CN104449096A - Environmental-friendly texture coating composition and preparation method thereof - Google Patents
Environmental-friendly texture coating composition and preparation method thereof Download PDFInfo
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- CN104449096A CN104449096A CN201410747665.9A CN201410747665A CN104449096A CN 104449096 A CN104449096 A CN 104449096A CN 201410747665 A CN201410747665 A CN 201410747665A CN 104449096 A CN104449096 A CN 104449096A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
- C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09D131/04—Homopolymers or copolymers of vinyl acetate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/28—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for wrinkle, crackle, orange-peel, or similar decorative effects
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/69—Particle size larger than 1000 nm
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/005—Additives being defined by their particle size in general
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Nanotechnology (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses an environmental-friendly texture coating composition and a preparation method thereof. The environmental-friendly texture coating composition comprises the following components in percentage by weight: 59%-62% of natural colored sand, 11.8%-15% of emulsions, 3.5%-4.5% of cellulose ether, 1%-2% of active adsorbents, 4%-6% of heavy calcium carbonate, 4%-6% of titanium dioxide, 0.3%-0.5% of film-forming auxiliary agents, 0.1%-0.2% of sterilizing agents and 9%-11% of water. When the environmental-friendly texture coating composition is prepared, the components are added and stirred according to a conventional coating process. The environmental-friendly texture coating mainly comprises fine graded fillers, the emulsions, other auxiliary agents, and the like, and the limit of harmful substances meets the requirement for GB 24408-2009 'limit of the harmful substance contained in an outer wall coating for building'. The environmental-friendly texture coating composition disclosed by the invention has good stain resistance and ageing resistance, is less in harmful substance limit by selectively adding the active adsorbents and capable of purifying the air, and has good coordination after being mixed with other materials.
Description
Technical field
The present invention relates to environmental protection coating material field, be specifically related to a kind of environment-friendly type texture coating composition and method of making the same.
Background technology
Texture coating is with its with countless changes three-dimensional texture, and the individual character of more options is arranged in pairs or groups.Stone material, facing tile can be substituted, enrich and vivo represent unique spatial view.Realize the weathering resistance of building exterior wall face, resistance to crocking, fire protection flame retarding, the environmental protection more of the fungi-proofing lasting protection basal plane of gas defence, safety, economical and become wall face construction technique.
In order to create three-dimensional texture, the color filters that in texture coating, a large amount of use particle is larger, the self gravitation of individual particle is large; In addition, the color filters proportion of most of texture coating is 70%-80%.Large and the particle self gravitation of color filters proportion causes greatly texture coating easily to occur peeling off, even ftractureing.Spallation problems is solved usually through adding the organic solvent such as glycol ether and close ester to strengthen viscosity in prior art.But the problems such as it often exists volatile organic matter (VOC), free formaldehyde content, glycol ether and close ester content summation, heavy metal content exceeds standard, cannot meet environmental requirement.
Summary of the invention
The object of the invention is to the deficiency overcoming the existence of above-mentioned prior art, a kind of environment-friendly type texture coating composition and method of making the same is provided.Volatile organic matter (VOC), free formaldehyde content, glycol ether and close ester content summation in the reduction texture coating of the maximum limitation of the present invention, heavy metal content (lead, mercury, chromium, cadmium etc.) and meet national standard, really accomplish environmental protection.
The object of the invention is to be achieved through the following technical solutions:
The present invention relates to a kind of environment-friendly type texture coating composition, described coating composition comprises each component of following weight percent content:
Preferably, the order number of described natural colour sand is 10 ~ 180 orders.This natural colour sand is processed through the multiple working procedure such as selected, broken, pulverizing, classification, packaging by the ore such as marble or grouan.
Preferably, described emulsion is selected from one or both in styrene-acrylic emulsion, acrylic ester emulsion, vinyl acetate-ethylene emulsion.
Preferably, described ether of cellulose is selected from hydroxypropyl methyl cellulose ether, and the molecular weight of described ether of cellulose is 10,000 ~ 100,000.
Preferably, described hypersober is selected from atlapulgite, diatomite, gac, activated alumina, silica gel, synthetic zeolite; The order number of described hypersober is 180 ~ 1500 orders.
Preferably, the particle diameter of described water-ground limestone is 1 ~ 10 μm.This water-ground limestone (GCC) is that marble is directly by the fine powder of the calcium carbonate of grinding acquisition.
Preferably, described film coalescence aid is alcohol ester 12; Described sterilant is the HY-6060 of Mai Er chemical industry.This film coalescence aid, also known as coalescing aid, can promote macromolecular compound plastic flow and recoverable deformation, improves coalescent performance.This sterilant toxicity is low, without unpleasant odor, not containing the objectionable constituent such as formaldehyde and heavy metal.
Preferably, described titanium dioxide formal name used at school titanium dioxide (TiO2), molecular weight: 79.88 is a kind of white inorganic powders, has nontoxic, best opacity, best whiteness and luminance brightness, oil number 13 ~ 24%.
Preferably, described water is deionized water, and specific conductivity is 1.0 ~ 10.0 μ s/cm.
The invention still further relates to a kind of preparation method according to environment-friendly type texture coating composition of the present invention, by 40% ~ 60% mixing and stirring in 30% ~ 40% in described natural colour sand, ether of cellulose, water cumulative volume, total emulsion volume, obtain component A; By the emulsion of remainder, hypersober, water-ground limestone, titanium dioxide mixing and stirring, obtain B component; By the water of film coalescence aid, sterilant and remainder, mixing and stirring, obtains component C; By A, B, component C mixing and stirring, obtain described environment-friendly type texture coating composition.
Aqueous environment protection texture coating prepared by the present invention has radiationless, natural environmental-protective, nonpoisonous and tasteless feature, construct relatively random simultaneously, can with any instrument such as: spray gun, cylinder, sawtooth ash cutter, illusion-colour gloves, various grey cutter, omnipotent brush, wood grain device, art brush etc.This coating material, has brought the smooth type epoch of wall body coating into the new era of the concavo-convex coating of natural environmental-protective type.
Compared with prior art, the present invention has following beneficial effect:
1, environmental type texture coating of the present invention is primarily of fine graded filler, the compositions such as emulsion and other auxiliary agent, and be devoted to radiationless, natural environmental-protective, in nonpoisonous and tasteless research environmental type of the present invention texture coating, limits of harmful substances meets GB 24408-2009 " in exterior coating for building limits of harmful substances " requirement; Really accomplish environmental protection.
2, environmental type texture coating of the present invention has good contamination resistance, ageing resistance, and simultaneously hypersober optionally adds and makes limits of harmful substances less, simultaneously capable of purifying air; Further, hypersober and ether of cellulose, alcohol ester 12 have played good synergetic property, make ageing resistance reach significant raising.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail.Be below that embodiment will contribute to those skilled in the art and understands the present invention further, but do not limit the present invention in any form.It should be pointed out that to those skilled in the art, without departing from the inventive concept of the premise, some distortion and improvement can also be made.These all belong to protection scope of the present invention.
embodiment 1
The present embodiment is to prepare 100kg water-borne coatings, and its preparation method is as follows.
By regulation proportioning weigh batching, the consumption (kg) of each raw material is as follows:
Natural colour sand is 10 ~ 80 orders; Emulsion is styrene-acrylic emulsion; Ether of cellulose is hydroxypropyl methyl cellulose ether (HPMC), and molecular weight is 10,000 ~ 50,000; Hypersober is atlapulgite, and order number is 180 ~ 600 orders; The particle diameter of water-ground limestone is 1 μm; Film coalescence aid is alcohol ester 12; Sterilant is the HY-6060 of Mai Er chemical industry.
Above-mentioned raw materials by proportioning weigh batching, conveniently coating process adds stirring and namely obtains water-borne coatings.
During use, texture coating construction technology can use routinely.
The water-borne coatings of above-mentioned preparation, volatile organic matter (VOC) content≤150g/L, free formaldehyde content≤100mg/kg, glycol ether and close ester content summation≤0.03%, heavy metal content (lead≤1000mg/kg, mercury≤1000mg/kg, chromium (sexavalence)≤1000mg/kg, cadmium≤100mg/kg etc.).Examination criteria: GB 24408-2009 " in exterior coating for building limits of harmful substances ".
Contamination resistance (after 5 round-robin tests)≤2 grades, ageing resistance (500h), outward appearance, coating is without ftractureing, playing drum, peeling off; Efflorescence, 0 grade; Variable color ,≤1 grade. examination criteria: JG/T24-2000 " SAND SLURRY SYNTHETIC EMULSION ARCHITECTURAL COATINGS ".
Other conventional indexs (texture coating) detect according to JG/T24-2000 " SAND SLURRY SYNTHETIC EMULSION ARCHITECTURAL COATINGS ".The results are shown in following table.
embodiment 2
The present embodiment is to prepare 100kg water-borne coatings, and its preparation method is as follows.
By regulation proportioning weigh batching, the consumption of each raw material is as follows:
Natural colour sand is 70 ~ 120 orders; Emulsion is acrylic ester emulsion; Ether of cellulose is hydroxypropyl methyl cellulose ether, and molecular weight is 80,000 ~ 100,000; Hypersober is diatomite, and order number is 600 ~ 1100 orders; The particle diameter of water-ground limestone is 6 μm; Film coalescence aid is alcohol ester 12; Sterilant is the HY-6060 of Mai Er chemical industry.
Above-mentioned raw materials by proportioning weigh batching, conveniently coating process adds stirring and namely obtains water-borne coatings.
The water-borne coatings of above-mentioned preparation, volatile organic matter (VOC) content≤150g/L, free formaldehyde content≤100mg/kg, glycol ether and close ester content summation≤0.03%, heavy metal content (lead≤1000mg/kg, mercury≤1000mg/kg, chromium (sexavalence)≤1000mg/kg, cadmium≤100mg/kg etc.).Examination criteria: GB 24408-2009 " in exterior coating for building limits of harmful substances ".
Contamination resistance (after 5 round-robin tests)≤2 grades, ageing resistance (500h), outward appearance, coating is without ftractureing, playing drum, peeling off; Efflorescence, 0 grade; Variable color ,≤1 grade. examination criteria: JG/T24-2000 " SAND SLURRY SYNTHETIC EMULSION ARCHITECTURAL COATINGS ".
Other conventional indexs (texture coating) detect according to JG/T24-2000 " SAND SLURRY SYNTHETIC EMULSION ARCHITECTURAL COATINGS ".
embodiment 3
The present embodiment is to prepare 100kg water-borne coatings, and its preparation method is as follows.
By regulation proportioning weigh batching, the consumption of each raw material is as follows:
Natural colour sand is 110 ~ 180 orders; Emulsion to be mass ratio be 1: 1 styrene-acrylic emulsion and vinyl acetate-ethylene emulsion; Ether of cellulose is hydroxypropyl methyl cellulose ether (HPMC), and molecular weight is 80,000 ~ 100,000; Hypersober is activated alumina, and order number is 1100 ~ 1500 orders; The particle diameter of water-ground limestone is 10 μm; Film coalescence aid is alcohol ester 12; Sterilant is the HY-6060 of Mai Er chemical industry.
Above-mentioned raw materials by proportioning weigh batching, conveniently coating process adds stirring and namely obtains water-borne coatings.
The water-borne coatings of above-mentioned preparation, volatile organic matter (VOC) content≤150g/L, free formaldehyde content≤100mg/kg, glycol ether and close ester content summation≤0.03%, heavy metal content (lead≤1000mg/kg, mercury≤1000mg/kg, chromium (sexavalence)≤1000mg/kg, cadmium≤100mg/kg etc.).Examination criteria: GB 24408-2009 " in exterior coating for building limits of harmful substances ".
Contamination resistance (after 5 round-robin tests)≤2 grades, ageing resistance (500h), outward appearance, coating is without ftractureing, playing drum, peeling off; Efflorescence, 0 grade; Variable color ,≤1 grade. examination criteria: JG/T24-2000 " SAND SLURRY SYNTHETIC EMULSION ARCHITECTURAL COATINGS ".
Other conventional indexs (texture coating) detect according to JG/T24-2000 " SAND SLURRY SYNTHETIC EMULSION ARCHITECTURAL COATINGS ".
Above specific embodiments of the invention are described.It is to be appreciated that the present invention is not limited to above-mentioned particular implementation, those skilled in the art can make various distortion or amendment within the scope of the claims, and this does not affect flesh and blood of the present invention.
Claims (8)
1. an environment-friendly type texture coating composition, is characterized in that, described coating composition comprises each component of following weight percent content:
2. environment-friendly type texture coating composition according to claim 1, is characterized in that, the order number of described natural colour sand is 10 ~ 180 orders.
3. environment-friendly type texture coating composition according to claim 1, is characterized in that, described emulsion be selected from styrene-acrylic emulsion, acrylic ester emulsion, vinyl acetate-ethylene emulsion one or both.
4. environment-friendly type texture coating composition according to claim 1, it is characterized in that, described ether of cellulose is selected from hydroxypropyl methyl cellulose ether; The molecular-weight average of described ether of cellulose is 10,000 ~ 100,000.
5. environment-friendly type texture coating composition according to claim 1, it is characterized in that, described hypersober is selected from atlapulgite, diatomite, gac, activated alumina, silica gel, synthetic zeolite; The order number of described hypersober is 180 ~ 1500 orders.
6. environment-friendly type texture coating composition according to claim 1, is characterized in that, the particle diameter of described water-ground limestone is 1 ~ 10 μm.
7. environment-friendly type texture coating composition according to claim 1, is characterized in that, described film coalescence aid is alcohol ester 12; Described sterilant is the HY-6060 of Mai Er chemical industry.
8. the preparation method of the environment-friendly type texture coating composition according to any one of claim 1 ~ 7, it is characterized in that, by 40% ~ 60% mixing and stirring in 30% ~ 40% in described natural colour sand, ether of cellulose, water cumulative volume, total emulsion volume, obtain component A; By the emulsion of remainder, hypersober, water-ground limestone, titanium dioxide mixing and stirring, obtain B component; By the water of film coalescence aid, sterilant and remainder, mixing and stirring, obtains component C; By A, B, component C mixing and stirring, obtain described environment-friendly type texture coating composition.
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| CN201410747665.9A CN104449096A (en) | 2014-12-08 | 2014-12-08 | Environmental-friendly texture coating composition and preparation method thereof |
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| CN201410747665.9A CN104449096A (en) | 2014-12-08 | 2014-12-08 | Environmental-friendly texture coating composition and preparation method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104877507A (en) * | 2015-06-16 | 2015-09-02 | 合肥启华环保科技有限公司 | External wall latex paint with good aging resistance and weather resistance and preparation method thereof |
| CN106118327A (en) * | 2016-06-30 | 2016-11-16 | 遵义市恒新化工有限公司 | A kind of building external paint and preparation method thereof |
| CN106243869A (en) * | 2016-08-24 | 2016-12-21 | 上海贝塔建筑科技有限公司 | A kind of sand wall-like fluorescent aqueous paint and preparation method |
| WO2018165874A1 (en) * | 2017-03-14 | 2018-09-20 | 苏州大学张家港工业技术研究院 | Multifunctional composite coating for removing formaldehyde and undesirable odors and preventing bacteria and mildew, and preparation method therefor |
| CN109181427A (en) * | 2018-06-09 | 2019-01-11 | 泉州大众山涂料有限公司 | A kind of skin texture matter colored paint and preparation method thereof |
| CN110869449A (en) * | 2017-07-11 | 2020-03-06 | 陶氏环球技术有限责任公司 | Aqueous dispersion and aqueous coating composition comprising the same |
| CN111777904A (en) * | 2019-04-03 | 2020-10-16 | 广东顺德宏燕建材有限公司 | Shell pure slurry coating |
-
2014
- 2014-12-08 CN CN201410747665.9A patent/CN104449096A/en active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104877507A (en) * | 2015-06-16 | 2015-09-02 | 合肥启华环保科技有限公司 | External wall latex paint with good aging resistance and weather resistance and preparation method thereof |
| CN106118327A (en) * | 2016-06-30 | 2016-11-16 | 遵义市恒新化工有限公司 | A kind of building external paint and preparation method thereof |
| CN106243869A (en) * | 2016-08-24 | 2016-12-21 | 上海贝塔建筑科技有限公司 | A kind of sand wall-like fluorescent aqueous paint and preparation method |
| CN106243869B (en) * | 2016-08-24 | 2019-06-18 | 上海贝塔建筑科技有限公司 | A kind of sand wall-like fluorescent aqueous paint and preparation method |
| WO2018165874A1 (en) * | 2017-03-14 | 2018-09-20 | 苏州大学张家港工业技术研究院 | Multifunctional composite coating for removing formaldehyde and undesirable odors and preventing bacteria and mildew, and preparation method therefor |
| CN110869449A (en) * | 2017-07-11 | 2020-03-06 | 陶氏环球技术有限责任公司 | Aqueous dispersion and aqueous coating composition comprising the same |
| CN109181427A (en) * | 2018-06-09 | 2019-01-11 | 泉州大众山涂料有限公司 | A kind of skin texture matter colored paint and preparation method thereof |
| CN109181427B (en) * | 2018-06-09 | 2021-03-19 | 泉州大众山涂料有限公司 | Texture color paint and preparation method thereof |
| CN111777904A (en) * | 2019-04-03 | 2020-10-16 | 广东顺德宏燕建材有限公司 | Shell pure slurry coating |
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Address after: 201505 Shanghai Jinshan District City Lin Zhen Lin Shing Road 318 Applicant after: Shanghai Bei Bei habitat Construction Group Co., Ltd. Address before: 201505 Shanghai Jinshan District City Lin Zhen Lin Shing Road 318 Applicant before: Shanghai Beiheng Chemical Building Material Co., Ltd. |
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Application publication date: 20150325 |