KR101299551B1 - Paint for building comprising trass and method producting the same - Google Patents

Paint for building comprising trass and method producting the same Download PDF

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KR101299551B1
KR101299551B1 KR1020130049819A KR20130049819A KR101299551B1 KR 101299551 B1 KR101299551 B1 KR 101299551B1 KR 1020130049819 A KR1020130049819 A KR 1020130049819A KR 20130049819 A KR20130049819 A KR 20130049819A KR 101299551 B1 KR101299551 B1 KR 101299551B1
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paint
volcanic soil
weight
content
volcanic
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김종민
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김종민
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Plant Pathology (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Building Environments (AREA)
  • Paints Or Removers (AREA)

Abstract

PURPOSE: A paint using trass is provided to decompose a harmful material such as volatile organic compounds and formaldehyde, to absorb and decompose bad-smelling compounds, and to have a humidification function. CONSTITUTION: A paint using trass consists of 35-40 wt% of trass, 15-18 wt% of a natural binder, 4-6 wt% of a silica, 9-11 wt% of a natural pigment, and residual water. A manufacturing method of the paint using trass includes a step of pulverizing the trass (S100); a step of injecting the trass, natural binder, silica, natural pigment, and water into a mixer (S200); and a step of mixing the compositions by using the mixer (S300). [Reference numerals] (AA) Start; (BB) End; (S100) Pulverize trass; (S200) Inject the trass, a natural binder, silica, a natural pigment, an antimicrobial agent, an antimycotic agent, and water with a specific ratio into a mixer; (S300) Mix the composition by using the mixer

Description

화산토를 이용한 도료 및 그 제조방법 {Paint for building comprising trass and method producting the same}Paint for volcanic soil and its manufacturing method {Paint for building comprising trass and method producting the same}

본 발명은 화산토를 이용한 도료 및 그 제조방법에 관한 것으로, 보다 상세하게는 화산토 및 천연 첨가제를 이용하여 유해물질 흡착 분해 및 조습 기능이 우수한 화산토를 이용한 도료 및 그 제조방법에 관한 것이다.The present invention relates to a paint using volcanic soil and a method of manufacturing the same, and more particularly, to a paint using volcanic soil and a method of manufacturing the same using volcanic soil and natural additives having excellent adsorption decomposition and humidity control functions.

일반적으로 건축 마감재로서 사용되는 재료로서는 몰타르와 물을 적정비율로 혼합한 시멘트 몰타르를 표면에 발라 주로 사용하고 있다. 이러한 시멘트 몰타르의 경우 미장시 압축강도에 비해 초기 인장강도가 약하다는 문제점이 발생되었으며, 시공시 접착성이 불량하고 가소성이 좋지 않아 흘림방지를 위하여 초벌, 재벌, 정벌 등의 순서로 수회 나누어 도포함으로써 작업성이 떨어지는 문제점이 있었다. In general, as a material used as a building finishing material, cement mortar obtained by mixing mortar and water in an appropriate ratio is mainly applied to the surface. In the case of cement mortar, the initial tensile strength was weak compared to the compressive strength at the time of plastering, and it is poor in adhesiveness and poor plasticity during construction. There was a problem of poor workability.

건축자재로 사용되는 화학제품의 내장재에서도 포르말린 등의 유해가스가 많이 발생되어 새집증후군으로 아토피성 피부염, 알레르기 비염, 두통, 호흡기질환 등 많은 질환을 일으키는 원인이 되고 있다. 최근에는 건축물 내부의 건축물의 실내공기에 대한 유해성에 대해서 관심이 고조되고 있고, 특히 발암물질이 포함되어 있는 휘발성 유기화합물, 라돈, 포름알데드 등의 저감 및 제거를 위한 건축재의 재료에 대한 요구가 점증되고 있는 실정이다.In the interior materials of chemical products used as building materials, a lot of harmful gases such as formalin are generated, which causes sickness such as atopic dermatitis, allergic rhinitis, headache, and respiratory diseases as a sick house syndrome. Recently, there is a growing interest in the harmfulness of indoor air in buildings, and in particular, there is a demand for materials for building materials for reducing and removing volatile organic compounds, radon, and formaldehyde, which contain carcinogens. It is increasing.

이러한 요구에 부응하여 최근에는 건축물의 내부 마감용 재료로서 여러 가지 유용 물질들을 혼합하여 마감재로서 사용하는 경향이 있고 특히 바이오 세라믹계 또는 천연황토, 각종 광물을 혼합하여 마감재로서 사용하고 있으나, 이러한 세라믹계 또는 황토를 사용할 경우에는 장시간 보관할 경우 침전이 발생하거나, 동절기 공사시에는 동결 등의 우려가 있다. 또한 기존의 액상 세라믹 건축마감재는 황토나 숯, 맥반석, 등의 분말을 유기 바인더 등과 혼합하여 붓칠이나 뿜칠을 하여 사용하는 경우도 있으나, 건축물 실내에서 발생하는 콘크리트 독성을 제거 차단하기에는 문제가 있고, 이 역시 제품 자체이서도 휘발성 유기 물질이 발생하기도 하는 문제가 있다.In order to meet these demands, recently, various useful materials are mixed and used as finishing materials for the interior finishing materials of buildings. Especially, they are used as finishing materials by mixing bio ceramics, natural loess, and various minerals. Or when using ocher, it may cause precipitation if it is stored for a long time, or there is a risk of freezing during winter construction. In addition, the conventional liquid ceramic building finishing materials may be used by mixing the powder such as ocher, charcoal, elvan, etc. with an organic binder and brushing or spraying, but there is a problem to remove the concrete toxicity generated in the interior of the building. There is also a problem that volatile organic substances are generated in the product itself.

따라서, 이러한 건축용 마감재에서는 생활 실내환경 수준의 향상과 욕구를 충족시킬 수 있고, 특히 건축물의 실내에 발생되는 휘발성 유기화합물 및 포름알데히드 등의 유해물질을 흡착 분해할 수 있고, 악취를 흡착 분해하고, 조습 기능을 갖는 건축용 도료에 대한 요구가 절실한 상황이다.
Therefore, the building finishing material can meet the needs and improvement of the indoor environment level of living, in particular, it is possible to adsorb and decompose harmful substances such as volatile organic compounds and formaldehyde generated in the interior of the building, adsorb and decompose odor, There is an urgent need for construction paints having a humidity control function.

한국등록특허 제10-0284859호Korean Patent Registration No. 10-0284859

본 발명은 상술한 종래의 문제점을 극복하기 위한 것으로서, 본 발명이 해결하고자 하는 과제는 휘발성 유기화합물 및 포름알데히드 등의 유해물질을 흡착 분해할 수 있고, 악취를 흡착 분해하고, 조습 기능을 갖는 화산토를 이용한 도료 및 그 제조방법을 제공하기 위한 것이다.
The present invention is to overcome the above-mentioned conventional problems, the problem to be solved by the present invention is to adsorb and decompose harmful substances such as volatile organic compounds and formaldehyde, adsorb and decompose odor, volcanic soil having a humidity control function To provide a paint and a method of manufacturing the same.

본 발명의 예시적인 실시예에 따르면, 화산토를 이용한 도료는 화산토, 천연 바인더, 실리카, 천연안료 및 물을 포함하며, 상기 화산토를 이용한 도료의 전체 중량 기준으로 화산토 함량은 35 ~ 40 중량%, 천연 바인더 함량은 15 ~ 18 중량%, 실리카 함량은 4 ~ 6 중량%, 천연안료 함량은 9 ~ 11 중량%이고, 나머지 함량은 물로 구성되는 화산토를 이용한 도료가 제공된다.According to an exemplary embodiment of the present invention, the paint using volcanic soil includes volcanic soil, natural binder, silica, natural pigment and water, and the volcanic soil content is 35 to 40 wt% based on the total weight of the paint using volcanic soil. The binder content is 15 to 18% by weight, the silica content is 4 to 6% by weight, the natural pigment content is 9 to 11% by weight, and the remaining content is provided with paint using volcanic soil.

상기 천연 바인더는 제올라이트와 산화마그네슘 계열의 해초류 추출물을 이용한다. The natural binder uses zeolite and seaweed extract of magnesium oxide series.

상기 화산토는 알로페인(allophane) 성분을 포함한다. The volcanic soil contains an allophane component.

상기 화산토를 이용한 도료는 항균제 및 항곰팡이제를 더 포함하며, 상기 항균제 함량은 0.1 ~ 0.5 중량%, 상기 항곰팡이제 함량은 0.1 ~ 0.5 중량%인 것을 특징으로 한다.The paint using volcanic soil further includes an antimicrobial agent and an antifungal agent, wherein the antimicrobial content is 0.1 to 0.5% by weight, and the antifungal content is 0.1 to 0.5% by weight.

본 발명의 다른 측면에 따르면 화산토를 분쇄하는 단계; 분쇄된 화산토, 천연 바인더, 실리카, 천연안료 및 물을 교반기에 투입하는 단계; 및 교반기를 이용하여 각 조성물을 혼합하되, 상기 화산토를 이용한 도료의 전체 중량 기준으로 화산토 함량은 35 ~ 40 중량%, 천연 바인더 함량은 15 ~ 18 중량%, 실리카 함량은 4 ~ 6 중량%, 천연안료 함량은 9 ~ 11 중량%이고, 나머지 함량은 물로 구성되도록 혼합하는 단계를 포함하는 화산토를 이용한 도료 제조 방법이 제공된다.
According to another aspect of the invention the step of crushing volcanic soil; Pulverizing volcanic earth, natural binder, silica, natural pigment and water into a stirrer; And each composition is mixed using a stirrer, based on the total weight of the paint using the volcanic soil content is 35 to 40% by weight, natural binder content is 15 to 18% by weight, silica content is 4 to 6% by weight, natural Pigment content is 9 to 11% by weight, the remaining content is provided with a method for producing a paint using volcanic soil comprising the step of mixing to consist of water.

본 발명에 따른 화산토를 이용한 도료는 불연 내외장재로서 건물의 내외벽에 페인트, 벽지 대용으로 사용이 가능하며, 조습성이 뛰어나 천정, 벽바닥 등에 발생하는 결로현상을 제거할 수 있다. The paint using volcanic soil according to the present invention can be used as a substitute for paint and wallpaper on the interior and exterior walls of buildings as non-combustible interior and exterior materials, and has excellent humidity control and can remove condensation occurring in ceilings and wall floors.

또한, 포름알데히드나 톨루엔 등과 같은 유해물질의 흡착 분해 기능이 우수하고, 악취(암모니아)의 흡착 분해 기능이 우수하여 공기 정화효과가 우수하다. In addition, the adsorption decomposition function of the harmful substances such as formaldehyde, toluene and the like is excellent, and the adsorption decomposition function of the odor (ammonia) is excellent, the air purification effect is excellent.

도 1은 본 발명의 일 실시예에 따른 화산토를 이용한 도료 제조방법의 과정을 나타낸 흐름도이다.
도 2는 본 발명에 따라 제조된 화산토를 이용한 도료의 중금속 검출 결과를 나타낸 표이다.
도 3 및 도 4는 본 발명의 실시예에 따라 제조된 화산토를 이용한 도료의 암모니아(NH3) 탈취시험 결과를 나타낸 표 및 그래프이다.
도 5 및 도 6은 본 발명의 실시예에 따라 제조된 화산토를 이용한 도료의 포름알데히드(HCHO)의 탈취시험 결과를 나타낸 표 및 그래프이다.
도 7 및 도 8은 본 발명의 실시예에 따라 제조된 화산토를 이용한 도료의 항곰팡이 시험 결과를 나타낸 표 및 그래프이다.
도 9는 본 발명의 실시예에 따라 제조된 화산토를 이용한 도료의 항균 시험 결과를 나타낸 표이다.
도 10a 및 도 10b는 대장균에 대한 항균 시험 결과를 나타낸 사진이다.
도 11a 및 도 11b는 녹농균에 대한 항균 시험 결과를 나타낸 사진이다.
도 12a 및 도 12b는 황색포도상구균에 대한 항균 시험 결과를 나타낸 사진이다.
도 13은 본 발명의 실시예에 따라 제조된 화산토를 이용한 도료의 흡습량 및 방습량 시험결과를 나타낸 도표이다.
도 14는 흡습량 및 방습량의 그래프이다.1 is a flow chart showing a process of the paint manufacturing method using volcanic soil according to an embodiment of the present invention.
Figure 2 is a table showing the detection results of heavy metals of the paint using volcanic soil prepared according to the present invention.
3 and 4 are tables and graphs showing ammonia (NH 3 ) deodorization test results of paint using volcanic soil prepared according to an embodiment of the present invention.
5 and 6 are tables and graphs showing the results of deodorization test of formaldehyde (HCHO) of paint using volcanic soil prepared according to an embodiment of the present invention.
7 and 8 are tables and graphs showing the anti-fungal test results of the paint using volcanic soil prepared according to an embodiment of the present invention.
9 is a table showing the antimicrobial test results of the paint using volcanic soil prepared according to an embodiment of the present invention.
10a and 10b are photographs showing the antimicrobial test results for Escherichia coli.
11a and 11b are photographs showing the antimicrobial test results for Pseudomonas aeruginosa.
12a and 12b are photographs showing the antimicrobial test results for Staphylococcus aureus.
13 is a chart showing the moisture absorption and moisture proof test results of the paint using volcanic soil prepared according to an embodiment of the present invention.
14 is a graph of moisture absorption amount and moisture proof amount.

이하, 첨부된 도면을 참조하여 본 발명의 바람직한 실시예에 대해 상세히 설명한다.Hereinafter, with reference to the accompanying drawings will be described in detail a preferred embodiment of the present invention.

도 1은 본 발명의 일 실시예에 따른 화산토를 이용한 도료 제조방법의 과정을 나타낸 흐름도이다.1 is a flow chart showing a process of the paint manufacturing method using volcanic soil according to an embodiment of the present invention.

도 1을 참조하면, 우선 화산토를 분말화하기 위하여, 화산토를 분쇄하는 과정을 수행한다(S100).Referring to FIG. 1, first, in order to powder volcanic soil, volcanic soil is pulverized (S100).

그 다음에 분쇄된 화산토, 천연 바인더, 실리카, 천연안료, 항균제, 항곰팡이제 및 물을 교반기에 투입하는 과정을 수행한다(S200). 그리고 나서, 교반기를 이용하여 각 조성물을 혼합하는 과정을 수행한다(S300).
Then pulverized volcanic soil, natural binder, silica, natural pigments, antibacterial, anti-mold and water is added to the stirrer (S200). Then, the process of mixing each composition using a stirrer is performed (S300).

이하에서 각 단계별 과정을 보다 상세히 설명한다.Hereinafter, each step process will be described in more detail.

화산토Volcanic soil 분쇄 과정( Grinding process ( S100S100 ))

화산토는 화산 작용으로 분출되어 응고된 고형물을 분쇄한 분말이다. 화산토는 알칼리성 규산 알루미늄인 알로페인(allophane) 성분을 포함한다. 천연 알로페인은 강하성 화산 분출물의 풍화물인 풍화 경석에 많이 포함되어 있으며, 이러한 알로페인 알갱이는 다공질 구형 구조로 형성되며, 다공질 구형 입자의 구멍 내부에 정부 양극성에 대전한 반응기가 존재하여 중금속을 포함한 다양한 물질의 흡착 능력이 우수하다.
Volcanic soil is a powder obtained by volcanizing and pulverizing solidified solids. Volcanic soil contains an allophane component which is alkaline aluminum silicate. Natural allofane is contained in weathered pumice, which is the weathering material of descending volcanic eruptions, and these allopein grains are formed into a porous spherical structure. Excellent adsorption capacity of various materials.

각 조성물 혼합 과정(Each composition mixing process ( S200S200 , , S300S300 ))

본 실시예에 따른 화산토를 이용한 도료의 조성물은 화산토, 천연 바인더, 실리카, 천연안료, 항균제 및 항곰팡이제를 포함한다.The composition of the paint using volcanic soil according to the present embodiment includes volcanic soil, natural binder, silica, natural pigment, antibacterial agent and antifungal agent.

천연 바인더로는 제올라이트와 산화마그네슘을 주성분으로 하는 해초류 추출물을 이용한다. As a natural binder, seaweed extracts containing zeolite and magnesium oxide as main components are used.

천연 안료는 색상에 따라 다양한 재료를 선택하여 사용할 수 있다. Natural pigments can be used to select a variety of materials depending on the color.

본 실시예에 따른 화산토를 이용한 도료는 전체 중량 기준으로 화산토 함량은 35 ~ 40 중량%, 천연 바인더 함량은 15 ~ 18 중량%, 실리카 함량은 4 ~ 6 중량%, 천연안료 함량은 9 ~ 11 중량%, 항균제 함량은 0.1 ~ 0.5 중량%, 항곰팡이제 함량은 0.1 ~ 0.5 중량%, 나머지 함량은 물(H2O)로 구성되도록, 교반기에 각 조성물을 투입한 후, 투입된 조성물을 교반기를 이용하여 골고루 혼합한다.
The paint using volcanic soil according to the present embodiment has a volcanic soil content of 35 to 40% by weight, a natural binder content of 15 to 18% by weight, silica content of 4 to 6% by weight, and natural pigment content of 9 to 11% by weight. %, The antimicrobial content is 0.1 to 0.5% by weight, the antifungal agent content is 0.1 to 0.5% by weight, the remaining content is added to the stirrer, so that the remaining content is composed of water (H 2 O), and then put the composition into the stirrer Mix evenly.

위의 제조방법에 따라 제조된 화산토 도료는 포름알데히드, 톨루엔, 암모니아등의 유해물질 흡착분해 및 공기 정화 항균 및 항곰팡이 기능이 우수하다.
Volcanic earth paint prepared according to the above method is excellent in adsorption decomposition and air purification antibacterial and antifungal function of harmful substances such as formaldehyde, toluene, ammonia.

[실험예][Experimental Example]

화산토를 이용한 도료의 전체 중량 기준으로 화산토 38 중량%, 바인더 16 중량%, 실리카 5 중량%, 천연안료 10 중량%, 항균제 0.3 중량%, 항곰팡이제 0.3 중량%, 나머지는 물로 이루어진 도료를 이용하여 중금속 검출 시험, 포름알데히드 탈취시험, 암모니아 탈취시험, 항곰팡이 시험 및 항균 시험을 수행하였다. 시험은 한국건설생활환경시험연구원에 위탁 의뢰하여 수행하였다.
38% by weight of volcanic earth, 16% by weight of binder, 5% by weight of silica, 10% by weight of natural pigments, 0.3% by weight of antibacterial agent, 0.3% by weight of antifungal agent, and the rest using water Heavy metal detection test, formaldehyde deodorization test, ammonia deodorization test, antifungal test and antibacterial test were performed. The test was commissioned by the Korea Institute of Construction and Living Testing.

도 2는 본 발명에 따라 제조된 화산토를 이용한 도료의 중금속 검출 결과를 나타낸 표이다. 도 2에 도시된 바와 같이, 본 발명에 따라 제조된 화산토를 이용한 도료에서는 Pb, Cd, Cr, Ba, Sb, Hg, As 및 Se 등의 중금속이 검출되지 않았다.
Figure 2 is a table showing the detection results of heavy metals of the paint using volcanic soil prepared according to the present invention. As shown in FIG. 2, heavy metals such as Pb, Cd, Cr, Ba, Sb, Hg, As, and Se were not detected in the paint using volcanic soil prepared according to the present invention.

도 3 및 도 4는 본 발명의 실시예에 따라 제조된 화산토를 이용한 도료의 암모니아(NH3) 탈취시험 결과를 나타낸 표 및 그래프이다.3 and 4 are tables and graphs showing ammonia (NH 3 ) deodorization test results of paint using volcanic soil prepared according to an embodiment of the present invention.

[실험방법]Experimental Method

- 위의 실험예에 따라 제조된 화산토를 이용한 도료의 시료를 40mm x 40mm x 3mm(가로x세로x두께)의 크기로 5L 크기의 반응기에 넣고 밀봉한 후, 시험가스의 초기 농도를 50ppm으로 하여 주입하고, 시험 가스의 농도를 초기(0분), 30분, 60분, 90분 및 120분에서 측정(이를 sample 농도라 함)하였다.The sample of paint prepared using volcanic soil prepared according to the above experimental example was placed in a 5L reactor having a size of 40mm x 40mm x 3mm (width x length x thickness) and sealed, and then the initial concentration of the test gas was 50 ppm. The concentration of the test gas was measured at initial (0 minutes), 30 minutes, 60 minutes, 90 minutes and 120 minutes (this is called sample concentration).

- 시험 조건은 온도 : 섭씨 23도 ± 5도, 습도는 50% ± 10% 유지하였다.The test conditions were maintained at 23 ° C ± 5 ° C and 50% ± 10% humidity.

- 시료가 없는 상태에서 동일하게 시험을 진행하고, 이때의 농도를 측정(이를 blank 농도라 함)하였다.The test was carried out in the absence of sample and the concentration was measured (this is called the blank concentration).

도 3 및 도 4에 도시된 바와 같이, 암모니아 탈취율은 30분 경과시 69.4%를 나타냈으며, 120분 경과시 77.1%를 나타냈다.
3 and 4, the ammonia deodorization rate was 69.4% after 30 minutes and 77.1% after 120 minutes.

도 5 및 도 6은 본 발명의 실시예에 따라 제조된 화산토를 이용한 도료의 포름알데히드(HCHO)의 탈취시험 결과를 나타낸 표 및 그래프이다.5 and 6 are tables and graphs showing the results of deodorization test of formaldehyde (HCHO) of paint using volcanic soil prepared according to an embodiment of the present invention.

포름알데히드의 탈취시험 역시 위의 방법과 동일하게 실행하였으며, 도 5 및 도 5에 도시된 바와 같이, 본 발명에 따른 화산토를 이용한 도료의 경우 120분이 경과했을 때 50%의 탈취율을 나타내었다.
Deodorization test of formaldehyde was also carried out in the same manner as the above method, as shown in Figure 5 and 5, the coating using volcanic soil according to the present invention showed a deodorization rate of 50% when 120 minutes have elapsed.

도 7 및 도 8은 본 발명의 실시예에 따라 제조된 화산토를 이용한 도료의 항곰팡이 시험 결과를 나타낸 표 및 그래프이다.7 and 8 are tables and graphs showing the anti-fungal test results of the paint using volcanic soil prepared according to an embodiment of the present invention.

도 7 및 도 8을 참조하면, 곰팡이 균주의 배양 시험을 총 4주간 실행하였으나 균사의 발육이 인지되지 않았음을 알 수 있었다.
7 and 8, the culture test of the fungus strain was performed for a total of 4 weeks, it was found that the development of the mycelia was not recognized.

도 9는 본 발명의 실시예에 따라 제조된 화산토를 이용한 도료의 항균 시험 결과를 나타낸 표이며, 도 10a 및 도 10b는 대장균에 대한 항균 시험 결과를 나타낸 사진이고, 도 11a 및 도 11b는 녹농균에 대한 항균 시험 결과를 나타낸 사진이고, 도 12a 및 도 12b는 황색포도상구균에 대한 항균 시험 결과를 나타낸 사진이다.Figure 9 is a table showing the antimicrobial test results of the paint using volcanic soil prepared according to an embodiment of the present invention, Figure 10a and 10b is a photograph showing the antimicrobial test results for E. coli, Figures 11a and 11b is to Pseudomonas aeruginosa It is a photograph showing the results of the antimicrobial test, Figure 12a and 12b is a photograph showing the antimicrobial test results for Staphylococcus aureus.

도 9 내지 12b를 참조하면, 시료 4g에 대하여 균주를 접종하였으며, 접종된 세균농도는 대장균은 1.6X106, 녹농균은 1.7X106, 황색포도상구균은 1.3X106 이다. 24시간 이후에 세균 감소율은 3가지 모두 99.9%를 나타내었다.Referring to Figure 9 to 12b, were inoculated with the strain with respect to the sample 4g, the inoculated bacteria concentration is 1.6X10 6 E. coli, P. aeruginosa is 1.7X10 6, Staphylococcus aureus 1.3X10 6. After 24 hours, bacterial reduction was 99.9% in all three.

따라서, 본 발명에 따른 화산토를 이용한 도료는 항곰팡이 기능 및 항균 기능이 우수함을 알 수 있다.
Therefore, it can be seen that the paint using volcanic soil according to the present invention has excellent antifungal function and antibacterial function.

도 13은 본 발명의 실시예에 따라 제조된 화산토를 이용한 도료의 흡습량 및 방습량 시험결과를 나타낸 도표이고, 도 14는 흡습량 및 방습량의 그래프이다.13 is a graph showing the moisture absorption and moisture proof test results of the paint using volcanic soil prepared according to an embodiment of the present invention, Figure 14 is a graph of the moisture absorption and moisture.

도 13 및 도 14를 참조하면, 흡습량 및 방습량 시험을 수행하기 위하여, 250mmX250mm 크기의 벽지에 본 발명에 따라 제조된 화산토를 이용한 도료를 도포한 시료를 이용하였다. 시료의 두께는 0.4mm이고, 질량은 18.8g이다.13 and 14, in order to perform the moisture absorption and moisture proof test, a sample coated with a coating using volcanic soil prepared according to the present invention on a 250mm × 250mm size wallpaper was used. The thickness of the sample is 0.4 mm and the mass is 18.8 g.

시험 결과를 살펴보면, 흡습량은 4.2g/m2, 방습량은 3.4g/m2였으며, 흡방습량의 차는 0.8g/m2로 측정되었다.
As a result of the test, the moisture absorption amount was 4.2g / m 2 , the moisture absorption amount was 3.4g / m 2 , and the difference in moisture absorption and moisture absorption amount was 0.8g / m 2 .

이상에서 설명한 것은 본 발명에 따른 화산토를 이용한 도료 및 그 제조방법의 예시적인 실시예에 불과한 것으로서, 본 발명은 상기한 실시예에 한정되지 않고, 이하의 특허청구범위에서 청구하는 바와 같이, 본 발명의 요지를 벗어남이 없이 당해 발명이 속하는 분야에서 통상의 지식을 가진 자라면 누구든지 다양한 변경 실시가 가능한 범위까지 본 발명의 기술적 정신이 있다고 할 것이다.
What has been described above is merely an exemplary embodiment of the paint using volcanic soil according to the present invention and its manufacturing method, the present invention is not limited to the above-described embodiment, as claimed in the following claims, the present invention Without departing from the gist of the present invention, those skilled in the art to which the present invention pertains to the technical spirit of the present invention to the extent that various modifications can be made.

Claims (6)

화산토를 이용한 도료에 있어서,
상기 화산토를 이용한 도료는 화산토, 천연 바인더, 실리카, 천연안료 및 물을 포함하며,
상기 화산토를 이용한 도료의 전체 중량 기준으로 화산토 함량은 35 ~ 40 중량%, 천연 바인더 함량은 15 ~ 18 중량%, 실리카 함량은 4 ~ 6 중량%, 천연안료 함량은 9 ~ 11 중량%이고, 나머지 함량은 물로 구성되는 것을 특징으로 하는 화산토를 이용한 도료.
In paint using volcanic soil,
The paint using volcanic soil includes volcanic soil, natural binder, silica, natural pigment and water,
The volcanic soil content is 35 to 40% by weight, the natural binder content is 15 to 18% by weight, the silica content is 4 to 6% by weight, and the natural pigment content is 9 to 11% by weight based on the total weight of the paint using volcanic soil. The content is paint using volcanic soil, characterized in that consisting of water.
청구항 1에 있어서,
상기 천연 바인더는 제올라이트와 산화마그네슘 계열의 해초류 추출물을 이용하는 것을 특징으로 하는 화산토를 이용한 도료.
The method according to claim 1,
The natural binder is a coating using volcanic soil, characterized in that using the zeolite and seaweed extract of magnesium oxide series.
청구항 1에 있어서,
상기 화산토는 알로페인(allophane) 성분을 포함하는 것을 특징으로 하는 화산토를 이용한 도료.
The method according to claim 1,
The volcanic soil is a paint using volcanic soil, characterized in that it comprises an allophane (allophane) component.
청구항 1에 있어서,
상기 화산토를 이용한 도료는 항균제 및 항곰팡이제를 더 포함하며,
상기 항균제 함량은 0.1 ~ 0.5 중량%, 상기 항곰팡이제 함량은 0.1 ~ 0.5 중량%인 것을 특징으로 하는 화산토를 이용한 도료.
The method according to claim 1,
The paint using volcanic soil further includes an antibacterial and antifungal agent,
The antimicrobial content is 0.1 to 0.5% by weight, the antifungal agent content is a paint using volcanic soil, characterized in that 0.1 to 0.5% by weight.
화산토를 이용한 도료 제조 방법에 있어서,
화산토를 분쇄하는 단계;
분쇄된 화산토, 천연 바인더, 실리카, 천연안료 및 물을 교반기에 투입하는 단계; 및
교반기를 이용하여 각 조성물을 혼합하되, 상기 화산토를 이용한 도료의 전체 중량 기준으로 화산토 함량은 35 ~ 40 중량%, 천연 바인더 함량은 15 ~ 18 중량%, 실리카 함량은 4 ~ 6 중량%, 천연안료 함량은 9 ~ 11 중량%이고, 나머지 함량은 물로 구성되도록 혼합하는 단계;를 포함하는 것을 특징으로 하는 화산토를 이용한 도료 제조 방법.
In the paint production method using volcanic soil,
Crushing volcanic soil;
Pulverizing volcanic earth, natural binder, silica, natural pigment and water into a stirrer; And
Mix each composition using a stirrer, the volcanic earth content is 35 to 40% by weight, the natural binder content is 15 to 18% by weight, silica content is 4 to 6% by weight, natural pigments based on the total weight of the paint using the volcanic soil The content is 9 to 11% by weight, and the remaining content is mixed to be composed of water; Paint production method using volcanic soil comprising a.
청구항 5에 있어서,
상기 천연 바인더는 제올라이트와 산화마그네슘 계열의 해초류 추출물을 이용하는 것을 특징으로 하는 화산토를 이용한 도료 제조 방법.The method according to claim 5,
The natural binder is a coating method using volcanic soil, characterized in that using the zeolite and seaweed extract of magnesium oxide series.
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CN109575731A (en) * 2018-12-19 2019-04-05 重庆美涂科技有限公司 A kind of Environmental Protective Water-paint and its production technology
KR20210064603A (en) * 2019-11-26 2021-06-03 곽상훈 Manufacturing method of eco-friendly paint containing Polygoum tinctoria and volcanic soil
KR102301436B1 (en) * 2019-11-26 2021-09-13 곽상훈 Manufacturing method of eco-friendly paint containing Polygoum tinctoria and volcanic soil

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