CN103468143B - A kind of waterproof paint of polymer and asphalt - Google Patents
A kind of waterproof paint of polymer and asphalt Download PDFInfo
- Publication number
- CN103468143B CN103468143B CN201310359685.4A CN201310359685A CN103468143B CN 103468143 B CN103468143 B CN 103468143B CN 201310359685 A CN201310359685 A CN 201310359685A CN 103468143 B CN103468143 B CN 103468143B
- Authority
- CN
- China
- Prior art keywords
- asphalt
- coalescence aid
- polymer
- film coalescence
- waterproof paint
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000010426 asphalt Substances 0.000 title claims abstract description 17
- 239000003973 paint Substances 0.000 title claims abstract description 15
- 229920000642 polymer Polymers 0.000 title claims abstract description 14
- 238000004581 coalescence Methods 0.000 claims abstract description 16
- 239000000839 emulsion Substances 0.000 claims abstract description 16
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 10
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 7
- 239000004113 Sepiolite Substances 0.000 claims abstract description 7
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 claims abstract description 7
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910021538 borax Inorganic materials 0.000 claims abstract description 7
- UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 7
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims abstract description 7
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims abstract description 7
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims abstract description 7
- 239000000843 powder Substances 0.000 claims abstract description 7
- 229910052624 sepiolite Inorganic materials 0.000 claims abstract description 7
- 235000019355 sepiolite Nutrition 0.000 claims abstract description 7
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 7
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 7
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims abstract description 4
- 244000043261 Hevea brasiliensis Species 0.000 claims abstract description 4
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 4
- 229920003052 natural elastomer Polymers 0.000 claims abstract description 4
- 229920001194 natural rubber Polymers 0.000 claims abstract description 4
- 229920002545 silicone oil Polymers 0.000 claims abstract description 4
- 229940095064 tartrate Drugs 0.000 claims abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 15
- CUVLMZNMSPJDON-UHFFFAOYSA-N 1-(1-butoxypropan-2-yloxy)propan-2-ol Chemical compound CCCCOCC(C)OCC(C)O CUVLMZNMSPJDON-UHFFFAOYSA-N 0.000 claims description 6
- IQXJCCZJOIKIAD-UHFFFAOYSA-N 1-(2-methoxyethoxy)hexadecane Chemical compound CCCCCCCCCCCCCCCCOCCOC IQXJCCZJOIKIAD-UHFFFAOYSA-N 0.000 claims description 6
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 6
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 6
- 229950009789 cetomacrogol 1000 Drugs 0.000 claims description 6
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 6
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 6
- 239000011118 polyvinyl acetate Substances 0.000 claims description 6
- 238000007599 discharging Methods 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 238000009413 insulation Methods 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 abstract description 5
- 238000000576 coating method Methods 0.000 abstract description 5
- 239000002253 acid Substances 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000010276 construction Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 239000003513 alkali Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The present invention discloses a kind of waterproof paint of polymer and asphalt, it is made up of the raw material of following weight parts: pitch 60-70, benzene emulsion 10-20, natural rubber 5-10, polyvinyl alcohol 5-7, octadecyl trimethyl ammonium chloride 2-4, dimethyl silicone oil 1-2, sodium tetraborate 1-2, tartrate 1-2, ��-aminopropyl triethoxysilane 1-2, sepiolite powder 10-20, nano aluminum alumina 10-20, polyvinylpyrrolidone 2-3, film coalescence aid 2-4, water is appropriate, the present invention by coating have very wide thermal adaptability, film-forming is fast, film forming good toughness, cohesive force is strong, acid and alkali-resistance, resistant of high or low temperature is strong, overall good water-proof effect.
Description
Technical field
The present invention relates generally to a kind of coating, particularly relates to a kind of waterproof paint of polymer and asphalt.
Background technology
Emulsified bitumen coating has certain water-repellancy and preservative property, due to the restriction of the performance of pitch own, the work-ing life of Emulsificated asphalt water-proof painting material is short, the poor-performing such as low temperature flexibility and thermotolerance, being applicable to classification of waterproof is waterproof layer and underground is moistureproof, the construction of corrosion protection coating between the industry of III, IV grade and covil construction roofing, lavatory are bathed, and is cheap low-grade waterproof paint, therefore, improve the over-all properties of Emulsificated asphalt water-proof painting material, so that it is necessary for expanding usage range.
Summary of the invention
The object of the invention is just to provide a kind of waterproof paint of polymer and asphalt.
The present invention is achieved by the following technical solutions:
A kind of waterproof paint of polymer and asphalt, it is made up of the raw material of following weight parts:
Pitch 60-70, benzene emulsion 10-20, natural rubber 5-10, polyvinyl alcohol 5-7, octadecyl trimethyl ammonium chloride 2-4, dimethyl silicone oil 1-2, sodium tetraborate 1-2, tartrate 1-2, ��-aminopropyl triethoxysilane 1-2, sepiolite powder 10-20, nano aluminum alumina 10-20, polyvinylpyrrolidone 2-3, film coalescence aid 2-4, water are appropriate;
Described film coalescence aid is made up of the raw material of following weight parts:
EVA emulsion 40-50, polyvinyl acetate emulsion 5-6, vinyltriethoxysilane 4-5, dipropylene glycol butyl ether 1-2, cetomacrogol 1000 2-3, aluminium hydroxide 2-4, tin-antiomony oxide 0.1-0.2;
Above-mentioned cetomacrogol 1000 is mixed with aluminium hydroxide, stirring reaction 10-15 minute at 50-60 DEG C, tin-antiomony oxide is added after being cooled to normal temperature, obtain Preblend, EVA emulsion is mixed with polyvinyl acetate emulsion, stir after evenly and add vinyltriethoxysilane, 400-500 rev/min dispersed with stirring 2-4 minute, adding above-mentioned Preblend and dipropylene glycol butyl ether, 100-120 DEG C of insulation leaves standstill 1-2 hour, obtains described film coalescence aid.
A preparation method for waterproof paint of polymer and asphalt, comprises the following steps:
Above-mentioned pitch is heated to 140-150 DEG C, adds polyvinyl alcohol, octadecyl trimethyl ammonium chloride, sodium tetraborate, polyvinylpyrrolidone, obtain Preblend; Sepiolite powder, nano aluminum alumina are mixed with ��-aminopropyl triethoxysilane, 300-400 rev/min dispersed with stirring 4-5 minute, join in above-mentioned Preblend after discharging, by colloidal mill grinding evenly, at temperature is 145-155 DEG C, add each raw material except film coalescence aid, fully it is uniformly mixed, it is cooled to normal temperature, add film coalescence aid, fully stir, obtain described waterproof paint of polymer and asphalt.
It is an advantage of the invention that:
The present invention by coating have very wide thermal adaptability, film-forming is fast, film forming good toughness, and cohesive force is strong, acid and alkali-resistance, and resistant of high or low temperature is strong, overall good water-proof effect.
Embodiment
Embodiment 1
A kind of waterproof paint of polymer and asphalt, it is made up of the raw material of following weight parts (kilogram):
Pitch 70, benzene emulsion 20, natural rubber 10, polyvinyl alcohol 7, octadecyl trimethyl ammonium chloride 4, dimethyl silicone oil 2, sodium tetraborate 1, tartrate 1, ��-aminopropyl triethoxysilane 1, sepiolite powder 20, nano aluminum alumina 20, polyvinylpyrrolidone 2, film coalescence aid 4, water are appropriate;
Described film coalescence aid is made up of the raw material of following weight parts:
EVA emulsion 50, polyvinyl acetate emulsion 6, vinyltriethoxysilane 5, dipropylene glycol butyl ether 2, cetomacrogol 1000 3, aluminium hydroxide 4, tin-antiomony oxide 0.2;
Above-mentioned cetomacrogol 1000 is mixed with aluminium hydroxide, stirring reaction 15 minutes at 60 DEG C, tin-antiomony oxide is added after being cooled to normal temperature, obtain Preblend, EVA emulsion is mixed with polyvinyl acetate emulsion, stir after evenly and add vinyltriethoxysilane, 500 revs/min of dispersed with stirring 2 minutes, adding above-mentioned Preblend and dipropylene glycol butyl ether, 120 DEG C of insulations leave standstill 1 hour, obtain described film coalescence aid.
A preparation method for waterproof paint of polymer and asphalt, comprises the following steps:
Above-mentioned pitch is heated to 150 DEG C, adds polyvinyl alcohol, octadecyl trimethyl ammonium chloride, sodium tetraborate, polyvinylpyrrolidone, obtain Preblend; Sepiolite powder, nano aluminum alumina are mixed with ��-aminopropyl triethoxysilane, 400 revs/min of dispersed with stirring 5 minutes, join in above-mentioned Preblend after discharging, by colloidal mill grinding evenly, at temperature is 155 DEG C, add each raw material except film coalescence aid, fully it is uniformly mixed, it is cooled to normal temperature, add film coalescence aid, fully stir, obtain described waterproof paint of polymer and asphalt.
Performance test:
Acid resistance: with the H of 5%2SO4Solution soaking 25 days film coated surface are unchanged;
Alkali resistance: soak 25 days film coated surface by the NaOH solution of 5% unchanged;
Watertightness (0.3MPa, 40min): waterproof.
Claims (2)
1. a waterproof paint of polymer and asphalt, it is characterised in that it is made up of the raw material of following weight parts: pitch 60-70, benzene emulsion 10-20, natural rubber 5-10, polyvinyl alcohol 5-7, octadecyl trimethyl ammonium chloride 2-4, dimethyl silicone oil 1-2, sodium tetraborate 1-2, tartrate 1-2, ��-aminopropyl triethoxysilane 1-2, sepiolite powder 10-20, nano aluminum alumina 10-20, polyvinylpyrrolidone 2-3, film coalescence aid 2-4, water are appropriate; Described film coalescence aid is made up of the raw material of following weight parts: EVA emulsion 40-50, polyvinyl acetate emulsion 5-6, vinyltriethoxysilane 4-5, dipropylene glycol butyl ether 1-2, cetomacrogol 1000 2-3, aluminium hydroxide 2-4, tin-antiomony oxide 0.1-0.2; Above-mentioned cetomacrogol 1000 is mixed with aluminium hydroxide, stirring reaction 10-15 minute at 50-60 DEG C, tin-antiomony oxide is added after being cooled to normal temperature, obtain Preblend, EVA emulsion is mixed with polyvinyl acetate emulsion, stir after evenly and add vinyltriethoxysilane, 400-500 rev/min dispersed with stirring 2-4 minute, adding above-mentioned Preblend and dipropylene glycol butyl ether, 100-120 DEG C of insulation leaves standstill 1-2 hour, obtains described film coalescence aid.
2. the preparation method of a waterproof paint of polymer and asphalt as claimed in claim 1, it is characterized in that comprising the following steps: above-mentioned pitch is heated to 140-150 DEG C, add polyvinyl alcohol, octadecyl trimethyl ammonium chloride, sodium tetraborate, polyvinylpyrrolidone, obtain Preblend; Sepiolite powder, nano aluminum alumina are mixed with ��-aminopropyl triethoxysilane, 300-400 rev/min dispersed with stirring 4-5 minute, join in above-mentioned Preblend after discharging, by colloidal mill grinding evenly, at temperature is 145-155 DEG C, add each raw material except film coalescence aid, fully it is uniformly mixed, it is cooled to normal temperature, add film coalescence aid, fully stir, obtain described waterproof paint of polymer and asphalt.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310359685.4A CN103468143B (en) | 2013-08-16 | 2013-08-16 | A kind of waterproof paint of polymer and asphalt |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310359685.4A CN103468143B (en) | 2013-08-16 | 2013-08-16 | A kind of waterproof paint of polymer and asphalt |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103468143A CN103468143A (en) | 2013-12-25 |
| CN103468143B true CN103468143B (en) | 2016-06-01 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310359685.4A Expired - Fee Related CN103468143B (en) | 2013-08-16 | 2013-08-16 | A kind of waterproof paint of polymer and asphalt |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103468143B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104130645A (en) * | 2014-06-26 | 2014-11-05 | 安徽快来防水防腐有限公司 | Waterproof coating with high adhesive strength |
| CN104130564B (en) * | 2014-07-18 | 2016-06-29 | 徐鹏飞 | A kind of preparation method of halogen-free flame retardants |
| CN104927430A (en) * | 2015-06-15 | 2015-09-23 | 张家港市山牧新材料技术开发有限公司 | Waterproof paint |
| CN106046811B (en) * | 2016-05-27 | 2017-05-31 | 长安大学 | A kind of modified pitch with anti-ultraviolet ageing function high |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1170022A (en) * | 1996-06-27 | 1998-01-14 | 耿耀宗 | Water based coating for automotive preventing stone hitting |
| JP3313255B2 (en) * | 1995-01-13 | 2002-08-12 | 株式会社ヤスヰ | Coating agent used for automatic application method |
| CN1613939A (en) * | 2004-09-16 | 2005-05-11 | 王耀波 | Waterproof sealing compound for asphalt road surface, production and applied constructing process |
| CN102936460A (en) * | 2012-09-20 | 2013-02-20 | 吴江市天源塑胶有限公司 | Asphalt rubber waterproof coating material |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2009241812B2 (en) * | 2008-04-30 | 2015-04-30 | Wright Advanced Asphalt Systems | System and method for pre-treatment of rubber-modified asphalt cement, and emulsions thereof |
-
2013
- 2013-08-16 CN CN201310359685.4A patent/CN103468143B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3313255B2 (en) * | 1995-01-13 | 2002-08-12 | 株式会社ヤスヰ | Coating agent used for automatic application method |
| CN1170022A (en) * | 1996-06-27 | 1998-01-14 | 耿耀宗 | Water based coating for automotive preventing stone hitting |
| CN1613939A (en) * | 2004-09-16 | 2005-05-11 | 王耀波 | Waterproof sealing compound for asphalt road surface, production and applied constructing process |
| CN102936460A (en) * | 2012-09-20 | 2013-02-20 | 吴江市天源塑胶有限公司 | Asphalt rubber waterproof coating material |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103468143A (en) | 2013-12-25 |
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Effective date of registration: 20210419 Address after: 1-3 / F, building 1, No. 10, Xingren Road, jinmayuan, Gaoliying Town, Shunyi District, Beijing Patentee after: ZHONGGUAN SHUNXIN HUALIN TECHNOLOGY DEVELOPMENT Co.,Ltd. Patentee after: Wuhan future technology construction new material Co.,Ltd. Address before: 430000, No. 30, metallurgy Avenue, Qingshan District, Wuhan City, Hubei Province (in WISCO Museum) Patentee before: Wuhan future technology construction new material Co.,Ltd. |
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Effective date of registration: 20220822 Address after: 430000, No. 30, metallurgy Avenue, Qingshan District, Wuhan City, Hubei Province (in WISCO Museum) Patentee after: Wuhan future technology construction new material Co.,Ltd. Address before: Floor 1-3, Building 1, No. 10, Xingren Road, Jinma Garden, Gaoliying Town, Shunyi District, Beijing 100000 Patentee before: ZHONGGUAN SHUNXIN HUALIN TECHNOLOGY DEVELOPMENT CO.,LTD. Patentee before: Wuhan future technology construction new material Co.,Ltd. |
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