CN107083123A - A kind of negative oxygen ion coating and preparation method thereof - Google Patents
A kind of negative oxygen ion coating and preparation method thereof Download PDFInfo
- Publication number
- CN107083123A CN107083123A CN201710472255.1A CN201710472255A CN107083123A CN 107083123 A CN107083123 A CN 107083123A CN 201710472255 A CN201710472255 A CN 201710472255A CN 107083123 A CN107083123 A CN 107083123A
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- Prior art keywords
- oxygen ion
- negative oxygen
- ion coating
- parts
- defoamer
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0831—Gold
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/221—Oxides; Hydroxides of metals of rare earth metal
- C08K2003/2213—Oxides; Hydroxides of metals of rare earth metal of cerium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of negative oxygen ion coating and preparation method thereof.The raw material of the negative oxygen ion coating includes by weight：35~40 parts of polymer emulsion, 1~3 part of tourmaline powder, 2~5 parts of cerium compound, 3~5 parts of titanate coupling agent, 1~2 part of nanogold, 0.1~1 part of germanium powder, 0.5~1 part of C 12 A 7,1~5 part of alcohol organic solvent, 0.1~0.3 part of Ricinate, 0.2~0.4 part of defoamer, 50~60 parts of water.The negative oxygen ion coating of the present invention is a kind of with excellent water resistance energy, the environmental protection coating material of wash-resistant property, it is chronically exposed in air and does not ftracture, do not fall off, bond strength is high, and can continue to produce anion for a long time after coating film forming, and anion burst size is higher.
Description
Technical field
The present invention relates to paint field, more particularly to a kind of negative oxygen ion coating and preparation method thereof.
Background technology
It is well known that the time of people 70% tides over indoors, therefore the cleannes of room air will directly influence people
Health.In recent years, as living standards of the people are improved constantly, living environment constantly improves, and indoor decorating is increasingly bold and unconstrained
While magnificent, attractive in appearance, more and more the problem of indoor pollution influences health caused by finishing, investigation shows：68%
Disease origin is relevant with the pollution of room air, and 80% cancer is relevant with living environment.Therefore, high-efficient and lasting in clean room
Pernicious gas, the target for keeping pure and fresh healthy life, working environment more and more urgently to be pursued into people.Negative ion paint
Come out and bring Gospel to the mankind, people can be allowed really to enjoy pure and fresh healthy air in room.This coating series
Not only there is decoration protective effect, and sustainable release anion, so as to increase the concentration of anion in air, improvement is reached
The purpose of environment.
However, in the existing coating containing anionic additive, although also added with a certain amount of anionic additive, but
It is that the air-anion concentration that its product is produced is not high, effect is not lasting.
The content of the invention
In view of this, the invention provides a kind of negative oxygen ion coating and preparation method thereof, in negative oxygen ion of the invention
Selection of the wall coating to coating base material has no particular/special requirement, and with the high excellent properties of water-fastness, bond strength, it is of the invention
Negative oxygen ion interior wall coating not only can rapidly peculiar smell suction, the negative aeroion produced after smoke, brushing can also be absorbed for a long time
Concentration is high, efficacy lasting.
The present invention, which is adopted the following technical scheme that, realizes above-mentioned purpose：
The invention provides a kind of negative oxygen ion coating, its raw material includes by weight：35~40 parts of polymer emulsion, electricity
1~3 part of gas stone powder, 2~5 parts of cerium compound, 3~5 parts of titanate coupling agent, 1~2 part of nanogold, 0.1~1 part of germanium powder,
0.5~1 part of C 12 A 7,1~5 part of alcohol organic solvent, 0.1~0.3 part of Ricinate, defoamer 0.2~0.4
Part, 50~60 parts of water.
Titanate coupling agent in the present invention, which will act not only as coupling agent, to fill out organic polymer base-material and inorganic face
Material combines, and its TiO 2 sol that a small amount of hydrolysis generation nanostructured occurs in whipping process is present in coating
In product, acted on the coordinated of nanogold, germanium metal, tourmaline and cerium compound, be more beneficial for negative aeroion
Sustained release.
The present invention is by adding C 12 A 7, using its unique cage cavity configuration and the oxonium ion group of high activity,
Again with the collective effect of other components, the continuous and effective release of anion is realized.
It is preferred that, the raw material of negative oxygen ion coating of the invention is made up of following components by weight：Polymer emulsion 35
~40 parts, 1~3 part of tourmaline powder, 2~5 parts of cerium compound, 3~5 parts of titanate coupling agent, 1~2 part of nanogold, germanium powder
0.1~1 part, 0.5~1 part of C 12 A 7,1~5 part of alcohol organic solvent, 0.1~0.3 part of Ricinate, defoamer
0.2~0.4 part, 50~60 parts of water.
Wherein, described polymer emulsion is preferably styrene-acrylic emulsion.
Wherein, described cerium compound is preferably cerium oxide, more preferably cerium sesquioxide and/or ceria.
Wherein, described titanate coupling agent be preferably isopropyl three (dioctylphyrophosphoric acid acyloxy) titanate esters, it is different
In (the dioctyl phosphoric acid acyloxy) titanate esters of propyl group three and the oleic acid acyloxy of isopropyl two (dioctyl phosphoric acid acyloxy) titanate esters
One or more.
Wherein, the particle diameter of described nanogold is preferably 10~20nm.
Wherein, described defoamer is preferably defoamer CF-16.
Wherein, described Ricinate is preferably dispersant SN-5040.
Wherein, described alcohol organic solvent is preferably ethanol and/or methanol.
Present invention also offers the preparation method of above-mentioned negative oxygen ion coating, it comprises the steps：
Water, polymer emulsion, Ricinate, alcohol organic solvent are added in agitator, is added after stirring
Tourmaline powder, cerium compound, titanate coupling agent, nanogold, germanium powder, C 12 A 7, defoamer, it is agitated uniform
.
The positive effect that the present invention is obtained：The negative oxygen ion coating of the present invention be it is a kind of have excellent water resistance energy,
The environmental protection coating material of wash-resistant property, is chronically exposed in air and does not ftracture, do not fall off, and bond strength is high, and can after coating film forming
To continue to produce anion for a long time, anion burst size is higher.
Embodiment
Technical scheme is further illustrated with reference to specific embodiment.
Negative ion concentration method of testing：Coating is coated in polyester fiber base fabric, controls base fabric to coat density for 150
Gram/m, baking.Using《The detection and evaluation of GBT 30128-2013 textile anion generating capacities》Determine anion hair
Raw amount, produces negative ion concentration.
The preparation of C 12 A 7 is specifically shown in model celebrating newly, Yu Qijun, Wei Jiang hero silicon using conventional high-temperature sintering process
Hydrochlorate is circulated a notice of, 2007,26 (5)：905-909
Embodiment 1
Composition of raw materials is as shown in the table：
Wherein, polymer emulsion is styrene-acrylic emulsion；Cerium compound is cerium sesquioxide；Alcohol organic solvent is ethanol；Titanium
Acid esters coupling agent is isopropyl three (dioctylphyrophosphoric acid acyloxy) titanate esters；The particle diameter of nanogold is 10~20nm；Defoamer
For defoamer CF-16；Ricinate is dispersant SN-5040.
Preparation method：Water, polymer emulsion, Ricinate, alcohol organic solvent are added in agitator, is stirred
After add tourmaline powder, cerium compound, titanate coupling agent, nanogold, germanium powder, C 12 A 7, defoamer, pass through
Stir.
The performance for the negative oxygen ion coating that the present embodiment is obtained is as shown in the table：
In addition, the present invention nagative ion inner wall coating not only can rapidly peculiar smell suction, smoke can also be absorbed for a long time, detection
The air-anion concentration that as shown by data is produced after brushing is high, efficacy lasting.
Embodiment 2
Composition of raw materials is as shown in the table：
| Sequence number | Title material | Parts by weight |
| 1 | Polymer emulsion | 37 |
| 2 | Tourmaline powder | 2 |
| 3 | Cerium compound | 5 |
| 4 | Titanate coupling agent | 3 |
| 5 | Nanogold | 2 |
| 6 | Germanium powder | 0.5 |
| 7 | C 12 A 7 | 0.7 |
| 8 | Alcohol organic solvent | 3 |
| 9 | Ricinate | 0.1 |
| 10 | Defoamer | 0.3 |
| 11 | Water | 55 |
Wherein, polymer emulsion is styrene-acrylic emulsion；Cerium compound is ceria；Alcohol organic solvent is methanol；Metatitanic acid
Ester coupling agent is isopropyl three (dioctyl phosphoric acid acyloxy) titanate esters；The particle diameter of nanogold is 10~20nm；Defoamer is to disappear
Infusion CF-16；Ricinate is dispersant SN-5040.
Preparation method：Water, polymer emulsion, Ricinate, alcohol organic solvent are added in agitator, is stirred
After add tourmaline powder, cerium compound, titanate coupling agent, nanogold, germanium powder, C 12 A 7, defoamer, pass through
Stir.
The performance for the negative oxygen ion coating that the present embodiment is obtained is as shown in the table：
In addition, the present invention nagative ion inner wall coating not only can rapidly peculiar smell suction, smoke can also be absorbed for a long time, detection
The air-anion concentration that as shown by data is produced after brushing is high, efficacy lasting.
Embodiment 3
Composition of raw materials is as shown in the table：
Wherein, polymer emulsion is styrene-acrylic emulsion；Cerium compound is cerium sesquioxide；Alcohol organic solvent is ethanol；Titanium
Acid esters coupling agent is the oleic acid acyloxy of isopropyl two (dioctyl phosphoric acid acyloxy) titanate esters；The particle diameter of nanogold be 10~
20nm；Defoamer is defoamer CF-16；Ricinate is dispersant SN-5040.
Preparation method：Water, polymer emulsion, Ricinate, alcohol organic solvent are added in agitator, is stirred
After add tourmaline powder, cerium compound, titanate coupling agent, nanogold, germanium powder, C 12 A 7, defoamer, pass through
Stir.
The performance for the negative oxygen ion coating that the present embodiment is obtained is as shown in the table：
In addition, the present invention nagative ion inner wall coating not only can rapidly peculiar smell suction, smoke can also be absorbed for a long time, detection
The air-anion concentration that as shown by data is produced after brushing is high, efficacy lasting.
Obviously, the explanation of above example is only intended to product, method and its core concept for helping to understand the present invention.Should
, under the premise without departing from the principles of the invention, can also be right for the those of ordinary skill of the technical field when pointing out
The present invention carries out some improvement and modification, and these are improved and modification is also fallen into the protection domain of the claims in the present invention.
Claims (10)
1. a kind of negative oxygen ion coating, its raw material includes by weight：35~40 parts of polymer emulsion, tourmaline powder 1~3
Part, 2~5 parts of cerium compound, 3~5 parts of titanate coupling agent, 1~2 part of nanogold, 0.1~1 part of germanium powder, C 12 A 7
0.5~1 part, 1~5 part of alcohol organic solvent, 0.1~0.3 part of Ricinate, 0.2~0.4 part of defoamer, 50~60 parts of water.
2. negative oxygen ion coating as claimed in claim 1, it is characterised in that the raw material of described negative oxygen ion coating is by weight
Part is made up of following components：35~40 parts of polymer emulsion, 1~3 part of tourmaline powder, 2~5 parts of cerium compound, titanate esters are even
Join 3~5 parts of agent, 1~2 part of nanogold, 0.1~1 part of germanium powder, 0.5~1 part of C 12 A 7, alcohol organic solvent 1~5
Part, 0.1~0.3 part of Ricinate, 0.2~0.4 part of defoamer, 50~60 parts of water.
3. negative oxygen ion coating as claimed in claim 1, it is characterised in that described polymer emulsion is styrene-acrylic emulsion.
4. negative oxygen ion coating as claimed in claim 1, it is characterised in that described cerium compound is cerium oxide, preferably
For cerium sesquioxide and/or ceria.
5. negative oxygen ion coating as claimed in claim 1, it is characterised in that described titanate coupling agent is isopropyl three
(dioctylphyrophosphoric acid acyloxy) titanate esters, (the dioctyl phosphoric acid acyloxy) titanate esters of isopropyl three and the oleic acid acyl-oxygen of isopropyl two
One or more in base (dioctyl phosphoric acid acyloxy) titanate esters.
6. negative oxygen ion coating as claimed in claim 1, it is characterised in that the particle diameter of described nanogold is 10~20nm.
7. negative oxygen ion coating as claimed in claim 1, it is characterised in that described defoamer is defoamer CF-16.
8. negative oxygen ion coating as claimed in claim 1, it is characterised in that described Ricinate is dispersant SN-
5040。
9. negative oxygen ion coating as claimed in claim 1, it is characterised in that described alcohol organic solvent be ethanol and/or
Methanol.
10. a kind of preparation method of such as negative oxygen ion coating according to any one of claims 1 to 9, it comprises the steps：
Water, polymer emulsion, Ricinate, alcohol organic solvent are added in agitator, tourmaline powder is added after stirring
End, cerium compound, titanate coupling agent, nanogold, germanium powder, C 12 A 7, defoamer, it is agitated uniform.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710472255.1A CN107083123A (en) | 2017-06-20 | 2017-06-20 | A kind of negative oxygen ion coating and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710472255.1A CN107083123A (en) | 2017-06-20 | 2017-06-20 | A kind of negative oxygen ion coating and preparation method thereof |
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| CN107083123A true CN107083123A (en) | 2017-08-22 |
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| CN201710472255.1A Pending CN107083123A (en) | 2017-06-20 | 2017-06-20 | A kind of negative oxygen ion coating and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110343441A (en) * | 2019-08-14 | 2019-10-18 | 炫杰复合材料（上海）有限公司 | A kind of water negative ion coating and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110343441A (en) * | 2019-08-14 | 2019-10-18 | 炫杰复合材料（上海）有限公司 | A kind of water negative ion coating and preparation method thereof |
| CN110343441B (en) * | 2019-08-14 | 2021-03-26 | 炫杰复合材料（上海）有限公司 | Water-based negative ion coating and preparation method thereof |
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Application publication date: 20170822 |