CN105295636A - Building waterproof antifouling paint and preparation method thereof - Google Patents
Building waterproof antifouling paint and preparation method thereof Download PDFInfo
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Abstract
The invention discloses building waterproof antifouling paint and a preparation method thereof. The building waterproof antifouling paint is prepared from the following raw materials in parts by weight: 18-25 parts of deionized water, 0.15-0.25 part of a dispersing agent, 0.2-0.3 parts of hydroxyethyl cellulose sodium, 7-12 parts of titanium dioxide, 3-5 parts of talcum powder, 4-6 parts of kieselguhr, 3.5-5 parts of calcium carbonate, 3.5-5 parts of an antifoaming agent, 0.6-0.8 part of sodium bicarbonate, 2.2-3.2 parts of ethylene glycol, 0.4-0.6 part of a film forming aid, 0.2-0.4 parts of a leveling agent, 0.2-0.4 part of a defoaming agent and 46-52 parts of modified silicon fluoride styrene-acrylate emulsion. According to the building waterproof antifouling paint, since fluorine-containing styrene-acrylate emulsion is modified by adding organic silicon, and through synergistic modification of silicon and fluoride, the production cost is reduced, the styrene-acrylate emulsion paint further has the characteristics of organic silicon and organic fluorine, and has the advantages of being good in antifouling effect, good in adhesion degree and high in water resistance and chemical resistance.
Description
Technical field
The present invention relates to a kind of coating, particularly a kind of buildings waterproof antifouling paint, belongs to technical field of chemical paint.
Background technology
Since the nineties in 20th century, the exploitation of building coating product innovation is the study hotspot of coating worker always, and many R&D institutions and enterprise are all devoted to development of new Functional Architectural Coatings in China.The coating that external wall uses, drenches with rain along with exposing to the weather, and exposes in atmosphere, dust is easily attached to coating top layer, and through one or two years, brand-new exterior coating will be dirty, and cleaning inconvenience, again can only brush in order to attractive in appearance, cause the great wasting of resources.
Now stain-resistant exterior wall coating anti-fouling effect is not commercially very desirable, the fluorine-containing benzene emulsion of existing one, improve film hydrophobicity, oleophobic property and compactness, make the film of coating spot in drying process can not be sucked in film with moisture, even if film is stained with spot, is also easy to spot to wash when scrubbing, thus makes film have high-leveling and contamination resistance; But because the price comparison of fluorochemical monomer is high, and kind is relatively less, cause the cost of fluorine-containing benzene emulsion higher; Now urgency is to be studied develops a kind of superior performance, lower-cost external wall water proof anti-soil coating.
Summary of the invention
For the deficiencies in the prior art, the object of this invention is to provide a kind of buildings waterproof antifouling paint, this coating carries out modification by adding organosilicon to fluorine-containing benzene emulsion, fluosilicic modified synergic, not only can reduce costs, styrene-acrylate emulsion coating can also be made to possess the feature of organosilicon and organic fluorine, and waterproof, antifouling property are more superior, and cost performance is higher simultaneously.
In order to achieve the above object, the technical scheme that the present invention takes is:
A kind of buildings waterproof antifouling paint, is formed by the preparation of raw material of following weight part: deionized water 18-25 part, dispersion agent 0.15-0.25 part, sodium hydroxyethyl cellulose 0.2-0.3 part, titanium dioxide 7-12 part, talcum powder 3-5 part, diatomite 4-6 part, calcium carbonate 3.5-5 part, defoamer 3.5-5 part, sodium bicarbonate 0.6-0.8 part, ethylene glycol 2.2-3.2 part, film coalescence aid 0.4-0.6 part, flow agent 0.2-0.4 part, defoamer 0.2-0.4 part, modified silicon fluorobenzene acrylic emulsion 46-52 part;
Described modified silicon fluorobenzene acrylic emulsion is made up of the raw material of following weight part: deionized water 80-90 part, sodium lauryl sulphate 0.1-0.2 part, fatty alcohol-polyoxyethylene ether 0.1-0.18 part, sodium bicarbonate 0.5-0.8 part, lauryl mercaptan 0.5-0.8 part, ammonium persulfate solution 53-62 part, vinylbenzene 4-5 part, butyl acrylate 6.5-7.6 part, pre-emulsion 30-38 part;
Described pre-emulsion is made up of the raw material of following weight part: acrylic polyether phosphoric acid ester 2.5-4 part, deionized water 40-55 part, sodium lauryl sulphate 0.2-0.4 part, fatty alcohol-polyoxyethylene ether 0.2-0.4 part, vinylbenzene 45-50 part, butyl acrylate 60-62 part, vinyltriethoxysilane 8-8.2 part, Hexafluorobutyl mathacrylate 3.5-4 part.
As specializing, described ammonium persulfate solution massfraction is 2.3%, and the massfraction of described sodium hydroxide is 5%.
The preparation method of described buildings waterproof antifouling paint comprises the steps:
(1) the acrylic polyether phosphoric acid ester sodium hydroxide taking above-mentioned weight part is neutralized to pH=6.5, then the deionized water of above-mentioned weight part, sodium lauryl sulphate, fatty alcohol-polyoxyethylene ether is added in reactor, under agitation be warming up to 45 ~ 55 DEG C, again the mix monomer of the vinylbenzene of above-mentioned weight part, butyl acrylate, vinyltriethoxysilane, Hexafluorobutyl mathacrylate is slowly added in reactor, stir 30 ~ 50 minutes, obtain milky pre-emulsion;
(2) deionized water of above-mentioned weight part is added in the reactor successively, emulsifying agent, sodium bicarbonate and lauryl mercaptan, stir and be warming up to 80 ~ 90 DEG C, drip ammonium persulfate solution and the vinylbenzene of above-mentioned weight part respectively, the mix monomer of butyl acrylate, when at the bottom of dropwising bottle there is blue light in emulsion, be incubated and obtain seed emulsion in 15 minutes, then respectively the ammonium persulfate solution of pre-emulsion and above-mentioned weight part is added drop-wise in seed emulsion, 3 hours dropwise, stir insulation 2 ~ 3 hours, use weak ammonia adjust ph to 6.5 after being down to room temperature, filter discharging, be fluosilicic benzene emulsion,
(3) by the deionized water of above-mentioned weight part and dispersion agent dispersed with stirring uniformly solution, add thickening material and stir 1h, be dispersed into clear viscous solution, by the fillers dispersed of above-mentioned weight part in solution, add defoamer, strong stirring 1h, moves in conoidal mill and grinds 2 ~ 3 times, be prepared into filler mill base; In modified silicon fluorobenzene acrylic emulsion, add sodium bicarbonate, ethylene glycol, film coalescence aid, the flow agent of above-mentioned weight part, strong stirring is even, adds filler mill base, adds defoamer simultaneously, stirs 1h, is namely prepared into coating.
Compared with prior art, beneficial effect of the present invention:
Coating of the present invention carries out modification by adding organosilicon to fluorine-containing benzene emulsion, fluosilicic modified synergic, not only can reduce costs, and styrene-acrylate emulsion coating can also be made to possess the feature of organosilicon and organic fluorine simultaneously, good antifouling effect, degree of adhesion are good, also have the advantage such as water tolerance, chemical resistant properties.
Embodiment
Below in conjunction with specific embodiment, the present invention is further described.
Embodiment 1
The preparation of pre-emulsion: by the acrylic polyether phosphoric acid ester of 2.5 weight parts with 5% sodium hydroxide be neutralized to pH=6.5, then the deionized water that 40 weight parts are housed is added, the sodium lauryl sulphate of 0.25 weight part, in the reactor of the fatty alcohol-polyoxyethylene ether of 0.3 weight part, under agitation be warming up to 45 DEG C, again by the vinylbenzene of 45 weight parts, the butyl acrylate of 60.4 weight parts, the vinyltriethoxysilane of 8.16 weight parts, the mix monomer of the Hexafluorobutyl mathacrylate of 3.75 weight parts slowly adds in reactor, stir 30 minutes, obtain milky pre-emulsion.
The synthesis of fluosilicic benzene emulsion: the lauryl mercaptan adding the deionized water of 80 weight parts, the sodium lauryl sulphate of 0.1 weight part, the fatty alcohol-polyoxyethylene ether of 0.15 weight part, the sodium bicarbonate of 0.8 weight part and 0.5 weight part in the reactor successively, stir and be warming up to 80 DEG C, drip respectively 15 weight part massfractions be 2.3% ammonium persulfate solution and the vinylbenzene of 4.8 weight parts, the butyl acrylate of 7.6 weight parts mix monomer, when blue light appears in emulsion at the bottom of dropwising bottle, be incubated and obtain seed emulsion in 15 minutes.Then the ammonium persulfate solution being 2.3% by pre-emulsion 30 and 40 weight part massfraction is respectively added drop-wise in seed emulsion, 3 hours dropwise, and stir guarantor 2 hours, use weak ammonia adjust ph to 6.5 after being down to room temperature, filter discharging, be fluosilicic benzene emulsion.
The synthesis of fluosilicic styrene-acrylate emulsion coating: by the dispersion agent dispersed with stirring uniformly solution of the deionized water of 21 weight parts and 0.2 weight part, the thickening material sodium hydroxyethyl cellulose adding 0.2 weight part stirs 1h, is dispersed into clear viscous solution.By the titanium dioxide of filler 10 weight part, the talcum powder of 4 weight parts, the diatomite of 4 weight parts, the calcium carbonate of 4 weight parts is distributed in solution respectively, adds the defoamer of 0.5 weight part, strong stirring 1h, moves in conoidal mill and grinds 2 ~ 3 times, be prepared into filler mill base.In the modified silicon fluorobenzene acrylic emulsion of 52 weight parts, add the sodium bicarbonate of 0.8 weight part simultaneously, the ethylene glycol of 2.2 weight parts, the film coalescence aid of 0.5 weight part, the flow agent of 0.3 weight part, strong stirring is even, adds filler mill base, adds the defoamer of 0.3 weight part, stir 1h, be namely prepared into coating.
Embodiment 2
The preparation of pre-emulsion: by the acrylic polyether phosphoric acid ester of 3 weight parts with 5% sodium hydroxide be neutralized to pH=6.5, then the deionized water that 45 weight parts are housed is added, the sodium lauryl sulphate of 0.2 weight part, in the reactor of the fatty alcohol-polyoxyethylene ether of 0.2 weight part, under agitation be warming up to 50 DEG C, again by the vinylbenzene of 50 weight parts, the butyl acrylate of 60 weight parts, the vinyltriethoxysilane of 8 weight parts, the mix monomer of the Hexafluorobutyl mathacrylate of 3.5 weight parts slowly adds in reactor, stir 40 minutes, obtain milky pre-emulsion.
The synthesis of fluosilicic benzene emulsion: the lauryl mercaptan adding the deionized water of 85 weight parts, the sodium lauryl sulphate of 0.15 weight part, the fatty alcohol-polyoxyethylene ether of 0.2 weight part, the sodium bicarbonate of 0.5 weight part and 0.6 weight part in the reactor successively, stir and be warming up to 85 DEG C, drip respectively 20 weight part massfractions be 2.3% ammonium persulfate solution and the vinylbenzene of 4.5 weight parts, the butyl acrylate of 6.8 weight parts mix monomer, when blue light appears in emulsion at the bottom of dropwising bottle, be incubated and obtain seed emulsion in 15 minutes.Then the ammonium persulfate solution being 2.3% by pre-emulsion 38 and 42 weight part massfraction is respectively added drop-wise in seed emulsion, 3 hours dropwise, and stir insulation 2.5 hours, use weak ammonia adjust ph to 6.5 after being down to room temperature, filter discharging, be fluosilicic benzene emulsion.
The synthesis of fluosilicic styrene-acrylate emulsion coating: by the dispersion agent dispersed with stirring uniformly solution of the deionized water of 20 weight parts and 0.15 weight part, the thickening material sodium hydroxyethyl cellulose adding 0.25 weight part stirs 1h, is dispersed into clear viscous solution.By the titanium dioxide of filler 9 weight part, the talcum powder of 3 weight parts, the diatomite of 5 weight parts, the calcium carbonate of 4.5 weight parts is distributed in solution respectively, adds the defoamer of 0.6 weight part, strong stirring 1h, move in conoidal mill and grind 2 ~ 3 times, be prepared into filler mill base.In the modified silicon fluorobenzene acrylic emulsion of 50 weight parts, add the sodium bicarbonate of 0.6 weight part simultaneously, the ethylene glycol of 3 weight parts, the film coalescence aid of 0.4 weight part, the flow agent of 0.25 weight part, strong stirring is even, adds filler mill base, adds the defoamer of 0.4 weight part, stir 1h, be namely prepared into coating.
Embodiment 3
The preparation of pre-emulsion: by the acrylic polyether phosphoric acid ester of 3.5 weight parts with 5% sodium hydroxide be neutralized to pH=6.5, then the deionized water that 50 weight parts are housed is added, the sodium lauryl sulphate of 0.3 weight part, in the reactor of the fatty alcohol-polyoxyethylene ether of 0.4 weight part, under agitation be warming up to 55 DEG C, again by the vinylbenzene of 45 weight parts, the butyl acrylate of 61 weight parts, the vinyltriethoxysilane of 8.2 weight parts, the mix monomer of the Hexafluorobutyl mathacrylate of 4 weight parts slowly adds in reactor, stir 50 minutes, obtain milky pre-emulsion.
The synthesis of fluosilicic benzene emulsion: the lauryl mercaptan adding the deionized water of 80 weight parts, the sodium lauryl sulphate of 0.1 weight part, the fatty alcohol-polyoxyethylene ether of 0.1 weight part, the sodium bicarbonate of 0.6 weight part and 0.7 weight part in the reactor successively, stir and be warming up to 90 DEG C, drip respectively 19 weight part massfractions be 2.3% ammonium persulfate solution and the vinylbenzene of 4 weight parts, the butyl acrylate of 7 weight parts mix monomer, when blue light appears in emulsion at the bottom of dropwising bottle, be incubated and obtain seed emulsion in 15 minutes.Then the ammonium persulfate solution being 2.3% by pre-emulsion 32 and 38 weight part massfraction is respectively added drop-wise in seed emulsion, 3 hours dropwise, and stir insulation 3 hours, use weak ammonia adjust ph to 6.5 after being down to room temperature, filter discharging, be fluosilicic benzene emulsion.
The synthesis of fluosilicic styrene-acrylate emulsion coating: by the dispersion agent dispersed with stirring uniformly solution of the deionized water of 25 weight parts and 0.2 weight part, the thickening material sodium hydroxyethyl cellulose adding 0.2 weight part stirs 1h, is dispersed into clear viscous solution.By the titanium dioxide of filler 7 weight part, the talcum powder of 4.5 weight parts, the diatomite of 4.5 weight parts, the calcium carbonate of 5 weight parts is distributed in solution respectively, adds the defoamer of 0.45 weight part, strong stirring 1h, move in conoidal mill and grind 2 ~ 3 times, be prepared into filler mill base.In the modified silicon fluorobenzene acrylic emulsion of 48 weight parts, add the sodium bicarbonate of 0.8 weight part simultaneously, the ethylene glycol of 2.8 weight parts, the film coalescence aid of 0.6 weight part, the flow agent of 0.3 weight part, strong stirring is even, adds filler mill base, adds the defoamer of 0.2 weight part, stir 1h, be namely prepared into coating.
Embodiment 4
The preparation of pre-emulsion: by the acrylic polyether phosphoric acid ester of 4 weight parts with 5% sodium hydroxide be neutralized to pH=6.5, then the deionized water that 55 weight parts are housed is added, the sodium lauryl sulphate of 0.4 weight part, in the reactor of the fatty alcohol-polyoxyethylene ether of 0.25 weight part, under agitation be warming up to 55 DEG C, again by the vinylbenzene of 50 weight parts, the butyl acrylate of 62 weight parts, the vinyltriethoxysilane of 8.1 weight parts, the mix monomer of the Hexafluorobutyl mathacrylate of 3.9 weight parts slowly adds in reactor, stir 45 minutes, obtain milky pre-emulsion.
The synthesis of fluosilicic benzene emulsion: the lauryl mercaptan adding the deionized water of 90 weight parts, the sodium lauryl sulphate of 0.2 weight part, the fatty alcohol-polyoxyethylene ether of 0.18 weight part, the sodium bicarbonate of 0.7 weight part and 0.8 weight part in the reactor successively, stir and be warming up to 85 DEG C, drip respectively 17 weight part massfractions be 2.3% ammonium persulfate solution and the vinylbenzene of 5 weight parts, the butyl acrylate of 6.5 weight parts mix monomer, when blue light appears in emulsion at the bottom of dropwising bottle, be incubated and obtain seed emulsion in 15 minutes.Then the ammonium persulfate solution being 2.3% by pre-emulsion 35 and 45 weight part massfraction is respectively added drop-wise in seed emulsion, 3 hours dropwise, and stir insulation 2.5 hours, use weak ammonia adjust ph to 6.5 after being down to room temperature, filter discharging, be fluosilicic benzene emulsion.
The synthesis of fluosilicic styrene-acrylate emulsion coating: by the dispersion agent dispersed with stirring uniformly solution of the deionized water of 18 weight parts and 0.25 weight part, the thickening material sodium hydroxyethyl cellulose adding 0.3 weight part stirs 1h, is dispersed into clear viscous solution.By the titanium dioxide of filler 12 weight part, the talcum powder of 5 weight parts, the diatomite of 6 weight parts, the calcium carbonate of 3.5 weight parts is distributed in solution respectively, adds the defoamer of 0.7 weight part, strong stirring 1h, move in conoidal mill and grind 2 ~ 3 times, be prepared into filler mill base.In the modified silicon fluorobenzene acrylic emulsion of 46 weight parts, add the sodium bicarbonate of 0.7 weight part simultaneously, the ethylene glycol of 3.2 weight parts, the film coalescence aid of 0.45 weight part, the flow agent of 0.2 weight part, strong stirring is even, adds filler mill base, adds the defoamer of 0.35 weight part, stir 1h, be namely prepared into coating.
The stability in storage of water proof anti-soil material obtained for embodiment 1,2,3,4, water-intake rate, dry/wet adhesion and erosion resistance time etc. are carried out performance test, and result is as shown in table 1 below.
Table 1
Coating of the present invention carries out modification by adding organosilicon to fluorine-containing benzene emulsion, fluosilicic modified synergic, not only can reduce costs, and styrene-acrylate emulsion coating can also be made to possess the feature of organosilicon and organic fluorine simultaneously, good antifouling effect, degree of adhesion are good, also have the advantage such as water tolerance, chemical resistant properties.
The above, it is only present pre-ferred embodiments, not technical scope of the present invention is imposed any restrictions, thus every above embodiment is done according to technical spirit of the present invention any trickle amendment, equivalent variations and modification, all still belong in the scope of technical solution of the present invention.
Claims (3)
1. a buildings waterproof antifouling paint, it is characterized in that, formed by the preparation of raw material of following weight part: deionized water 18-25 part, dispersion agent 0.15-0.25 part, sodium hydroxyethyl cellulose 0.2-0.3 part, titanium dioxide 7-12 part, talcum powder 3-5 part, diatomite 4-6 part, calcium carbonate 3.5-5 part, defoamer 3.5-5 part, sodium bicarbonate 0.6-0.8 part, ethylene glycol 2.2-3.2 part, film coalescence aid 0.4-0.6 part, flow agent 0.2-0.4 part, defoamer 0.2-0.4 part, modified silicon fluorobenzene acrylic emulsion 46-52 part;
Further, described modified silicon fluorobenzene acrylic emulsion is made up of the raw material of following weight part: deionized water 80-90 part, sodium lauryl sulphate 0.1-0.2 part, fatty alcohol-polyoxyethylene ether 0.1-0.18 part, sodium bicarbonate 0.5-0.8 part, lauryl mercaptan 0.5-0.8 part, ammonium persulfate solution 53-62 part, vinylbenzene 4-5 part, butyl acrylate 6.5-7.6 part, pre-emulsion 30-38 part;
Further, described pre-emulsion is made up of the raw material of following weight part: acrylic polyether phosphoric acid ester 2.5-4 part, deionized water 40-55 part, sodium lauryl sulphate 0.2-0.4 part, fatty alcohol-polyoxyethylene ether 0.2-0.4 part, vinylbenzene 45-50 part, butyl acrylate 60-62 part, vinyltriethoxysilane 8-8.2 part, Hexafluorobutyl mathacrylate 3.5-4 part.
2. buildings waterproof antifouling paint according to claim 1, is characterized in that, described ammonium persulfate solution massfraction is 2.3%, and the massfraction of described sodium hydroxide is 5%.
3. the preparation method of buildings waterproof antifouling paint according to claim 1, is characterized in that comprising the steps:
(1) the acrylic polyether phosphoric acid ester sodium hydroxide taking above-mentioned weight part is neutralized to pH=6.5, then the deionized water of above-mentioned weight part, sodium lauryl sulphate, fatty alcohol-polyoxyethylene ether is added in reactor, under agitation be warming up to 45 ~ 55 DEG C, again the mix monomer of the vinylbenzene of above-mentioned weight part, butyl acrylate, vinyltriethoxysilane, Hexafluorobutyl mathacrylate is slowly added in reactor, stir 30 ~ 50 minutes, obtain milky pre-emulsion;
(2) deionized water of above-mentioned weight part, emulsifying agent, sodium bicarbonate and lauryl mercaptan is added in the reactor successively, stir and be warming up to 80 ~ 90 DEG C, drip the mix monomer of the ammonium persulfate solution of above-mentioned weight part and vinylbenzene, butyl acrylate respectively, when blue light appears in emulsion at the bottom of dropwising bottle, be incubated and obtain seed emulsion in 15 minutes; Then be added drop-wise in seed emulsion by the ammonium persulfate solution of pre-emulsion and above-mentioned weight part respectively, 3 hours dropwise, and stir insulation 2 ~ 3 hours, use weak ammonia adjust ph to 6.5, filter discharging, be fluosilicic benzene emulsion after being down to room temperature;
(3) by the deionized water of above-mentioned weight part and dispersion agent dispersed with stirring uniformly solution, add thickening material and stir 1h, be dispersed into clear viscous solution, by the fillers dispersed of above-mentioned weight part in solution, add defoamer, strong stirring 1h, moves in conoidal mill and grinds 2 ~ 3 times, be prepared into filler mill base; In modified silicon fluorobenzene acrylic emulsion, add sodium bicarbonate, ethylene glycol, film coalescence aid, the flow agent of above-mentioned weight part, strong stirring is even, adds filler mill base, adds defoamer simultaneously, stirs 1h, is namely prepared into coating.
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| CN106398435A (en) * | 2016-11-17 | 2017-02-15 | 岳承华 | External wall elastic waterproof coating with modified soybean protein isolate capable of enhancing adhesion force |
| CN106590290A (en) * | 2016-11-17 | 2017-04-26 | 岳承华 | Sol-modified acrylate based waterproof elastic coating material for exterior walls |
| CN106634358A (en) * | 2016-11-17 | 2017-05-10 | 岳承华 | High-elasticity external wall coating with enhanced anti-corrosive performance of composite epoxy resin emulsion |
| CN106634360A (en) * | 2016-11-17 | 2017-05-10 | 岳承华 | Super-hydrophobic high-elastic emulsion used for water resistance of anti-freezing outer wall and having needle-like nano-alumina compounded with propylene glycol |
| CN106634359A (en) * | 2016-11-17 | 2017-05-10 | 岳承华 | Outer wall waterproof elastic acrylic coating with photocatalytic air purifying effect |
| CN106634361A (en) * | 2016-11-17 | 2017-05-10 | 岳承华 | Acrylic acid elastic waterproof outer wall coating with modified tea saponin fire retardant |
| CN106700800A (en) * | 2016-11-17 | 2017-05-24 | 岳承华 | Modified lanthanum hexaboride heat-insulating property enhanced exterior wall acrylic high-elasticity waterproof coating |
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| CN110734519A (en) * | 2019-11-13 | 2020-01-31 | 中国科学院兰州化学物理研究所 | low-surface-energy water-based self-polishing emulsion, preparation method thereof and low-surface-energy water-based self-polishing anti-drag antifouling paint |
| CN111826049A (en) * | 2020-07-23 | 2020-10-27 | 马鞍山市金韩防水保温工程有限责任公司 | Waterproof heat-insulation coating for building exterior wall and preparation method thereof |
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| CN105733371A (en) * | 2016-04-23 | 2016-07-06 | 陈斌 | Anti-seepage contamination-resistant paint for construction and preparation method thereof |
| CN106398435A (en) * | 2016-11-17 | 2017-02-15 | 岳承华 | External wall elastic waterproof coating with modified soybean protein isolate capable of enhancing adhesion force |
| CN106590290A (en) * | 2016-11-17 | 2017-04-26 | 岳承华 | Sol-modified acrylate based waterproof elastic coating material for exterior walls |
| CN106634358A (en) * | 2016-11-17 | 2017-05-10 | 岳承华 | High-elasticity external wall coating with enhanced anti-corrosive performance of composite epoxy resin emulsion |
| CN106634360A (en) * | 2016-11-17 | 2017-05-10 | 岳承华 | Super-hydrophobic high-elastic emulsion used for water resistance of anti-freezing outer wall and having needle-like nano-alumina compounded with propylene glycol |
| CN106634359A (en) * | 2016-11-17 | 2017-05-10 | 岳承华 | Outer wall waterproof elastic acrylic coating with photocatalytic air purifying effect |
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Application publication date: 20160203 |