CN104370498A - Building waterproof agent - Google Patents
Building waterproof agent Download PDFInfo
- Publication number
- CN104370498A CN104370498A CN201410491375.2A CN201410491375A CN104370498A CN 104370498 A CN104370498 A CN 104370498A CN 201410491375 A CN201410491375 A CN 201410491375A CN 104370498 A CN104370498 A CN 104370498A
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- CN
- China
- Prior art keywords
- parts
- stearate
- building
- waterproof agent
- clay
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Sealing Material Composition (AREA)
Abstract
The present invention provides a safe and non-toxic building waterproof agent, and belongs to the field of building additives. The building waterproof agent of the present invention comprises, by weight, 40-70 parts of an acrylic acid emulsion, 1-5 parts of polyvinyl alcohol amine, 5-10 parts of clay, 5-10 parts of calcium stearate, 2-7 parts of ammonium stearate, 1-5 parts of aluminum stearate, 3-5 parts of calcium fluoride, 1-5 parts of dimethyl silicone oil, 1-2 parts of vinyltrimethoxysilane, 1-2 parts of sodium methyl acryl sulfonate, and 6-20 parts of deionized water. The preparation method comprises: uniformly mixingan an acrylic acid emulsion, polyvinyl alcohol amine, clay, calcium stearate, ammonium stearate, aluminum stearate, calcium fluoride and sodium methyl acryl sulfonate to obtain a mixture, heating to a temperature of 30-50 DEG C, stirring dimethyl silicone oil, vinyltrimethoxysilane and deionized water to obtain a mixed material, and slowly adding the mixed material to the mixture. The building waterproof agent of the present invention has characteristics of inexpensive raw materials, simple preparation method and significant waterproof effect.
Description
Technical field
The present invention relates to a kind of waterproof agent for building be made up of organism, belong to the admixture of material of construction.
Background technology
The important component part of construction work during buildings waterproof, in this year, buildings waterproof problem receives the concern of the country and people especially day by day.Exploitation waterproof novel material is a new problem of Building technology personnel.The advantage of water-proof material to improve density and the impermeability of concrete or mortar, and cost is low, does not substantially increase executive cost.Waterproof type water-resisting agent provides effective sealing and no matter is liquid or the moisture of gaseous state, it by substrate surface or near.
Traditional water-proof material such as pitch adds malthoid, exist easily aging, the life-span is short, difficulty of construction is large, high in cost of production shortcoming.But the complex regions such as modified bituminous pitch coiled material, APP, SBS coiled material, BBI mortar water-proof material are not easily constructed, ageing-resistant, water tolerance is bad.
At present, water-resisting agent has become the important application of aqueous polymer modified cement-based material.In numerous water-resisting agent kind, waterproofing agent of organosilicon is extensively promoted in buildings waterproof owing to having excellent hydrophober, antifouling, weathering resistance and endurance quality.It directly can mix in sand-cement slurry or concrete with the aqueous solution or emulsion form and make water-resisting agent, produces Chemical bond, forms firmly integral rigidity waterproof, improve concrete water-repellancy weathering resistance and endurance quality with concrete surface.
The water-based organic silicon waterproof agent of current building field widespread use mainly contains Methyl-CpG binding proteins and the large class of containing hydrogen silicone oil emulsion two, and is mainly used in the surface treatment of base material, is formed directly mix in cement concrete with water-based.The former can make cement concrete rapid hardening too by force at alkalescence, even if still very large on the setting and harden impact of cement concrete with modification in passing through; The latter can produce a large amount of hydrogen and foam in the alkaline environment of cement concrete, can not use.Alkoxyalkyl silicon and modified compound thereof have active reactive group, react, are attached on cement concrete securely, thus greatly improve its water-repellancy and weather resistance under catalyst action with grout or concrete.
Alkoxyalkyl silicon has very large delayed coagulation to sand-cement slurry.The intensity of waterproof mortar is high, and the space of mortar concrete reduces, and space refinement, has more excellent waterproof effect, the problem that gross porosity refinement also makes water-repellancy under higher aliphatic acids water-resisting agent Long term immersion reduce be improved significantly.
Waterproof paint of the present invention is mainly applicable to the anticorrosion of the nontoxic environment such as tap water water factory, is specially adapted to industry and the protection of sewage treatment plants concrete structure, the protection of water pipe, provide protection are lasting.
The invention provides that one is prepared simply, construction technology is easy, cost is low, and ageing-resistant, that waterproof, cohesiveness are good waterproof agent for building.
For a high-effect water-proof agent for construction work, containing organosilicon-modified acrylate 14 ~ 30%, inorganic calcium salt 2 ~ 3%, inorganic molysite or inorganic ferrous salt 2 ~ 3%, inorganic potassium salt 2% ~ 3%, pH value regulate 0.05 ~ 1%, and surplus is water.
Summary of the invention
The invention provides a kind of waterproof agent for building, it is mainly made up of following parts by weight of component: ACRYLIC EMULSION 40 ~ 70 parts, polyethylene hydramine 1 ~ 5 part, clay 5 ~ 10 parts, calcium stearate 5 ~ 10 parts, hard aliphatic ammonium 2 ~ 7 parts, 1 ~ 5 part, stearic fat aluminium, 3 ~ 5 parts, Calcium Fluoride (Fluorspan), dimethyl silicone oil 1 ~ 5 part, vinyltrimethoxy silane 1 ~ 2 part, methylpropene sodium sulfonate 1 ~ 2 part, deionized water 6 ~ 20 parts.
Waterproof agent for building of the present invention, it forms primarily of following parts by weight of component: ACRYLIC EMULSION 50 ~ 60 parts, polyethylene hydramine 1 ~ 3 part, clay 7 ~ 10 parts, calcium stearate 5 ~ 7 parts, hard aliphatic ammonium 2 ~ 5 parts, 1 ~ 3 part, stearic fat aluminium, 3 ~ 5 parts, Calcium Fluoride (Fluorspan), dimethyl silicone oil 1 ~ 3 part, vinyltrimethoxy silane 1 ~ 2 part, methylpropene sodium sulfonate 1 ~ 2 part, deionized water 10 ~ 20 parts.
Waterproof agent for building of the present invention, it forms primarily of following parts by weight of component: ACRYLIC EMULSION 55 parts, polyethylene hydramine 2 parts, clay 8 parts, calcium stearate 6 parts, hard aliphatic ammonium 3 parts, 2 parts, stearic fat aluminium, 4 parts, Calcium Fluoride (Fluorspan), dimethyl silicone oil 2 parts, vinyltrimethoxy silane 1 part, methylpropene sodium sulfonate 1 ~ 2 part, deionized water 15 parts.
Another object of the present invention is the preparation method of waterproof agent for building, the propylene lactate buffer solution of above-mentioned weight part, polyethylene hydramine, clay, calcium stearate, ammonium stearate, aluminum stearate, Calcium Fluoride (Fluorspan) and methylpropene sodium sulfonate are mixed to obtain mixture, and be heated to 30 ~ 50 DEG C, then namely obtain water-resisting agent by slowly dropping in said mixture after dimethyl silicone oil, vinyl trimethyl oxosilane and deionized water and stirring.
advantage of the present invention:
Present invention process is simple, easy to operate, the reaction times is short.In the present invention, the raw material of water-resisting agent is easy to get, and cheap, and preparation method is simple, so cost is low; Water-resisting agent easy construction of the present invention, only need stir, and brushing evenly, just can reach waterproof object; Can construct without open fire as long as water-resisting agent of the present invention has certain water-soluble, humidity, processing requirement is low; Water-resisting agent of the present invention is good, generally high temperature resistant reach 80 DEG C, low temperature resistantly reach-20 DEG C, high temperature trickling and cold cracking phenomenon can not be there is after construction; Water-resisting agent of the present invention can be constructed under normal temperature condition, greatly improves the work situation of workman, reduces labor intensity; Water-resisting agent cohesive strength of the present invention is high, for chapping, crack, the sand-cement slurry of weathering or dusting, after brushing, reaches and does not ftracture, do not fall slag, waterproof; In addition the raw material of above-mentioned water-resisting agent is all pollution-free, transportation safety, convenience.
Contriver is from the operation of actual factory, and the equipment wherein related to and condition should not be construed as restriction of the present invention.Those of ordinary skill in the art, according to such scheme, can also make various forms of amendment, replacement, change.Every amendment, replacement and change done based on above-mentioned technological thought all belongs to protection scope of the present invention.
Embodiment
The composition of waterproof agent for building
The water-resisting agent being made up of preparation above-mentioned raw materials through freezing and after thawing quality product constant, can acidproof, alkaline-resisting, ethanol-tolerant, nontoxicity.After buildings top layer is handled well, difficult drop-off, not affected by environment, thus long service life, can effectively prevent top layer from leaking, seep water, water resistance can to more than 99%.Formula of the present invention is reasonable, and production cost is low, and preparation method is simple, can be widely used in architectural top waterproof, leakproof, impermeable, also can be used for existingly in buildings leaking, the process at the hidden danger that seeps water place.
Claims (4)
1. a waterproof agent for building, is characterized in that: it is made up of the component of following weight part: ACRYLIC EMULSION 40 ~ 70 parts, polyethylene hydramine 1 ~ 5 part, clay 5 ~ 10 parts, calcium stearate 5 ~ 10 parts, hard aliphatic ammonium 2 ~ 7 parts, 1 ~ 5 part, stearic fat aluminium, 3 ~ 5 parts, Calcium Fluoride (Fluorspan), dimethyl silicone oil 1 ~ 5 part, vinyltrimethoxy silane 1 ~ 2 part, methylpropene sodium sulfonate 1 ~ 2 part, deionized water 6 ~ 20 parts.
2. a waterproof agent for building, is characterized in that: it is made up of the component of following weight part: ACRYLIC EMULSION 50 ~ 60 parts, polyethylene hydramine 1 ~ 3 part, clay 7 ~ 10 parts, calcium stearate 5 ~ 7 parts, hard aliphatic ammonium 2 ~ 5 parts, 1 ~ 3 part, stearic fat aluminium, 3 ~ 5 parts, Calcium Fluoride (Fluorspan), dimethyl silicone oil 1 ~ 3 part, vinyltrimethoxy silane 1 ~ 2 part, methylpropene sodium sulfonate 1 ~ 2 part, deionized water 10 ~ 20 parts.
3. a waterproof agent for building, is characterized in that: it is made up of the component of following weight part: ACRYLIC EMULSION 55 parts, polyethylene hydramine 2 parts, clay 8 parts, calcium stearate 6 parts, hard aliphatic ammonium 3 parts, 2 parts, stearic fat aluminium, 4 parts, Calcium Fluoride (Fluorspan), dimethyl silicone oil 2 parts, vinyltrimethoxy silane 1 part, methylpropene sodium sulfonate 1 ~ 2 part, deionized water 15 parts.
4. the preparation method of the waterproof agent for building as described in claim 1 ~ 3, it is characterized in that: the propylene lactate buffer solution of above-mentioned weight part, polyethylene hydramine, clay, calcium stearate, ammonium stearate, aluminum stearate, Calcium Fluoride (Fluorspan) and methylpropene sodium sulfonate are mixed and be heated to 30 ~ 50 DEG C mixture, then slowly drop into after dimethyl silicone oil, vinyl trimethyl oxosilane and deionized water and stirring in said mixture.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201410491375.2A CN104370498A (en) | 2014-09-24 | 2014-09-24 | Building waterproof agent |
Applications Claiming Priority (1)
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CN201410491375.2A CN104370498A (en) | 2014-09-24 | 2014-09-24 | Building waterproof agent |
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CN104370498A true CN104370498A (en) | 2015-02-25 |
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CN201410491375.2A Pending CN104370498A (en) | 2014-09-24 | 2014-09-24 | Building waterproof agent |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104529234A (en) * | 2014-12-11 | 2015-04-22 | 青岛佰众化工技术有限公司 | Water-proof agent for building |
CN106007464A (en) * | 2016-05-16 | 2016-10-12 | 江苏苏博特新材料股份有限公司 | Concretecorrosive medium transmission inhibiting material and preparing method and application thereof |
CN106810160A (en) * | 2017-01-22 | 2017-06-09 | 北京朗坤防水材料有限公司 | Cement-base infiltration crystallization waterproofing agent and preparation method thereof |
CN110482904A (en) * | 2019-09-16 | 2019-11-22 | 广州泰祥实业新材料科技(新丰)有限公司 | Surface modifier, the modification multi-metallic minerals for the anti-water resistance tide of cement products, compound additive and preparation method thereof |
CN114014583A (en) * | 2021-11-19 | 2022-02-08 | 广西筑园建材有限公司 | Multifunctional concrete waterproofing agent and preparation method thereof |
-
2014
- 2014-09-24 CN CN201410491375.2A patent/CN104370498A/en active Pending
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104529234A (en) * | 2014-12-11 | 2015-04-22 | 青岛佰众化工技术有限公司 | Water-proof agent for building |
CN106007464A (en) * | 2016-05-16 | 2016-10-12 | 江苏苏博特新材料股份有限公司 | Concretecorrosive medium transmission inhibiting material and preparing method and application thereof |
CN106007464B (en) * | 2016-05-16 | 2018-05-04 | 江苏苏博特新材料股份有限公司 | The transmission of concrete corrosion medium suppresses material and its preparation method and application |
CN106810160A (en) * | 2017-01-22 | 2017-06-09 | 北京朗坤防水材料有限公司 | Cement-base infiltration crystallization waterproofing agent and preparation method thereof |
CN110482904A (en) * | 2019-09-16 | 2019-11-22 | 广州泰祥实业新材料科技(新丰)有限公司 | Surface modifier, the modification multi-metallic minerals for the anti-water resistance tide of cement products, compound additive and preparation method thereof |
CN110482904B (en) * | 2019-09-16 | 2021-12-10 | 广州泰祥混凝土外加剂有限公司 | Surface modifier, modified polymetallic mineral for preventing water and moisture of cement product and composite additive |
CN114014583A (en) * | 2021-11-19 | 2022-02-08 | 广西筑园建材有限公司 | Multifunctional concrete waterproofing agent and preparation method thereof |
CN114014583B (en) * | 2021-11-19 | 2022-12-16 | 广西筑园建材有限公司 | Multifunctional concrete waterproofing agent and preparation method thereof |
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Application publication date: 20150225 |
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