CN102585619B - Environment-friendly emulsion paint with high solid volume content - Google Patents
Environment-friendly emulsion paint with high solid volume content Download PDFInfo
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- CN102585619B CN102585619B CN201210016148.5A CN201210016148A CN102585619B CN 102585619 B CN102585619 B CN 102585619B CN 201210016148 A CN201210016148 A CN 201210016148A CN 102585619 B CN102585619 B CN 102585619B
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- emulsion paint
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- 239000000839 emulsion Substances 0.000 title claims abstract description 38
- 239000003973 paint Substances 0.000 title claims abstract description 35
- 239000007787 solid Substances 0.000 title abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000013530 defoamer Substances 0.000 claims abstract description 11
- 239000002562 thickening agent Substances 0.000 claims abstract description 11
- 239000003899 bactericide agent Substances 0.000 claims abstract description 6
- 239000000080 wetting agent Substances 0.000 claims abstract description 6
- 239000003002 pH adjusting agent Substances 0.000 claims abstract 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 21
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 19
- 239000000463 material Substances 0.000 claims description 12
- 230000008719 thickening Effects 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 238000007689 inspection Methods 0.000 claims description 8
- 238000005070 sampling Methods 0.000 claims description 8
- 239000006185 dispersion Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 239000004408 titanium dioxide Substances 0.000 claims description 6
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 5
- 238000004581 coalescence Methods 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 239000005995 Aluminium silicate Substances 0.000 claims description 3
- 235000012211 aluminium silicate Nutrition 0.000 claims description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 3
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 claims 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims 1
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 238000010276 construction Methods 0.000 abstract description 2
- 239000002270 dispersing agent Substances 0.000 abstract description 2
- 239000012855 volatile organic compound Substances 0.000 abstract 2
- 239000002671 adjuvant Substances 0.000 abstract 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract 1
- 230000002421 anti-septic effect Effects 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 231100000252 nontoxic Toxicity 0.000 abstract 1
- 230000003000 nontoxic effect Effects 0.000 abstract 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 10
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 10
- 235000003140 Panax quinquefolius Nutrition 0.000 description 5
- 240000005373 Panax quinquefolius Species 0.000 description 5
- 229910002092 carbon dioxide Inorganic materials 0.000 description 5
- 230000003750 conditioning effect Effects 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 238000001514 detection method Methods 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 238000010009 beating Methods 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000029553 photosynthesis Effects 0.000 description 1
- 238000010672 photosynthesis Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
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- Paints Or Removers (AREA)
Abstract
The invention discloses an environment-friendly emulsion paint with high solid volume content, which comprises the following components in percentage by weight: 30.0-40.0% of styrene acrylic emulsion, 0.8%-2% of dispersing agent, 0.2%-1% of wetting agent, 0.1%-0.5% of defoamer, 1.0%-10.0% of propylene glycol, 30.0%-40.0% of color filler, 1.5%-2.0% of film forming adjuvant, 0.02%-0.05% of antiseptic bactericide, 0.1%-0.2% of pH modifier, 0.2%-2.0% of thickener and balance of water. According to the invention, the solid volume content of the emulsion paint can be effectively improved; and the emulsion paint is non-toxic, harmless and low in VOC (volatile organic compound) content. Therefore, the emulsion paint disclosed by the invention is an excellent-performance waterborne environment-friendly emulsion paint, and can be widely applied to the coating construction of various wall surfaces.
Description
Technical field
The present invention relates to a kind of environmental protection wall surface paint for building, be specifically related to one and there is high volume and admittedly contain, can improve film thickness and reduce carbon emission, save the environment friendly emulsion paint of use cost.
Background technology
International community, causes global air temperature warming, Melting Glaciers:, sea-level rise etc. to ascribe surging of CO2 to Greenhouse effect, so destroyed the global environment that the mankind depend on for existence now.In order to contain excessive emissions CO2, balance of plant has been signed Kyoto Protocol and " Copenhagen letter of intent ", in November, 2009, Chinese Government proposed, will decline on the basis of 2005 target of 40%-45% of the year two thousand twenty per GDP carbon emission amount, indicates that from then on China go on low-carbon economy development.Also include the Chinese government's 12 energy-saving and emission-reduction important goals simultaneously in.Find out that thus the global environment that the reduction of CO2 is depended on for existence to us is how important.
As everyone knows, in traditional emulsion paint, the content of water is at 20%-50%, even higher, and within 2010, Architectural Paint in China ultimate production reaches 3,520,000 tons, and wherein water content approximately reaches ten thousand tons of 70.4-176.To liberate ten tons of trucies as example, fully loaded per 100 km oil consumption is 20 liters, the carbon emission amount of 1 liter of 93# gasoline of burning is about 3.8kg, suppose that emulsion paint product needed per ton betransported 1000km and could be used, emulsion paint in 2010 is because the carbon emission amount of transport of water is up to ten thousand tons of 5.4-13.4, with the common tree growing 50 years, every day can absorbing carbon dioxide 5.023kg, by there being every year 3/4 time can carry out photosynthesis, every year can absorbing carbon dioxide 1.375 tons, need the trees of ten thousand age of trees of 3.92-9.75 more than 50 years can run out of consequent carbon emission.Add processing, the carbon emission amount of processing, actual carbon emission amount will be far above this.
After emulsion paint construction finishes to treat volatilizable thing volatilization; the paint film of staying building surface is only the effective constituent of protection body of wall; conventionally admittedly contain and weigh with volume; therefore how to reduce the content of water in emulsion paint; the volume that improves product contains admittedly, not only greatly reduces the carbon emission of bringing thus, meets national energy-saving and reduces discharging policy; also can reduce costs, be of value to raising Social benefit and economic benefit simultaneously.
Summary of the invention
The environment friendly emulsion paint that the object of the present invention is to provide a kind of high volume admittedly to contain, its use can reduce carbon emission, reduces costs.
For achieving the above object, the present invention adopts following technical scheme:
The environment friendly emulsion paint that high volume contains admittedly, its component and content (percentage meter by weight) are as follows:
Described benzene emulsion is one or more the mixture in the TL-615B of the good BLJ-818 of ROHM AND HAAS DC-420, Poly, sunrise.
Described dispersion agent is selected from least one in SN5027, SN5029, SN5040, the Clariant KANALENE92 of Sheng Nuopuke.
Described wetting agent is selected from least one in WET 996, WET 997, the DOW Chemical CF-10 of Sheng Nuopuke.
It is peaceful that described defoamer is selected from NXZ, the section of Sheng Nuopuke
at least one in A10, Blackburn CF-245.
Described color stuffing is one or more the mixture in Rutile type Titanium Dioxide, dicalcium powder, kaolin, talcum powder; Rutile type Titanium Dioxide is selected from
r-902,
any in R-960, TRONOX CR-826.
Described film coalescence aid is the TEAXNAL of Yi Shiman.
Described anticorrosion and bactericidal agent is selected from the Sol of ROHM AND HAAS
mV, Sol
ePWKathon
tMthe Rocima of LXE, ROHM AND HAAS
tMat least one in 361.
Described PH conditioning agent is selected from least one in the AMP-95 of concentration 28% ammoniacal liquor, DOW Chemical.
Described thickening material is selected from least one in the ASE-60 of THICKENER 625N, ROHM AND HAAS of sub-THICKENER 629N, Sheng Nuopuke across imperial NATROSAL 250 HBR, Sheng Nuopuke.
Know-why of the present invention: the present invention has selected the benzene emulsion of the low VOC of mechanical stability excellence, this type of benzene emulsion is introduced MAA (methacrylic acid) group, for providing hydroxyl, molecular chain carries out chemically crosslinked, the carboxylic acid functional of MAA can be promoted latex mechanical stability greatly, simultaneously when pH value is transferred to alkalescence, carboxyl dissociation in copolymer emulsion, producing electric charge forms repulsion and fully stretches, mutually exclusive between polymer particle, emulsion viscosity and mechanical stability are significantly improved.
In emulsion paint technique, emulsion was added and stirring at low speed in the paint stage at present, the present invention adds place of water as dispersion medium high speed dispersion in the making beating stage emulsion, therefore good mechanical stability is the precondition that obtains excellent product performance, the usage quantity that the present invention is based on above-mentioned principle minimizing water improves small product size solid content, obtains the emulsion paint product of high performance-price ratio.
The present invention adopts A, B component, and A component is that high volume contains emulsion paint admittedly, and B component is efficient polyurethane thickener, and both use in the time using latting drown simultaneously, avoid causing viscosity to decline rapidly because being watered in a large number, guarantee product workability.
The present invention compared with prior art, has following excellent effect:
1, low VOC, APEO, guarantees that product meets environmental requirement;
2, high volume contains admittedly, can increase film thickness, effectively wall guard;
3, high latting drown ratio, paint: water=100: 40-80, cost performance is high;
4, low carbon products, meets national energy-saving and reduces discharging policy;
5, strong, the water tolerance of film adhesive, alkaline resistance properties are excellent.
Embodiment
Example 1:
A component: 100 parts of meters take 33.0 parts, water by weight, benzene emulsion TL-615B:30 part, under the rotating speed of 300～600 revs/min, drop into successively dispersion agent SN 5027:1.0 part, thickening material NATROSAL 250 HBR:0.3 parts, wetting agent WET 996:0.3 part, defoamer NXZ:0.3 part, propylene glycol: 1.2 parts, disperse 5 minutes; Under 600～1000 revs/min of rotating speeds, drop into Rutile type Titanium Dioxide
r-902:26.0 part, kaolin: 5.0 parts; Under 1000～1300 revs/min of rotating speeds, disperse 20～30 minutes; Inspection by sampling fineness≤50 micron; Under the rotating speed of 300～600 revs/min, drop into successively film coalescence aid TEAXNAL:1.5 part, anticorrosion and bactericidal agent EPWKathon
tMlXE:0.03 part, disperseed after 5 minutes, and PH conditioning agent AMP-95:0.17 part, defoamer NXZ:0.2 part, thickening material THICKENER 629N:0.4 part, disperse 5 minutes; Inspection by sampling; After qualified, filter and package.
B component: thickening material THICKENER 629N:0.6 part.
Using method: by B component in paint: water=100: 50 ratio, pre-soluble in water after, adding while stirring in A component, can use until mix.
This emulsion paint detection method, project and detected result are shown in subordinate list 1,2.
Example 2:
A component: 100 parts of meters take 27.0 parts, water by weight, benzene emulsion DC-420:32 part, under the rotating speed of 300～600 revs/min, drop into successively dispersion agent SN 5029:0.8 part, thickening material NATROSAL 250 HBR:0.1 parts, wetting agent WET 997:0.5 part, defoamer
a10:0.3 part, propylene glycol: 1.0 parts, disperse 5 minutes; Under 600～1000 revs/min of rotating speeds, drop into Rutile type Titanium Dioxide
r-902:25.8 part, talcum powder: 10.0 parts; Under 1000～1300 revs/min of rotating speeds, disperse 20～30 minutes; Inspection by sampling fineness≤50 micron; Under the rotating speed of 300～600 revs/min, drop into successively film coalescence aid TEAXNAL:1.6 part, anticorrosion and bactericidal agent EPWKathon
tMlXE:0.05 part, disperseed after 5 minutes, and PH conditioning agent AMP-95:0.15 part, defoamer CF-245:0.2 part, thickening material THICKENER 629N:0.1 part, disperse 5 minutes; Inspection by sampling; After qualified, filter and package.
B component: thickening material THICKENER 625N:0.4 part.
Using method: by B component in paint: water=100: 54 ratio, pre-soluble in water after, adding while stirring in A component, can use until mix.
This emulsion paint detection method, project and detected result are shown in subordinate list 1,2.
Example 3:
100 parts of meters take 22.0 parts, water by weight, benzene emulsion BLJ-818:40 part, under the rotating speed of 300～600 revs/min, drop into successively dispersion agent Dispersant 5040:1.0 part, thickening material NATROSAL 250 HBR:0.2 parts, wetting agent CF-10:0.2 part, defoamer
a10:0.2 part, propylene glycol: 1.0 parts, disperse 5 minutes; Under 600～1000 revs/min of rotating speeds, drop into Rutile type Titanium Dioxide
18.0 parts of R-902:15.0 part, dicalcium powders; Under 1000～1300 revs/min of rotating speeds, disperse 20～30 minutes; Inspection by sampling fineness≤50 micron; Under the rotating speed of 300～600 revs/min, drop into successively film coalescence aid TEAXNAL:1.8 part, anticorrosion and bactericidal agent EPWKathon
tMlXE:0.04 part, disperseed after 5 minutes, and PH conditioning agent AMP-95:0.16 part, defoamer DEFOAMER 154S:0.2 part, disperse 5 minutes; Inspection by sampling; After qualified, filter and package.
B component: thickening material THICKENER 625N:0.2 part.
Using method: by B component in paint: water=100: 60 ratio, pre-soluble in water after, adding while stirring in A component, can use until mix.
This emulsion paint detection method, project and detected result are shown in subordinate list 1,2.
Three case study on implementation of the environment friendly emulsion paint that a kind of high volume of the present invention contains admittedly according to requirements after latting drown by GB/9756-2009 and GB 18582-2008 standard testing, test result is as following table 1:
Environment friendly emulsion paint technical performance index and test result that table 1 high volume contains admittedly
It is as shown in table 2 that three case study on implementation A components of the environment friendly emulsion paint that a kind of high volume of the present invention contains admittedly detect data
The environment friendly emulsion paint test result that table 2 high volume contains admittedly
Claims (1)
1. the preparation method of the environment friendly emulsion paint that a high volume contains admittedly, it is characterized in that: A component: 100 parts of meters take 33.0 parts, water by weight, benzene emulsion TL-615B:30 part, under the rotating speed of 300～600 revs/min, drop into successively dispersion agent SN 5027:1.0 part, thickening material NATROSOL 250HBR:0.3 part, wetting agent WET 996:0.3 part, defoamer NXZ:0.3 part, propylene glycol: 1.2 parts, disperse 5 minutes; Under 600～1000 revs/min of rotating speeds, drop into Rutile type Titanium Dioxide
-902:26.0 part, kaolin: 5.0 parts; Under 1000～1300 revs/min of rotating speeds, disperse 20～30 minutes; Inspection by sampling fineness≤50 micron; Under the rotating speed of 300～600 revs/min, drop into successively film coalescence aid TEXANOL:1.5 part, anticorrosion and bactericidal agent EPW Kathon
tMlXE:0.03 part, disperseed after 5 minutes, and pH adjusting agent AMP-95:0.17 part, defoamer NXZ:0.2 part, thickening material THICKENER 629N:0.4 part, disperse 5 minutes; Inspection by sampling; After qualified, filter and package;
B component: thickening material THICKENER 629N:0.6 part;
Using method: by B component in paint: the ratio of water=100:50, pre-soluble in water after, adding while stirring in A component, can use until mix.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210016148.5A CN102585619B (en) | 2012-01-17 | 2012-01-17 | Environment-friendly emulsion paint with high solid volume content |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210016148.5A CN102585619B (en) | 2012-01-17 | 2012-01-17 | Environment-friendly emulsion paint with high solid volume content |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102585619A CN102585619A (en) | 2012-07-18 |
| CN102585619B true CN102585619B (en) | 2014-06-11 |
Family
ID=46474880
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210016148.5A Expired - Fee Related CN102585619B (en) | 2012-01-17 | 2012-01-17 | Environment-friendly emulsion paint with high solid volume content |
Country Status (1)
| Country | Link |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103756548B (en) * | 2013-12-12 | 2016-08-24 | 澳达树熊涂料(惠州)有限公司 | A kind of aqueous high-solid-content paint and preparation method thereof |
| CN104059439A (en) * | 2014-05-23 | 2014-09-24 | 李世跃 | Antimicrobial anticorrosive latex paint |
| CN104592818A (en) * | 2014-12-16 | 2015-05-06 | 三棵树涂料股份有限公司 | High-temperature-resistant high-pressure-resistant water-based wood paint and preparation method thereof |
| CN110684402A (en) * | 2019-10-23 | 2020-01-14 | 樊福生 | High-plasticity building coating and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101338099A (en) * | 2007-07-02 | 2009-01-07 | 深圳市海川实业股份有限公司 | External wall latex paint and method for preparing same |
| CN101486862A (en) * | 2008-12-25 | 2009-07-22 | 雅士利涂料（苏州）有限公司 | Environment friendly inner wall emulsion paint and preparation thereof |
-
2012
- 2012-01-17 CN CN201210016148.5A patent/CN102585619B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101338099A (en) * | 2007-07-02 | 2009-01-07 | 深圳市海川实业股份有限公司 | External wall latex paint and method for preparing same |
| CN101486862A (en) * | 2008-12-25 | 2009-07-22 | 雅士利涂料（苏州）有限公司 | Environment friendly inner wall emulsion paint and preparation thereof |
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| Publication number | Publication date |
|---|---|
| CN102585619A (en) | 2012-07-18 |
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Owner name: CHONGZHOU MEITUSHI COATINGS TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: GUANGDONG MAYDOS BUILDING MATERIALS CO., LTD. Effective date: 20141219 |
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Effective date of registration: 20141219 Address after: 611230 Sichuan Province, Chongzhou of Chengdu City Industrial Development Zone Hongye Road No. 2 Patentee after: CHONGZHOU MEITUSHI PAINT TECHNOLOGY CO., LTD. Address before: 528308 Guangdong Province, Foshan city Shunde District Lunjiao three Chau Industrial Zone Patentee before: Guangdong Maydos Building Materials Co., Ltd. |
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Effective date of registration: 20191209 Address after: 528308 East Road, Xiashi Industrial Zone, Lunjiao street, Shunde District, Foshan City, Guangdong Province Patentee after: Guangdong Sunzo Chemical Industrial Co., Ltd. Address before: 611230 Sichuan Province, Chongzhou of Chengdu City Industrial Development Zone Hongye Road No. 2 Patentee before: CHONGZHOU MEITUSHI PAINT TECHNOLOGY CO., LTD. |
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Granted publication date: 20140611 Termination date: 20210117 |
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