CN103086640A - Diatom ooze decorative wall material modified by silicate mineral powder - Google Patents

Diatom ooze decorative wall material modified by silicate mineral powder Download PDF

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Publication number
CN103086640A
CN103086640A CN2013100574923A CN201310057492A CN103086640A CN 103086640 A CN103086640 A CN 103086640A CN 2013100574923 A CN2013100574923 A CN 2013100574923A CN 201310057492 A CN201310057492 A CN 201310057492A CN 103086640 A CN103086640 A CN 103086640A
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wall material
diatom ooze
sepiolite
order
orders
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CN2013100574923A
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Chinese (zh)
Inventor
万克权
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HUNAN BOTONG NEW BUILDING MATERIAL CO Ltd
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HUNAN BOTONG NEW BUILDING MATERIAL CO Ltd
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Priority to CN2013100574923A priority Critical patent/CN103086640A/en
Publication of CN103086640A publication Critical patent/CN103086640A/en
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Abstract

The invention discloses a diatom ooze decorative wall material modified by silicate mineral powder, and relates to the technical field of interior decoration materials. The diatom ooze decorative wall material is prepared from the following raw materials in percentage by weight: 30-35% of diatomite (325-800 meshes), 10-15% of clay sepiolite (200-300 meshes), 0.4-0.6% of sodium-based bentonite (200-400 meshes), 0.3-0.4% of fibrous sepiolite, 35-45% of sierozem (calcium content: 95%),10-20% of natural colored sand (5-10 meshes), 0.15-0.17% of high-strength adhesive, 0.01-0.05% of water-retention and thickening plasticizer, 0.01-0.1% of ecological pigments, 0.005-0.01% of wetting dispersant, and 0.03-0.04% of nano titanium dioxide diatomite composite photocatalytic material. The wall material disclosed by the invention has the advantages of simple production process, easily-purchased raw materials, low cost, simple construction, low cost, strong adsorption, easiness for maintenance, and capability of preventing dust retention and degrading formaldehyde, and the like.

Description

A kind of diatom ooze decoration wall material by the silicate mineral powder structural reform
Technical field
The present invention relates to the house decorative material technical field, specifically be a kind of diatom ooze decoration wall material by the silicate mineral powder structural reform.
Background technology
Along with improving constantly of the progress of the development of society, science and technology, standard of living, people constantly strengthen health environment-friendly consciousness, living environment self health is more and more paid attention to, be embodied in the life all respects, home decoration also is listed as wherein, is decorated by original single aesthetic property, transfers present functional ornamentation to, quality, comfortableness, the feature of environmental protection and individual decoration to room air have unprecedented requirement.
For these years, home decoration wall material is by paint class (containing liquid wallpaper), and wallpaper class etc. is held monopoly position, and the decoration wall material of a small amount of Art Stone and so on occurred afterwards.Above-mentioned several wall material respectively has relative merits but can not be complementary, therefore caused many congenital defects of existing wall material, the more important thing is these wall materials in decorating and using, and VOC discharging is in various degree arranged, and has affected people's health, very not environmental protection.And reducing the method for these harmful effects, people tightly just put flavor by windowing, and be aided with the passive means such as scavenging material of objectionable impurities in absorbed air, not only can not fundamentally remove objectionable impurities, and the scavenging material ubiquity is expensive, adsorption efficiency is also limited, and the effect that purifies air is also not obvious.
Summary of the invention
The deficiency that exists in order to overcome above-mentioned prior art, the invention provides a kind of cheap, adsorptivity strong, can prevent hanging dirt, degraded Jia Chuo, the diatom ooze decoration wall material by the silicate mineral powder structural reform being convenient to safeguard.
technical scheme of the present invention is: a kind of diatom ooze decoration wall material by the silicate mineral powder structural reform, preparation of raw material by following weight percent forms: diatomite (325 orders-800 order) 30-35%, clay sepiolite (200 orders-300 order) 10-15%, sodium bentonite (200 orders-400 order) 0.4-0.6%, fibrous sepiolite 0.3-0.4%, ash calcium (calcium content 95%) 35-45%, natural colour sand (5 orders-10 order) 10-20%, high-strength binding agent 0.15-0.17%, water-keeping thickening fluidizer 0.01-0.05%, ecological pigment 0.01-0.1%, Ricinate 0.005-0.01%, nano titanium oxide diatomite composite photocatalytic material 0.03-0.04%.
As preferred version, in above-mentioned diatom ooze decoration wall material, the optimum weight ratio of each raw material is: diatomite (325 orders-800 order) 33%, clay sepiolite (200 orders-300 order) 11%, sodium bentonite (200 orders-400 order) 0.4%, fibrous sepiolite 0.35%, grey calcium (calcium content 95%) 45%, natural colour sand (5 orders-10 order) 10%, high-strength binding agent 0.16%, water-keeping thickening fluidizer 0.04%, ecological pigment 0.01%, Ricinate 0.005%, nano titanium oxide diatomite composite photocatalytic material 0.035%.
In above-mentioned formula, diatomite, clay sepiolite, fibrous sepiolite, sodium bentonite all belong to silicate mine and are, physico-chemical property has many something in common, and adsorptivity is stronger.There is numerous foveola on the diatomite surface, and the hole volume is large, and porosity reaches 80%-90%, so adsorptivity is very strong, energy is adjusting air humidity degraded VOC well, and sepiolite is also a kind of porous material, and specific surface area and pore volume are very large, and (theoretical total surface area reaches 900m 2/ g) pore volume 0.385m 2/ g), very strong adsorptivity being arranged also, the moisture of absorption compares itself the large 2-3 of weight times, the i.e. characteristics such as plasticity-, dispersiveness, thixotropy.Diatomite and sepiolite are composite, and workability is greatly improved under the constant condition of adsorptivity.The clay sepiolite is the one-level sepiolite, and concrete composition is sepiolite 70%, quartzite 10%, talcum 15%, calcite 5%.Fibrous sepiolite also has the effect of anti-cracking resistance except the performance that above-mentioned clay sepiolite is arranged.
Sodium bentonite has water-swellable and the large characteristics of cation exchange capacity, the good dispersity in water, and colloid index is high, and stickiness, oilness and thermostability are all good, can further improve the over-all propertieies such as application property of product; Can reduce simultaneously the volume of high molecular polymer, environmental protection is more energy-conservation more to make product.
Ash calcium is the air-setting inorganic coagulation material, and water retaining function, Yi Hexing, plasticity-are good, can absorb airborne CO 2, become Ca CO 3Strengthen raw-material intensity; Natural colour sand is selected through fragmentation, and its effect strengthens the color of wall material, plays skeleton function in the system of product.Different particles, distinct colors can satisfy the individual demand of different user.Ecological pigment strengthens the ornamental of product.
In above-mentioned formula, high-strength binding agent is the modification kollidon, and it can strengthen sticking power, cohesive force, the interior sticking power of product and basal plane; Water-keeping thickening fluidizer (HPMC) plays water-keeping thickening, extends the open hour; Ricinate is the polyphosphoric acid sodium salt, and effect is to disperse those to be difficult to be dissolved in the particle of liquid, reduces mutual reactive force, frictional force, plays simultaneously the sedimentation and the cohesion that prevent solid particulate, forms stable suspension, needs to control addition.
Nano titanium oxide diatomite composite photocatalytic material in above-mentioned formula (China Mining University's development), the objectionable impuritiess such as airborne free formaldehyde of can repeatedly degrading under illumination condition, degradation rate reaches more than 75%.Because the carrier of this material is diatomite, so better with the intermiscibility of original product, sticking power is stronger, inhale that to put degradation function better, has played the effect of 1+1>2.
At the construction field (site), with the diatom ooze decoration wall material of silicate mineral powder structural reform, can construct after adding water and stirring, by weight, wall material with the ratio of water is: 1: 1.5; Its construction process is: the basal plane levelling, and------------smearing by hand moulding or mechanically spraying moulding---removes moulding mould after little doing to the cementation moulding mould to the snap the line lattice to add water and material on request.
The present invention has following advantage compared to existing technology; 1, production technique of the present invention is simple, and raw material is easily purchased, cheap, easy construction; 2, compare with existing emulsion wall material, the honest nature of accumulating convenient construction facing, texture is vividly true, goes back the objectionable impuritiess such as degradable air Free-formaldehyde, can prevent hanging dirt, has certain metope self-cleaning function; 3, compare with wallpaper material, texture is abundanter, and the design randomness greatly, more easily represents personalization, fashion-orientation is decorated, VOC free objectionable impurities in construction and use; 4, compare with cultural cliff material, cost hangs down easy construction various shapes, color variation, easily renovation; 5, compare with existing diatom ooze wall material, due to sepiolite add adsorptivity stronger, reduced simultaneously the volume of macromolecule organic, reduced cost, more environmental protection is more energy-conservation, construction Yi Hexing, plasticity-, thixotropy are better.Owing to making adding of color sand material slightly be constructed with order, the better effects if of imitative Art Stone can form unique anaglyph, further improves the textural effect of material, and people's imagination space is expressed in sustenances that can more carrying people, shows the color of Artline.Adding of nano titanium dioxide/diatomite composite photocatalytic material in addition, can more effective degraded Kong gas Zhong Jia Chuo etc. objectionable impurities (under the condition of illumination), degradation rate reaches more than 75%.
Embodiment
Now in conjunction with specific embodiments, technology contents of the present invention is further described.
embodiment 1: each material content of diatom ooze decoration wall material of this example silicate mineral powder structural reform is: diatomite (325 orders-800 order) 33%, clay sepiolite (200 orders-300 order) 11%, sodium bentonite (200 orders-400 order) 0.4%, fibrous sepiolite 0.35%, ash calcium (calcium content 95%) 45%, natural colour sand (5 orders-10 order) 10%, high-strength binding agent 0.16%, water-keeping thickening fluidizer 0.04%, ecological pigment 0.01%, Ricinate 0.005%, nano titanium oxide diatomite composite photocatalytic material 0.035%, strict with above-mentioned weight percent metering during production.Be transported to the building site and add water stirring, material-water ratio: 1: 1.5.This example diatom ooze wall material is used for Indoor Residential Ecological and decorates.
embodiment 2: each material content of diatom ooze decoration wall material of this example silicate mineral powder structural reform is: diatomite (325 orders-800 order) 35%, clay sepiolite (200 orders-300 order) 12.8%, sodium bentonite (200 orders-400 order) 0.5%, fibrous sepiolite 0.4%, ash calcium (calcium content 95%) 36%, natural colour sand (5 orders-10 order) 15%, high-strength binding agent 0.17%, water-keeping thickening fluidizer 0.05%, ecological pigment 0.04%, Ricinate 0.01%, nano titanium oxide diatomite composite photocatalytic material 0.03%.Strict with above-mentioned weight percent metering during production.Be transported to the building site and add water stirring, material-water ratio: 1: 1.5.This example diatom ooze wall material is used for the hotel, hotel is decorated.
Above content is to further illustrate in conjunction with concrete preferred implementation is made for the present invention; can not assert that concrete enforcement of the present invention is confined to these explanations; for the general technical staff of the technical field of the invention; under the prerequisite that does not break away from design of the present invention; can also do some simple deductions and replacement, all should be considered as belonging to protection scope of the present invention.

Claims (6)

1. diatom ooze decoration wall material by the silicate mineral powder structural reform, it is characterized in that: the preparation of raw material by following weight percent forms: diatomite (325 orders-800 order) 30-35%, clay sepiolite (200 orders-300 order) 10-15%, sodium bentonite (200 orders-400 order) 0.4-0.6%, fibrous sepiolite 0.3-0.4%, ash calcium (calcium content 95%) 35-45%, natural colour sand (5 orders-10 order) 10-20%, high-strength binding agent 0.15-0.17%, water-keeping thickening fluidizer 0.01-0.05%, ecological pigment 0.01-0.1%, Ricinate 0.005-0.01%, nano titanium oxide diatomite composite photocatalytic material 0.03-0.04%.
2. a kind of diatom ooze decoration wall material by the silicate mineral powder structural reform according to claim 1, it is characterized in that: in above-mentioned diatom ooze decoration wall material, the optimum weight ratio of each raw material is: diatomite (325 orders-800 order) 33%, clay sepiolite (200 orders-300 order) 11%, sodium bentonite (200-400 order) 0.4%, fibrous sepiolite 0.35%, ash calcium (calcium content 95%) 45%, large right color sand (5 orders-10 order) 10%, high-strength binding agent 0.16%, water-keeping thickening fluidizer 0.04%, ecological pigment 0.01%, Ricinate 0.005%, nano titanium oxide diatomite composite photocatalytic material 0.035%.
3. a kind of diatom ooze decoration wall material by the silicate mineral powder structural reform according to claim 1 and 2, it is characterized in that: described high-strength binding agent is the modification kollidon.
4. a kind of diatom ooze decoration wall material by the silicate mineral powder structural reform according to claim 3, it is characterized in that: described Ricinate is the polyphosphoric acid sodium salt.
5. a kind of diatom ooze decoration wall material by the silicate mineral powder structural reform according to claim 3, it is characterized in that: by weight, when wherein constructing, material-water ratio is wall material: water=1: 1.5.
6. a kind of diatom ooze decoration wall material by the silicate mineral powder structural reform according to claim 3, it is characterized in that: the clay sepiolite is the one-level sepiolite, concrete composition is sepiolite 70%, quartzite 10%, talcum 15%, calcite 5%.
CN2013100574923A 2013-02-25 2013-02-25 Diatom ooze decorative wall material modified by silicate mineral powder Pending CN103086640A (en)

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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103467053A (en) * 2013-08-30 2013-12-25 成都新柯力化工科技有限公司 Novel multifunctional diatom ooze decorative wall material and preparation method thereof
CN103755219A (en) * 2014-01-26 2014-04-30 邵水永 Diatomite wall material imitating Australian sandstones and construction method thereof
CN103864344A (en) * 2014-01-26 2014-06-18 邵水永 Italian light travertine-like kieselguhr wall material and construction method thereof
CN103864343A (en) * 2014-01-26 2014-06-18 邵水永 Diatomite wall material with Barcelona style of Royal Family series and construction method thereof
CN103864348A (en) * 2014-01-26 2014-06-18 邵水永 Diatomite wall material for archaized loam wall and construction method of diatomite wall material
CN103880325A (en) * 2014-01-26 2014-06-25 邵水永 Diatomite wall material with dreamy effect and construction method thereof
CN104895206A (en) * 2015-06-10 2015-09-09 青岛科瑞新型环保材料有限公司 Composite vacuum heat insulation and preservation plate and long-term breathing mud thereof
CN104912212A (en) * 2015-06-10 2015-09-16 青岛科瑞新型环保材料有限公司 Composite vacuum thermal isolation heat preservation board and long-acting breathing mud thereof
CN104962198A (en) * 2015-01-25 2015-10-07 孙远慧 Liquid diatom ooze
CN105504894A (en) * 2015-12-23 2016-04-20 湖北格林森新型建材科技有限公司 Algae and calcium containing inorganic ecological coating and preparation method thereof
CN106032312A (en) * 2015-03-18 2016-10-19 山西亮龙涂料有限公司 Diatom mud and preparation method thereof
CN106277982A (en) * 2016-08-16 2017-01-04 成都斯米利亚硅藻新材料有限公司 A kind of Concha Tridacna squamosa mud of energy the nerves calming and preparation method thereof
CN106316211A (en) * 2016-08-08 2017-01-11 凡音环保科技(苏州)有限公司 Environmentally friendly embossed coating
CN107089814A (en) * 2017-05-27 2017-08-25 绍兴职业技术学院 A kind of low-carbon environment-friendly fine fitment decoration mortar and preparation method thereof

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CN101574640A (en) * 2008-05-08 2009-11-11 王岚 Mineral micro powder lasting aldehyde and odor removing bag
CN102633475A (en) * 2012-04-27 2012-08-15 青岛泉佳美硅藻泥科技有限公司 Non-glue diatom ooze building material

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CN101574640A (en) * 2008-05-08 2009-11-11 王岚 Mineral micro powder lasting aldehyde and odor removing bag
CN102633475A (en) * 2012-04-27 2012-08-15 青岛泉佳美硅藻泥科技有限公司 Non-glue diatom ooze building material

Cited By (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103467053B (en) * 2013-08-30 2015-01-07 成都新柯力化工科技有限公司 Novel multifunctional diatom ooze decorative wall material and preparation method thereof
CN103467053A (en) * 2013-08-30 2013-12-25 成都新柯力化工科技有限公司 Novel multifunctional diatom ooze decorative wall material and preparation method thereof
CN103864348B (en) * 2014-01-26 2016-01-06 邵水永 Loam wall kieselguhr wall material modelled after an antique and constructional method thereof
CN103864343B (en) * 2014-01-26 2016-04-27 邵水永 Kieselguhr wall material and constructional method thereof
CN103864348A (en) * 2014-01-26 2014-06-18 邵水永 Diatomite wall material for archaized loam wall and construction method of diatomite wall material
CN103880325A (en) * 2014-01-26 2014-06-25 邵水永 Diatomite wall material with dreamy effect and construction method thereof
CN103864344A (en) * 2014-01-26 2014-06-18 邵水永 Italian light travertine-like kieselguhr wall material and construction method thereof
CN103755219A (en) * 2014-01-26 2014-04-30 邵水永 Diatomite wall material imitating Australian sandstones and construction method thereof
CN103864343A (en) * 2014-01-26 2014-06-18 邵水永 Diatomite wall material with Barcelona style of Royal Family series and construction method thereof
CN103755219B (en) * 2014-01-26 2015-12-30 邵水永 Imitative Australian Sandstone kieselguhr wall material and constructional method thereof
CN103880325B (en) * 2014-01-26 2015-12-30 邵水永 Kieselguhr wall material and constructional method thereof
CN103864344B (en) * 2014-01-26 2016-01-06 邵水永 Imitative Italian rice hole stone kieselguhr wall material and constructional method thereof
CN104962198A (en) * 2015-01-25 2015-10-07 孙远慧 Liquid diatom ooze
CN106032312A (en) * 2015-03-18 2016-10-19 山西亮龙涂料有限公司 Diatom mud and preparation method thereof
CN104912212A (en) * 2015-06-10 2015-09-16 青岛科瑞新型环保材料有限公司 Composite vacuum thermal isolation heat preservation board and long-acting breathing mud thereof
CN104895206B (en) * 2015-06-10 2016-08-24 安徽科瑞克保温材料有限公司 A kind of composite evacuated heat insulating board and long-acting breathing mud thereof
CN104912212B (en) * 2015-06-10 2016-09-28 青岛科瑞新型环保材料有限公司 A kind of long-acting breathing mud
CN106242460A (en) * 2015-06-10 2016-12-21 青岛科瑞新型环保材料集团有限公司 A kind of interior decoration mud
CN106242459A (en) * 2015-06-10 2016-12-21 青岛科瑞新型环保材料集团有限公司 A kind of long-acting mud of indoor decoration
CN106242460B (en) * 2015-06-10 2018-05-04 青岛克瑞克绿色建材有限公司 A kind of interior decoration mud
CN106242459B (en) * 2015-06-10 2018-05-01 青岛克瑞克绿色建材有限公司 A kind of long-acting mud of indoor decoration
CN104895206A (en) * 2015-06-10 2015-09-09 青岛科瑞新型环保材料有限公司 Composite vacuum heat insulation and preservation plate and long-term breathing mud thereof
CN105504894A (en) * 2015-12-23 2016-04-20 湖北格林森新型建材科技有限公司 Algae and calcium containing inorganic ecological coating and preparation method thereof
CN106316211A (en) * 2016-08-08 2017-01-11 凡音环保科技(苏州)有限公司 Environmentally friendly embossed coating
CN106277982A (en) * 2016-08-16 2017-01-04 成都斯米利亚硅藻新材料有限公司 A kind of Concha Tridacna squamosa mud of energy the nerves calming and preparation method thereof
CN107089814A (en) * 2017-05-27 2017-08-25 绍兴职业技术学院 A kind of low-carbon environment-friendly fine fitment decoration mortar and preparation method thereof

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Application publication date: 20130508