CN103496922B - Double-component ceramic tile interface agent as well as preparation method and using method thereof - Google Patents
Double-component ceramic tile interface agent as well as preparation method and using method thereof Download PDFInfo
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- CN103496922B CN103496922B CN201310467129.9A CN201310467129A CN103496922B CN 103496922 B CN103496922 B CN 103496922B CN 201310467129 A CN201310467129 A CN 201310467129A CN 103496922 B CN103496922 B CN 103496922B
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Abstract
The invention aims at solving a ceramic tile dropping problem caused by low water absorption and a smooth interface of the existing ceramic file, especially a vitrified porcelain tile, and provides a double-component ceramic tile interface agent for improving interface performance and construction performance of a ceramic tile. The double-component ceramic tile interface agent comprises a component A and a component B, wherein the component A comprises cement, quartz sand, metakaolin and a thickener; the component B comprises a water reducing agent, a flexibilizer, a penetrating agent, a dispersing agent, an antifoaming agent, a bactericide, an accelerator, a season regulator and water. According to the invention, two strength forming materials of multiple polymers and cement are used at the same time, so that possibility of forming an interface for a second time is reduced, and bonding strength of the interface agent and the ceramic tile is improved. Besides, while construction time is ensured, setting time is shortened, construction performance is effectively improved, and long-term aesthetic sense of the ceramic tile is ensured.
Description
Technical field
The invention belongs to building material technical field, especially relate to a kind of two component ceramic tile interface agent and preparation thereof, using method.
Background technology
Ceramic tile is the widely used finishing material in body of wall and ground, there is low water absorption, high abrasion, size uniform, the advantage such as acidproof, radiationless, particularly in family's fitment process, ceramic tile has economy, attractive in appearance, durable feature, simultaneously numerous in variety, the user demand of different levels, different-style can be met, people to be accustomed to ceramic tile as toilet, the finishing material in kitchen.But after traditional decoration construction, ceramic tile is easy to the phenomenon occurring loosening, even coming off, and not only causes more serious financial loss, also brings the trouble of again constructing.
Ceramic tile occurs that the reason come off mainly contains 3 points: first is that the feature of ceramic tile causes, using at present more is on the market that the good high quality ceramic tile of decorative effect is as polished tile or vitrified tile, be characterized in that smooth surface, water-intake rate are low, water-intake rate is less than 0.1%, causes ceramic tile in taping process, form obvious interface and come off; Second caused due to ceramic tile bond, a large amount of tile bonding mode used remains the mode directly adopting cement and husky mixing bonding at present, as extensively adopted cement: the dry laid process basal layer of fine sand=1:3, cement: the adhered layer of fine sand=1:2, wherein cement is No. 325 cement, a small amount of engineering employs special matrix material, but due to ceramic tile when constructing from great, easily sagging, its effect improving interface is still needed and is improved further; 3rd, construction technology causes, and current ceramic tile usually can use the mode of immersion to carry out pre-treatment before stickup, but due to ceramic tile body water-intake rate low, its soak effect not remarkable.Based on above problem, first need the interface problem solving ceramic tile targetedly, on this basis, consider the factor of convenient construction.
At present, existing specially for the adhesive special of tile paste, as Henkel tile adhesives series product, it is a kind of cement-based binders that with the addition of mineral material and organic additive, be applicable to indoor and outdoor ceramic wall and floor bricks, the sumble of ceramic mosaic and stone material is pasted, and there is hydrophobic and jointing function, its special interfacial agents is the boundary material being applicable to concrete surface, in addition the report that the interfacial agents of a large amount of insulating wall materials uses is also had, but these interfacial agents are all constructed for surface of wall, and there is larger difference in the water-intake rate of the water-intake rate of surface of wall and ceramic tile.Therefore, invent a kind of be suitable for ceramic tile site operation, improve ceramic tile interface performance and have great importance and actual demand with the interfacial agents improving ceramic tile tensile strength.
Summary of the invention
The invention of this reality is intended at least to solve one of technical problem existed in prior art.For this reason, the object of the invention is to overcome because of existing ceramic tile particularly vitrified tile because water-intake rate is low, the smooth problem causing ceramic tile to come off in interface, a kind of two component ceramic tile interface agent improving ceramic tile interface performance and workability are provided, comprise component A and B component, described component A comprises: cement, quartz sand, metakaolin, thickening material; Described B component comprises: water reducer, toughner, permeate agent, dispersion agent, defoamer, sterilant, accelerating chemicals, season conditioning agent, water.The basic role principle of above-mentioned substance is:
Cement is conventional gelling material, and the primary intensity as interfacial agents is originated.
Quartz sand is conventional aggregate, as improving interfacial agents intensity and the important substance improving workability.
Metakaolin is conventional filler, has stronger mineral active, while increase system denseness, improves the intensity of interfacial agents.
Water reducer can reduce the consumption of water, improves serviceability and improves intensity.
Thickening material mainly increases product denseness, improves spreading property.
Toughner mainly plays the ability increasing interfacial agents interfacial bond property.
Permeate agent a kind ofly has fabulous sticking power, the fluent material that seepage force is extremely strong, by effective infiltration, have an effect with the composition in concrete and solid, concrete each composition is made to be solidified into a firm entity, and block concrete each size pore, obtain the entirety of a dustless densification, thus improve concrete wear resistance, crushing resistance, compactness and impermeability;
Dispersion agent makes system even, and suspension property increases, and does not precipitate, makes whole system physico-chemical property the same.
Defoamer is mainly the bubble in order to eliminate interiors of products, improves degree of compactness.
Sterilant mainly plays the effect of building antibacterial and mouldproof, improves ornamental.
Accelerating chemicals mainly plays accelerates interfacial agents time of coagulation, improves the object of operating efficiency.
Conditioning agent was mainly in order to improve the ability of the anti-seasonal temperature change of product, with the material of seasonal temperature conversion adjustment volume season.
Water plays dispersion interfacial agents, ensures the effect of the gelling material hydrating capacities such as cement.
Because this technology employs polymkeric substance and cement two kinds of strength derived value materials simultaneously, this product in use, polymkeric substance rapid solidification film forming forms firmly interface at ceramic tile surface, the hydrated product that the hydrated product that cement simultaneously in the technical program is formed is formed with adhesive mortar in tile paste process is close, decreases the possibility at secondary formation interface; In addition, add defoamer, improve product compactness in use, ensure that the bonding strength of product, improve interfacial agents and tile bonding intensity, improve interface performance during ceramic tile construction.By adding thickening material, water reducer, dispersion agent, improve denseness and the mix of mortar, effectively improving workability, add simultaneously accelerating chemicals and season conditioning agent, guarantee the engineering time while, shorten setting time, ensure that the continuity of construction, effectively improve workability.Owing to adding antiseptic-germicide, effectively reduce the bacteria breed of ceramic tile inside, thus reduce the possibility that ceramic tile surface facing pollutes, make ceramic tile keep good ornamental.
Further, each composition in described A component is as follows according to part by weight composition: cement 200-400 part, quartz sand 200-400 part, metakaolin 10-50 part, thickening material 0.2-1 part.
Further, each composition in described B component is as follows according to part by weight composition: water reducer 1-5 part, toughner 50-150 part, permeate agent 3-5 part, dispersion agent 0.1-1 part, defoamer 0.3-1 part, sterilant 0.1-1 part, accelerating chemicals 1-5 part, season conditioning agent 2-10 part, 100 parts, water.
Further, described cement be silicate cement, ordinary Portland cement, aluminosulfate cement, phosphate cement one or more; Described quartz sand is SiO2 weight content is 90%-99%, granularity is 60-120 object building sand; The commercial powder that the described metakaolin SiO2 weight content that to be kaolin formed after 600-900 DEG C of calcining is greater than 45%, Al2O3 weight content is greater than 40%, median size is 2.179 μm; Thickening material is refer to one or more in base ether of cellulose of methyl cellulose ether, TYLOSE 30000, carboxylic propyl methocel ether, starch ethers or carboxylic.
Further, described water reducer is one or more in naphthalene water reducer, poly carboxylic acid series water reducer or polyamide-based water reducer; Toughner is one or more of the emulsions such as ACRYLIC EMULSION, styrene-butadiene emulsion, propyl benzene emulsion; Permeate agent is fatty alcohol-polyoxyethylene ether; Dispersion agent is one or more in triethyl hexyl phosphoric acid, sodium lauryl sulphate, methyl amyl alcohol; Defoamer be organo-siloxane, polyethers, silicon and ether grafting, containing one or more in amine, imines and amides; Sterilant is commercially available water-repellent preservation sterilant; Accelerating chemicals is industrial oleum lini; Season, conditioning agent was butyl glycol ether; Water is tap water.
The present invention also provides a kind of preparation method of above-mentioned pair of component ceramic tile interface agent, comprises the steps:
A, measure cement, quartz sand, metakaolin, thickening material dry mash by aforementioned ratio, add in stirrer and stir, mix, be packaged into A material;
B, to measure by aforementioned ratio water reducer, toughner, permeate agent, dispersion agent, defoamer, sterilant, accelerating chemicals, season conditioning agent, water, add in stirrer and stir, mix, be packaged into B material;
The present invention also provides a kind of using method of above-mentioned pair of component ceramic tile interface agent, comprises the steps:
A, by A material and B material carry out mixing, stirring 5 minutes according to the ratio of weight ratio 1:1;
B, the interfacial agents be stirred evenly is brushed in tile paste face;
C, interfacial agents are evenly brushed in tile paste face after 15 minutes-30 minutes, adopt traditional mortar or adhesive special to carry out tile paste.
Embodiment
Further illustrate the invention of the application below in conjunction with embodiment, but embodiment should not regard as the restriction to right of the present invention.
Embodiment 1:
A kind of two component ceramic tile interface agent, its component and weight content are: cement 200 parts, quartz sand 400 parts, metakaolin 50 parts, thickening material 1 part, water reducer 1 part, toughner 150 parts, permeate agent 3 parts, dispersion agent 1 part, defoamer 1 part, 1 part, sterilant, accelerating chemicals 5 parts, season conditioning agent 10 parts, 100 parts, water.Wherein cement is ordinary Portland cement; Quartz sand is SiO2 weight content is 90%-99%, granularity is 60-120 object building sand; The metakaolin SiO2 weight content that to be kaolin formed after 600-900 DEG C of calcining is 45%, Al2O3 weight content is 40%, the commercial powder of median size 2.179 μm; Thickening material is methyl cellulose ether; Water reducer is naphthalene water reducer; Toughner is ACRYLIC EMULSION; Permeate agent is fatty alcohol-polyoxyethylene ether; Dispersion agent is triethyl hexyl phosphoric acid; Defoamer is organo-siloxane; Sterilant is commercially available water-repellent preservation sterilant; Accelerating chemicals is industrial oleum lini; Season, conditioning agent was butyl glycol ether; Water is tap water.
This couple of component ceramic tile interface agent preparation method is: measure cement respectively according to aforementioned weight ratio, quartz sand, metakaolin, thickening material 4 kinds of dry mash mix in stirrer, be packaged into A material; According to aforementioned weight ratio measure respectively water reducer, toughner, permeate agent, dispersion agent, defoamer, sterilant, accelerating chemicals, season conditioning agent, water, mix in stirrer, be packaged into B material.
The using method of this pair of component ceramic tile interface agent is: A material and B material are mixed according to the ratio of weight ratio 1:1, stir 5 minutes, the interfacial agents be stirred evenly is brushed in tile paste face, wait for after 20 minutes, adopt traditional mortar or adhesive special to carry out tile paste.After the process of this interfacial agents, its interfacial agents and tile bonding intensity can reach 5Mpa.
Embodiment 2:
A kind of two component ceramic tile interface agent, its component and weight content are: cement 400 parts, quartz sand 400 parts, metakaolin 10 parts, thickening material 0.2 part, water reducer 1 part, toughner 50 parts, permeate agent 3 parts, dispersion agent 0.1 part, defoamer 0.3 part, 0.1 part, sterilant, accelerating chemicals 1 part, season conditioning agent 2 parts, 100 parts, water.Wherein cement is ordinary Portland cement; Quartz sand is SiO2 weight content is 90%-99%, granularity is 60-120 object building sand; The metakaolin SiO2 weight content that to be kaolin formed after 600-900 DEG C of calcining is 45%, Al2O3 weight content is 50%, the commercial powder of median size 2.179 μm; Thickening material is TYLOSE 30000; Water reducer is poly carboxylic acid series water reducer; Toughner is styrene-butadiene emulsion; Permeate agent is fatty alcohol-polyoxyethylene ether; Dispersion agent is sodium lauryl sulphate; Defoamer is polyethers defoamer; Sterilant is commercially available water-repellent preservation sterilant; Accelerating chemicals is industrial oleum lini; Season, conditioning agent was butyl glycol ether; Water is tap water.
This couple of component ceramic tile interface agent preparation method is: measure cement respectively according to aforementioned weight ratio, quartz sand, metakaolin, thickening material 4 kinds of dry mash mix in stirrer, be packaged into A material; According to aforementioned weight ratio measure respectively water reducer, toughner, permeate agent, dispersion agent, defoamer, sterilant, accelerating chemicals, season conditioning agent, water, mix in stirrer, be packaged into B material.
The using method of this pair of component ceramic tile interface agent is: A material and B material are mixed according to the ratio of weight ratio 1:1, stir 5 minutes, the interfacial agents be stirred evenly is brushed in tile paste face, wait for after 30 minutes, adopt traditional mortar or adhesive special to carry out tile paste.After the process of this interfacial agents, its interfacial agents and tile bonding intensity can reach 7Mpa.
Embodiment 3:
A kind of two component ceramic tile interface agent, its component and weight content are: cement 300 parts, quartz sand 300 parts, metakaolin 40 parts, thickening material 0.5 part, water reducer 5 parts, toughner 95 parts, permeate agent 4 parts, dispersion agent 0.5 part, defoamer 2 parts, 0.5 part, sterilant, accelerating chemicals 2 parts, season conditioning agent 4 parts, 100 parts, water.Wherein cement is the mixture of ordinary Portland cement weight content 90%, aluminosulfate cement weight content 10% composition; Quartz sand is SiO2 weight content is 90%, granularity is 60-120 object building sand; The metakaolin SiO2 weight content that to be kaolin formed after 600-900 DEG C of calcining is 48%, Al2O3 weight content is 46%, the commercial powder of median size 2.179 μm; Thickening material is starch ethers; Water reducer is that naphthalene water reducer, poly carboxylic acid series water reducer are according to the mixture of weight ratio 1:1; Toughner is propyl benzene emulsion; Permeate agent is fatty alcohol-polyoxyethylene ether; Dispersion agent is methyl amyl alcohol; Defoamer is that organo-siloxane, polyethers are according to the mixture of 1:1; Sterilant is commercially available water-repellent preservation sterilant; Accelerating chemicals is industrial oleum lini; Season, conditioning agent was butyl glycol ether; Water is tap water.
This couple of component ceramic tile interface agent preparation method is: measure cement respectively according to aforementioned weight ratio, quartz sand, metakaolin, thickening material 4 kinds of dry mash mix in stirrer, be packaged into A material; According to aforementioned weight ratio measure respectively water reducer, toughner, permeate agent, dispersion agent, defoamer, sterilant, accelerating chemicals, season conditioning agent, water, mix in stirrer, be packaged into B material.
The using method of this pair of component ceramic tile interface agent is: A material and B material are mixed according to the ratio of weight ratio 1:1, stir 5 minutes, the interfacial agents be stirred evenly is brushed in tile paste face, wait for after 15 minutes, adopt traditional mortar or adhesive special to carry out tile paste.After the process of this interfacial agents, its interfacial agents and tile bonding intensity can reach 6.5Mpa.
Embodiment 4:
A kind of two component ceramic tile interface agent, its component and weight content are: cement 300 parts, quartz sand 200 parts, metakaolin 30 parts, thickening material 0.8 part, water reducer 5 parts, toughner 140 parts, permeate agent 5 parts, dispersion agent 0.8 part, defoamer 0.4 part, 0.8 part, sterilant, accelerating chemicals 3 parts, season conditioning agent 6 parts, 100 parts, water.Wherein cement is aluminosulfate cement; Quartz sand is SiO2 weight content is 90%-99%, granularity is 60-120 object building sand; The metakaolin SiO2 weight content that to be kaolin formed after 600-900 DEG C of calcining is 52%, Al2O3 weight content is 45%, the commercial powder of median size 2.179 μm; Increasing thickening material is methyl cellulose ether and the TYLOSE 30000 mixture according to weight ratio 1:1; Water reducer is polyamide-based water reducer; Toughner is ACRYLIC EMULSION and the styrene-butadiene emulsion mixture according to 2:3; Permeate agent is fatty alcohol-polyoxyethylene ether; Dispersion agent is triethyl hexyl phosphoric acid, sodium lauryl sulphate two kinds of mixtures according to weight ratio 3:4; Defoamer is organo-siloxane and the polyethers mixture according to weight ratio 1:9; Sterilant is commercially available water-repellent preservation sterilant; Accelerating chemicals is industrial oleum lini; Season, conditioning agent was butyl glycol ether; Water is tap water.
This couple of component ceramic tile interface agent preparation method is: measure cement respectively according to aforementioned weight ratio, quartz sand, metakaolin, thickening material 4 kinds of dry mash mix in stirrer, be packaged into A material; According to aforementioned weight ratio measure respectively water reducer, toughner, permeate agent, dispersion agent, defoamer, sterilant, accelerating chemicals, season conditioning agent, water, mix in stirrer, be packaged into B material.
The using method of this pair of component ceramic tile interface agent is: A material and B material are mixed according to the ratio of weight ratio 1:1, stir 5 minutes, the interfacial agents be stirred evenly is brushed in tile paste face, wait for after 25 minutes, adopt traditional mortar or adhesive special to carry out tile paste.After the process of this interfacial agents, its interfacial agents and tile bonding intensity can reach 6.8Mpa.
In the description of this specification sheets, specific features, structure, material or feature that the description of reference term " embodiment ", " some embodiments ", " illustrative examples ", " example ", " concrete example " or " some examples " etc. means to describe in conjunction with this embodiment or example are contained at least one embodiment of the present invention or example.In this manual, identical embodiment or example are not necessarily referred to the schematic representation of above-mentioned term.And the specific features of description, structure, material or feature can combine in an appropriate manner in any one or more embodiment or example.
Although illustrate and describe embodiments of the invention, those having ordinary skill in the art will appreciate that: can carry out multiple change, amendment, replacement and modification to these embodiments when not departing from principle of the present invention and aim, scope of the present invention is by claim and equivalents thereof.
Claims (3)
1. a two component ceramic tile interface agent, it is characterized in that, comprise component A and B component, described component A comprises: cement, quartz sand, metakaolin, thickening material; Described B component comprises: water reducer, toughner, permeate agent, dispersion agent, defoamer, sterilant, accelerating chemicals, season conditioning agent, water; Each composition in described component A is as follows according to part by weight composition: cement 200-400 part, quartz sand 200-400 part, metakaolin 10-50 part, thickening material 0.2-1 part; Each composition in described B component is as follows according to part by weight composition: water reducer 1-5 part, toughner 50-150 part, permeate agent 3-5 part, dispersion agent 0.1-1 part, defoamer 0.3-1 part, sterilant 0.1-1 part, accelerating chemicals 1-5 part, season conditioning agent 2-10 part, 100 parts, water; Described cement be silicate cement, ordinary Portland cement, aluminosulfate cement, phosphate cement one or more; Described quartz sand is SiO
2weight content is 90%-99%, granularity is 60-120 object building sand; Described metakaolin is the SiO that kaolin is formed after 600-900 DEG C of calcining
2weight content is greater than 45%, Al
2o
3the commercial powder that weight content is greater than 40%, median size is 2.179 μm; Thickening material is one or more in base ether of cellulose of methyl cellulose ether, TYLOSE 30000, carboxylic propyl methocel ether, starch ethers or carboxylic; Described water reducer is one or more in naphthalene water reducer, poly carboxylic acid series water reducer or polyamide-based water reducer; Toughner be ACRYLIC EMULSION, styrene-butadiene emulsion, propyl benzene emulsion one or more; Permeate agent is fatty alcohol-polyoxyethylene ether; Dispersion agent is one or more in triethyl hexyl phosphoric acid, sodium lauryl sulphate, methyl amyl alcohol; Defoamer be organo-siloxane, polyethers, containing one or more in amine, imines and amides; Sterilant is commercially available water-repellent preservation sterilant; Accelerating chemicals is industrial oleum lini; Season, conditioning agent was butyl glycol ether; Water is tap water.
2. the preparation method of according to claim 1 pair of component ceramic tile interface agent, comprises the steps:
A, get cement, quartz sand, metakaolin, thickening material dry mash, add in stirrer and stir, mix, be packaged into A material;
B, get water reducer, toughner, permeate agent, dispersion agent, defoamer, sterilant, accelerating chemicals, season conditioning agent, water, add in stirrer and stir, mix, be packaged into B material.
3. the using method of according to claim 1 pair of component ceramic tile interface agent, comprises the steps:
A, by A material and B material carry out mixing, stirring 5 minutes according to the ratio of weight ratio 1:1;
B, the interfacial agents be stirred evenly is brushed in tile paste face;
C, interfacial agents are evenly brushed in tile paste face after 15 minutes-30 minutes, adopt traditional mortar or adhesive special to carry out tile paste.
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