CN102585619A - Environment-friendly emulsion paint with high solid volume content - Google Patents

Environment-friendly emulsion paint with high solid volume content Download PDF

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Publication number
CN102585619A
CN102585619A CN2012100161485A CN201210016148A CN102585619A CN 102585619 A CN102585619 A CN 102585619A CN 2012100161485 A CN2012100161485 A CN 2012100161485A CN 201210016148 A CN201210016148 A CN 201210016148A CN 102585619 A CN102585619 A CN 102585619A
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China
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emulsion paint
high volume
environment friendly
friendly emulsion
contains admittedly
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CN2012100161485A
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CN102585619B (en
Inventor
李腾飞
周伟健
谭俊峰
李君荣
李淑燕
李光强
郭金坚
梁振霖
莫勇华
童炜
何盖
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Guangdong Sunzo Chemical Industrial Co., Ltd.
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Guangdong Maydos Building Materials Co Ltd
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Abstract

The invention discloses an environment-friendly emulsion paint with high solid volume content, which comprises the following components shown in the specification in percentage by weight. According to the invention, the solid volume content of the emulsion paint can be effectively improved; and the emulsion paint is non-toxic, harmless and low in VOC (volatile organic compound) content. Therefore, the emulsion paint disclosed by the invention is an excellent-performance waterborne environment-friendly emulsion paint, and can be widely applied to the coating construction of various wall surfaces.

Description

The environment friendly emulsion paint that a kind of high volume contains admittedly
Technical field
The present invention relates to a kind of environmental protection wall surface paint for building, be specifically related to a kind ofly have high volume and contain admittedly, can improve film thickness and reduce carbon emission, practice thrift the environment friendly emulsion paint of use cost.
Background technology
International community causes Greenhouse effect global air temperature warming, glacier thawing, sea-level rise etc. to ascribe the surge of CO2 to now, so destroyed human global environment of depending on for existence.In order to contain excessive emissions CO2; Balance of plant has been signed Kyoto Protocol and " Copenhagen letter of intent "; In November, 2009, China government proposed; The year two thousand twenty per GDP carbon emission amount will be on basis in 2005 target of decline 40%-45%, indicate that from then on China go on the low-carbon economy development.Also include simultaneously the Chinese government's 12 energy-saving and emission-reduction important goals in.Find out that thus the global environment that the reduction of CO2 is depended on for existence to us is how important.
As everyone knows, the content of water is at 20%-50% in traditional rubber-emulsion paint, even higher, the Architectural Paint in China ultimate production reached 3,520,000 tons in 2010, and wherein water cut reaches ten thousand tons of 70.4-176 approximately.To liberate ten tons of trucies is example; Fully loaded per 100 km oil consumption is 20 liters, and the carbon emission amount of 1 liter of 93# gasoline of burning is about 3.8kg, supposes that rubber-emulsion paint product needed per ton betransported 1000km and just can be used; Then rubber-emulsion paint in 2010 because of the carbon emission amount of transport of water up to ten thousand tons of 5.4-13.4; With a common tree that grew 50 years, but every day absorbing carbon dioxide 5.023kg, by having every year to carry out photosynthesis 3/4 time; But then every year 1.375 tons of absorbing carbon dioxides, then need ten thousand age of trees of 3.92-9.75 can run out of consequent carbon emission the trees more than 50 years.Add processing, the carbon emission amount of handling, actual carbon emission amount will be far above this.
After the rubber-emulsion paint construction finished to treat that volatilizable thing volatilization finishes, the paint film of staying building surface was only the effective constituent of protection body of wall, contains measurement admittedly with volume usually; Therefore how to reduce the content of water in the rubber-emulsion paint; The volume that improves product contains admittedly, not only reduces the carbon emission of bringing thus greatly, meets national energy-saving and emission-reduction policy; Also can reduce cost simultaneously, be of value to and improve social benefit and economic benefit.
Summary of the invention
The environment friendly emulsion paint that the object of the present invention is to provide a kind of high volume to contain admittedly, its use can reduce carbon emission, reduces cost.
For achieving the above object, the present invention adopts following technical scheme:
The environment friendly emulsion paint that a kind of high volume contains admittedly, its component and content (percentage meter by weight) be as follows:
Figure BSA00000660113700021
Said benzene emulsion is one or more the mixture among the TL-615B of the good BLJ-818 of ROHM AND HAAS DC-420, Poly, sunrise.
Said dispersion agent is selected from least a among the SN5027, SN5029, SN5040, Clariant KANALENE92 of Sheng Nuopuke.
Said wetting agent is selected from least a among the WET 996, WET 997, DOW Chemical CF-10 of Sheng Nuopuke.
Said skimmer is selected from least a among peaceful A10 of NXZ, the section of Sheng Nuopuke, the Blackburn CF-245.
Said color stuffing is one or more the mixture in Rutile type Titanium Dioxide, dicalcium powder, kaolin, the talcum powder; Rutile type Titanium Dioxide is selected from
Figure BSA00000660113700031
R-902;
Figure BSA00000660113700032
R-960; Among the TRONOX CR-826 any.
Said film coalescence aid is the TEAXNAL of Yi Shiman.
Said anticorrosion and bactericidal agent is selected from the Sol of ROHM AND HAAS
Figure BSA00000660113700033
MV, Sol
Figure BSA00000660113700034
EPWKathon TMThe Rocima of LXE, ROHM AND HAAS TMAt least a in 361.
Said PH regulator is selected from least a among the AMP-95 of concentration 28% ammoniacal liquor, DOW Chemical.
Said thickening material is selected from the Asia and strides at least a among the ASE-60 of the THICKENER 625N of the THICKENER 629N of NATROSAL 250 HBR, the Sheng Nuopuke of dragon, Sheng Nuopuke, ROHM AND HAAS.
Know-why of the present invention: the present invention has selected the benzene emulsion of the excellent low VOC of mechanical stability for use, and this type of benzene emulsion is introduced MAA (methylacrylic acid) group, carries out chemically crosslinked for molecular chain provides hydroxyl; The carboxylic acid functional of MAA can be promoted latex mechanical stability greatly; Be transferred to alkalescence when the pH value simultaneously, then carboxyl disassociation in the copolymer emulsion produces electric charge and forms repulsion and abundant the stretching, extension; Mutually exclusive between polymer particle, make emulsion viscosity and mechanical stability significantly improve.
In the rubber-emulsion paint technology emulsion was added and stirring at low speed in the paint stage at present; The present invention adds place of water as dispersion medium and high speed dispersion with emulsion in the making beating stage; Therefore favorable mechanical stability is the precondition that obtains the excellent product performance; The usage quantity that the present invention is based on above-mentioned principle minimizing water improves the small product size solid content, obtains the rubber-emulsion paint product of high performance-price ratio.
The present invention adopts A, B component, and the A component is that high volume contains rubber-emulsion paint admittedly, and the B component is efficient polyurethane thickener, and both use when using latting drown simultaneously, avoid causing viscosity to descend rapidly because of converting water in a large number, guarantee the product workability.
The present invention compared with prior art has following excellent effect:
1, low VOC, APEO guarantee the product compliance with environmental protection requirements;
2, high volume contains admittedly, can increase film thickness, effectively wall guard;
3, high latting drown ratio, lacquer: water=100: 40-80, cost performance is high;
4, low carbon products meets national energy-saving and emission-reduction policy;
5, strong, the water tolerance of film adhesive, alkaline resistance properties are excellent.
Embodiment
Instance 1:
The A component: 100 parts of meters take by weighing 33.0 parts in water by weight; Benzene emulsion TL-615B:30 part, under 300~600 rev/mins rotating speed; Drop into dispersion agent SN 5027:1.0 part, thickening material NATROSAL 250 HBR:0.3 parts, wetting agent WET 996:0.3 part, skimmer NXZ:0.3 part successively; Ucar 35: 1.2 parts, disperseed 5 minutes; Under 600~1000 rev/mins of rotating speeds, drop into Rutile type Titanium Dioxide
Figure BSA00000660113700041
R-902:26.0 part, kaolin: 5.0 parts; Under 1000~1300 rev/mins of rotating speeds, disperseed 20~30 minutes; Inspection by sampling fineness≤50 micron; Under 300~600 rev/mins rotating speed, drop into film coalescence aid TEAXNAL:1.5 part, anticorrosion and bactericidal agent EPWKathon successively TMLXE:0.03 part was disperseed after 5 minutes, and PH regulator AMP-95:0.17 part, skimmer NXZ:0.2 part, thickening material THICKENER 629N:0.4 part were disperseed 5 minutes; Inspection by sampling; Qualified after-filtration packing.
B component: thickening material THICKENER 629N:0.6 part.
Method of use: with the B component in lacquer: the ratio of water=100: 50, soluble in water in advance after, adding in the A component, can use up to mixing while stirring.
This rubber-emulsion paint detection method, project and detected result are shown in the subordinate list 1,2.
Instance 2:
The A component: 100 parts of meters take by weighing 27.0 parts in water by weight; Benzene emulsion DC-420:32 part; Under 300~600 rev/mins rotating speed, drop into dispersion agent SN 5029:0.8 part, thickening material NATROSAL 250 HBR:0.1 parts, wetting agent WET 997:0.5 part, skimmer successively
Figure BSA00000660113700051
A10:0.3 part, Ucar 35: 1.0 parts, disperseed 5 minutes; Under 600~1000 rev/mins of rotating speeds, drop into Rutile type Titanium Dioxide
Figure BSA00000660113700052
R-902:25.8 part, talcum powder: 10.0 parts; Under 1000~1300 rev/mins of rotating speeds, disperseed 20~30 minutes; Inspection by sampling fineness≤50 micron; Under 300~600 rev/mins rotating speed, drop into film coalescence aid TEAXNAL:1.6 part, anticorrosion and bactericidal agent EPWKathon successively TMLXE:0.05 part was disperseed after 5 minutes, and PH regulator AMP-95:0.15 part, skimmer CF-245:0.2 part, thickening material THICKENER 629N:0.1 part were disperseed 5 minutes; Inspection by sampling; Qualified after-filtration packing.
B component: thickening material THICKENER 625N:0.4 part.
Method of use: with the B component in lacquer: the ratio of water=100: 54, soluble in water in advance after, adding in the A component, can use up to mixing while stirring.
This rubber-emulsion paint detection method, project and detected result are shown in the subordinate list 1,2.
Instance 3:
100 parts of meters take by weighing 22.0 parts in water by weight; Benzene emulsion BLJ-818:40 part; Under 300~600 rev/mins rotating speed, drop into dispersion agent Dispersant 5040:1.0 part, thickening material NATROSAL 250 HBR:0.2 parts, wetting agent CF-10:0.2 part, skimmer successively A10:0.2 part, Ucar 35: 1.0 parts, disperseed 5 minutes; Under 600~1000 rev/mins of rotating speeds, drop into Rutile type Titanium Dioxide
Figure BSA00000660113700054
18.0 parts of R-902:15.0 part, dicalcium powders; Under 1000~1300 rev/mins of rotating speeds, disperseed 20~30 minutes; Inspection by sampling fineness≤50 micron; Under 300~600 rev/mins rotating speed, drop into film coalescence aid TEAXNAL:1.8 part, anticorrosion and bactericidal agent EPWKathon successively TMLXE:0.04 part was disperseed after 5 minutes, and PH regulator AMP-95:0.16 part, skimmer DEFOAMER 154S:0.2 part were disperseed 5 minutes; Inspection by sampling; Qualified after-filtration packing.
B component: thickening material THICKENER 625N:0.2 part.
Method of use: with the B component in lacquer: the ratio of water=100: 60, soluble in water in advance after, adding in the A component, can use up to mixing while stirring.
This rubber-emulsion paint detection method, project and detected result are shown in the subordinate list 1,2.
Three case study on implementation of the environment friendly emulsion paint that a kind of high volume of the present invention contains admittedly according to the request for utilization latting drown after by GB/9756-2009 and GB 18582-2008 standard testing, test result such as following table 1:
Environment friendly emulsion paint technical performance index and test result that table 1 high volume contains admittedly
Figure BSA00000660113700061
It is as shown in table 2 that three case study on implementation A components of the environment friendly emulsion paint that a kind of high volume of the present invention contains admittedly detect data
The environment friendly emulsion paint test result that table 2 high volume contains admittedly
Figure BSA00000660113700072

Claims (10)

1. environment friendly emulsion paint that high volume contains admittedly is characterized in that: its component and content (percentage meter by weight) as follows:
Figure FSA00000660113600011
2. the environment friendly emulsion paint that a kind of high volume according to claim 1 contains admittedly is characterized in that: said benzene emulsion is one or more the mixture among the TL-615B of the good BLJ-818 of ROHM AND HAAS DC-420, Poly, sunrise.
3. the environment friendly emulsion paint that a kind of high volume according to claim 1 contains admittedly is characterized in that: said dispersion agent is selected from least a among the SN5027, SN5029, SN5040, Clariant KANALENE92 of Sheng Nuopuke.
4. the environment friendly emulsion paint that a kind of high volume according to claim 1 contains admittedly is characterized in that: said wetting agent is selected from least a among the WET 996, WET 997, DOW Chemical CF-10 of Sheng Nuopuke.
5. the environmentally-friendly latex paint for interior walls of a kind of high temperature steam according to claim 1 is characterized in that: said skimmer is selected from least a among peaceful
Figure FSA00000660113600012
A10 of NXZ, the section of Sheng Nuopuke, the Blackburn CF-245.
As claimed in claim 1 containing a high volume of green latex solids, characterized in that: said pigment is rutile titanium dioxide, heavy calcium, kaolin, talc in one or more of mixture; rutile titanium dioxide selected?
Figure FSA00000660113600021
R-902,?
Figure FSA00000660113600022
R-960, TRONOX? CR-826 in any one.
7. the environment friendly emulsion paint that a kind of high volume according to claim 1 contains admittedly is characterized in that: said film coalescence aid is the TEAXNAL of Yi Shiman.
8. the environment friendly emulsion paint that a kind of high volume according to claim 1 contains admittedly is characterized in that: said anticorrosion and bactericidal agent is selected from the Sol of ROHM AND HAAS
Figure FSA00000660113600023
MV, Sol
Figure FSA00000660113600024
EPWKathon TMThe Rocima of LXE, ROHM AND HAAS TMAt least a in 361.
9. the environment friendly emulsion paint that a kind of high volume according to claim 1 contains admittedly is characterized in that: said PH regulator is selected from least a among the AMP-95 of concentration 28% ammoniacal liquor, DOW Chemical.
10. the environment friendly emulsion paint that a kind of high volume according to claim 1 contains admittedly is characterized in that: said thickening material is selected from the Asia and strides at least a among the ASE-60 of the THICKENER 625N of the THICKENER 629N of NATROSAL 250 HBR, the Sheng Nuopuke of dragon, Sheng Nuopuke, ROHM AND HAAS.
CN201210016148.5A 2012-01-17 2012-01-17 Environment-friendly emulsion paint with high solid volume content Expired - Fee Related CN102585619B (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103756548A (en) * 2013-12-12 2014-04-30 澳达树熊涂料(惠州)有限公司 Water-based high-solid-content paint and preparation method thereof
CN104059439A (en) * 2014-05-23 2014-09-24 李世跃 Antimicrobial anticorrosive latex paint
CN104592818A (en) * 2014-12-16 2015-05-06 三棵树涂料股份有限公司 High-temperature-resistant high-pressure-resistant water-based wood paint and preparation method thereof
CN110684402A (en) * 2019-10-23 2020-01-14 樊福生 High-plasticity building coating and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101338099A (en) * 2007-07-02 2009-01-07 深圳市海川实业股份有限公司 Exterior wall latex paint and preparation method thereof
CN101486862A (en) * 2008-12-25 2009-07-22 雅士利涂料(苏州)有限公司 Environment friendly inner wall emulsion paint and preparation thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101338099A (en) * 2007-07-02 2009-01-07 深圳市海川实业股份有限公司 Exterior wall latex paint and preparation method thereof
CN101486862A (en) * 2008-12-25 2009-07-22 雅士利涂料(苏州)有限公司 Environment friendly inner wall emulsion paint and preparation thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103756548A (en) * 2013-12-12 2014-04-30 澳达树熊涂料(惠州)有限公司 Water-based high-solid-content paint and preparation method thereof
CN103756548B (en) * 2013-12-12 2016-08-24 澳达树熊涂料(惠州)有限公司 A kind of aqueous high-solid-content paint and preparation method thereof
CN104059439A (en) * 2014-05-23 2014-09-24 李世跃 Antimicrobial anticorrosive latex paint
CN104592818A (en) * 2014-12-16 2015-05-06 三棵树涂料股份有限公司 High-temperature-resistant high-pressure-resistant water-based wood paint and preparation method thereof
CN110684402A (en) * 2019-10-23 2020-01-14 樊福生 High-plasticity building coating and preparation method thereof

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Owner name: CHONGZHOU MEITUSHI COATINGS TECHNOLOGY CO., LTD.

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Address after: 611230 Sichuan Province, Chongzhou of Chengdu City Industrial Development Zone Hongye Road No. 2

Patentee after: CHONGZHOU MEITUSHI PAINT TECHNOLOGY CO., LTD.

Address before: 528308 Guangdong Province, Foshan city Shunde District Lunjiao three Chau Industrial Zone

Patentee before: Guangdong Maydos Building Materials Co., Ltd.

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Address after: 528308 East Road, Xiashi Industrial Zone, Lunjiao street, Shunde District, Foshan City, Guangdong Province

Patentee after: Guangdong Sunzo Chemical Industrial Co., Ltd.

Address before: 611230 Sichuan Province, Chongzhou of Chengdu City Industrial Development Zone Hongye Road No. 2

Patentee before: CHONGZHOU MEITUSHI PAINT TECHNOLOGY CO., LTD.

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Granted publication date: 20140611

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CF01 Termination of patent right due to non-payment of annual fee