CN103601453B - Multifunctional concentrated material used for preparing kitchen and bath cement-based waterproof material - Google Patents
Multifunctional concentrated material used for preparing kitchen and bath cement-based waterproof material Download PDFInfo
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- CN103601453B CN103601453B CN201310525123.2A CN201310525123A CN103601453B CN 103601453 B CN103601453 B CN 103601453B CN 201310525123 A CN201310525123 A CN 201310525123A CN 103601453 B CN103601453 B CN 103601453B
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Abstract
The invention relates to a multifunctional concentrated material used for preparing a kitchen and bath cement-based waterproof material. The multifunctional concentrated material is composed of waste rubber powder, a silane coupling agent, alcohol blend, high-alumina cement, redispersible latex powder, cellulose ether, a delayed coagulant, a coagulation accelerator, a water reducer, an anti-freezing agent (added in winter), and a water repellent, and is a one-component material. The cement-based waterproof material is prepared by mixing the multifunctional concentrated material with cement and quartz powder; is used for kitchen and bath waterproof construction; possesses both excellent characteristics of waterproofing coatings and waterproof mortars, and excellent waterproof performance, so that waterproof effect can be achieved just by a thin coating layer in construction; and also possesses excellent rigidity which is convenient for paving of tiling in following procedures, and is suitable for waterproofing of waterward sides and water lee sides. Addition of waste rubber powder is capable of reducing density of the polymer cement waterproof material, increasing spreading rate of waterproof coatings, changing waste into valuables, and realizing recycling of resources.
Description
Technical field
The present invention relates to a kind of concentrate feed of water-proof material, particularly the multi-functional concentrate feed of a kind of kitchen guarding's cement group water-proofing material, belongs to the water-proof material technical field in building trade.
Background technology
Water-proof material is a kind of important materials in construction safety field, is mainly divided into waterproof roll and the large class of waterproof paint two.Polymer cement waterproof paint is a kind of organic liquid material with the polymer emulsions such as polyacrylate dispersion, ethylene-vinyl acetate copolymer emulsion and various additive composition, and the inorganic powder that the mineral filler such as cement, quartz sand, light water-ground limestone and various additive form is by rational proportion, the two components of compounded one, aqueous architectural waterproof paint.Polymer cement waterproof paint be best suited for non-exposure roofing, lavatory bathe between and the waterproof of exterior wall, anti-ly blend moistureproof engineering.
The water-proof material that is applied to kitchen guarding's waterproof construction requires water resistance excellence, good environmental protection.Polymer cement waterproof material has been taken into account the snappiness of polymkeric substance and the weather resistance of cement material, hard and soft combination, and extensively obtain application with the feature of its aqueous, environmental protective.The traditional polymer cement waterproofing material that is applied at present kitchen guarding mainly comprises: flexible excellent polymer cement waterproof paint and partially rigidity are the main large class of polymer cement waterproof mortar two.Polymer cement waterproof paint hydrophobic nature is strong, flexible excellent, but exists the later stage to be difficult to paving ceramic tile, cannot carry out the defect of back side waterproof; Polymer cement waterproof mortar excellent rigidity, but water proof anti-seepage effect is poor, conventionally requires water-proof coating thickness thicker (2cm left and right), for kitchen guarding's construction, has the defect that easily makes kitchen guarding's volume diminish.In addition, traditional cement group water-proofing material is in the majority with two components (powder, liquid separately packaging), has complex manufacturing, and liquid material was easily frozen and caused breakdown of emulsion winter, cannot transport, the defect such as shops's display, use.
In the existing relevant report of cement group water-proofing material that relates to kitchen guarding's waterproofing work, above-mentioned defect still fails to obtain basic overcoming.As patent CN101891432 B discloses a kind of penetration crystallization type water proofing paint, by silicate cement, quartz sand, filler, ionic calcium cpd, crystalline deposit agent, complexing auxiliary agent, film coalescence aid, complexing agent, polycarboxylic acids dehydragent, methylcellulose gum composition, this product is by growing and do not dissolve crystal in concrete surface pore and tiny crack, capillary porosity duct and tiny crack are stopped up, thereby improve concrete anti-permeability performance, reach waterproof, the object of leak stopping, though the waterproof paint of this type can obtain good waterproof effect, but its flexibility is poor, patent CN 1952030 B disclose a kind of double-composition polyurethane waterproof paint, described A component comprises: three kinds of polyethers (3050#, 220#, 210#), TDI, softening agent, B component comprises: tenderizer (liquid petroleum resin), inorganic powder (cement, flyash, talcum powder, dicalcium powder, zinc oxide, lime powder), mixed solution (water and nonionogenic tenside), Namigai, its preparation method is including preparing the step performed polymer, and technique is comparatively loaded down with trivial details.
In conjunction with the feature of kitchen guarding's waterproofing work and above-mentioned defect, produce a kind of single-component and have waterproof paint concurrently and the polymer cement-based waterproof material of the excellent properties of waterproof mortar can well solve prior art exist deficiency, have no at present report.
Summary of the invention
The object of the present invention is to provide the multi-functional concentrate feed of a kind of kitchen guarding's cement group water-proofing material, utilize this concentrate feed with cement, silica powder mixes by proportioning can be for the preparation of the single-component polymer cement waterproof material of kitchen guarding's waterproof construction, this kind of single polymer cement waterproofing material has excellent water resistance, when construction, only need shallow layer can realize waterproof, also there is good rigidity, be easy to the paving of follow-up ceramic tile, be applicable to the waterproof of meet/back side; This concentrate feed formula can be by regulating respective components content to form winter and summer formula, transport, easy to use; Modification waste Crumb rubber in concentrate feed can reduce the density of polymer cement waterproof material, greatly improves the spreading rate of water-proof coating.
In order to address the above problem, the technical solution adopted in the present invention is as follows: the multi-functional concentrate feed of a kind of kitchen guarding's cement group water-proofing material, formed by following component, and each component concentration is the kg number containing this component in concentrate feed per ton, as follows:
Waste Crumb rubber 50-600
Silane coupling agent 0.5-3
Alcohol blend 0.5-10
High-alumina cement 30-350
Redispersable latex powder 20-350
Ether of cellulose 1-50
Retardant 1-50
Setting accelerator 1-40
Water reducer 1-40
Frostproofer 0-50
Hydrophober 1-30.
Described waste Crumb rubber preferable particle size is 60-200 order.
Described silane coupling agent is preferably methoxy silane or Ethoxysilane or aminosilane.
Described high-alumina cement strength grade is preferably 42.5 or 52.5.
Described redispersible latex powder is preferably ethylene-vinyl acetate copolymer latex powder or acrylic acid or the like latex powder.
Described ether of cellulose is preferably hydroxyethylmethyl-cellulose ether or hydroxypropyl methyl cellulose ether, and viscosity is 500-100000mPas.
Described retardant is preferably tartrate or citric acid or its esters.
Described setting accelerator is preferably Quilonum Retard, calcium formiate.
Described water reducer is preferably polycarboxylate water-reducer or naphthalene water reducer.
Described alcohol blend refers to ethanol aqueous solution, and preferred mass concentration is 10-50%.
Described frostproofer preferably sulfuric acid sodium or calcium chloride, add while using in the winter time this formula.
The preferred organosilicon powder of described hydrophober or silylation powder.
Kitchen guarding's cement group water-proofing material of the present invention with multi-functional concentrate feed in when application, according to 1 part of multi-functional concentrate feed: 1-5 part 42.5 silicate cements: the ratio of 1-10 part 100-200 order silica powder, concentrate feed, silicate cement, silica powder are put into high speed dispersor and disperse 5-10 minute, until mix, can obtain the cement group water-proofing material for kitchen guarding's waterproof construction.
Kitchen guarding's cement group water-proofing material of the present invention adopts following methods preparation with multi-functional concentrate feed:
(1) prepare each component by proportioning, first silane coupling agent is added in spirituous solution and is diluted, waste Crumb rubber is inserted in super mixer, spray into fine mist silane coupler solution simultaneously, after mixing, place in 80-120 DEG C of baking oven and dry 20-30 minute dried for standby;
(2) the dry waste Crumb rubber after step (1) modification and high-alumina cement, redispersible latex powder, ether of cellulose, retardant, setting accelerator, water reducer, hydrophober and the frostproofer that adds are as required put into mixing and blending machine, stir 10-20 minute, until mix.
The present invention is as follows with respect to the beneficial effect of prior art:
(1) the present invention designs according to the principle of hard and soft combination, in concentrate feed formula, select high-alumina cement, the silicate cement required with preparing water-proof material is as complex cement base-material, the polymeric additives such as coupling redispersable latex powder, water reducer, can jointly form the fine and close waterproof layer of interpenetrating(polymer)networks, greatly improve the impermeability of coating, can realize thin layer construction, coat-thickness only needs 1-1.5mm can obtain excellent water resistance; Meanwhile, the water-proof material of acquisition can be used for meeting, back side construction, during for kitchen guarding, does not hinder next road patch block operation;
(2) the present invention selects high-alumina cement in concentrate feed formula, the silicate cement required with preparing water-proof material is as complex cement base-material, the additives such as coupling retardant, setting accelerator, the time of coagulation of adjustable this water-proof material, ensureing has sufficient operable time in workman construction process, brushes to having quick-drying, early strong feature after in basic unit simultaneously, be conducive to workman easy to operate, shorten the engineering time of next process, increase work efficiency, save the duration;
(3) formula of the present invention can be used for preparing the polymer cement waterproof material of single-component, and in filling a prescription by adjusting, the volume of frostproofer, retardant etc., can form winter and summer formula simultaneously, transport, easy to use, and more than-5 DEG C temperature can be used;
(4) in the present invention formula by adding modification waste Crumb rubber can reduce the density of polymer cement waterproof material, greatly improve the spreading rate of water-proof coating; Meanwhile, waste Crumb rubber is processed by junked tire, and realization is turned waste into wealth, resource circulation utilization.
Embodiment
Below by embodiment, the present invention is described in further details, these embodiment are only used for illustrating the present invention, do not limit the scope of the invention.
embodiment 1prepare the multi-functional concentrate feed of a kind of kitchen guarding's cement group water-proofing material of the present invention by following formula and method:
(1) fill a prescription as shown in the table:
(2) preparation: prepare each constituent materials by proportioning, first silane coupling agent is added in spirituous solution and is diluted, waste Crumb rubber is inserted in super mixer, spray into fine mist silane coupler solution simultaneously, after mixing, place in 110 DEG C of baking ovens and dry 25 minutes dried for standby; Dry waste Crumb rubber after modification and high-alumina cement, redispersible latex powder, ether of cellulose, retardant, setting accelerator, water reducer, hydrophober, frostproofer are put into mixing and blending machine, stir 15 minutes, can obtain multi-functional concentrate feed of the present invention until mix;
(3) application: according to 1 part of multi-functional concentrate feed: 1 part of 42.5 silicate cement: the ratio of 1 part of 100 order silica powder, concentrate feed, silicate cement, silica powder are put into high speed dispersor to be disperseed 10 minutes, until mix, can obtain the cement group water-proofing material for kitchen guarding's waterproof construction.
Kitchen guarding's cement group water-proofing material to above-mentioned preparation carries out performance index detection, as shown in the table:
。
embodiment 2prepare the multi-functional concentrate feed of a kind of kitchen guarding's cement group water-proofing material of the present invention by following formula and method:
(1) fill a prescription as shown in the table:
(2) preparation: prepare each constituent materials by proportioning, first silane coupling agent is added in spirituous solution and is diluted, waste Crumb rubber is inserted in super mixer, spray into fine mist silane coupler solution simultaneously, after mixing, place in 90 DEG C of baking ovens and dry 20 minutes dried for standby; Dry waste Crumb rubber after modification and high-alumina cement, redispersible latex powder, ether of cellulose, retardant, setting accelerator, water reducer, hydrophober are put into mixing and blending machine, stir 20 minutes, can obtain multi-functional concentrate feed of the present invention until mix;
(3) application: according to 1 part of multi-functional concentrate feed: 5 part of 42.5 silicate cement: the ratio of 10 part of 200 order silica powder, concentrate feed, silicate cement, silica powder are put into high speed dispersor to be disperseed 8 minutes, until mix, can obtain the cement group water-proofing material for kitchen guarding's waterproof construction.
embodiment 3prepare the multi-functional concentrate feed of a kind of kitchen guarding's cement group water-proofing material of the present invention by following formula and method:
(1) fill a prescription as shown in the table:
(2) preparation: prepare each constituent materials by proportioning, first silane coupling agent is added in spirituous solution and is diluted, waste Crumb rubber is inserted in super mixer, spray into fine mist silane coupler solution simultaneously, after mixing, place in 80 DEG C of baking ovens and dry 30 minutes dried for standby; Dry waste Crumb rubber after modification and high-alumina cement, redispersible latex powder, ether of cellulose, retardant, setting accelerator, water reducer, hydrophober and frostproofer are put into mixing and blending machine, stir 10 minutes, can obtain multi-functional concentrate feed of the present invention until mix;
(3) application: according to 1 part of multi-functional concentrate feed: 2 part of 42.5 silicate cement: the ratio of 4 part of 100 order silica powder, concentrate feed, silicate cement, silica powder are put into high speed dispersor to be disperseed 5 minutes, until mix, can obtain the cement group water-proofing material for kitchen guarding's waterproof construction.
embodiment 4prepare the multi-functional concentrate feed of a kind of kitchen guarding's cement group water-proofing material of the present invention by following formula and method:
(1) fill a prescription as shown in the table:
(2) preparation: prepare each constituent materials by proportioning, first silane coupling agent is added in spirituous solution and is diluted, waste Crumb rubber is inserted in super mixer, spray into fine mist silane coupler solution simultaneously, after mixing, place in 100 DEG C of baking ovens and dry 25 minutes dried for standby; Dry waste Crumb rubber after modification and high-alumina cement, redispersible latex powder, ether of cellulose, retardant, setting accelerator, water reducer, hydrophober are put into mixing and blending machine, stir 15 minutes, can obtain multi-functional concentrate feed of the present invention until mix;
(3) application: according to 1 part of multi-functional concentrate feed: 3 part of 42.5 silicate cement: the ratio of 8 part of 100 order silica powder, concentrate feed, silicate cement, silica powder are put into high speed dispersor to be disperseed 10 minutes, until mix, can obtain the cement group water-proofing material for kitchen guarding's waterproof construction.
embodiment 5prepare the multi-functional concentrate feed of a kind of kitchen guarding's cement group water-proofing material of the present invention by following formula and method:
(1) fill a prescription as shown in the table:
(2) preparation: prepare each constituent materials by proportioning, first silane coupling agent is added in spirituous solution and is diluted, waste Crumb rubber is inserted in super mixer, spray into fine mist silane coupler solution simultaneously, after mixing, place in 120 DEG C of baking ovens and dry 20 minutes dried for standby; Dry waste Crumb rubber after modification and high-alumina cement, redispersible latex powder, ether of cellulose, retardant, setting accelerator, water reducer, hydrophober and frostproofer are put into mixing and blending machine, stir 20 minutes, can obtain multi-functional concentrate feed of the present invention until mix;
(3) application: according to 1 part of multi-functional concentrate feed: 4 part of 42.5 silicate cement: the ratio of 7 part of 200 order silica powder, concentrate feed, silicate cement, silica powder are put into high speed dispersor to be disperseed 5 minutes, until mix, can obtain the cement group water-proofing material for kitchen guarding's waterproof construction.
Claims (10)
1. the multi-functional concentrate feed of kitchen guarding's cement group water-proofing material, is characterized in that: be made up of following component, each component concentration is the kg number containing this component in concentrate feed per ton, as follows:
Waste Crumb rubber 50-600
Silane coupling agent 0.5-3
Alcohol blend 0.5-10
High-alumina cement 30-350
Redispersable latex powder 20-350
Ether of cellulose 1-50
Retardant 1-50
Setting accelerator 1-40
Water reducer 1-40
Frostproofer 0-50
Hydrophober 1-30.
2. the multi-functional concentrate feed of a kind of kitchen guarding's cement group water-proofing material according to claim 1, is characterized in that: described waste Crumb rubber particle diameter is 60-200 order.
3. the multi-functional concentrate feed of a kind of kitchen guarding's cement group water-proofing material according to claim 1, is characterized in that: described silane coupling agent is methoxy silane or Ethoxysilane or aminosilane.
4. the multi-functional concentrate feed of a kind of kitchen guarding's cement group water-proofing material according to claim 1, is characterized in that: described high-alumina cement strength grade is 42.5 or 52.5.
5. the multi-functional concentrate feed of a kind of kitchen guarding's cement group water-proofing material according to claim 1, is characterized in that: described redispersible latex powder is ethylene-vinyl acetate copolymer latex powder or acrylic acid or the like latex powder.
6. the multi-functional concentrate feed of a kind of kitchen guarding's cement group water-proofing material according to claim 1, is characterized in that: described ether of cellulose is hydroxyethylmethyl-cellulose ether or hydroxypropyl methyl cellulose ether, viscosity is 500-100000mPas.
7. the multi-functional concentrate feed of a kind of kitchen guarding's cement group water-proofing material according to claim 1, is characterized in that: described retardant is tartrate or citric acid or its esters.
8. the multi-functional concentrate feed of a kind of kitchen guarding's cement group water-proofing material according to claim 1, is characterized in that: described setting accelerator is Quilonum Retard or calcium formiate.
9. want the multi-functional concentrate feed of a kind of kitchen guarding's cement group water-proofing material described in 1 according to right, it is characterized in that: described water reducer is polycarboxylate water-reducer or naphthalene water reducer.
10. the multi-functional concentrate feed of a kind of kitchen guarding's cement group water-proofing material according to claim 1, it is characterized in that: described concentrate feed mixes with silicate cement, silica powder according to following part by weight, makes kitchen guarding's cement group water-proofing material: 1 part of multi-functional concentrate feed: 1-5 part 42.5 silicate cements: 1-10 part 100-200 order silica powder.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105731924B (en) * | 2016-01-28 | 2018-03-09 | 云南潮涌科技有限公司 | A kind of water-repellent paint for being used for roofing and swimming pool |
| CN107216066A (en) * | 2017-06-08 | 2017-09-29 | 合肥峰腾节能科技有限公司 | It is a kind of for waterproof material of toilet and preparation method thereof |
| CN112521111B (en) * | 2019-09-17 | 2022-04-01 | 北京华泥新材料科技有限公司 | Ultrafast hard concrete repair material and preparation method and use method thereof |
| CN113105767B (en) * | 2021-03-15 | 2023-04-28 | 昆明晶活生物科技有限公司 | High-permeability-resistance self-healing waterproof coating and preparation method thereof |
| CN113683364A (en) * | 2021-09-06 | 2021-11-23 | 宁波森泰新材料有限公司 | Flexible anti-cracking waterproof mortar and production method thereof |
| CN113896496A (en) * | 2021-09-16 | 2022-01-07 | 上海三棵树防水技术有限公司 | Preparation method of single-component polymer ultrafast waterproof slurry |
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| CN102351487A (en) * | 2011-07-14 | 2012-02-15 | 深圳市嘉达节能环保科技有限公司 | Building external wall powder paint and preparation method thereof |
| CN102503321A (en) * | 2011-10-27 | 2012-06-20 | 北京东方雨虹防水技术股份有限公司 | Cement base self-leveling for cushion layer |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101328046A (en) * | 2008-07-29 | 2008-12-24 | 中国建筑材料科学研究总院 | Bonding mortar for exterior wall external insulation and preparation thereof |
| CN102344271A (en) * | 2010-08-04 | 2012-02-08 | 胡舜钦 | Preparation method of flashing compound for tile |
| CN102351487A (en) * | 2011-07-14 | 2012-02-15 | 深圳市嘉达节能环保科技有限公司 | Building external wall powder paint and preparation method thereof |
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