CN102936119B - Interior wall decoration material composed of ecological inorganic minerals - Google Patents

Interior wall decoration material composed of ecological inorganic minerals Download PDF

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Publication number
CN102936119B
CN102936119B CN201210443903.8A CN201210443903A CN102936119B CN 102936119 B CN102936119 B CN 102936119B CN 201210443903 A CN201210443903 A CN 201210443903A CN 102936119 B CN102936119 B CN 102936119B
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powder
internal wall
inorganic mineral
decorative material
ecological
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CN102936119A (en
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陈胡星
邓妮
许远荣
诸晓峰
马先伟
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Zhejiang University ZJU
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Zhejiang University ZJU
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Abstract

The invention discloses an interior wall decoration material composed of ecological inorganic minerals. The material is composed of materials of, by weight, 15% to 30% of white cement, 5% to 20% of zeolite powder, 5% to 20% of roasted diatomite powder, 20% to 50% of quartz sand, 5% to 20% of ground calcium carbonate powder, 0.5% to 1% of nanometer titanium dioxide, 1% to 3% of dispersible emulsion powder, 0% to 3% of bentonite, 0% to 1.5% of pigments and 0% to 0.4% of cellulose ether. The material is almost composed of inorganic minerals, volatile organic compounds are not contained; and the material is ecological and environment friendly, has adsorption and self humidity adjusting effects and certain anti-microbial and air purifying effects simultaneously and is convenient for storage, transportation and usage.

Description

A kind of ecological inorganic mineral decorative material for internal wall
Technical field
The present invention relates to technical field of construction and decoration materials, be specifically related to a kind of ecological inorganic mineral decorative material for internal wall.
Background technology
Along with growth in the living standard, people are more and more higher to the requirement of the decoration of inner wall of building, not only require attractive in appearancely, more require amenity, safety, environmental protection.At present, decorative material for internal wall mostly is organic chemical industry's coating, conventionally contains the organism such as formaldehyde, benzene, and HUMAN HEALTH is produced to harm.In order to overcome the deficiency of traditional coating, people attach great importance to the exploitation of ecological environment-friendly type decorative material for internal wall, and obtain certain progress.
People add the material with decomposing organic matter effect on traditional coating base, or utilize inorganic materials to prepare finishing material with organic binder bond, to reach the effect purifying air.Publication number is to disclose a kind of composite photocatalysis coating in the Chinese patent application of CN102206450A, contain the components such as matrix material, nano titanium oxide, nanometer diatom ooze, bamboo carbon extracting solution, membrane-forming agent, can be initiatively, fast, lastingly, purify air in all directions, effectively suppress harmful microbe breeding; But such coating not only cost is high, and its matrix material is various emulsions, store and transportation etc. all inconvenient.Publication number is that the Chinese patent application of CN101700965A discloses a kind of environment-friendly diatom ooze wall material powder, wall material and preparation method, according to weight percent, by following component proportion, is formed: diatomite in powder (calcining one-level) 30%~60%, kaolin powder (calcining one-level) 8%~9%, sepiolite powder (calcining one-level) 7%~8%, bentonite in powder (calcining one-level) 5%~8%, marble English rock dust (special one-level) 10%~30%, Attapulgite stone flour (dry superfine) 6%~10%, vermiculite power (calcining one-level) 3%~4%, tackifier 0.6%~0.7%, staple cellulose 0.3%~0.4%; It is prepared from raw materials such as the ceramic such as diatomite in powder, kaolin powder, cloud silica powder and tackifier, have cheap, purify air, the function such as moisture absorbing and deodorizing; But the raw materials cost of such material is higher, restricted its widespread use, there is pending improvement.
For fear of organic volatilization in chemistry painting industry, people also attempt directly usining sand-cement slurry as decorative material for internal wall.For example, publication number is that the Chinese patent application of CN101948278A discloses a kind of color mortar coating, consists of: cement 21-24, grey calcium 5-10, quartz sand 52-58, water-ground limestone 12-18, silicon powder 5-10, redispersable latex powder 2-4, hydrophober 0.25-0.35, thixotroping lubricant 0.35-0.45, hydroxypropylcelluloether ether 0.25-0.3 and ferric oxide mineral dye 1-5 the raw material of following weight part ratio; This type of material is comprised of cement, grey calcium, quartz sand, coarse whiting, silicon powder, latex powder, ether of cellulose and iron oxide pigment etc., have that cheap, pollution-free, good weatherability, fast colours are lasting, good ultraviolet resistance, be combined well with bottom, the advantage such as not easy to crack, hydrophobic nature is good, but also need select from material, form the many-sides such as design and study and improve from attractive in appearance, comfortable equal angles consideration.
Summary of the invention
The invention provides a kind of ecological inorganic mineral decorative material for internal wall, take zeolite powder, diatomite in powder, bentonite in powder is basis, using white cement as matrix material, be aided with the additives such as a small amount of titanium dioxide, pigment, ether of cellulose or auxiliary agent is prepared from simultaneously, have the function of coating and mortar concurrently, and have and purify air and the effect such as automatic humidity-regulating, be a kind of environmental decorative material for internal wall.
For realizing above target, the present invention adopts following technical solution:
An ecological inorganic mineral decorative material for internal wall, is comprised of the raw material of following weight percent:
Figure BDA00002370390600021
The weight percent sum of above-mentioned raw materials is 100%.
The main component of the white cement described in ecological inorganic mineral decorative material for internal wall of the present invention is tricalcium silicate (C 3s), Dicalcium Phosphate (Feed Grade) (C 2s) and tricalcium aluminate (C 3a), a main cohesive action after aquation.Described white cement should meet the requirement of GB/T 2015-2005 white portland cement national standard.
Zeolite powder described in ecological inorganic mineral decorative material for internal wall of the present invention is natural levigate the forming of Zeolite Rock.Described calcined diatomite powder is that natural diatomaceous earth is through high temperature (550 ℃-850 ℃) calcining and levigate forming.Zeolite powder and this bi-material of calcined diatomite powder are vesicular structure, and specific surface area is large, has moisture adsorption and releasing effect, and its fineness requirement is all preferably 200 order-400 orders, and moisture adsorption and releasing effect is more remarkable; Existing silicon powder does not have vesicular structure, and moisture adsorption and releasing effect is not obvious.
Quartz sand described in ecological inorganic mineral decorative material for internal wall of the present invention plays fine aggregate effect, and fineness requirement is preferably 40 order-120 orders.
Dicalcium powder described in ecological inorganic mineral decorative material for internal wall of the present invention is as filler, and fineness requirement is preferably 200 order-400 orders.
Nano titanium oxide described in ecological inorganic mineral decorative material for internal wall of the present invention plays antibacterial and air purification effect.
Polymer dispersion powder described in ecological inorganic mineral decorative material for internal wall of the present invention mainly plays auxiliary cohesive action.
Ether of cellulose described in ecological inorganic mineral decorative material for internal wall of the present invention mainly plays water retention; after making it to add water, moisture is difficult for losing; and progressively discharge within long period of time; it forms protective colloid after also dissolving in water simultaneously; " parcel " lives solid particulate; at solid particulate outside surface, form one deck lubricant film, improve in the mobility of whipping process and the slipping of construction.The combined influence of considering ether of cellulose dispersiveness, water-retentivity and application property, in selecting, low viscous Vltra tears (HPMC) is advisable.Therefore, described ecological inorganic mineral decorative material for internal wall, preferably the raw material by following weight percent forms:
Figure BDA00002370390600031
Wilkinite main component described in ecological inorganic mineral decorative material for internal wall of the present invention is polynite, has the performance of adsorptivity and thixotroping, also has thickening power, and fineness requirement is preferably 200 order-400 orders.
Pigment described in ecological inorganic mineral decorative material for internal wall of the present invention is used to ecological inorganic mineral decorative material for internal wall color is provided, can select as required the pigment of respective color, as wanted, keep the reality color of ecological inorganic mineral decorative material for internal wall without adding pigment.
Further preferably, described ecological inorganic mineral decorative material for internal wall, is comprised of the raw material of following weight percent:
Figure BDA00002370390600042
Described raw material all can adopt commercially available prod.
The preparation method of described ecological inorganic mineral decorative material for internal wall is very simple, only each raw material fully need to be mixed and can obtain ecological inorganic mineral decorative material for internal wall.
Described ecological inorganic mineral decorative material for internal wall is used also very convenient, in use, in described ecological inorganic mineral decorative material for internal wall, adds appropriate water, stirs, by whitewashing or the prior art such as spraying is applied to wall.
Compared with prior art, tool of the present invention has the following advantages:
Ecological inorganic mineral decorative material for internal wall of the present invention, it is all almost inorganic mineral material, a small amount of additive used is not also completely containing volatility and toxic substances such as formaldehyde, benzene, simultaneously, the materials such as diatomite used, zeolite also have absorption and automatic humidity-regulating effect, simultaneously nano titanium oxide also has certain antibacterial and air purification effect, because of but a kind of multi-functional environmental finishing material has the features such as attractive in appearance, comfortable, safety and environmental protection concurrently.
Each component of ecological inorganic mineral decorative material for internal wall of the present invention is commercial goods, manufacture craft is simple, product is single dry powder material, add water and stir and can be used for whitewashing or spraying, store, transportation and use all very conveniently, can be used as inner wall of building finishing material.
Embodiment
Below in conjunction with following embodiment, the present invention is made to further detailed description.
Described per-cent is all weight percentage.
Described white cement, quartz sand, calcined diatomite powder, zeolite powder, dicalcium powder, bentonite in powder, nano titanium oxide, pigment, polymer dispersion powder etc. are commercially available prod, and wherein white cement main component is C 3s, C 2s and C 3a, meets the requirement of GB/T 2015-2005 white portland cement national standard, and strength grade is 42.5.Calcined diatomite powder is natural diatomaceous earth levigate powder forming after 700 ℃ ± 50 ℃ are calcined 2 hours, and fineness is 200 order-400 orders.
Embodiment 1:
Press white cement 15%, 200 order-400 object zeolite powders 5%, calcined diatomite powder 15%, 40 order-120 object quartz sands 50%, 200 order-400 object dicalcium powders 6.5%, 200 order-400 object bentonite in powder 3%, nano titanium oxide 1%, iron oxide red pigment 1.5% and Wa Ke polymer dispersion powder (5044, Germany watt gram) 3% take raw material, fully mix, obtain ecological inorganic mineral decorative material for internal wall.
In above-mentioned ecological inorganic mineral decorative material for internal wall, add suitable quantity of water (ecological inorganic mineral decorative material for internal wall dry powder: water=1:0.33, weight ratio), stir by whitewashing or be sprayed at wall, obtain having the decorated wall surface of texture, can be used for the decoration of interior wall.
Embodiment 2:
Press white cement 20%, 200 order-400 object zeolite powders 10%, calcined diatomite powder 10%, 40 order-120 object quartz sands 40%, 200 order-400 object dicalcium powders 12.4%, 200 order-400 object bentonite in powder 3%, nano titanium oxide 1%, iron oxide yellow pigments 1%, HPMC 0.1% and Wa Ke polymer dispersion powder (5044, Germany watt gram) 2.5% take raw material, fully mix, obtain ecological inorganic mineral decorative material for internal wall.
In above-mentioned ecological inorganic mineral decorative material for internal wall, add suitable quantity of water (ecological inorganic mineral decorative material for internal wall dry powder: water=1:0.35, weight ratio), stir by whitewashing or be sprayed at wall, obtain having the decorated wall surface of texture, can be used for the decoration of interior wall.
Embodiment 3:
Press white cement 25%, 200 order-400 object zeolite powders 15%, calcined diatomite powder 5%, 40 order-120 object quartz sands 40%, 200 order-400 object dicalcium powders 9.9%, 200 order-400 object bentonite in powder 2%, nano titanium oxide 0.5%, green composite pigment 0.5%, HPMC 0.1% and Wa Ke polymer dispersion powder (5044, Germany watt gram) 2% take raw material, fully mix, obtain ecological inorganic mineral decorative material for internal wall.
In above-mentioned ecological inorganic mineral decorative material for internal wall, add suitable quantity of water (ecological inorganic mineral decorative material for internal wall dry powder: water=1:0.37, weight ratio), stir by whitewashing or be sprayed at wall, obtain having the decorated wall surface of texture, can be used for the decoration of interior wall.
Embodiment 4:
Press white cement 30%, 200 order-400 object zeolite powders 15%, calcined diatomite powder 5%, 40 order-120 object quartz sands 40%, 200 order-400 object dicalcium powders 5.9%, 200 order-400 object bentonite in powder 1.9%, nano titanium oxide 0.5%, cologne earth pigment 0.5%, HPMC 0.2% and Wa Ke polymer dispersion powder (5044, Germany watt gram) 1% take raw material, fully mix, obtain ecological inorganic mineral decorative material for internal wall.
In above-mentioned ecological inorganic mineral decorative material for internal wall, add suitable quantity of water (ecological inorganic mineral decorative material for internal wall dry powder: water=1:0.38, weight ratio), stir by whitewashing or be sprayed at wall, obtain having the decorated wall surface of texture, can be used for the decoration of interior wall.
Embodiment 5:
Calcined diatomite powder is natural diatomaceous earth levigate powder forming after 500 ℃ are calcined 2 hours, and fineness is 200 order-400 orders.
Press white cement 20%, 200 order-400 object zeolite powders 10.6%, calcined diatomite powder 15%, 40 order-120 object quartz sands 30%, 200 order-400 object dicalcium powders 20%, nano titanium oxide 1%, compound blue pigment 1%, HPMC 0.4% and Wa Ke polymer dispersion powder (5044, Germany watt gram) 2% take raw material, fully mix, obtain ecological inorganic mineral decorative material for internal wall.
In above-mentioned ecological inorganic mineral decorative material for internal wall, add suitable quantity of water (ecological inorganic mineral decorative material for internal wall dry powder: water=1:0.4, weight ratio), stir by whitewashing or be sprayed at wall, obtain having the decorated wall surface of texture, can be used for the decoration of interior wall.

Claims (6)

1. an ecological inorganic mineral decorative material for internal wall, is characterized in that, the raw material of following weight percent, consists of:
Described calcined diatomite powder be natural diatomaceous earth through 550 ℃ of-850 ℃ of high-temperature calcinations and levigate forming, the fineness of described calcined diatomite powder is 200 order-400 orders.
2. ecological inorganic mineral decorative material for internal wall according to claim 1, is characterized in that, the fineness of described zeolite powder is 200 order-400 orders.
3. ecological inorganic mineral decorative material for internal wall according to claim 1, is characterized in that, described quartz sand fineness is 40 order-120 orders.
4. ecological inorganic mineral decorative material for internal wall according to claim 1, is characterized in that, described dicalcium powder fineness is 200 order-400 orders.
5. ecological inorganic mineral decorative material for internal wall according to claim 1, is characterized in that, described wilkinite fineness is 200 order-400 orders.
6. ecological inorganic mineral decorative material for internal wall according to claim 1, is characterized in that, described ether of cellulose is Vltra tears.
CN201210443903.8A 2012-11-07 2012-11-07 Interior wall decoration material composed of ecological inorganic minerals Expired - Fee Related CN102936119B (en)

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