CN107216754A - One kind is except haze interiro wall latex paint and preparation method thereof - Google Patents
One kind is except haze interiro wall latex paint and preparation method thereof Download PDFInfo
- Publication number
- CN107216754A CN107216754A CN201710439484.3A CN201710439484A CN107216754A CN 107216754 A CN107216754 A CN 107216754A CN 201710439484 A CN201710439484 A CN 201710439484A CN 107216754 A CN107216754 A CN 107216754A
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- China
- Prior art keywords
- latex paint
- wall latex
- interiro wall
- parts
- haze
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses one kind except haze interiro wall latex paint and preparation method thereof, the emulsion paint is prepared from by the raw material of following mass parts：25~30 parts of hydrophobic and oil repellent emulsion, 15~20 parts of rutile type titanium white, 5~10 parts of nano-tourmaline powder, 0.3~0.5 part of modified hydroxyethylcellulosadsorbing, 3~18 parts of filler, 0.5~1.0 part of defoamer, 0.1~2.0 part of wetting agent, 0.5~1.0 part of dispersant, 0.5~1.0 part of thickener, 0.1~0.5 part of bactericide, 0.1~0.5 part of preservative, 0.1~0.5 part of pH adjusting agent, 0~2 part of coalescents, 0~5 part of functional additive, 15~25 parts of water.The present invention's removes the low VOC of haze interiro wall latex paint, being capable of decomposing formaldehyde and releasing negative oxygen ion, indoor air environment can be significantly improved for interior decoration, and can quickly move in, compared with the similar-type products of in the market, with contrast ratio is high, abrasion resistance and the features such as excellent stain resistance, preparation method is simple, it is cheap, it can be widely popularized and use.
Description
Technical field
The present invention relates to one kind except haze interiro wall latex paint and preparation method thereof, belong to technical field of coatings.
Background technology
In recent years, developing rapidly with industry, air pollution is increasingly severe, is subject to the people's attention.Air is dirty
Dye is mainly derived from three aspects：1) industrial pollution：The harmful substances such as flue dust, sulfide, nitride, the halide of plant emissions；
2) domestic pollution：People are cooked, warmed oneself, taking a shower etc. during daily life, and the coal of air is discharged into due to combustion of fossil fuels
Cigarette, sulfur dioxide etc., with discharge capacity is big, distribution is wide, the low feature of height of release, endanger big；3) automobile exhaust pollution：Discharge
Waste gas mainly have carbon monoxide, sulfur dioxide, nitrogen oxides and hydrocarbon etc., respirator of these pollutants to human body
Official's harm is very big.PM2.5 is the important indicator for weighing particulate in air, and the requirement with people to living environment is increasingly
Height, this obscure specific term of PM2.5 has been known to ordinary populace.In addition, with the rise of low-carbon environment-friendly concept, people
Everyway in life starts to pursue environmental protection concept, for example：In house decoration, prevalence uses environment-friendly type coating.
At present, commercially available environment-friendly type emulsion paint is primarily present following shortcoming：Although 1) the pernicious gas content energy discharged
GB18582-2008 standards are enough met, but are also far from reaching low VOC standards；2) the anti-formaldehyde function having is physics
Adsorption process, can not be fully achieved effect of decomposing formaldehyde；3) dust in air, little particle can not be adsorbed, to Interior Space
The catharsis of gas is limited；4) cost is too high, and selling price is not human-oriented, it is impossible to popularization and application.
Therefore, it is necessary to which developing a kind of can significantly improve the interiro wall latex paint of indoor air environment.
The content of the invention
It is an object of the invention to provide one kind except haze interiro wall latex paint and preparation method thereof.
The technical solution used in the present invention is：
One kind removes haze interiro wall latex paint, is prepared from by the raw material of following mass parts：25~30 parts of hydrophobic and oil repellent emulsion, gold
Red 15~20 parts of stone-type titanium dioxide, 5~10 parts of nano-tourmaline powder, 0.3~0.5 part of modified hydroxyethylcellulosadsorbing, filler 3~18
Part, 0.5~1.0 part of defoamer, 0.1~2.0 part of wetting agent, 0.5~1.0 part of dispersant, 0.5~1.0 part of thickener, bactericide
0.1~0.5 part, 0.1~0.5 part of preservative, 0.1~0.5 part of pH adjusting agent, 0~2 part of coalescents, functional additive 0~5
Part, 15~25 parts of water.
Described hydrophobic and oil repellent emulsion be in the rich RS-2683 emulsions of Ahmedabad, the NPE-9169 emulsions of DOW Chemical extremely
Few one kind.
Described filler is at least one of calcined kaolin, diatomite, dicalcium powder.
Described defoamer be organic silicon defoamer, polyether antifoam agent, polymer compounded mineral oil defoamer at least
It is a kind of.
Described wetting agent is at least one of alkyl polyoxyethylene ether, ethylene oxide-propylene oxide block copolymer.
Described dispersant is at least one of phosphate, hydrophobically modified ammonium polyacrylate salt, polycarboxylic acids sodium.
Described thickener is at least one of alkali swelling thickener, polyethers thickener.
Described bactericide be CMIT, OIT, ZPT in extremely
Few one kind.
Described preservative is 2- benzimidazole carbamates.
Described pH adjusting agent is 2-amino-2-methyl-1-propanol.
The above-mentioned preparation method except haze interiro wall latex paint comprises the following steps：
1) premix：Water and dispersant are added into dispersion machine, are well mixed, modified hydroxyethylcellulosadsorbing is added, mixing is equal
It is even, wetting agent, filler, rutile type titanium white and nano-tourmaline powder are added, pH adjusting agent is added, is well mixed；
2) it is let down：Sampling detection, when granularity is less than 50 μm, adds coalescents, bactericide, preservative and thickener,
It is well mixed, hydrophobic and oil repellent emulsion, functional additive and defoamer are added, is well mixed, obtains removing haze interiro wall latex paint.
The beneficial effects of the invention are as follows：
1) removing for the present invention is added with nano modification tourmaline in haze interiro wall latex paint, not only increases the stain resistant of paint film
Property, and can releasing negative oxygen ion, indoor air environment can be significantly improved；
2) removing in haze interiro wall latex paint for the present invention is not added with any component containing formaldehyde and VOC, not only low VOC, and
Function with decomposing formaldehyde, and the process of decomposing formaldehyde is irreversible, can quickly be moved in for interior decoration；
3) it is of the invention except haze interiro wall latex paint is compared with the similar-type products of in the market, with contrast ratio height, washability
Property and stain resistance it is excellent the features such as, preparation method is simple, cheap, can be widely popularized and use.
Embodiment
One kind removes haze interiro wall latex paint, is prepared from by the raw material of following mass parts：25~30 parts of hydrophobic and oil repellent emulsion, gold
Red 15~20 parts of stone-type titanium dioxide, 5~10 parts of nano-tourmaline powder, 0.3~0.5 part of modified hydroxyethylcellulosadsorbing, filler 3~18
Part, 0.5~1.0 part of defoamer, 0.1~2.0 part of wetting agent, 0.5~1.0 part of dispersant, 0.5~1.0 part of thickener, bactericide
0.1~0.5 part, 0.1~0.5 part of preservative, 0.1~0.5 part of pH adjusting agent, 0~2 part of coalescents, functional additive 0~5
Part, 15~25 parts of water.
It is preferred that, described hydrophobic and oil repellent emulsion is the rich RS-2683 emulsions of Ahmedabad, the NPE-9169 emulsions of DOW Chemical
At least one of.
It is preferred that, described filler is at least one of calcined kaolin, diatomite, dicalcium powder.
It is preferred that, described defoamer is in organic silicon defoamer, polyether antifoam agent, polymer compounded mineral oil defoamer
At least one.
It is preferred that, described wetting agent be in alkyl polyoxyethylene ether, ethylene oxide-propylene oxide block copolymer extremely
Few one kind.
It is preferred that, described dispersant is at least one in phosphate, hydrophobically modified ammonium polyacrylate salt, polycarboxylic acids sodium
Kind.
It is preferred that, described thickener is at least one of alkali swelling thickener, polyethers thickener.
It is preferred that, described bactericide is CMIT, OIT, pyrithione
At least one of zinc.
It is preferred that, described preservative is 2- benzimidazole carbamates.
It is preferred that, described pH adjusting agent is 2-amino-2-methyl-1-propanol.
The above-mentioned preparation method except haze interiro wall latex paint comprises the following steps：
1) premix：Water and dispersant are added into dispersion machine, are well mixed, modified hydroxyethylcellulosadsorbing is added, mixing is equal
It is even, wetting agent, filler, rutile type titanium white and nano-tourmaline powder are added, pH adjusting agent is added, is well mixed；
2) it is let down：Sampling detection, when granularity is less than 50 μm, adds coalescents, bactericide, preservative and thickener,
It is well mixed, hydrophobic and oil repellent emulsion, functional additive and defoamer are added, is well mixed, obtains removing haze interiro wall latex paint.
It is preferred that, the above-mentioned preparation method except haze interiro wall latex paint comprises the following steps：
1) pre-mix stage：Water and dispersant are added into dispersion machine, rotating speed is adjusted to 400~600r/min, stirs 1~3min,
Modified hydroxyethylcellulosadsorbing is added, 1~3min is to solution pulp for stirring, and rotating speed is adjusted to 900~1100r/min, then successively
Wetting agent, filler, rutile type titanium white and nano-tourmaline powder are added, pH adjusting agent is added, rotating speed is adjusted to 1200~
1400r/min, stirs 15~20min；
2) it is let down the stage：Sampling detection, when granularity is less than 50 μm, is adjusted to 900~1100r/min by rotating speed, adds successively
Enter coalescents, bactericide, preservative and thickener, stir 2~4min, add hydrophobic and oil repellent emulsion, functional additive and
Defoamer, stirs 2~4min, obtains removing haze interiro wall latex paint.
The present invention is made further explanation and description with reference to specific embodiment.
Embodiment 1：
One kind removes haze interiro wall latex paint, its raw material composition such as following table：
Table 1 is except the raw material composition table of haze interiro wall latex paint
Embodiment 2：
One kind removes haze interiro wall latex paint, its raw material composition such as following table：
Table 2 is except the raw material composition table of haze interiro wall latex paint
Embodiment 3：
One kind removes haze interiro wall latex paint, its raw material composition such as following table：
Table 3 is except the raw material composition table of haze interiro wall latex paint
Embodiment 4：
One kind removes haze interiro wall latex paint, its raw material composition such as following table：
Table 4 is except the raw material composition table of haze interiro wall latex paint
Embodiment 5：
One kind removes haze interiro wall latex paint, its raw material composition such as following table：
Table 5 is except the raw material composition table of haze interiro wall latex paint
Embodiment 6：
One kind removes haze interiro wall latex paint, its raw material composition such as following table：
Table 6 is except the raw material composition table of haze interiro wall latex paint
Test case：
Prepared by the present invention removes haze interiro wall latex paint and the progress performance test of certain commercially available environment-friendly type emulsion paint, test result
It is as shown in the table：
The performance test results for removing haze interiro wall latex paint and certain commercially available environment-friendly type emulsion paint of the present invention of table 7
Above-described embodiment is preferably embodiment, but embodiments of the present invention are not by above-described embodiment of the invention
Limitation, other any Spirit Essences without departing from the present invention and the change made under principle, modification, replacement, combine, simplification,
Equivalent substitute mode is should be, is included within protection scope of the present invention.
Claims (10)
1. one kind removes haze interiro wall latex paint, it is characterised in that：It is prepared from by the raw material of following mass parts：Hydrophobic and oil repellent emulsion 25
~30 parts, 15~20 parts of rutile type titanium white, 5~10 parts of nano-tourmaline powder, 0.3~0.5 part of modified hydroxyethylcellulosadsorbing,
3~18 parts of filler, 0.5~1.0 part of defoamer, 0.1~2.0 part of wetting agent, 0.5~1.0 part of dispersant, thickener 0.5~1.0
Part, 0.1~0.5 part of bactericide, 0.1~0.5 part of preservative, 0.1~0.5 part of pH adjusting agent, 0~2 part of coalescents, function add
Plus 0~5 part of agent, 15~25 parts of water.
2. according to claim 1 remove haze interiro wall latex paint, it is characterised in that：Described hydrophobic and oil repellent emulsion is that Ahmedabad is rich
RS-2683 emulsions, at least one of NPE-9169 emulsions of DOW Chemical.
3. according to claim 1 remove haze interiro wall latex paint, it is characterised in that：Described filler is calcined kaolin, silicon
At least one of diatomaceous earth, dicalcium powder.
4. according to claim 1 remove haze interiro wall latex paint, it is characterised in that：Described defoamer is organosilicon froth breaking
At least one of agent, polyether antifoam agent, polymer compounded mineral oil defoamer.
5. according to claim 1 remove haze interiro wall latex paint, it is characterised in that：Described wetting agent is alkyl polyoxyethylene
At least one of ether, ethylene oxide-propylene oxide block copolymer.
6. according to claim 1 remove haze interiro wall latex paint, it is characterised in that：Described dispersant is phosphate, hydrophobic
At least one of modified polypropene acid ammonium salt, polycarboxylic acids sodium.
7. according to claim 1 remove haze interiro wall latex paint, it is characterised in that：Described thickener thickens for alkali swelling
At least one of agent, polyethers thickener.
8. according to claim 1 remove haze interiro wall latex paint, it is characterised in that：Described bactericide be 5- chloro-2-methyls-
At least one of 4- isothiazoline -3- ketone, OIT, ZPT；Described preservative is 2- benzimidazole ammonia
Carbamate.
9. according to claim 1 remove haze interiro wall latex paint, it is characterised in that：Described pH adjusting agent is 2- amino -2-
Methyl isophthalic acid-propyl alcohol.
10. in claim 1~9 described in any one except the preparation method of haze interiro wall latex paint, it is characterised in that：Including with
Lower step：
1) premix：Water and dispersant are added into dispersion machine, is well mixed, adds modified hydroxyethylcellulosadsorbing, be well mixed, then
Wetting agent, filler, rutile type titanium white and nano-tourmaline powder are added, pH adjusting agent is added, is well mixed；
2) it is let down：Sampling detection, when granularity is less than 50 μm, adds coalescents, bactericide, preservative and thickener, mixing
Uniformly, hydrophobic and oil repellent emulsion, functional additive and defoamer are added, is well mixed, obtains removing haze interiro wall latex paint.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710439484.3A CN107216754A (en) | 2017-06-12 | 2017-06-12 | One kind is except haze interiro wall latex paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710439484.3A CN107216754A (en) | 2017-06-12 | 2017-06-12 | One kind is except haze interiro wall latex paint and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107216754A true CN107216754A (en) | 2017-09-29 |
Family
ID=59947788
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710439484.3A Pending CN107216754A (en) | 2017-06-12 | 2017-06-12 | One kind is except haze interiro wall latex paint and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN107216754A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107868166A (en) * | 2017-11-02 | 2018-04-03 | 佛山市顺德区巴德富实业有限公司 | Modified acrylate emulsion for eliminating formaldehyde in air and preparation method thereof |
| CN108485494A (en) * | 2018-02-05 | 2018-09-04 | 广州立邦涂料有限公司 | A kind of environment friendly emulsion paint for balcony |
| CN111100506A (en) * | 2018-10-25 | 2020-05-05 | 立邦涂料（中国）有限公司 | Mildew-proof environment-friendly water-based color paste suitable for color mixing of automatic color mixer and preparation method thereof |
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| CN104031499A (en) * | 2014-06-09 | 2014-09-10 | 青岛兴国涂料有限公司 | Water-based air purification paint and preparation method thereof |
| CN104371436A (en) * | 2014-11-14 | 2015-02-25 | 三棵树涂料股份有限公司 | Smell-purifying inner wall latex paint and preparation method thereof |
| CN104497685A (en) * | 2014-11-27 | 2015-04-08 | 浙江大学自贡创新中心 | Negative ion-containing antibacterial haze-cleaning paint |
| CN104650735A (en) * | 2015-01-10 | 2015-05-27 | 广东顺德嘉乐士涂料有限公司 | Nano-photocatalytic composite haze and formaldehyde removal latex paint and preparation method thereof |
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2017
- 2017-06-12 CN CN201710439484.3A patent/CN107216754A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104031499A (en) * | 2014-06-09 | 2014-09-10 | 青岛兴国涂料有限公司 | Water-based air purification paint and preparation method thereof |
| CN104371436A (en) * | 2014-11-14 | 2015-02-25 | 三棵树涂料股份有限公司 | Smell-purifying inner wall latex paint and preparation method thereof |
| CN104497685A (en) * | 2014-11-27 | 2015-04-08 | 浙江大学自贡创新中心 | Negative ion-containing antibacterial haze-cleaning paint |
| CN104650735A (en) * | 2015-01-10 | 2015-05-27 | 广东顺德嘉乐士涂料有限公司 | Nano-photocatalytic composite haze and formaldehyde removal latex paint and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107868166A (en) * | 2017-11-02 | 2018-04-03 | 佛山市顺德区巴德富实业有限公司 | Modified acrylate emulsion for eliminating formaldehyde in air and preparation method thereof |
| CN108485494A (en) * | 2018-02-05 | 2018-09-04 | 广州立邦涂料有限公司 | A kind of environment friendly emulsion paint for balcony |
| CN111100506A (en) * | 2018-10-25 | 2020-05-05 | 立邦涂料（中国）有限公司 | Mildew-proof environment-friendly water-based color paste suitable for color mixing of automatic color mixer and preparation method thereof |
| CN111100506B (en) * | 2018-10-25 | 2022-06-28 | 立邦涂料（中国）有限公司 | Mildew-proof environment-friendly color paste suitable for color mixing of automatic color mixer and preparation method thereof |
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Application publication date: 20170929 |