CN105295578A - Silicone-modified styrene-acrylic emulsion coating and preparation method thereof - Google Patents
Silicone-modified styrene-acrylic emulsion coating and preparation method thereof Download PDFInfo
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- CN105295578A CN105295578A CN201510856493.3A CN201510856493A CN105295578A CN 105295578 A CN105295578 A CN 105295578A CN 201510856493 A CN201510856493 A CN 201510856493A CN 105295578 A CN105295578 A CN 105295578A
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Abstract
The invention discloses silicone-modified styrene-acrylic emulsion coating and a preparation method thereof. The silicone-modified styrene-acrylic emulsion coating is prepared from the following raw materials in parts by weight: 46 to 52 parts of silicone-modified styrene-acrylic emulsion, 15 to 22.5 parts of deionized water, 0.2 to 0.6 parts of dispersing agent, 2 to 4 parts of cellulose, 0.2 to 0.8 parts of thickener, 14 to 20 parts of filler, 0.4 to 0.7 parts of defoamer, 3 to 4 parts of propylene glycol, 4 to 8 parts of coalescing agent and 0.2 to 0.5 parts of wetting agent. The silicone-modified styrene-acrylic emulsion coating disclosed by the invention is stable in properties, rapid in drying rate, resistant in rinse, pollution and artificial weathering aging, the coating effect is good and the construction is convenient.
Description
Technical field
The present invention relates to chemical preparations field, be specifically related to a kind of silicone modified styrene-acrylate emulsion coating and preparation method thereof.
Background technology
As time goes on, expose aerial building outer wall material and can be subject to ultraviolet irradiation, the erosion of wind and rain, the adhesion of dust etc. and change so much that one loses one's identity, on the one hand Building life cycle is shortened, destroy the view of buildings on the other hand.In order to attractive in appearance, again can only brush, cause the great wasting of resources.And in existing coating, due to cost restriction, in order to the abrasion resistance providing coating good, PVC comparision contents is high, this just make the levelling property of coating and contamination resistance poor, easily make pollutent go deep into being difficult in film wipe with moisture.
Summary of the invention
For the deficiencies in the prior art, the object of this invention is to provide a kind of silicone modified styrene-acrylate emulsion coating and preparation method thereof, this coating proterties is stablized, and drying hastens soon, washability, stain resistant, resistance to artificial weathering, the good and easy construction of painting effect.
For achieving the above object, the present invention adopts following technical scheme:
A kind of silicone modified styrene-acrylate emulsion coating, is formed by the preparation of raw material of following weight part: silicone modified styrene-acrylate emulsion 46 ~ 52 parts, deionized water 15 ~ 22.5 parts, dispersion agent 0.2 ~ 0.6 part, Mierocrystalline cellulose 2 ~ 4 parts, thickening material 0.2 ~ 0.8 part, filler 14 ~ 20 parts, defoamer 0.4 ~ 0.7 part, propylene glycol 3 ~ 4 parts, film coalescence aid 4 ~ 8 parts, wetting agent 0.2 ~ 0.5 part;
Described silicone modified styrene-acrylate emulsion is made up of the raw material of following weight part: organosilicon 4.8 ~ 6.5 parts, Witco 1298 Soft Acid 2 ~ 3.4 parts, emulsifying agent 2.1 ~ 5 parts, vinylbenzene 30 ~ 36 parts, butyl acrylate 23 ~ 27 parts, 3.5 ~ 6 parts, vinylformic acid, ammonium persulphate 5 ~ 7 parts, sodium bicarbonate 2 ~ 4 parts, deionized water 12.5 ~ 19 parts.
As specializing, described organosilicon is one or more in vinyltriethoxysilane, hydrogen containing siloxane, octamethylcyclotetrasiloxane.
As specializing, the mass ratio of described vinylbenzene and butyl acrylate is (1.2 ~ 1.4): 1.
As specializing, described emulsifying agent is polyoxyethylene nonylphenol ether, sodium lauryl sulphate, and wherein the mass ratio of polyoxyethylene nonylphenol ether and sodium lauryl sulphate is (1.5 ~ 3.5): 1.
As specializing, described thickening material is sodium hydroxyethyl cellulose, and described filler is rutile titanium white powder and ultrafine heavy calcium powder, and described film coalescence aid is propandiol butyl ether.
A kind of preparation method of silicone modified styrene-acrylate emulsion coating comprises the steps:
(1) organosilicon, Witco 1298 Soft Acid, emulsifying agent are put in reactor by above-mentioned weight part, under agitation be warming up to 50 ~ 60 DEG C, again the vinylbenzene of above-mentioned weight part, butyl acrylate, acrylic acid mix monomer are slowly added in reactor, stir 40 ~ 50 minutes, obtain pre-emulsion A; By the ammonium persulphate water dissolution wiring solution-forming B of above-mentioned weight part, get that pre-emulsion A, solution B are each 1/3, the sodium bicarbonate of above-mentioned weight part, deionized water join in reactor, stirring is warming up to 78 ~ 80 DEG C, start after about 30 minutes to drip residue pre-emulsion A and solution B, about 3h drips off, insulation reaction 1.5h, is cooled to 30 ~ 40 DEG C, be 7 ~ 8 with ammoniacal liquor adjust pH, filter discharging and namely obtain silicone modified styrene-acrylate emulsion;
(2) by the deionized water of above-mentioned weight part and dispersion agent dispersed with stirring uniformly solution, add Mierocrystalline cellulose, thickening material stirs 1h, be dispersed into clear viscous solution, filler is distributed in solution respectively by above-mentioned weight part, add defoamer, strong stirring 1h, moves in conoidal mill and grinds 2 ~ 3 times, be prepared into filler mill base.In silicone modified styrene-acrylate emulsion, add propylene glycol, film coalescence aid, wetting agent, strong stirring is even, adds filler mill base, adds defoamer simultaneously, stirs 1h, is namely prepared into coating.
Beneficial effect of the present invention:
Coating of the present invention carries out modification by adding organosilicon to benzene emulsion, and coating proterties is stablized, and drying hastens soon, washability, stain resistant, resistance to artificial weathering, the good and easy construction of painting effect.
Embodiment
Below in conjunction with specific embodiment, the present invention is further described.
Embodiment 1
The preparation of silicone modified styrene-acrylate emulsion: 5.5g vinyltriethoxysilane, 3g Witco 1298 Soft Acid, 3g polyoxyethylene nonylphenol ether, 2g sodium lauryl sulphate are put in reactor, under agitation be warming up to 50 DEG C, again 30g vinylbenzene, 24g butyl acrylate, the acrylic acid mix monomer of 6g are slowly added in reactor, stir 40 minutes, obtain pre-emulsion A.By 6.5g ammonium persulphate water dissolution wiring solution-forming B, get that pre-emulsion A, solution B are each 1/3,2g sodium bicarbonate, 18g deionized water join in reactor, stirring is warming up to 78 DEG C, start after about 30 minutes to drip residue pre-emulsion A and solution B, about 3h drips off, insulation reaction 1.5h, is cooled to 30 DEG C, be 7 ~ 8 with ammoniacal liquor adjust pH, filter discharging and namely obtain silicone modified styrene-acrylate emulsion.
The synthesis of silicone modified styrene-acrylate emulsion coating: by the dispersion agent dispersed with stirring uniformly solution of the deionized water of 22.5g and 0.5g, adds the Mierocrystalline cellulose of 2g, the thickening material sodium hydroxyethyl cellulose of 0.2g stirs 1h, be dispersed into clear viscous solution.By the rutile titanium white powder of filler 10g, the ultrafine heavy calcium powder of 4g is distributed in solution respectively, adds the defoamer of 0.2g, strong stirring 1h, moves in conoidal mill and grinds 2 ~ 3 times, be prepared into filler mill base.In the silicone modified styrene-acrylate emulsion of 52g, add the propylene glycol of 3g, the film coalescence aid propandiol butyl ether of 5g, the wetting agent of 0.3g, strong stirring is even, adds filler mill base, adds the defoamer of 0.3g simultaneously, stirs 1h, is namely prepared into coating.
Embodiment 2
The preparation of silicone modified styrene-acrylate emulsion: 6g hydrogen containing siloxane, 2.4g Witco 1298 Soft Acid, 1.4g polyoxyethylene nonylphenol ether, 0.7g sodium lauryl sulphate are put in reactor, under agitation be warming up to 55 DEG C, again 35g vinylbenzene, 26g butyl acrylate, the acrylic acid mix monomer of 4.5g are slowly added in reactor, stir 45 minutes, obtain pre-emulsion A.By 6.5g ammonium persulphate water dissolution wiring solution-forming B, get that pre-emulsion A, solution B are each 1/3,2.5g sodium bicarbonate, 15g deionized water join in reactor, stirring is warming up to 79 DEG C, start after about 30 minutes to drip residue pre-emulsion A and solution B, about 3h drips off, insulation reaction 1.5h, is cooled to 35 DEG C, be 7 ~ 8 with ammoniacal liquor adjust pH, filter discharging and namely obtain silicone modified styrene-acrylate emulsion.
The synthesis of silicone modified styrene-acrylate emulsion coating: by the dispersion agent dispersed with stirring uniformly solution of the deionized water of 18.5g and 0.3g, adds the Mierocrystalline cellulose of 3g, the thickening material sodium hydroxyethyl cellulose of 0.3g stirs 1h, be dispersed into clear viscous solution.By the rutile titanium white powder of filler 12g, the ultrafine heavy calcium powder of 7g is distributed in solution respectively, adds the defoamer of 0.4g, strong stirring 1h, moves in conoidal mill and grinds 2 ~ 3 times, be prepared into filler mill base.In the silicone modified styrene-acrylate emulsion of 50g, add the propylene glycol of 4g, the film coalescence aid propandiol butyl ether of 4g, the wetting agent of 0.2g, strong stirring is even, adds filler mill base, adds the defoamer of 0.3g simultaneously, stirs 1h, is namely prepared into coating.
Embodiment 3
The preparation of silicone modified styrene-acrylate emulsion: 6.5g octamethylcyclotetrasiloxane, 2g Witco 1298 Soft Acid, 2g polyoxyethylene nonylphenol ether, 0.8g sodium lauryl sulphate are put in reactor, under agitation be warming up to 60 DEG C, again 36g vinylbenzene, 26g butyl acrylate, the acrylic acid mix monomer of 3.5g are slowly added in reactor, stir 50 minutes, obtain pre-emulsion A.By 7g ammonium persulphate water dissolution wiring solution-forming B, get that pre-emulsion A, solution B are each 1/3,3.7g sodium bicarbonate, 12.5g deionized water join in reactor, stirring is warming up to 80 DEG C, start after about 30 minutes to drip residue pre-emulsion A and solution B, about 3h drips off, insulation reaction 1.5h, is cooled to 40 DEG C, be 7 ~ 8 with ammoniacal liquor adjust pH, filter discharging and namely obtain silicone modified styrene-acrylate emulsion.
The synthesis of silicone modified styrene-acrylate emulsion coating: by the dispersion agent dispersed with stirring uniformly solution of the deionized water of 22g and 0.3g, adds the Mierocrystalline cellulose of 2.5g, the thickening material sodium hydroxyethyl cellulose of 0.6g stirs 1h, be dispersed into clear viscous solution.By the rutile titanium white powder of filler 8g, the ultrafine heavy calcium powder of 6g is distributed in solution respectively, adds the defoamer of 0.3g, strong stirring 1h, moves in conoidal mill and grinds 2 ~ 3 times, be prepared into filler mill base.In the silicone modified styrene-acrylate emulsion of 48g, add the propylene glycol of 3.5g, the film coalescence aid propandiol butyl ether of 8g, the wetting agent of 0.5g, strong stirring is even, adds filler mill base, adds the defoamer of 0.3g simultaneously, stirs 1h, is namely prepared into coating.
Embodiment 4
The preparation of silicone modified styrene-acrylate emulsion: 4.8g vinyltriethoxysilane, 1.6g octamethylcyclotetrasiloxane, 2.6g Witco 1298 Soft Acid, 3.5g polyoxyethylene nonylphenol ether, 1g sodium lauryl sulphate are put in reactor, under agitation be warming up to 50 DEG C, again 32g vinylbenzene, 27g butyl acrylate, the acrylic acid mix monomer of 3.8g are slowly added in reactor, stir 45 minutes, obtain pre-emulsion A.By 5g ammonium persulphate water dissolution wiring solution-forming B, get that pre-emulsion A, solution B are each 1/3,3g sodium bicarbonate, 15.7g deionized water join in reactor, stirring is warming up to 78 DEG C, start after about 30 minutes to drip residue pre-emulsion A and solution B, about 3h drips off, insulation reaction 1.5h, is cooled to 30 DEG C, be 7 ~ 8 with ammoniacal liquor adjust pH, filter discharging and namely obtain silicone modified styrene-acrylate emulsion.
The synthesis of silicone modified styrene-acrylate emulsion coating: by the dispersion agent dispersed with stirring uniformly solution of the deionized water of 15g and 0.6g, adds the Mierocrystalline cellulose of 2g, the thickening material sodium hydroxyethyl cellulose of 0.8g stirs 1h, be dispersed into clear viscous solution.By the rutile titanium white powder of filler 11g, the ultrafine heavy calcium powder of 5g is distributed in solution respectively, adds the defoamer of 0.2g, strong stirring 1h, moves in conoidal mill and grinds 2 ~ 3 times, be prepared into filler mill base.In the silicone modified styrene-acrylate emulsion of 55g, add the propylene glycol of 3.8g, the film coalescence aid propandiol butyl ether of 6g, the wetting agent of 0.4g, strong stirring is even, adds filler mill base, adds the defoamer of 0.2g simultaneously, stirs 1h, is namely prepared into coating.
Embodiment 5
The preparation of silicone modified styrene-acrylate emulsion: 2.6g vinyltriethoxysilane, 1.3g octamethylcyclotetrasiloxane, 1.3g hydrogen containing siloxane, 3.4g Witco 1298 Soft Acid, 3g polyoxyethylene nonylphenol ether, 1g sodium lauryl sulphate are put in reactor, under agitation be warming up to 50 DEG C, again 31g vinylbenzene, 23g butyl acrylate, the acrylic acid mix monomer of 5.2g are slowly added in reactor, stir 45 minutes, obtain pre-emulsion A.By 5.2g ammonium persulphate water dissolution wiring solution-forming B, get that pre-emulsion A, solution B are each 1/3,4g sodium bicarbonate, 19g deionized water join in reactor, stirring is warming up to 78 DEG C, start after about 30 minutes to drip residue pre-emulsion A and solution B, about 3h drips off, insulation reaction 1.5h, is cooled to 30 DEG C, be 7 ~ 8 with ammoniacal liquor adjust pH, filter discharging and namely obtain silicone modified styrene-acrylate emulsion.
The synthesis of silicone modified styrene-acrylate emulsion coating: by the dispersion agent dispersed with stirring uniformly solution of the deionized water of 17.5g and 0.2g, adds the Mierocrystalline cellulose of 4g, the thickening material sodium hydroxyethyl cellulose of 0.5g stirs 1h, be dispersed into clear viscous solution.By the rutile titanium white powder of filler 12g, the ultrafine heavy calcium powder of 8g is distributed in solution respectively, adds the defoamer of 0.3g, strong stirring 1h, moves in conoidal mill and grinds 2 ~ 3 times, be prepared into filler mill base.In the silicone modified styrene-acrylate emulsion of 46g, add the propylene glycol of 4g, the film coalescence aid propandiol butyl ether of 7g, the wetting agent of 0.2g, strong stirring is even, adds filler mill base, adds the defoamer of 0.3g simultaneously, stirs 1h, is namely prepared into coating.
The water tolerance of silicone modified styrene-acrylate emulsion coating obtained for embodiment 1,2,3,4,5, alkali resistance, abrasion resistance and resistance to soiling etc. are carried out performance test, and result is as shown in table 1 below.
Table 1
The above, it is only present pre-ferred embodiments, not technical scope of the present invention is imposed any restrictions, thus every above embodiment is done according to technical spirit of the present invention any trickle amendment, equivalent variations and modification, all still belong in the scope of technical solution of the present invention.
Claims (6)
1. a silicone modified styrene-acrylate emulsion coating, it is characterized in that, formed by the preparation of raw material of following weight part: silicone modified styrene-acrylate emulsion 46 ~ 52 parts, deionized water 15 ~ 22.5 parts, dispersion agent 0.2 ~ 0.6 part, Mierocrystalline cellulose 2 ~ 4 parts, thickening material 0.2 ~ 0.8 part, filler 14 ~ 20 parts, defoamer 0.4 ~ 0.7 part, propylene glycol 3 ~ 4 parts, film coalescence aid 4 ~ 8 parts, wetting agent 0.2 ~ 0.5 part;
Further, described silicone modified styrene-acrylate emulsion is made up of the raw material of following weight part: organosilicon 4.8 ~ 6.5 parts, Witco 1298 Soft Acid 2 ~ 3.4 parts, emulsifying agent 2.1 ~ 5 parts, vinylbenzene 30 ~ 36 parts, butyl acrylate 23 ~ 27 parts, 3.5 ~ 6 parts, vinylformic acid, ammonium persulphate 5 ~ 7 parts, sodium bicarbonate 2 ~ 4 parts, deionized water 12.5 ~ 19 parts.
2. silicone modified styrene-acrylate emulsion coating according to claim 1, is characterized in that, described organosilicon is one or more in vinyltriethoxysilane, hydrogen containing siloxane, octamethylcyclotetrasiloxane.
3. silicone modified styrene-acrylate emulsion coating according to claim 1, is characterized in that, described vinylbenzene and the mass ratio of butyl acrylate are (1.2 ~ 1.4): 1.
4. silicone modified styrene-acrylate emulsion coating according to claim 1, it is characterized in that, described emulsifying agent is polyoxyethylene nonylphenol ether, sodium lauryl sulphate, and wherein the mass ratio of polyoxyethylene nonylphenol ether and sodium lauryl sulphate is (1.5 ~ 3.5): 1.
5. silicone modified styrene-acrylate emulsion coating according to claim 1, is characterized in that, described filler is rutile titanium white powder and ultrafine heavy calcium powder.
6. the preparation method of silicone modified styrene-acrylate emulsion coating according to claim 1, is characterized in that comprising the steps:
(1) organosilicon, Witco 1298 Soft Acid, emulsifying agent are put in reactor by above-mentioned weight part, under agitation be warming up to 50 ~ 60 DEG C, again the vinylbenzene of above-mentioned weight part, butyl acrylate, acrylic acid mix monomer are slowly added in reactor, stir 40 ~ 50 minutes, obtain pre-emulsion A; By the ammonium persulphate water dissolution wiring solution-forming B of above-mentioned weight part, get that pre-emulsion A, solution B are each 1/3, the sodium bicarbonate of above-mentioned weight part, deionized water join in reactor, stirring is warming up to 78 ~ 80 DEG C, start after about 30 minutes to drip residue pre-emulsion A and solution B, about 3h drips off, insulation reaction 1.5h, is cooled to 30 ~ 40 DEG C, be 7 ~ 8 with ammoniacal liquor adjust pH, filter discharging and namely obtain silicone modified styrene-acrylate emulsion;
(2) by the deionized water of above-mentioned weight part and dispersion agent dispersed with stirring uniformly solution, add Mierocrystalline cellulose, thickening material stirs 1h, be dispersed into clear viscous solution; Filler is distributed in solution respectively by above-mentioned weight part, adds defoamer, strong stirring 1h, move in conoidal mill and grind 2 ~ 3 times, be prepared into filler mill base; In silicone modified styrene-acrylate emulsion, add propylene glycol, film coalescence aid, wetting agent, strong stirring is even, adds filler mill base, adds defoamer simultaneously, stirs 1h, is namely prepared into coating.
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| CN106085228A (en) * | 2016-06-26 | 2016-11-09 | 仇颖莹 | A kind of preparation method of stone-like coating |
| CN106082794A (en) * | 2016-06-28 | 2016-11-09 | 郭舒洋 | A kind of preparation method of the true mineral varnish of high durable |
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| CN106009798A (en) * | 2016-06-27 | 2016-10-12 | 安徽省思维新型建材有限公司 | Elastic rough coating |
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| CN107011756A (en) * | 2017-05-12 | 2017-08-04 | 段宝荣 | The preparation method of environment-friendly type graphene modified water-soluble styrene-acrylic resin antifouling conductive coating |
| CN107936648A (en) * | 2017-12-12 | 2018-04-20 | 安徽宇瑞环保建设有限公司 | A kind of spotter mildew-proof water-resistant coating |
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