CN103483941A - Development of super-weatherproof acid-resistant efficient waterproof elastic coating - Google Patents

Development of super-weatherproof acid-resistant efficient waterproof elastic coating Download PDF

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Publication number
CN103483941A
CN103483941A CN201310351716.1A CN201310351716A CN103483941A CN 103483941 A CN103483941 A CN 103483941A CN 201310351716 A CN201310351716 A CN 201310351716A CN 103483941 A CN103483941 A CN 103483941A
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China
Prior art keywords
proof
water
elastic
antiacid
highly effective
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Pending
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CN201310351716.1A
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Chinese (zh)
Inventor
董善刚
王伯凤
祝洒虎
张洪梅
李春波
张喆
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Qingdao Yiqun Paint Industry Group Co Ltd
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Qingdao Yiqun Paint Industry Group Co Ltd
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Priority to CN201310351716.1A priority Critical patent/CN103483941A/en
Publication of CN103483941A publication Critical patent/CN103483941A/en
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Abstract

The invention discloses development of a super-weatherproof acid-resistant efficient waterproof elastic coating. The coating comprises the following concrete components by weight ratio: 8-16% of water, 0.1-0.2% of multifunctional additive, 0.1-0.2% of wetting agent, 0.4-0.8% of dispersing agent, 0.3-0.6% of defoaming agent, 1.5-3.0% of propylene glycol, 16-20% of rutile titanium dioxide, 6-8% of precipitated barium sulphate, 5-8% of ground limestone, 3-5% of opaque polymer, 28-35% of fluorocarbon emulsion, 10-15% of elastic emulsion, 0.8-1.5% of Texanol, 0.5-1% of stain-resistant additive, 0.1-0.2% of corrosion remover, and 0.6-0.9% of thickener. The elastic coating has excellent weather resistance and acid rain resistance, and excellent fouling resistance, is non-toxic and environment-friendly, low in cost and simple to construct, protects the perfect decorative effect of a building, and plays a role of maintaining the magnificent appearance beauty.

Description

The development of super weather-proof antiacid highly effective water-proof elastic dope
Technical field the present invention relates to a kind of coating, and particularly a kind of protection for the skin surface and decoration, have super weather-proof, antiacid, stain resistant water-proof elastic dope, belongs to the chemistry painting industry technical field.
The current domestic whole elastic coating market of making a general survey of of background technology, most product is confined to possess snappiness, the feature of waterproof, and its weathering resistance and resistance to acid are poor.Because its weathering resistance is not strong, Acid Rain is poor, peel off in the wall surface coating integral body that causes apt to deteriorate of its paint film after rain drop erosion, or, because the difference of water ratio causes cracking or peels off, acid rain water just infiltrates metope the corrosion metope.These disadvantages that exist have at present had a strong impact on its protection to basic unit had and decorative effect.Therefore research has good contamination resistance, highly effective water-proof elastic dope significant of super weather-proof antiacid cun.
Summary of the invention the purpose of this invention is to provide a kind of super weather-proof antiacid highly effective water-proof elastic dope; this elastic coating not only has high-elastic waterproof; also there is the stain resistant performance; excellent weathering resistance and Acid Rain performance; tensile strength is good; can significantly improve the advantages such as cracking performance of body of wall, can protect the perfect decorative effect of buildings, play again lasting magnificent image appearance.
A kind of concrete component and part by weight of super weather-proof antiacid highly effective water-proof elastic dope are: water: 8-16%; Multifunctional assistant: 0.1-0.2%; Wetting agent: 0.1-0.2%; Dispersion agent: 0.4-0.8%; Defoamer: 0.3-0.6%; Propylene glycol: 1.5-3.0%; Rutile type Titanium Dioxide: 16-20%; Process white: 6-8%; Water-ground limestone: 5-8%; Opacifying polymers: 3-5%; Fluorine carbon emulsion: 28-35%; Elastic emulsion: 10-15%; Texanol:0.8-1.5%; Stain resistant auxiliary agent: 0.5-1%; Sanitas: 0.1-0.2%; Thickening material: 0.6-0.9%.
In general, the elasticity of elastic coating and the contamination resistance relation that is inversely proportional to, coating has lower contamination resistance under high-elastic state.The pollution channel of paint film mainly contains organism adhesion, electrostatic adhesion and imbedibility and pollutes.Filming of stain resistance excellence, from the angle that prevents from adhering to, hard, that anti-electrostatic effect good and surface smoothing has been considered to films, as the angle from resistant, the clean effect of hydrophilic film surface rainwater and surface uniform pollute and the rain mark that causes and non-the manifesting effect of spot have been considered to films.The present invention can form rigidity, the soap-free emulsion that contains special hydrophilic radical antistatic and surface smoothing is filmed, make paint film not only have snappiness also have antistatic, paint film is level and smooth, hydrophilic advantage, especially there is super weather-proof Acid Rain performance, thus make that elastic coating possesses that super-weathering resistance, Acid Rain are good, high-effective water-proof, have excellent water-resistance, the performance of stain resistant.
The 998FA fluorine carbon emulsion that the present invention uses, its organic fluorine element surpasses 6%, has splendid water tolerance, the weather resistance of overlength, anti-contamination, not xanthochromia.Have more the splendid performance of alkali resistant, Acid Rain, salt fog resistance.Paint film light, plentiful, good fluidity.
The elastic emulsion that the present invention uses is the soap-free emulsion containing special hydrophilic radical, there is again the performances such as excellent stain resistant in order to give the basic physical properties of filming, film coated surface is designed to wetting ability, its low temperature elasticity, sticking power is good, tensile strength is high, good with the color stuffing consistency, make the emulsion particle surface have effective hydrophilic functional group, thereby the water tolerance of making and wettability are simultaneously and deposit, and sticking power is good.
The Rutile type Titanium Dioxide that the titanium dioxide that the present invention uses is made for chlorination process, be characterized in having high gloss, fabulous color, opacifying power and dispersed and good exterior durability.Its performance and opacifying power, weathering resistance and the chalking resistance close relation of filming.
The dispersion agent that the present invention uses is low-molecular-weight polypropylene amine acid salt dispersion agent, can significantly improve concentration and the stability thereof of color stuffing dispersion pulp, by this dispersion agent, can surround a layer charge at the color stuffing particle surface, make repulsion mutually between particle, thereby reach the effect of stable slurry.
The Opacifying polymers that the present invention uses is the hollow polymer spheroid, can show extremely strong covering performance, improve coating contamination resistance (dirt pickup resistant), strengthen outdoor tint retention.
The stain resistant auxiliary agent that the present invention uses is for nano modification stain resistant auxiliary agent, and in the coating film process, nanoparticle plays the hinge point effect, and the organic polymer hinge of line style is reticulated to structure, improves film coated surface hardness; The pore dimension of filming by reduction, improve the smooth coating degree; By the reduction static charge of filming, reduce the absorption of atmospheric dust; Making to film possesses good self-cleaning, has improved the stain resistant performance of coating.
Thickening material used in the present invention mainly contains newton-type nonionic polyoxyalkylene class rheology modifier and alkali swelling class thickening material.
In general, fluorocarbon coating is used widely in the every field of building, chemical industry, electric appliance and electronic industry, mechanical industry, aerospace industry, household supplies, and effect is better.
Below embodiment, be one embodiment of the present of invention.
The composition of super weather-proof antiacid highly effective water-proof elastic dope of the present invention (weight percent) and production technique are: the stirring at low speed stage adds 10% deionized water according to order, 0.15% multifunctional assistant, 0.1% wetting agent, 0.55% poly amic acid dipersant, 0.25% defoamer, 2% propylene glycol, 18% titanium dioxide 595, 7% fineness 800 purpose process whites, 8% fineness 1250 purpose water-ground limestones enter the high-speed stirring stage after all adding, and after stirring, speed lapping, to fineness≤50um, then adds successively the fluorine carbon emulsion AP5085 of 30 parts under stirring at low speed, 12% elastic emulsion, 4% Opacifying polymers, 0.8% Texanol, 0.8% stain resistant auxiliary agent NM-1, 0.2% defoamer NXZ, 0.15% sanitas MV, 0.4% newton-type nonionic polyoxyalkylene class rheology modifier thickening material DSX2000 and 0.25% alkali swelling thickening material TT935,4% deionized water and stirring is even, then stirring at low speed 10min, then through check, filter, the packing of weighing.
Super weather-proof its indices of antiacid highly effective water-proof elastic dope of making according to the present invention all reaches the requirement of JG/T172-2005 about the elastic building paint defined, this elastic coating not only has excellent weathering resistance and Acid Rain performance, its water resistance, stain resistant performance are splendid, good tensile strength is good, can significantly improve the advantages such as cracking performance of body of wall.Asepsis environment-protecting, nuisanceless, cost is low, and construction is simple, and the multiple function of its super weather-proof antiacid highly effective water-proof elastic dope had both been protected the perfect decorative effect of buildings, played again lasting magnificent aesthetic appearance.

Claims (8)

1. concrete component and the part by weight of the development of super weather-proof antiacid highly effective water-proof elastic dope are: water: 8-16%; Multifunctional assistant: 0.1-0.2%; Wetting agent: 0.1-0.2%; Dispersion agent: 0.4-0.8%; Defoamer: 0.3-0.6%; Propylene glycol: 1.5-3.0%; Rutile type Titanium Dioxide: 16-20%; Process white: 6-8%; Water-ground limestone: 5-8%; Opacifying polymers: 3-5%; Fluorine carbon emulsion: 28-35%; Elastic emulsion: 10-15%; Texanol:0.8-1.5%; Stain resistant auxiliary agent: 0.5-1%; Sanitas: 0.1-0.2%; Thickening material: 0.6-0.9%.
2. super weather-proof antiacid highly effective water-proof elastic dope according to claim 1, it is characterized in that this elastic coating production stage is: add part water under stirring at low speed, multifunctional assistant, wetting agent, dispersion agent, the early stage defoamer, propylene glycol, titanium dioxide, process white, water-ground limestone, after being ground to slurry fineness≤50um after high speed dispersion, stirring at low speed adds fluorine carbon emulsion, elastic emulsion, Texanol, the later stage defoamer, sanitas, thickening material, the stain resistant auxiliary agent, excess water, after meeting the requirements of viscosity, stirring at low speed 10min again, again through check, filter, the packing of weighing.
3. super weather-proof antiacid highly effective water-proof elastic dope according to claim 1, is characterized in that its organic fluorine element of said 998FA fluorine carbon emulsion surpasses 6%, has splendid water tolerance, the weather resistance of overlength, anti-contamination, not xanthochromia.Have more the splendid performance of alkali resistant, Acid Rain, salt fog resistance.Paint film light, plentiful, good fluidity.
4. super weather-proof antiacid highly effective water-proof elastic dope according to claim 1, it is characterized in that said elastic emulsion, for low temperature elasticity, sticking power is good, tensile strength is high, good with the color stuffing consistency, make the emulsion particle surface have effective hydrophilic functional group, thereby the water tolerance of making and wettability while also deposit, and sticking power is good.
5. super weather-proof antiacid highly effective water-proof elastic dope according to claim 1, it is characterized in that said titanium dioxide is the Rutile type Titanium Dioxide that chlorination process is made, be characterized in thering is high gloss, fabulous color, opacifying power and dispersed and good exterior durability.
6. super weather-proof antiacid highly effective water-proof elastic dope according to claim 1, it is characterized in that said dispersion agent is low-molecular-weight polypropylene amine acid salt dispersion agent, can significantly improve concentration and the stability thereof of color stuffing dispersion pulp, by this dispersion agent, can surround a layer charge at the color stuffing particle surface, make repulsion mutually between particle, thereby reach the effect of stable slurry.
7. super weather-proof antiacid highly effective water-proof elastic dope according to claim 1, it is characterized in that said Opacifying polymers is the hollow polymer spheroid, can show extremely strong covering performance, improve coating contamination resistance (dirt pickup resistant), strengthen outdoor tint retention.
8. super weather-proof antiacid highly effective water-proof elastic dope according to claim 1, it is characterized in that said stain resistant auxiliary agent is nano modification stain resistant auxiliary agent, in the coating film process, nanoparticle plays the hinge point effect, the organic polymer hinge of line style is reticulated to structure, improve film coated surface hardness; The pore dimension of filming by reduction, improve the smooth coating degree; By the reduction static charge of filming, reduce the absorption of atmospheric dust; Making to film possesses good self-cleaning, has improved the stain resistant performance of coating.
CN201310351716.1A 2013-08-13 2013-08-13 Development of super-weatherproof acid-resistant efficient waterproof elastic coating Pending CN103483941A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104559592A (en) * 2014-12-19 2015-04-29 北京东方雨虹防水技术股份有限公司 Fluorocarbon elastic paint and preparation method thereof
CN105111801A (en) * 2015-08-25 2015-12-02 石海旺 Hydrophobic coating
CN105368219A (en) * 2015-12-22 2016-03-02 青岛博泰美联化工技术有限公司 Elastic coating for exterior walls of buildings
CN105419536A (en) * 2015-12-22 2016-03-23 青岛博泰美联化工技术有限公司 Elastic hydrophobic construction exterior wall coating
CN106046970A (en) * 2016-08-12 2016-10-26 安庆市七仙女电器制造有限公司 Anticorrosion coating for desk lamp and preparation method thereof
CN107365544A (en) * 2017-09-21 2017-11-21 苏州振振好新型建材科技有限公司 A kind of extra-weather-proof color inhibition elastic coating

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104559592A (en) * 2014-12-19 2015-04-29 北京东方雨虹防水技术股份有限公司 Fluorocarbon elastic paint and preparation method thereof
CN105111801A (en) * 2015-08-25 2015-12-02 石海旺 Hydrophobic coating
CN105368219A (en) * 2015-12-22 2016-03-02 青岛博泰美联化工技术有限公司 Elastic coating for exterior walls of buildings
CN105419536A (en) * 2015-12-22 2016-03-23 青岛博泰美联化工技术有限公司 Elastic hydrophobic construction exterior wall coating
CN106046970A (en) * 2016-08-12 2016-10-26 安庆市七仙女电器制造有限公司 Anticorrosion coating for desk lamp and preparation method thereof
CN107365544A (en) * 2017-09-21 2017-11-21 苏州振振好新型建材科技有限公司 A kind of extra-weather-proof color inhibition elastic coating

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Application publication date: 20140101