로 혼합하여 추출한 화산석 추출물 10-30 중량%; 및 10-30% by weight of the volcanic stone extract extracted by mixing the volcanic stone powder of 320-370 mesh and the raw material of 1-2 cm volcanic stone at 50:50, and mixed with water at 40:60; And

50-350 메쉬의 화산석 분말 20-60중량%20-60% by weight of 50-350 mesh volcanic stone powder

를 포함하는 것을 특징으로 한다.Characterized in that it comprises a.

이러한 본 발명의 페인트는 휘발성 유기 화합물이 전혀 없으며, 냄새가 없고, 방충, 항균 및 항 곰팡이 기능을 갖는다. 또한, 실내 습도조절 기능을 함유하고 있어 실내를 쾌적하게 하고 인체에 건강증진에 유익한 효과가 있다. These paints of the present invention are completely free of volatile organic compounds, odorless, and have insect repellent, antibacterial and antifungal functions. In addition, it contains a room humidity control function to make the room comfortable and has a beneficial effect on health promotion for the human body.

이하, 본 발명을 구체적으로 설명한다.Hereinafter, the present invention will be described in detail.

본 발명에 사용되는 도료 성분은 휘발성 유기 물질을 사용하지 않는 것이 바람직한데 본 발명에서는 티타늄 옥사이드 20-25중량%, 실리케이트 24-28 중량%, 비닐 아크릴 수지 12-16 중량% 및 기타 물, 계면활성제, 디포머 35-40 중량%를 일반적인 방법으로 혼합하여 이루어진 도료 성분을 사용한다. 이 도료 성분은 악취가 나지 않으며 휘발성 유기 화합물을 사용하지 않는다. 이러한 도료 성분은 20-60 중량%가 사용된다. 20 중량% 이하이면 색상에 문제가 있으며 60 중량% 이상이면 항균 및 항 곰팡이 기능에 문제가 있다.The paint component used in the present invention preferably does not use volatile organic materials. In the present invention, 20-25% by weight of titanium oxide, 24-28% by weight of silicate, 12-16% by weight of vinyl acrylic resin, and other water and surfactants A paint component consisting of mixing 35-40% by weight of the deformer in the usual manner is used. This paint component is odor free and does not use volatile organic compounds. 20-60% by weight of these paint components are used. If it is less than 20% by weight, there is a problem in color, and if it is more than 60% by weight, there is a problem in antibacterial and antifungal function.

한편, 화산석은 화산이 폭발한 후 마그마가 냉각되어 조성된 희귀 광석으로서 본 발명에 사용되는 화산석은 원적외선 방사율(5-20㎛)이 0.927이며 방사에너지가 3.74 x 102 W/m2을 갖는다. 또한, 탈취기능이 우수할 뿐만 아니라 촉매기능도 갖는다. On the other hand, the volcanic stone is a rare ore formed by cooling the magma after the volcanic eruption, the volcanic stone used in the present invention has a far-infrared emissivity (5-20 μm) of 0.927 and a radiation energy of 3.74 × 10 2 W / m 2 . In addition, the deodorizing function is excellent and also has a catalytic function.

본 발명의 화산석 추출물은 먼저 화산석 원석을 320-370 메쉬의 미세 분말로 분쇄하여 화산석 미세분말을 제공한다. 이어서 화산석 원석을 1-2㎝로 분쇄한 작은원석을 제조하고 화산석 미세 분말과 약 50: 50의 비율로 배합한다. 이 배합물에 물을 배합물 40 중량% 와 물 60 중량%의 비율로 혼합하여 3일간 숙성시켜 화산석 추출물을 제조한다. 이러한 화산석 추출물을 사용하는 이유는 도료성분과 화산석을 직접 혼합하여 페인트를 제조하는 경우 페인트 도포 후 크랙이 발생하고 강도가 약 해지기 때문이다. 본 발명의 화산석 추출물을 사용할 경우 페인트 도포 후 크랙이 발생하지 않으며 강도가 강해진다. The volcanic stone extract of the present invention first pulverizes the volcanic stone ore into fine powder of 320-370 mesh to provide volcanic stone fine powder. Subsequently, a small gemstone obtained by crushing the volcanic stone gemstone into 1-2 cm is prepared and blended with the volcanic stone fine powder in a ratio of about 50:50. Water is added to the blend in a proportion of 40% by weight and 60% by weight of water, and aged for 3 days to produce volcanic stone extract. The reason for using such volcanic stone extract is that when paint is directly mixed with paint components and volcanic stone, cracks occur after application of paint and the strength becomes weak. When the volcanic stone extract of the present invention is used, cracks do not occur after the paint is applied and the strength is increased.

이러한 본 발명의 화산석 추출물은 10-30 중량%의 양을 사용되는 것이 바람직하다. 10 중량% 이하이면 효과가 미약해지며 30 중량% 이상이면 페인트 도포시 점착성에 문제가 있다.The volcanic stone extract of the present invention is preferably used in an amount of 10-30% by weight. If it is 10 wt% or less, the effect is insignificant, and if it is 30 wt% or more, there is a problem in adhesion during coating.

본 발명의 화산석 분말은 상기한 화산석을 50-350 메쉬로 분쇄하여 사용하는 것이 바람직하다. 화산석 분말의 입자크기는 사용되는 페인트의 용도에 따라 적절하게 정해질 수 있다. 이러한 화산석 분말은 20-60 중량%의 양으로 사용되는 것이 바람직하다. 20 중량% 이하이면 항균 및 항 곰팡이 기능에 문제가 있으며, 60 중량% 이상이면 페인트 제형에 문제가 있다.Volcanic stone powder of the present invention is preferably used by grinding the above-mentioned volcanic stone to 50-350 mesh. The particle size of the volcanic stone powder may be appropriately determined depending on the use of the paint used. Such volcanic stone powder is preferably used in an amount of 20-60% by weight. If it is 20% by weight or less, there is a problem in antibacterial and anti-fungal function, and if it is 60% by weight or more, there is a problem in paint formulation.

이하, 본발명을 실시예에 의거하여 보다 상세히 설명한다. Hereinafter, the present invention will be described in more detail based on examples.

티타늄 옥사이드 21중량%, 실리케이트 26 중량%, 비닐 아크릴 수지 14 중량% 및 기타 물, 계면 활성제 및 디포머 39중량%를 사용하여 도료 성분을 제조하였다. 이어서 화산석 원석을 350 메쉬의 미세 분말 및 2㎝로 각각 분쇄하고 이를 50: 50으로 혼합하였다. 이 혼합물 40중량%와 물 60중량%를 혼합하고 3일간 숙성시켜 화산석 추출물을 제조하였다. 또한, 화산석 분말을 350 메쉬로 분쇄하여 화산석 분말을 제조하였다. 도료 성분 50 중량%, 화산석 추출물 20 중량% 및 화산석 분말 30중량%를 혼합하여 본 발명에 따른 페인트용 조성물을 제조하였다. 이 페인트용 조성물에 대하여 탈취시험 및 항균 시험을 수행하였다. 탈취시험은 KICM-FIR-1085에 따 라 수행하였으며, 항균 시험은 KICM-FIR-1002에 따라 수행하였다. 그 결과를 각각 표 1 및 표 2에 제시하였다. A paint component was prepared using 21 wt% titanium oxide, 26 wt% silicate, 14 wt% vinyl acrylic resin, and 39 wt% other water, surfactants and deformers. The volcanic stone ore was then ground into 350 mesh fine powder and 2 cm, respectively, and mixed at 50:50. 40% by weight of the mixture and 60% by weight of water were mixed and aged for 3 days to prepare a volcanic stone extract. In addition, the volcanic stone powder was pulverized to 350 mesh to produce a volcanic stone powder. A paint composition according to the present invention was prepared by mixing 50 wt% paint component, 20 wt% volcanic stone extract, and 30 wt% volcanic stone powder. The deodorizing test and the antibacterial test were carried out for this paint composition. Deodorization test was performed according to KICM-FIR-1085, and antibacterial test was performed according to KICM-FIR-1002. The results are shown in Table 1 and Table 2, respectively.

탈취 시험(HCHO)Deodorization Test (HCHO) 경과 시간   Elapsed time 미처리시(ppm) Untreated (ppm) 본발명처리(ppm)The present invention treatment (ppm) 탈취율(%)  Deodorization rate (%) 0      0 82     82 82     82 -      - 30     30 78     78 43     43 44.9     44.9 60     60 75     75 35     35 53.3     53.3 90     90 71     71 25     25 64.8     64.8 120    120 67     67 20     20 70.1     70.1

항균시험Antibacterial test 시험 항목        Test Items 초기농도(CFU/40p)Initial concentration (CFU / 40p) 24시간 후 농도(CFU/40p)Concentration after 24 hours (CFU / 40p) 세균 감소율(%)Bacterial Reduction (%) 대정균     Escherichia coli 미처리   Untreated 421    421 2855   2855 -     - 본발명 처리The present invention 421    421 1      One 99.8    99.8 녹농균     Pseudomonas aeruginosa 미처리   Untreated 432    432 2947    2947 -     - 본 발명 처리 Invention treatment 532    532 1      One 99.8    99.8

*사용균주* Use strain

E. Coli ATCC 25922E. Coli ATCC 25922

Pseudomonas aeruginosa ATCC 15442Pseudomonas aeruginosa ATCC 15442

상기 표들로 부터 본 발명의 페인트는 탈취 효과가 우수할 뿐 만 아니라 항균작용도 매우 우수함을 알 수 있다. It can be seen from the above tables that the paint of the present invention not only has excellent deodorizing effect but also has excellent antibacterial effect.

Claims (1)

화산석을 이용한 친환경 기능성 페인트용 조성물에 있어서, In the composition for eco-friendly functional paint using volcanic stone, 티타늄 옥사이드 20-25중량%, 실리케이트 24-28 중량%, 비닐 아크릴 수지 12-16 중량% 및 기타 물, 계면활성제, 디포머 35-40 중량%로 이루어진 도료 성분 20-60 중량%;20-60% by weight of the paint component consisting of 20-25% by weight of titanium oxide, 24-28% by weight of silicate, 12-16% by weight of vinyl acrylic resin and 35-40% by weight of other water, surfactants, and deformers; 320-370 메쉬의 화산석 분말과 1-2㎝ 화산석 원석을 50:50으로 배합하고 물과 40:60로 혼합하여 추출한 화산석 추출물 10-30 중량%; 및 10-30% by weight of the volcanic stone extract extracted by mixing the volcanic stone powder of 320-370 mesh and the raw material of 1-2 cm volcanic stone at 50:50, and mixed with water at 40:60; And 50-350 메쉬의 화산석 분말 20-60중량%20-60% by weight of 50-350 mesh volcanic stone powder 를 포함하는 것을 특징으로 하는 페인트용 조성물.A composition for paint comprising a.
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