CN106590318A - Marine anticorrosion metal coating - Google Patents
Marine anticorrosion metal coating Download PDFInfo
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- CN106590318A CN106590318A CN201611148748.1A CN201611148748A CN106590318A CN 106590318 A CN106590318 A CN 106590318A CN 201611148748 A CN201611148748 A CN 201611148748A CN 106590318 A CN106590318 A CN 106590318A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/18—Condensation polymers of aldehydes or ketones with aromatic hydrocarbons or their halogen derivatives only
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to a marine anticorrosion metal coating. The marine anticorrosion metal coating comprises a coating matrix and an anti-icing adhesion emulsion, and the addition amount of the anti-icing adhesion emulsion is 26-28% of the weight of the coating matrix; and the coating matrix comprises, by weight, 14-16 parts of yttrium series rare earth micro-powder, 5-7 parts of ceramic micro-powder, 6-8 parts of silicon carbide, 2-3 parts of polyvinyl chloride, 6-8 parts of xylene formaldehyde resin, 1-2 parts of zinc citrate, 2.5-2.7 parts of epoxy resin, 3.3-3.5 parts of sodium sulfoxylate formaldehyde, 2.5-2.7 parts of butyl acetate and 3.6-3.8 parts of polymethyl methacrylate. The marine anticorrosion metal coating has excellent seawater corrosion resistance, can tolerate salt spray for 2200 h or above, can tolerate a 10% NaOH solution for 50 d or above, and can tolerate artificial seawater for 5100 h or above.
Description
Technical field
The invention belongs to technical field of coatings, and in particular to a kind of marine anticorrosion metallic paint.
Background technology
Marine anticorrosion is very high to the quality requirement of coating, typically requires that its protection period, at least in more than 10a, belongs to heavy antisepsis
Field.Anticorrosive paint is referred to can be applied and with the coating of long-acting service life under severe corrosive environment.Seawater is to coagulation
The nonmetallic corrosion such as soil is different to corrosion of metal, what it often started from internal corrosion.Uncoated privacy protection
In the seawater during use, the chemical mediator in seawater enters the micropore of inside concrete to the concrete of coating, wherein
Crystallization, can produce swelling stress, cause the rupture of concrete material, and chemical spalling；Simultaneously the salt branch in seawater is to mixed
Reinforcing bar in solidifying soil produces corrosion, makes concrete lose strong or spalling.
The content of the invention
The technical problem to be solved is：(1) how to make Marine Antifouling Paint that there is excellent resistance to corrosion seawater
Energy；(2) how the antifreeze and anti-anti-ice cover performance of waterproof of Marine Antifouling Paint is improved.
The present invention solves the technical scheme of above technical problem：
A kind of marine anticorrosion metallic paint, including coating matrix and anti-anti-ice cover attachment emulsion, anti-anti-ice cover adheres to emulsion
Addition is the 26-28% of coating matrix weight；The parts by weight of component of coating matrix includes：Rare earth yttrium micro mist 14-16 parts, pottery
Porcelain micro mist 5-7 parts, carborundum 6-8 parts, polyvinyl chloride 2-3 parts, xylene formaldehyde resin 6-8 parts, zinc citrate 1-2 parts, epoxy
Resin 2.5-2.7 parts, sodium sulfoxylate formaldehyde 3.3-3.5 parts, butyl acetate 2.5-2.7 parts, polymethyl methacrylate 3.6-3.8
Part；Anti- anti-ice cover adheres to the mass percent component of emulsion：4- isocyanatomethyls：6.3-6.5%, carbamic acid
Ethyl ester：14.6-14.8%, alpha-linolenic acid：2.6-2.8%, ethoxylated bisphenol A dimethylacrylates：1.3-1.5%, three hydroxyls
Trimethacrylate：2.5-2.7%, benzoyl peroxide：4.2-4.4%, butyl acrylate：1.6-1.8%,
2- hydroxyl -1,2- diphenylethans：2.7-2.9%, antimony doped stannum oxide nano-crystal：3.8-4%, nano titanium oxide：4.3-
4.5%, nanometer silicon carbide：1.1-1.3%, ethene-vinyl acetate：3.5-3.7%, polyoxyethylene aliphatic alcohol ether：3.3-
3.5%, dimethyl silicone polymer：1.8-2%, sodium salicylate：2.4-2.6%, adhesion promoter：7.3-7.5%, Organic fluoride
Waterproofing agent：Surplus.
The preparation of marine anticorrosion metallic paint of the present invention is comprised the following steps：
(i) with the weight portion of setting, by rare earth yttrium micro mist, ceramic, carborundum, polyvinyl chloride, dimethylbenzene formaldehyde tree
Fat, zinc citrate, epoxy resin, sodium sulfoxylate formaldehyde, butyl acetate, polymethyl methacrylate, in adding mixer, stirring
Speed is 200～400rpm, and mixing time is 10～30min, obtains coating matrix；
(ii) anti-anti-ice cover attachment emulsion each component is carried out into heating stirring by the weight portion of setting and is well mixed to obtain anti-anti-
Icing adheres to emulsion；Mixing speed is 100～300rpm, and mixing time is 20～40min, and heating-up temperature is 85-87 DEG C；
(iii) the proportioning that coating matrix and anti-anti-ice cover adhere to emulsion setting is mixed, is obtained the painting of marine anticorrosion metal
Material.
The invention has the beneficial effects as follows：Marine Antifouling Paint of the present invention has excellent sea water corrosion resistant, salt spray resistance
, up to more than 2200 hours, up to more than 50 days, resistance to artificial seawater performance was up to more than 5100 hours for the solution of resistance to 10%NaOH for property.
The marine anticorrosion metallic paint of the present invention contains anti-anti-ice cover attachment emulsion, and the coating of the present invention is coated in outer metallic surface
Afterwards, anti-anti-ice cover adheres to emulsion in the presence of outdoor ultraviolet light, and wherein polymer can occur secondary copolymerization and cross-linking reaction,
Cancellated diaphragm is generated, adhesion strength, strong peel strength and the tear of coating and outer metallic surface is greatly improved
Intensity, so as to solve the technical problem that anti-anti-ice cover attachment emulsion and outer metallic surface are difficult to combine, makes metal package mask
There are excellent water repellency, waterproof antifreeze and anti-anti-ice cover performance so as to still to keep premium properties during for rainy day cold environment；Root
According to test, the metal of the present invention is placed in heavy rain, water repellency is 4-5 times of common metal；The metal of the present invention is external
In subzero 1-15 DEG C of environment, outer metallic surface is not-easy-to-freeze after rainwater.In addition, in present invention attachment emulsion, Sb doped oxygen
Changing the addition of the compositions such as nanocrystalline tin, nano titanium oxide, nanometer silicon carbide energy makes outer metallic surface with antistatic well
Property and absorb thermal insulation, and with antimycotic antiseptic and soil resistance, moreover it is possible to improve its wear resistance, obtain unexpected technology
Effect.
Specific embodiment
Embodiment 1
The present embodiment is a kind of marine anticorrosion metallic paint, coating matrix and anti-anti-ice cover attachment emulsion, and anti-anti-ice cover is attached
Emulsion addition for the 26% of coating matrix weight.
The parts by weight of component of coating matrix includes：14 parts of rare earth yttrium micro mist, 5 parts of ceramic, 6 parts of carborundum, polychlorostyrene
2 parts of ethene, 6 parts of xylene formaldehyde resin, 1 part of zinc citrate, 2.5 parts of epoxy resin, 3.3 parts of sodium sulfoxylate formaldehyde, acetic acid fourth
2.5 parts of ester, 3.6 parts of polymethyl methacrylate.
Anti- anti-ice cover adheres to the mass percent component of emulsion：4- isocyanatomethyls：6.3%, amino first
Acetoacetic ester：14.6%, alpha-linolenic acid：2.6%, ethoxylated bisphenol A dimethylacrylates：1.3%, trimethylolpropane tris first
Base acrylate：2.5%, benzoyl peroxide：4.2%, butyl acrylate：1.6%, 2- hydroxyl -1,2- diphenylethans：
2.7%, antimony doped stannum oxide nano-crystal：3.8%, nano titanium oxide：4.3%, nanometer silicon carbide：1.1%, ethyl vinyl acetate
Ethene：3.5%, polyoxyethylene aliphatic alcohol ether：3.3%, dimethyl silicone polymer：1.8%, sodium salicylate：2.4%, adhesive force
Accelerator：7.3%, organic fluorine waterproof agent：Surplus.
The preparation of the present embodiment marine anticorrosion metallic paint is comprised the following steps：
(i) with the weight portion of setting, by rare earth yttrium micro mist, ceramic, carborundum, polyvinyl chloride, dimethylbenzene formaldehyde tree
Fat, zinc citrate, epoxy resin, sodium sulfoxylate formaldehyde, butyl acetate, polymethyl methacrylate, in adding mixer, stirring
Speed is 400rpm, and mixing time is 10min, obtains coating matrix；
(ii) anti-anti-ice cover attachment emulsion each component is carried out into heating stirring by the weight portion of setting and is well mixed to obtain anti-anti-
Icing adheres to emulsion；Mixing speed is 100rpm, and mixing time is 40min, and heating-up temperature is 85 DEG C；
(iii) the proportioning that coating matrix and anti-anti-ice cover adhere to emulsion setting is mixed, is obtained the painting of marine anticorrosion metal
Material.
Embodiment 2
The present embodiment is a kind of marine anticorrosion metallic paint, including coating matrix and anti-anti-ice cover attachment emulsion, anti-anti- to cover
Ice attachment emulsion addition is the 27% of coating matrix weight.
The parts by weight of component of coating matrix includes：15 parts of rare earth yttrium micro mist, 6 parts of ceramic, 7 parts of carborundum, polychlorostyrene
2.5 parts of ethene, 7 parts of xylene formaldehyde resin, 1.5 parts of zinc citrate, 2.6 parts of epoxy resin, 3.4 parts of sodium sulfoxylate formaldehyde, second
2.6 parts of acid butyl ester, 3.7 parts of polymethyl methacrylate.
Anti- anti-ice cover adheres to the mass percent component of emulsion：4- isocyanatomethyls：6.4%, amino first
Acetoacetic ester：14.7%, alpha-linolenic acid：2.7%, ethoxylated bisphenol A dimethylacrylates：1.4%, trimethylolpropane tris first
Base acrylate：2.6%, benzoyl peroxide：4.3%, butyl acrylate：1.7%, 2- hydroxyl -1,2- diphenylethans：
2.8%, antimony doped stannum oxide nano-crystal：3.9%, nano titanium oxide：4.4%, nanometer silicon carbide：1.2%, ethyl vinyl acetate
Ethene：3.6%, polyoxyethylene aliphatic alcohol ether：3.4%, dimethyl silicone polymer：1.9%, sodium salicylate：2.5%, adhesive force
Accelerator：7.4%, organic fluorine waterproof agent：Surplus.
The preparation of the present embodiment marine anticorrosion metallic paint is comprised the following steps：
(i) with the weight portion of setting, by rare earth yttrium micro mist, ceramic, carborundum, polyvinyl chloride, dimethylbenzene formaldehyde tree
Fat, zinc citrate, epoxy resin, sodium sulfoxylate formaldehyde, butyl acetate, polymethyl methacrylate, in adding mixer, stirring
Speed is 300rpm, and mixing time is 20min, obtains coating matrix；
(ii) anti-anti-ice cover attachment emulsion each component is carried out into heating stirring by the weight portion of setting and is well mixed to obtain anti-anti-
Icing adheres to emulsion；Mixing speed is 200rpm, and mixing time is 30min, and heating-up temperature is 86 DEG C；
(iii) the proportioning that coating matrix and anti-anti-ice cover adhere to emulsion setting is mixed, is obtained the painting of marine anticorrosion metal
Material.
Embodiment 3
The present embodiment is a kind of marine anticorrosion metallic paint, including coating matrix and anti-anti-ice cover attachment emulsion, anti-anti- to cover
Ice attachment emulsion addition is the 28% of coating matrix weight.
The parts by weight of component of coating matrix includes：16 parts of rare earth yttrium micro mist, 7 parts of ceramic, 8 parts of carborundum, polychlorostyrene
3 parts of ethene, 8 parts of xylene formaldehyde resin, 2 parts of zinc citrate, 2.7 parts of epoxy resin, 3.5 parts of sodium sulfoxylate formaldehyde, acetic acid fourth
2.7 parts of ester, 3.8 parts of polymethyl methacrylate.
Anti- anti-ice cover adheres to the mass percent component of emulsion：4- isocyanatomethyls：6.5%, amino first
Acetoacetic ester：14.8%, alpha-linolenic acid：2.8%, ethoxylated bisphenol A dimethylacrylates：1.5%, trimethylolpropane tris first
Base acrylate：2.7%, benzoyl peroxide：4.4%, butyl acrylate：1.8%, 2- hydroxyl -1,2- diphenylethans：
2.9%, antimony doped stannum oxide nano-crystal：4%, nano titanium oxide：4.5%, nanometer silicon carbide：1.3%, ethyl vinyl acetate second
Alkene：3.7%, polyoxyethylene aliphatic alcohol ether：3.5%, dimethyl silicone polymer：2%, sodium salicylate：2.6%, adhesive force promotes
Agent：7.5%, organic fluorine waterproof agent：Surplus.
The preparation of the present embodiment marine anticorrosion metallic paint is comprised the following steps：
(i) with the weight portion of setting, by rare earth yttrium micro mist, ceramic, carborundum, polyvinyl chloride, dimethylbenzene formaldehyde tree
Fat, zinc citrate, epoxy resin, sodium sulfoxylate formaldehyde, butyl acetate, polymethyl methacrylate, in adding mixer, stirring
Speed is 400rpm, and mixing time is 10min, obtains coating matrix；
(ii) anti-anti-ice cover attachment emulsion each component is carried out into heating stirring by the weight portion of setting and is well mixed to obtain anti-anti-
Icing adheres to emulsion；Mixing speed is 300rpm, and mixing time is 20min, and heating-up temperature is 87 DEG C；
(iii) the proportioning that coating matrix and anti-anti-ice cover adhere to emulsion setting is mixed, is obtained the painting of marine anticorrosion metal
Material.
The gained coating of embodiment 1 to 3 is put on and carry out on steel plate performance test, it is as a result as follows：
From result above, the coating that the present invention is provided has excellent sea water corrosion resistant, and salt fog resistance is reachable
More than 3200 hours, up to more than 50 days, resistance to artificial seawater performance was up to more than 5100 hours for the solution of resistance to 10%NaOH.
In addition to the implementation, the present invention can also have other embodiment.All employing equivalents or equivalent transformation shape
Into technical scheme, all fall within the protection domain of application claims.
Claims (4)
1. a kind of marine anticorrosion metallic paint, it is characterised in that：It is described anti-anti- including coating matrix and anti-anti-ice cover attachment emulsion
Icing attachment emulsion addition is the 26-28% of the coating matrix weight；
The parts by weight of component of the coating matrix includes：Rare earth yttrium micro mist 14-16 parts, ceramic 5-7 parts, carborundum 6-8
Part, polyvinyl chloride 2-3 parts, xylene formaldehyde resin 6-8 parts, zinc citrate 1-2 parts, epoxy resin 2.5-2.7 parts, formaldehyde time sulphur
Sour sodium 3.3-3.5 parts, butyl acetate 2.5-2.7 parts, polymethyl methacrylate 3.6-3.8 parts；
The mass percent component of the anti-anti-ice cover attachment emulsion is：4- isocyanatomethyls：6.3-6.5%, amino
Ethyl formate：14.6-14.8%, alpha-linolenic acid：2.6-2.8%, ethoxylated bisphenol A dimethylacrylates：1.3-1.5%, three hydroxyls
Trimethacrylate：2.5-2.7%, benzoyl peroxide：4.2-4.4%, butyl acrylate：1.6-1.8%, 2-
Hydroxyl -1,2- diphenylethans：2.7-2.9%, antimony doped stannum oxide nano-crystal：3.8-4%, nano titanium oxide：4.3-4.5%,
Nanometer silicon carbide：1.1-1.3%, ethene-vinyl acetate：3.5-3.7%, polyoxyethylene aliphatic alcohol ether：3.3-3.5%, poly dimethyl
Siloxanes：1.8-2%, sodium salicylate：2.4-2.6%, adhesion promoter：7.3-7.5%, organic fluorine waterproof agent：Surplus.
2. marine anticorrosion metallic paint as claimed in claim 1, it is characterised in that：Including coating matrix and the attachment of anti-anti-ice cover
Emulsion, the anti-anti-ice cover attachment emulsion addition is the 26% of the coating matrix weight；
The parts by weight of component of the coating matrix includes：14 parts of rare earth yttrium micro mist, 5 parts of ceramic, 6 parts of carborundum, polychlorostyrene
2 parts of ethene, 6 parts of xylene formaldehyde resin, 1 part of zinc citrate, 2.5 parts of epoxy resin, 3.3 parts of sodium sulfoxylate formaldehyde, acetic acid fourth
2.5 parts of ester, 3.6 parts of polymethyl methacrylate；
The mass percent component of the anti-anti-ice cover attachment emulsion is：4- isocyanatomethyls：6.3%, carbamic acid
Ethyl ester：14.6%, alpha-linolenic acid：2.6%, ethoxylated bisphenol A dimethylacrylates：1.3%, trimethylol propane trimethyl third
Olefin(e) acid ester：2.5%, benzoyl peroxide：4.2%, butyl acrylate：1.6%, 2- hydroxyl -1,2- diphenylethans：2.7%, antimony is mixed
Miscellaneous stannum oxide nano-crystal：3.8%, nano titanium oxide：4.3%, nanometer silicon carbide：1.1%, ethene-vinyl acetate：3.5%, polyoxy
Ethene fatty alcohol ether：3.3%, dimethyl silicone polymer：1.8%, sodium salicylate：2.4%, adhesion promoter：7.3%, Organic fluoride
Waterproofing agent：Surplus.
3. marine anticorrosion metallic paint as claimed in claim 1, it is characterised in that：Including coating matrix and the attachment of anti-anti-ice cover
Emulsion, the anti-anti-ice cover attachment emulsion addition is the 27% of the coating matrix weight；
The parts by weight of component of the coating matrix includes：15 parts of rare earth yttrium micro mist, 6 parts of ceramic, 7 parts of carborundum, polychlorostyrene
2.5 parts of ethene, 7 parts of xylene formaldehyde resin, 1.5 parts of zinc citrate, 2.6 parts of epoxy resin, 3.4 parts of sodium sulfoxylate formaldehyde, second
2.6 parts of acid butyl ester, 3.7 parts of polymethyl methacrylate；
The mass percent component of the anti-anti-ice cover attachment emulsion is：4- isocyanatomethyls：6.4%, carbamic acid
Ethyl ester：14.7%, alpha-linolenic acid：2.7%, ethoxylated bisphenol A dimethylacrylates：1.4%, trimethylol propane trimethyl third
Olefin(e) acid ester：2.6%, benzoyl peroxide：4.3%, butyl acrylate：1.7%, 2- hydroxyl -1,2- diphenylethans：2.8%, antimony is mixed
Miscellaneous stannum oxide nano-crystal：3.9%, nano titanium oxide：4.4%, nanometer silicon carbide：1.2%, ethene-vinyl acetate：3.6%, polyoxy
Ethene fatty alcohol ether：3.4%, dimethyl silicone polymer：1.9%, sodium salicylate：2.5%, adhesion promoter：7.4%, Organic fluoride
Waterproofing agent：Surplus.
4. marine anticorrosion metallic paint as claimed in claim 1, it is characterised in that：Including coating matrix and the attachment of anti-anti-ice cover
Emulsion, the anti-anti-ice cover attachment emulsion addition is the 28% of the coating matrix weight；
The parts by weight of component of the coating matrix includes：16 parts of rare earth yttrium micro mist, 7 parts of ceramic, 8 parts of carborundum, polychlorostyrene
3 parts of ethene, 8 parts of xylene formaldehyde resin, 2 parts of zinc citrate, 2.7 parts of epoxy resin, 3.5 parts of sodium sulfoxylate formaldehyde, acetic acid fourth
2.7 parts of ester, 3.8 parts of polymethyl methacrylate；
The mass percent component of the anti-anti-ice cover attachment emulsion is：4- isocyanatomethyls：6.5%, carbamic acid
Ethyl ester：14.8%, alpha-linolenic acid：2.8%, ethoxylated bisphenol A dimethylacrylates：1.5%, trimethylol propane trimethyl third
Olefin(e) acid ester：2.7%, benzoyl peroxide：4.4%, butyl acrylate：1.8%, 2- hydroxyl -1,2- diphenylethans：2.9%, antimony is mixed
Miscellaneous stannum oxide nano-crystal：4%, nano titanium oxide：4.5%, nanometer silicon carbide：1.3%, ethene-vinyl acetate：3.7%, polyoxy
Ethene fatty alcohol ether：3.5%, dimethyl silicone polymer：2%, sodium salicylate：2.6%, adhesion promoter：7.5%, Organic fluoride is prevented
Aqua：Surplus.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611148748.1A CN106590318A (en) | 2016-12-13 | 2016-12-13 | Marine anticorrosion metal coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611148748.1A CN106590318A (en) | 2016-12-13 | 2016-12-13 | Marine anticorrosion metal coating |
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| CN106590318A true CN106590318A (en) | 2017-04-26 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201611148748.1A Pending CN106590318A (en) | 2016-12-13 | 2016-12-13 | Marine anticorrosion metal coating |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113150655A (en) * | 2021-05-26 | 2021-07-23 | 河北道融管道设备制造有限公司 | High-performance seawater-resistant antifouling corrosion-resistant liquid coating for marine equipment engineering |
| CN113667364A (en) * | 2021-08-20 | 2021-11-19 | 中烯新材料(福建)股份有限公司 | Anticorrosive weather-resistant coating for offshore wind power generation |
| CN115109480A (en) * | 2022-07-25 | 2022-09-27 | 江苏海晟涂料有限公司 | High-performance middle coating for metal surface |
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| CN106149658A (en) * | 2016-08-25 | 2016-11-23 | 江苏大津重工有限公司 | A kind of jack up broken stone pile offshore engineering platform leg and processing technology thereof |
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|---|---|---|---|---|
| WO2007102587A1 (en) * | 2006-03-09 | 2007-09-13 | Chugoku Marine Paints, Ltd. | High-solid anticorrosive coating composition |
| CN104962121A (en) * | 2015-07-01 | 2015-10-07 | 赵志海 | High-temperature-resistant and anticorrosive composite ceramic coating |
| CN105176286A (en) * | 2015-08-18 | 2015-12-23 | 苏州赛斯德工程设备有限公司 | Preparation method for marine anticorrosive paint |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113150655A (en) * | 2021-05-26 | 2021-07-23 | 河北道融管道设备制造有限公司 | High-performance seawater-resistant antifouling corrosion-resistant liquid coating for marine equipment engineering |
| CN113667364A (en) * | 2021-08-20 | 2021-11-19 | 中烯新材料(福建)股份有限公司 | Anticorrosive weather-resistant coating for offshore wind power generation |
| CN115109480A (en) * | 2022-07-25 | 2022-09-27 | 江苏海晟涂料有限公司 | High-performance middle coating for metal surface |
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Application publication date: 20170426 |