CN106634358A - High-elasticity external wall coating with enhanced anti-corrosive performance of composite epoxy resin emulsion - Google Patents

High-elasticity external wall coating with enhanced anti-corrosive performance of composite epoxy resin emulsion Download PDF

Info

Publication number
CN106634358A
CN106634358A CN201611010807.9A CN201611010807A CN106634358A CN 106634358 A CN106634358 A CN 106634358A CN 201611010807 A CN201611010807 A CN 201611010807A CN 106634358 A CN106634358 A CN 106634358A
Authority
CN
China
Prior art keywords
epoxy resin
parts
minutes
resin emulsion
coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201611010807.9A
Other languages
Chinese (zh)
Inventor
岳承华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201611010807.9A priority Critical patent/CN106634358A/en
Publication of CN106634358A publication Critical patent/CN106634358A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04—Homopolymers or copolymers of monomers containing silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a high-elasticity external wall coating with enhanced anti-corrosive performance of composite epoxy resin emulsion. The high-elasticity external wall coating is prepared from, by weight, 20-22 parts of methyl methacrylate, 29-31 parts of butyl acrylate, 8.5-9.5 parts of hexafluorobutyl acrylate, 4-5 parts of vinyl triethoxy silane, 0.1-0.12 part of ammonium persulfate, 2-3 parts of OP-1, proper amount of deionized water, proper amount of amino water, 1.5-2 parts of n-dodecanol ester, 8-10 parts of superfine kaoline, 3-4 parts of polyether polyol, 2-3 parts of epoxy resin, 7-8 parts of epoxy resin emulsion, and 1-2 parts of boron trifluoride diethyl etherate. The high-elasticity coating has water-based formula and is free from toxic and pollution, high in ductility, excellent in weather fastness, convenient to construct; the coating is especially suitable for the waterproof use of the external wall of the building engineering; the coating film is smooth and beautiful.

Description

A kind of enhanced elastic exterior wall paint of composite epoxy resin emulsion antiseptic property
Technical field
The present invention relates to technical field of coatings, more particularly to a kind of composite epoxy resin emulsion antiseptic property is enhanced high-elastic Property exterior coating.
Background technology
At present, an important development direction of building external paint is exactly energy-saving heat preserving, and the performance of finish coat emulsion is excellent The resistance to water of bad External Thermal Insulation Composite Systems, resistance to soiling, durability and temperature-change resistance have a direct impact relation, and wall body slit Rainwater and carbon dioxide invasion can be caused, cause steel bar corrosion, accelerate body of wall carbonization speed, building masonry wall crackle into One of common fault for impact construction engineering quality.Elastic building paint preferable extensibility because coating has, to a certain extent may be used The crack of basic unit's generation is resisted and covered, is favored by market.Conventional coating can not accomplish both there is excellent weatherability, resistance to Aqueous and resistance to soiling, and while with good elasticity, pliability and splitting resistance, so a kind of new high-performance of exploitation Elastic water proofing paint becomes an important topic of research external wall heat insulation system project.
《The research and its application of tenacity acrylic's water-repellent paint》By organic silicon monomer, organic fluorine monomer and third in one text Olefin(e) acid esters monomer carries out copolymerization, and using soap-free core-shell emulsion polymerization technique a kind of high performance fluorine fluorine-silicon modified acrylic bullet is prepared for Property emulsion, with good elasticity, water proofing property and resistance to soiling, but due to the development of building trade, need further externally Wall coating carries out the improvement of other additional properties, and needed for meet industry, this is accomplished by changing coating made by its emulsion Property.
The content of the invention
The object of the invention is exactly to make up the defect of prior art, there is provided a kind of composite epoxy resin emulsion antiseptic property Enhanced elastic exterior wall paint.
The present invention is achieved by the following technical solutions：
A kind of enhanced elastic exterior wall paint of composite epoxy resin emulsion antiseptic property, is prepared by the raw materials in： Methyl methacrylate 20-22, butyl acrylate 29-31, hexafluorobutyl acrylate 8.5-9.5, VTES 4-5, ammonium persulfate 0.1-0.12, OP-102-3, appropriate deionized water, appropriate ammoniacal liquor, Lauryl Alcohol ester 1.5-2, ultra-fine kaolinite Native 8-10, PPG 3-4, epoxy resin 2-3, epoxy resin latex 7-8, BFEE 1-2.
A kind of enhanced elastic exterior wall paint of the composite epoxy resin emulsion antiseptic property according to claims 1, It is prepared from by following concrete grammar：
（1）OP-10 is dissolved in the 35-30 times of deionized water measured, is stirred to after being completely dissolved with 200-300 rev/min of speed Methyl methacrylate, butyl acrylate are slowly added to, to be warming up to 80-85 after 800 revs/min of speed stirring 20-30 minutes DEG C insulation 15-20 minutes, ammonium persulfate is added, hexafluorobutyl acrylate and the ethoxy of vinyl three are slowly added dropwise after stirring The mixed liquor of base silane, time for adding is controlled in 2.5-3 hours, after dripping off, at 80-85 DEG C 60-90 minutes is incubated, and is cooled to 40 DEG C, it is 7-8 to adjust pH with ammoniacal liquor, then crosses 200 mesh sieves, obtains fluorinated silicone modified acrylic elastic emulsion；
（2）PPG is mixed with epoxy resin, 80-85 DEG C is heated to until both fully dissolvings, are subsequently adding trifluoro Change borate ether, under nitrogen protection, be heated to 100 DEG C, after stirring reaction 5-6 hour emulsifying agent is obtained；By epoxy resin latex with Mentioned emulsifier mixes, and with 600-800 rev/min of speed 60-90 minutes are stirred, and obtains composite epoxy resin emulsion；
（3）By step（1）（2）The product mixing for obtaining, adds appropriate amount of deionized water and remaining residual components, controls solid content For 68-70%, ball milling 40-60 minutes in ball mill are put into after stirring 15-20 minutes with 300-400 rev/min of speed, finally mistake 200 mesh sieves are obtained final product.
It is an advantage of the invention that：The present invention is introduced using core-shell emulsion polymerization technique in acrylic emulsion polymerization process Organosilicon and organic fluorin radical, reduce the surface energy of polymer, and good protective effect can be formed to matrix polymer segment, Its non-oxidizability is improved, while fluorine and silicon can be made to be enriched in coating surface after film forming, fluorine and silicon list in emulsion can be so reduced The consumption of body, neither reduce material cost does not reduce the combination property of coating again；Using coating temperature-change resistance made by its emulsion Greatly improved with durability, the film after film forming has extremely low surface energy, impart again the higher resistance to water of film, The performance such as oil resistivity and resistance to soiling；Coating made by the present invention has excellent outdoor decorative, long durability and temp. variation resistant Cracking behavior, can solve the problems, such as that conventional outer wall external thermal insulation emulsion system is easy to crack, come off and reduce service life.
The present invention carries out reaction and generates wax-like emulsifying agent by using epoxy resin and PPG, then again with epoxy Resin emulsion is compounded, and makes complex emulsions, in being added to the preparation of coating, the waterproof effect of coating is enhanced, while enhancing The weatherability and antiseptic property of coating；High elastic coating of the present invention, water prescription, nontoxic pollution-free, elongation percentage is high, weatherability Excellent, easy construction is particularly suitable for being used in architectural engineering external wall waterproof, film smooth and beautiful appearance.
Specific embodiment
The enhanced elastic exterior wall paint of a kind of composite epoxy resin emulsion antiseptic property, by following weight portion（Kilogram）'s Raw material is made：Methyl methacrylate 20, butyl acrylate 29, hexafluorobutyl acrylate 8.5, VTES 4, Ammonium persulfate 0.1, OP-10 2, appropriate deionized water, appropriate ammoniacal liquor, Lauryl Alcohol ester 1.5, ultrafine kaolin 8, polyether polyols Alcohol 3, epoxy resin 2, epoxy resin latex 7, BFEE 1.
A kind of enhanced elastic exterior wall paint of the composite epoxy resin emulsion antiseptic property according to claims 1, It is prepared from by following concrete grammar：
（1）OP-10 is dissolved in the deionized water of 35 times of amounts, is stirred to after being completely dissolved with 200 revs/min of speed and is slowly added to Methyl methacrylate, butyl acrylate, are warming up to 80 DEG C and are incubated 15 minutes after being stirred 20 minutes with 800 revs/min of speed, then Ammonium persulfate is added, the mixed liquor of hexafluorobutyl acrylate and VTES is slowly added dropwise after stirring, dripped Plus time control was at 2.5 hours, after dripping off, 60 minutes are incubated at 80 DEG C, cool to 40 DEG C, it is 7 to adjust pH with ammoniacal liquor, then 200 mesh sieves are crossed, fluorinated silicone modified acrylic elastic emulsion is obtained；
（2）PPG is mixed with epoxy resin, 80 DEG C is heated to until both fully dissolvings, are subsequently adding boron trifluoride Ether, under nitrogen protection, is heated to 100 DEG C, and stirring reaction obtains emulsifying agent after 5 hours；By epoxy resin latex and above-mentioned breast Agent mixes, and is stirred 60 minutes with 600 revs/min of speed, obtains composite epoxy resin emulsion；
（3）By step（1）（2）The product mixing for obtaining, adds appropriate amount of deionized water and remaining residual components, controls solid content For 68%, ball milling 40 minutes in ball mill are put into after stirring 15 minutes with 300 revs/min of speed, finally cross 200 mesh sieves and obtain final product.
The present embodiment coating is detected according to the requirement of JC/T 864-2008, after product is agitated, uniformly, without knot Block, solid content is more than 65%, and tensile strength is more than 1MPa, and elongation at break is more than 300%, meets professional standard.

Claims (2)

1. the enhanced elastic exterior wall paint of a kind of composite epoxy resin emulsion antiseptic property, it is characterised in that by following weight The raw material of part is made：Methyl methacrylate 20-22, butyl acrylate 29-31, hexafluorobutyl acrylate 8.5-9.5, vinyl Triethoxysilane 4-5, ammonium persulfate 0.1-0.12, OP-102-3, appropriate deionized water, appropriate ammoniacal liquor, Lauryl Alcohol ester 1.5-2, ultrafine kaolin 8-10, PPG 3-4, epoxy resin 2-3, epoxy resin latex 7-8, BFEE 1- 2。
2. the enhanced elastic exterior wall paint of a kind of composite epoxy resin emulsion antiseptic property according to claims 1, its It is characterised by, is prepared from by following concrete grammar：
（1）OP-10 is dissolved in the 35-30 times of deionized water measured, is stirred to after being completely dissolved with 200-300 rev/min of speed Methyl methacrylate, butyl acrylate are slowly added to, to be warming up to 80-85 after 800 revs/min of speed stirring 20-30 minutes DEG C insulation 15-20 minutes, ammonium persulfate is added, hexafluorobutyl acrylate and the ethoxy of vinyl three are slowly added dropwise after stirring The mixed liquor of base silane, time for adding is controlled in 2.5-3 hours, after dripping off, at 80-85 DEG C 60-90 minutes is incubated, and is cooled to 40 DEG C, it is 7-8 to adjust pH with ammoniacal liquor, then crosses 200 mesh sieves, obtains fluorinated silicone modified acrylic elastic emulsion；
（2）PPG is mixed with epoxy resin, 80-85 DEG C is heated to until both fully dissolvings, are subsequently adding trifluoro Change borate ether, under nitrogen protection, be heated to 100 DEG C, after stirring reaction 5-6 hour emulsifying agent is obtained；By epoxy resin latex with Mentioned emulsifier mixes, and with 600-800 rev/min of speed 60-90 minutes are stirred, and obtains composite epoxy resin emulsion；
（3）By step（1）（2）The product mixing for obtaining, adds appropriate amount of deionized water and remaining residual components, controls solid content For 68-70%, ball milling 40-60 minutes in ball mill are put into after stirring 15-20 minutes with 300-400 rev/min of speed, finally mistake 200 mesh sieves are obtained final product.
CN201611010807.9A 2016-11-17 2016-11-17 High-elasticity external wall coating with enhanced anti-corrosive performance of composite epoxy resin emulsion Withdrawn CN106634358A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611010807.9A CN106634358A (en) 2016-11-17 2016-11-17 High-elasticity external wall coating with enhanced anti-corrosive performance of composite epoxy resin emulsion

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611010807.9A CN106634358A (en) 2016-11-17 2016-11-17 High-elasticity external wall coating with enhanced anti-corrosive performance of composite epoxy resin emulsion

Publications (1)

Publication Number Publication Date
CN106634358A true CN106634358A (en) 2017-05-10

Family

ID=58807304

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611010807.9A Withdrawn CN106634358A (en) 2016-11-17 2016-11-17 High-elasticity external wall coating with enhanced anti-corrosive performance of composite epoxy resin emulsion

Country Status (1)

Country Link
CN (1) CN106634358A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107353779A (en) * 2017-08-17 2017-11-17 芜湖县双宝建材有限公司 A kind of anti-corrosion and high strength aqueous epoxide resin paint
CN109666377A (en) * 2018-12-31 2019-04-23 方少章 A kind of heat-resisting emulsified epoxy coating and preparation method thereof
CN111019453A (en) * 2019-10-31 2020-04-17 青川源泰建材科技有限公司 Environment-friendly waterproof coating and preparation method thereof
CN112251094A (en) * 2020-11-03 2021-01-22 徐洪涛 High-weather-resistance waterproof exterior wall coating for buildings and preparation method thereof
CN115029044A (en) * 2022-06-07 2022-09-09 安徽同益净化科技有限公司 Reinforced acid and alkali resistant coating for constructional engineering and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1486996A (en) * 2003-06-26 2004-04-07 江汉大学 Prepn process of modified styrene-acrylic emulsion
CN105295636A (en) * 2015-11-30 2016-02-03 桂林市和鑫防水装饰材料有限公司 Building waterproof antifouling paint and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1486996A (en) * 2003-06-26 2004-04-07 江汉大学 Prepn process of modified styrene-acrylic emulsion
CN105295636A (en) * 2015-11-30 2016-02-03 桂林市和鑫防水装饰材料有限公司 Building waterproof antifouling paint and preparation method thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107353779A (en) * 2017-08-17 2017-11-17 芜湖县双宝建材有限公司 A kind of anti-corrosion and high strength aqueous epoxide resin paint
CN109666377A (en) * 2018-12-31 2019-04-23 方少章 A kind of heat-resisting emulsified epoxy coating and preparation method thereof
CN111019453A (en) * 2019-10-31 2020-04-17 青川源泰建材科技有限公司 Environment-friendly waterproof coating and preparation method thereof
CN112251094A (en) * 2020-11-03 2021-01-22 徐洪涛 High-weather-resistance waterproof exterior wall coating for buildings and preparation method thereof
CN114163890A (en) * 2020-11-03 2022-03-11 徐洪涛 Preparation method of high-weather-resistance waterproof exterior wall coating for building
CN115029044A (en) * 2022-06-07 2022-09-09 安徽同益净化科技有限公司 Reinforced acid and alkali resistant coating for constructional engineering and preparation method thereof
CN115029044B (en) * 2022-06-07 2023-11-10 安徽同益净化科技有限公司 Acid and alkali resistant reinforced paint for building engineering and preparation method thereof

Similar Documents

Publication Publication Date Title
CN106634358A (en) High-elasticity external wall coating with enhanced anti-corrosive performance of composite epoxy resin emulsion
CN106590405B (en) A kind of low temperature resistant anti-cracking waterborne coating
CN109369094A (en) Polymer cement waterproof paint and its application method and preparation method thereof
CN104449154A (en) Water-based chromium-free fingerprint-resistant paint for galvanized steel plate
CN106433441B (en) A kind of water-fast environment protecting water-based paint
CN106752859A (en) A kind of water-fast knot water paint easy to stick
CN106752845A (en) A kind of polyurethane building coating
CN114213907A (en) Water-based rubber asphalt waterproof coating and preparation method thereof
CN105462479B (en) A kind of weather-proof self demixing single-component waterproof coating material of environment-friendly type and preparation method thereof
CN110218491A (en) A kind of water nano hollow glass microbead insulating mold coating and preparation method thereof
KR100882840B1 (en) The water-resistant paint composite and method of manufacturing the same
CN110857370A (en) Hydrophobic elastic waterproof coating and preparation method thereof
CN107603533A (en) Chromatic metallic watt water-and acrylate emulsion binding agent and preparation method thereof
CN106398435A (en) External wall elastic waterproof coating with modified soybean protein isolate capable of enhancing adhesion force
CN107286634A (en) The steady Weatherproof of one germplasm hits water-proof plugging material and preparation method thereof
CN111363500A (en) Vinyl acetate-acrylic emulsion adhesive for glass chopped strand mats and preparation method thereof
CN106700800A (en) Modified lanthanum hexaboride heat-insulating property enhanced exterior wall acrylic high-elasticity waterproof coating
CN113337196A (en) Water-based polyurethane waterproof coating with excellent heat insulation reflection performance and preparation method thereof
CN112708319A (en) Inorganic composite primer-topcoat integrated exterior wall coating and preparation method thereof
CN109608971B (en) Water-based exterior wall coating with temperature control and mildew resistance and preparation method thereof
CN106752597A (en) A kind of pitch compounds the enhanced polyacrylic water-proof elastic exterior coating material of diatomite anti-corrosion
CN106590318A (en) Marine anticorrosion metal coating
CN113861765B (en) Aramid fiber modified polymer cement waterproof coating and preparation method thereof
CN107721361B (en) Concrete protective terrace material and preparation method thereof
CN106634361A (en) Acrylic acid elastic waterproof outer wall coating with modified tea saponin fire retardant

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication
WW01 Invention patent application withdrawn after publication

Application publication date: 20170510