CN104031465A - Anionic aqueous ink and preparation method thereof - Google Patents
Anionic aqueous ink and preparation method thereof Download PDFInfo
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- CN104031465A CN104031465A CN201410185152.3A CN201410185152A CN104031465A CN 104031465 A CN104031465 A CN 104031465A CN 201410185152 A CN201410185152 A CN 201410185152A CN 104031465 A CN104031465 A CN 104031465A
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- negative ion
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- ion water
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- 125000000129 anionic group Chemical group 0.000 title claims abstract description 17
- 238000002360 preparation method Methods 0.000 title claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 45
- 239000000839 emulsion Substances 0.000 claims abstract description 35
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 34
- 239000000654 additive Substances 0.000 claims abstract description 13
- 230000000996 additive effect Effects 0.000 claims abstract description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000000945 filler Substances 0.000 claims abstract description 9
- 239000000049 pigment Substances 0.000 claims abstract description 8
- 229920000642 polymer Polymers 0.000 claims abstract description 8
- 239000002562 thickening agent Substances 0.000 claims abstract description 6
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 4
- 150000002500 ions Chemical class 0.000 claims description 62
- 239000006185 dispersion Substances 0.000 claims description 29
- 239000000463 material Substances 0.000 claims description 27
- 239000000203 mixture Substances 0.000 claims description 20
- 239000000843 powder Substances 0.000 claims description 20
- 150000002148 esters Chemical class 0.000 claims description 16
- 230000008719 thickening Effects 0.000 claims description 16
- 239000013530 defoamer Substances 0.000 claims description 15
- 238000003756 stirring Methods 0.000 claims description 14
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 12
- 239000004576 sand Substances 0.000 claims description 12
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 8
- 241000276489 Merlangius merlangus Species 0.000 claims description 7
- 239000011521 glass Substances 0.000 claims description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- 239000004408 titanium dioxide Substances 0.000 claims description 6
- 239000006229 carbon black Substances 0.000 claims description 5
- -1 divinyl anhydride Chemical class 0.000 claims description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- 229920002125 Sokalan® Polymers 0.000 claims description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- 239000004584 polyacrylic acid Substances 0.000 claims description 4
- 239000002480 mineral oil Substances 0.000 claims description 3
- 235000010446 mineral oil Nutrition 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 229910052613 tourmaline Inorganic materials 0.000 claims description 3
- 229940070527 tourmaline Drugs 0.000 claims description 3
- 239000011032 tourmaline Substances 0.000 claims description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 3
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 2
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- 229920000147 Styrene maleic anhydride Polymers 0.000 claims description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 2
- 239000005083 Zinc sulfide Substances 0.000 claims description 2
- 150000001298 alcohols Chemical class 0.000 claims description 2
- 235000012211 aluminium silicate Nutrition 0.000 claims description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 2
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 claims description 2
- 229920005601 base polymer Polymers 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 2
- 239000001913 cellulose Substances 0.000 claims description 2
- 229920002678 cellulose Polymers 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 238000009833 condensation Methods 0.000 claims description 2
- 230000005494 condensation Effects 0.000 claims description 2
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 claims description 2
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 2
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims description 2
- 239000010419 fine particle Substances 0.000 claims description 2
- AVWWPFWBTLONRB-UHFFFAOYSA-N furan-2,5-dione;2-methylprop-1-ene Chemical group CC(C)=C.CC(C)=C.O=C1OC(=O)C=C1 AVWWPFWBTLONRB-UHFFFAOYSA-N 0.000 claims description 2
- 125000000623 heterocyclic group Chemical group 0.000 claims description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000004816 latex Substances 0.000 claims description 2
- 229920000126 latex Polymers 0.000 claims description 2
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 claims description 2
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 claims description 2
- 229920000058 polyacrylate Polymers 0.000 claims description 2
- 229920005646 polycarboxylate Polymers 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 229920005989 resin Polymers 0.000 claims description 2
- 239000011347 resin Substances 0.000 claims description 2
- 229920002050 silicone resin Polymers 0.000 claims description 2
- 239000000052 vinegar Substances 0.000 claims description 2
- 235000021419 vinegar Nutrition 0.000 claims description 2
- 239000010456 wollastonite Substances 0.000 claims description 2
- 229910052882 wollastonite Inorganic materials 0.000 claims description 2
- 239000011787 zinc oxide Substances 0.000 claims description 2
- 229910052984 zinc sulfide Inorganic materials 0.000 claims description 2
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 claims description 2
- 230000036541 health Effects 0.000 abstract description 17
- 239000011248 coating agent Substances 0.000 abstract description 14
- 238000000576 coating method Methods 0.000 abstract description 14
- 230000007613 environmental effect Effects 0.000 abstract description 10
- 150000001450 anions Chemical class 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 2
- 230000001954 sterilising effect Effects 0.000 abstract description 2
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 2
- 238000003860 storage Methods 0.000 abstract description 2
- 238000004887 air purification Methods 0.000 abstract 1
- 230000002421 anti-septic effect Effects 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 238000012423 maintenance Methods 0.000 abstract 1
- 239000000126 substance Substances 0.000 description 17
- 239000003570 air Substances 0.000 description 14
- 238000001514 detection method Methods 0.000 description 12
- 238000012360 testing method Methods 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 10
- 238000007639 printing Methods 0.000 description 8
- 230000008901 benefit Effects 0.000 description 7
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 5
- 239000002131 composite material Substances 0.000 description 4
- 230000006870 function Effects 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 238000010276 construction Methods 0.000 description 3
- 238000005034 decoration Methods 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 101100412856 Mus musculus Rhod gene Proteins 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 239000012847 fine chemical Substances 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- 238000005457 optimization Methods 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 125000003636 chemical group Chemical group 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 229940074391 gallic acid Drugs 0.000 description 1
- 235000004515 gallic acid Nutrition 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000008447 perception Effects 0.000 description 1
- 230000002186 photoactivation Effects 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Abstract
The invention discloses an anionic aqueous ink and a preparing method thereof. The anionic aqueous ink comprises, by weight, 28-40 parts of a polymer emulsion, 15 parts of a pigment, 4-8 parts of a filler, 1-5 parts of an anion additive, 3.5-8 parts of alcohol, 0.6-3.6 parts of a dispersant, 0.1-0.8 parts of a thickening agent, 0.05-0.3 parts of a leveling agent, 0.1-0.8 parts of an antifoaming agent, 0.05-0.06 parts of an antiseptic and 26.92-41 parts of water. The anionic aqueous ink can sustainably release air anions without external energy, and is conducive to the maintenance of the health of human bodies in order to realize sterilization and air purification, and the anionic aqueous ink has the characteristics of environmental protection, safety, good storage stability, coating fullness, good decorative effect and the like.
Description
(1) technical field
The present invention relates to water color ink and preparation method thereof, be specifically related to water color ink of a kind of energy anion releasing and preparation method thereof, water color ink of the present invention can be applicable to wallpaper printing.
(2) background technology
Wallpaper is as a kind of house decorative material, because of features such as its color are various, pattern abundant, construction safety is convenient, more and more by the popular part of being accepted has also replaced interior wall coating.Wallpaper, from being applied at first the public places such as hotel, hotel and office, is applied to more and more widely by now the interior decoration of family, thereby is more and more paid close attention to.But, wallpaper printing ink mostly in the market is solvent type ink, it contains a large amount of organic volatile (content is conventionally more than 40%), these organic volatile materials discharged to atmosphere, have all caused larger murder by poisoning to the health of inhabitation personnel in printing, construction workman and wallpaper decoration building in printing and construction process.Therefore become the development trend of industry with the environment-friendly type aqueous printing-ink of water to replace organic solvent.On the other hand, at present the research of wallpaper is rested on to its surperficial decorate properties research more, and few to its health application function research.Because people's most of the time is all spent indoor, the quality of indoor environmental quality directly affects the healthy of people, and for the wallpaper of upholstery because its shared indoor area is larger, if therefore can make it possess some functional health performance, will more be subject to consumers in general's welcome.In sum; along with the enhancing of popular environmental protection, health perception; people are no longer only confined to beautiful decoration effect to the requirement of wallpaper; and more wish that it has many-sided performance such as the environment of improvement, to protect mankind health; therefore, developing a kind of environment protection type wallpaper printing water color ink with nourishing function is the key of widening its market application.
At present, airborne negative ion concentration has been listed in an important indicator of weighing environment, Air quality.Its content and HUMAN HEALTH have substantial connection, as shown in the table:
Negative ion concentration and HUMAN HEALTH relation in table 1. environment (drawing from " International Medical magazine " report)
From table 1, in the enclosed spaces such as house, office, airborne negative ion concentration does not reach the basic demand that maintains HUMAN HEALTH far away.A kind of settling mode of now taking is at indoor location anion generator, but this both took up space, and increases again the expense such as equipment, power consumption, and the switching on and shutting down of every day operation makes troubles also to people's use.Another kind of relatively efficient manner is to add anionic additive in indoor interior wall coating or wallpaper ink, makes interior wall coating or wallpaper ink can produce constantly negative aeroion.Common anionic additive is the natural crystal mixtures such as tourmalinite.The anionic additives such as tourmalinite, containing multiple elements such as Si, Mg, Fe, Al, K, Na, have permanent spontaneous electrode, and this electrode can make the water molecules in ambient air that faint electrolytic action occurs, and generate OH-and H
+.H
+in weak current between tourmalinite electrode, obtain electronics, OH
-form negative aeroion (H with airborne water molecules
3o
2)
-.Numerous results of study show, interior wall coating or the wallpaper ink of introducing anionic additive can improve room air negative ion concentration significantly, are conducive to HUMAN HEALTH.But major part is in the market solvent-based system containing function interior wall coating, the wallpaper ink etc. of anionic additive, unfavorable to environment; And the film that solvent-based system forms is comparatively fine and close, be unfavorable for contacting of tourmalinite and water in air molecule, therefore can not produce more negative ion.In addition, part interior wall coating, wallpaper ink adopt photoactivation mode to produce negative aeroion, must under illumination condition, could produce negative ion, and this has greatly limited it and has applied.
The object of the invention is to overcome the deficiencies in the prior art, a kind of wallpaper printing water color ink of energy anion releasing is provided.This ink adopts water miscible liquid system, Environmental Safety, and it not only has the effect of attractive, decorative, for good and all release air negative ion, and without external energy, be a kind of novel environment friendly wallpaper printing water color ink with nourishing function.
(3) summary of the invention
The object of the present invention is to provide a kind of negative ion water-based ink that can be used for wallpaper printing and preparation method thereof, and, negative ion water-based ink of the present invention, without just release air negative ion constantly of external energy, reaches room air negative ion concentration and maintains the required level of HUMAN HEALTH.
The object of the invention is to be achieved through the following technical solutions:
A kind of negative ion water-based ink, described negative ion water-based ink is made up of the raw material of following weight proportion: 28～40 parts of polymer emulsions, 15 parts of pigment, 4～8 parts of fillers, 1～5 part of anionic additive, 3.5～8 parts of alcohol, 0.6～3.6 part of dispersion agent, 0.1～0.8 part of thickening material, 0.05～0.3 part of flow agent, 0.1～0.8 part of defoamer, 0.05～0.06 part of sanitas, 26.92～41 parts, water; Described polymer emulsion is the mixture of one or more arbitrary proportions in benzene emulsion, the tertiary emulsion of vinegar, acrylate and vinyl acetate emulsion, polyacrylic ester pure-acrylic emulsion, polyaminoester emulsion, organosilicon crylic acid latex, fluoro-resin emulsion, and the solid content of described polymer emulsion is 45wt%～50wt%; Described filler can be the mixture of one or more arbitrary proportions in talcum powder, coarse whiting, fine particle calcium carbonate, kaolin, wollastonite powder physique filler.
Polymer emulsion described in the present invention is preferably that solid content is the polyacrylic ester pure-acrylic emulsion of 45wt%～50wt%.
Pigment of the present invention can be the one in titanium dioxide, zinc oxide, zinc sulfide white, carbon black, iron oxide black, nigrosine, lead-chrome yellow, iron oxide yellow, iron oxide red, red, phthalocyanine blue b, ultramarine, and the preferred described pigment of the present invention is titanium dioxide R-902+ (E.I.Du Pont Company) or water-based carbon black HD-300M (Hangzhou Hei Yuan Chemical Co., Ltd.).
Anionic additive of the present invention is preferably tourmaline powder, as TZY-01 (Beijing Health-care Science & Technology Co., Ltd.).
Dispersion agent of the present invention can be polycarboxylate (as Disponer W-922, De Qian company; KP010, Shanghai De Yu get trade Co., Ltd; BYK-P-104, BYK company), polyacrylic acid derivative (as Disponer W-511, De Qian company; Disponer W-519, De Qian company), along divinyl anhydride multipolymer (as diisobutylene-cis-butenedioic anhydride multipolymer or styrene-maleic anhydride copolymer; As SMA1000P, Sartomer company), condensation naphthalenesulfonate is (as PD, Qingdao Chemical Inst.), poly carboxylic acid (as Anti-Terra-203, BYK company), polyvinyl alcohol (as BP-20, the good Chemical Industry Science Co., Ltd of Shanghai fond dream; BP-17, the good Chemical Industry Science Co., Ltd of Shanghai fond dream) in the mixture of one or more arbitrary proportions; Preferably polycarboxylic acid salt's dispersion agent.
Thickening material of the present invention can be that cellulose thickener is (as CELLOSIZE
tMqP4400H, Dow Chemical; CELLOSIZE
tMqP15000H, Dow Chemical; CELLOSIZE
tMqP30000H, Dow Chemical; CELLOSIZE
tMqP52000H, Dow Chemical; CELLOSIZE
tMqP100MH, Dow Chemical; CELLOSIZE
tMeR30M, Dow Chemical; CELLOSIZE
tMeR52M, Dow Chemical), polyurethanes thickening material is (as 8020, Long Shida Chemical Industry Science Co., Ltd;
216, De Qian company; DeuRheo WT-105A, De Qian company; DeuRheo WT-201, De Qian company; DeuRheo WT-202, De Qian company; DeuRheo WT-204, De Qian company), agent for polyacrylic acid thickening (as DeuRheo WT-113, De Qian company; DeuRheo WT-115, De Qian company; DeuRheo WT-120, De Qian company), polyacrylate-type thickeners (as thickening material D-11, Gaoming District, Foshan City Hang Run auxiliary agent company limited; Latekoll D, BASF AG) in the mixture of any one or two or more arbitrary proportions; Optimization polypropylene acids or polyacrylate-type thickeners.
Flow agent of the present invention can be polyacrylate(s) flow agent (as A900, Mei Liken Chemical Group company limited of the U.S.; Resiflow W50, BYK company), silicone resin class flow agent is (as Silcn353, Shanghai De Yu get trade Co., Ltd), the mixture of one or more arbitrary proportions in fluoroolefins flow agent (as 5100, Long Shida Chemical Industry Science Co., Ltd); Optimization polypropylene esters of gallic acid flow agent.
Defoamer of the present invention can be lower alcohols defoamer (as
dF1492, De Qian company;
dF1760, De Qian company;
dF3163, De Qian company), mineral oil defoaming agent (as Drewplus T-4507, ASHLAND-AQUALON company; ADVANTAGE AM-1512, ASHLAND-AQUALON company), silicone based defoamer (as Pulcra1918, Kekai Fine Chemical (Shanghai) Co., Ltd.; Pulcra1920, Kekai Fine Chemical (Shanghai) Co., Ltd.; Drewplus T-4201, ASHLAND-AQUALON company; Drewplus TS-4400, ASHLAND-AQUALON company; Drewplus TS-4481, ASHLAND-AQUALON company) in the mixture of one or more arbitrary proportions; Preferably mineral oil defoaming agent.
Sanitas of the present invention is the mixture of one or more arbitrary proportions in substituted arene class sanitas, heterocycles sanitas, aminated compounds class sanitas, as DeuAdd MB-11 (De Qian company), DeuAdd MB-16 (De Qian company), Kathon LXE (Rhom and Hass) etc., prerequisite is the stability that does not hinder ink system, little on system impact, preferably Kathon LXE (Rhom and Hass).
The present invention also provides a kind of preparation method of negative ion water-based ink of the present invention, and described preparation method carries out as follows:
(1) water of formula ratio, dispersion agent, pigment, filler, anionic additive and granulated glass sphere are added in rapid dispersion machine, disperse 2～3 hours, obtain mill base;
(2) mill base polymer emulsion of formula ratio, defoamer and step (1) being prepared adds and disperses in sand mill, stirs 10～60 minutes, then add thickening material and the flow agent of formula ratio with the speed of 800～1500 turn/min;
(3) keep stirring, obtain described negative ion water-based ink after adding the alcohol, sanitas of formula ratio.
Compared with prior art, the present invention has following advantage:
1, adopting tourmaline powder is anionic additive, evenly, is stably dispersed in ink, without just release air negative ion sustainably of external energy, makes airborne negative ion concentration up to 1200～2300/cm
3, reach the Air quality of town park rank, be conducive to maintain HUMAN HEALTH, and and then the object that reaches sterilization, purify air;
2, (homemade polyacrylic ester pure-acrylic emulsion has been applied for patent of invention to select homemade polyacrylic ester pure-acrylic emulsion, application number is 2013105793039, publication number is CN103601837A) be the low-melting ink vehicle of ink, conventional solvent type ink is become to water color ink, not only Environmental Safety, and increased the ventilation property of coating, and can make more tourmalinite contact with airborne water molecules, discharge more negative ion;
3,, by the choose reasonable of each analog assistant, ensured ink exquisiteness, do not precipitated, not stratified to there is excellent storage stability, coating is plentiful, decorative effect is good feature.
(4) embodiment
Below in conjunction with specific embodiment, the present invention is described further, but protection scope of the present invention is not limited in this:
The package stability of ink refers to that ink leaves standstill 6 days under 60 DEG C of conditions, not precipitating, not stratifiedly represent ink package stability >6 month;
The detection of the negative ion concentration that wallpaper ink discharges is according to the generating capacity of Q/JC JJT030～2002 inspection negative aeroion, by Chinese architecture material tests Spot detection.
Embodiment 1
The composition of raw materials (1wt% negative ion powder addition) of table 2 ink composite
Note: homemade polyacrylic ester pure-acrylic emulsion has been applied for patent of invention, application number is 2013105793039, publication number is CN103601837A.
The preparation method of ink product carries out as follows:
(1) according to the formula in table 2, the granulated glass sphere that is 2mm by water, BYK-P-104 dispersion agent, titanium dioxide R-902+, coarse whiting and TZY-01 negative ion powder and diameter adds rapid dispersion machine (KS-370 coating rapid dispersion machine, Shanghai Modern Environmental Engineering Technology Co., Ltd.) in, disperse 2 hours, obtain stock white;
(2) stock white polyacrylic ester pure-acrylic emulsion, ADVANTAGE AM-1512 defoamer and step (1) being prepared adds and disperses sand mill (SDF400 experiment dispersion sand mill, Shuan Feng chemical machinery company limited of Jiangyin City) in, speed with 1000 turn/min stirs 60 minutes, and adds successively Latekoll D thickening material and Resiflow W50 flow agent;
(3) keep stirring, can be packaged to be ink product after adding alcohol and Kathon LXE sanitas.
Target ink product package stability >6 month, after ink is coated on PVC wallpaper, by Chinese architecture material tests Spot detection, the negative ion concentration that detected result shows to use the PVC wallpaper that scribbles target ink to produce was 1213/cm
3, compared with following comparative example 1, increased by 992/cm
3negative ion concentration, reach the Air quality of town park rank.
Comparative example 1
Press the formula ratio in table 2, the addition of TZY-01 negative ion powder is 0, all the other component formula ratios remain unchanged, be made into ink by the operation steps of embodiment 1, obtain target ink product package stability >6 month, after ink is coated on PVC wallpaper, by Chinese architecture material tests Spot detection, the negative ion concentration that detected result shows to use the PVC wallpaper that scribbles target ink to produce is 221/cm
3, far below the primary demand that maintains HUMAN HEALTH.
Embodiment 2
The composition of raw materials (2wt% negative ion powder addition) of table 3. ink composite
Note: homemade polyacrylic ester pure-acrylic emulsion has been applied for patent of invention, application number is 2013105793039, publication number is CN103601837A.
The preparation method of ink product carries out as follows:
(1) according to the formula in table 3, the granulated glass sphere that is 2mm by water, BYK-P-104 dispersion agent, titanium dioxide R-902+, coarse whiting and TZY-01 negative ion powder and diameter adds rapid dispersion machine (KS-370 coating rapid dispersion machine, Shanghai Modern Environmental Engineering Technology Co., Ltd.) in, disperse 3 hours, obtain stock white;
(2) stock white polyacrylic ester pure-acrylic emulsion, ADVANTAGE AM-1512 defoamer and step (1) being prepared adds and disperses sand mill (SDF400 experiment dispersion sand mill, Shuan Feng chemical machinery company limited of Jiangyin City) in, speed with 1200 turn/min stirs 40 minutes, and adds successively Latekoll D thickening material and Resiflow W50 flow agent;
(3) keep stirring, can be packaged to be ink product after adding alcohol and Kathon LXE sanitas.
Target ink product package stability >6 month, after ink is coated on PVC wallpaper, by Chinese architecture material tests Spot detection, the negative ion concentration that detected result shows to use the PVC wallpaper that scribbles target ink to produce was 1340/cm
3, compared with following comparative example 2, increased by 1109/cm
3negative ion concentration, reach the Air quality of town park rank.
Comparative example 2
Press the formula ratio in table 3, the addition of TZY-01 negative ion powder is 0, all the other component formula ratios remain unchanged, be made into ink by the operation steps of embodiment 2, obtain target ink product package stability >6 month, after ink is coated on PVC wallpaper, by Chinese architecture material tests Spot detection, the negative ion concentration that detected result shows to use the PVC wallpaper that scribbles target ink to produce is 231/cm
3, far below the primary demand that maintains HUMAN HEALTH.
Embodiment 3
The composition of raw materials (3wt% negative ion powder addition) of table 4. ink composite
Note: homemade polyacrylic ester pure-acrylic emulsion has been applied for patent of invention, application number is 2013105793039, publication number is CN103601837A.
The preparation method of ink product carries out as follows:
(1) according to the formula in table 4, the granulated glass sphere that is 2mm by water, BYK-P-104 dispersion agent, water-based carbon black HD-300M, coarse whiting and TZY-01 negative ion powder and diameter adds rapid dispersion machine (KS-370 coating rapid dispersion machine, Shanghai Modern Environmental Engineering Technology Co., Ltd.) in, disperse 3 hours, obtain black slurry;
(2) black slurry polyacrylic ester pure-acrylic emulsion, ADVANTAGE AM-1512 defoamer and step (1) being prepared adds disperses sand mill (SDF400 experiment dispersion sand mill, Shuan Feng chemical machinery company limited of Jiangyin City) in, speed with 800 turn/min stirs 60 minutes, and adds successively Latekoll D thickening material and Resiflow W50 flow agent;
(3) keep stirring, can be packaged to be ink product after adding alcohol and Kathon LXE sanitas.
Target ink product package stability >6 month, after ink is coated on PVC wallpaper, by Chinese architecture material tests Spot detection, the negative ion concentration that detected result shows to use the PVC wallpaper that scribbles target ink to produce was 1575/cm
3, compared with following comparative example 3, increased by 1360/cm
3negative ion concentration, reach the Air quality of town park rank.
Comparative example 3
Press the formula ratio in table 4, the addition of TZY-01 negative ion powder is 0, all the other component formula ratios remain unchanged, be made into ink by the operation steps of embodiment 3, obtain target ink product package stability >6 month, after ink is coated on PVC wallpaper, by Chinese architecture material tests Spot detection, the negative ion concentration that detected result shows to use the PVC wallpaper that scribbles target ink to produce is 215/cm
3, far below the primary demand that maintains HUMAN HEALTH.
Embodiment 4
The composition of raw materials (4wt% negative ion powder addition) of table 5. ink composite
Note: homemade polyacrylic ester pure-acrylic emulsion has been applied for patent of invention, application number is 2013105793039, publication number is CN103601837A.
The preparation method of ink product carries out as follows:
(1) according to the formula in table 5, the granulated glass sphere that is 2mm by water, BYK-P-104 dispersion agent, water-based carbon black HD-300M, coarse whiting and TZY-01 negative ion powder and diameter adds rapid dispersion machine (KS-370 coating rapid dispersion machine, Shanghai Modern Environmental Engineering Technology Co., Ltd.) in, disperse 3 hours, obtain black slurry;
(2) black slurry polyacrylic ester pure-acrylic emulsion, ADVANTAGE AM-1512 defoamer and step (1) being prepared adds disperses sand mill (SDF400 experiment dispersion sand mill, Shuan Feng chemical machinery company limited of Jiangyin City) in, speed with 1300 turn/min stirs 20 minutes, and adds successively Latekoll D thickening material and Resiflow W50 flow agent;
(3) keep stirring, can be packaged to be ink product after adding alcohol and Kathon LXE sanitas.
Target ink product package stability >6 month, after ink is coated on PVC wallpaper, by Chinese architecture material tests Spot detection, the negative ion concentration that detected result shows to use the PVC wallpaper that scribbles target ink to produce was 2054/cm
3, compared with following comparative example 4, increased by 1825/cm
3negative ion concentration, reach the Air quality of town park rank.
Comparative example 4
Press the formula ratio in table 5, the addition of TZY-01 negative ion powder is 0, all the other component formula ratios remain unchanged, be made into ink by the operation steps of embodiment 4, obtain target ink product package stability >6 month, after ink is coated on PVC wallpaper, by Chinese architecture material tests Spot detection, the negative ion concentration that detected result shows to use the PVC wallpaper that scribbles target ink to produce is 229/cm
3, far below the primary demand that maintains HUMAN HEALTH.
Embodiment 5
Table 6. ink combination composition formula (5wt% negative ion powder addition)
Note: homemade polyacrylic ester pure-acrylic emulsion has been applied for patent of invention, application number is 2013105793039, publication number is CN103601837A.
The preparation method of ink product carries out as follows:
(1) according to the formula in table 6, the granulated glass sphere that is 2mm by water, BYK-P-104 dispersion agent, titanium dioxide R-902+, coarse whiting and TZY-01 negative ion powder and diameter adds rapid dispersion machine (KS-370 coating rapid dispersion machine, Shanghai Modern Environmental Engineering Technology Co., Ltd.) in, disperse 3 hours, obtain stock white;
(2) stock white polyacrylic ester pure-acrylic emulsion, ADVANTAGE AM-1512 defoamer and step (1) being prepared adds and disperses sand mill (SDF400 experiment dispersion sand mill, Shuan Feng chemical machinery company limited of Jiangyin City) in, speed with 1500 turn/min stirs 10 minutes, and adds successively Latekoll D thickening material and Resiflow W50 flow agent;
(3) keep stirring, can be packaged to be ink product after adding alcohol and Kathon LXE sanitas.
Target ink product package stability >6 month, after ink is coated on PVC wallpaper, by Chinese architecture material tests Spot detection, the negative ion concentration that detected result shows to use the PVC wallpaper that scribbles target ink to produce was 2296/cm
3, compared with following comparative example 5, increased by 2064/cm
3negative ion concentration, reach the Air quality of town park rank.
Comparative example 5
Press the formula ratio in table 6, the addition of TZY-01 negative ion powder is 0, all the other component formula ratios remain unchanged, be made into ink by the operation steps of embodiment 5, obtain target ink product package stability >6 month, after ink is coated on PVC wallpaper, by Chinese architecture material tests Spot detection, the negative ion concentration that detected result shows to use the PVC wallpaper that scribbles target ink to produce is 232/cm
3, far below the primary demand that maintains HUMAN HEALTH.
Above-described embodiment is used for the present invention that explains, instead of limits the invention, and in the protection domain of spirit of the present invention and claim, any amendment and change that the present invention is made, all fall into protection scope of the present invention.
Claims (10)
1. a negative ion water-based ink, it is characterized in that described negative ion water-based ink is made up of the raw material of following weight proportion: 28～40 parts of polymer emulsions, 15 parts of pigment, 4～8 parts of fillers, 1～5 part of anionic additive, 3.5～8 parts of alcohol, 0.6～3.6 part of dispersion agent, 0.1～0.8 part of thickening material, 0.05～0.3 part of flow agent, 0.1～0.8 part of defoamer, 0.05～0.06 part of sanitas, 26.92～41 parts, water; Described polymer emulsion is the mixture of one or more arbitrary proportions in benzene emulsion, the tertiary emulsion of vinegar, acrylate and vinyl acetate emulsion, polyacrylic ester pure-acrylic emulsion, polyaminoester emulsion, organosilicon crylic acid latex, fluoro-resin emulsion, and the solid content of described polymer emulsion is 45wt%～50wt%; Described filler is the mixture of one or more arbitrary proportions in talcum powder, coarse whiting, fine particle calcium carbonate, kaolin, wollastonite powder physique filler.
2. negative ion water-based ink as claimed in claim 1, is characterized in that described pigment is the one in titanium dioxide, zinc oxide, zinc sulfide white, carbon black, iron oxide black, nigrosine, lead-chrome yellow, iron oxide yellow, iron oxide red, red, phthalocyanine blue b, ultramarine.
3. negative ion water-based ink as claimed in claim 1, is characterized in that described anionic additive is tourmaline powder.
4. negative ion water-based ink as claimed in claim 1, is characterized in that described dispersion agent is the mixture of one or more arbitrary proportions in polycarboxylate, polyacrylic acid derivative, suitable divinyl anhydride multipolymer, condensation naphthalenesulfonate, poly carboxylic acid or polyvinyl alcohol.
5. negative ion water-based ink as claimed in claim 4, is characterized in that wherein said suitable divinyl anhydride multipolymer is diisobutylene-cis-butenedioic anhydride multipolymer or styrene-maleic anhydride copolymer.
6. negative ion water-based ink as claimed in claim 1, is characterized in that described thickening material is the mixture of any one or two or more arbitrary proportions in cellulose thickener, polyurethanes thickening material, agent for polyacrylic acid thickening, polyacrylate-type thickeners.
7. negative ion water-based ink as claimed in claim 1, is characterized in that described flow agent is the mixture of one or more arbitrary proportions in polyacrylate(s) flow agent, silicone resin class flow agent, fluoroolefins flow agent.
8. negative ion water-based ink as claimed in claim 1, is characterized in that described defoamer is the mixture of one or more arbitrary proportions in lower alcohols defoamer, mineral oil defoaming agent, silicone based defoamer.
9. negative ion water-based ink as claimed in claim 1, is characterized in that described sanitas is the mixture of one or more arbitrary proportions in substituted arene class sanitas, heterocycles sanitas, aminated compounds class sanitas.
10. the preparation method of negative ion water-based ink as claimed in claim 1, is characterized in that described preparation method carries out as follows:
(1) water of formula ratio, dispersion agent, pigment, filler, anionic additive and granulated glass sphere are added in rapid dispersion machine, disperse 2～3 hours, obtain mill base;
(2) mill base polymer emulsion of formula ratio, defoamer and step (1) being prepared adds and disperses in sand mill, stirs 10～60 minutes, then add thickening material and the flow agent of formula ratio with the speed of 800～1500 turn/min;
(3) keep stirring, obtain described negative ion water-based ink after adding the alcohol, sanitas of formula ratio.
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| CN104312267A (en) * | 2014-11-11 | 2015-01-28 | 合肥皖为电气设备工程有限责任公司 | Anti-freezing printing ink and preparation method thereof |
| CN105111794A (en) * | 2015-07-27 | 2015-12-02 | 安徽明珠颜料科技有限公司 | Black iron oxide pigment containing tourmalinite powder and preparation method thereof |
| CN105368155A (en) * | 2015-11-20 | 2016-03-02 | 深圳市摩码科技有限公司 | Invisible anti-counterfeiting printing ink and its anti-counterfeiting membrane |
| CN105482542A (en) * | 2014-10-07 | 2016-04-13 | 许继胜 | Multifunctional health care printing ink capable of releasing far infrared and negative oxygen ions |
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| CN105482542A (en) * | 2014-10-07 | 2016-04-13 | 许继胜 | Multifunctional health care printing ink capable of releasing far infrared and negative oxygen ions |
| CN104312267A (en) * | 2014-11-11 | 2015-01-28 | 合肥皖为电气设备工程有限责任公司 | Anti-freezing printing ink and preparation method thereof |
| CN105111794A (en) * | 2015-07-27 | 2015-12-02 | 安徽明珠颜料科技有限公司 | Black iron oxide pigment containing tourmalinite powder and preparation method thereof |
| CN105368155A (en) * | 2015-11-20 | 2016-03-02 | 深圳市摩码科技有限公司 | Invisible anti-counterfeiting printing ink and its anti-counterfeiting membrane |
| CN106318028A (en) * | 2016-08-19 | 2017-01-11 | 杭州电子科技大学 | Water-based ink applicable to aluminum plate coating and preparation method thereof |
| CN106318028B (en) * | 2016-08-19 | 2019-08-27 | 杭州电子科技大学 | A kind of water-based ink and preparation method thereof suitable for aluminium sheet coating |
| CN108610811A (en) * | 2016-12-07 | 2018-10-02 | 任细川 | A kind of functionality negative ion paint and preparation method thereof |
| CN107164998A (en) * | 2017-05-18 | 2017-09-15 | 青岛瑞利特新材料科技有限公司 | A kind of graphene removes the heat-insulated wallpaper of aldehyde, wall paper and preparation method |
| CN107163681A (en) * | 2017-07-03 | 2017-09-15 | 安徽真劲智能科技有限公司 | A kind of alphabetical mark printing ink of computer keyboard key |
| CN107384014A (en) * | 2017-09-11 | 2017-11-24 | 杭州海维特化工科技有限公司 | A kind of PVC furniture film water foam ink and preparation method thereof |
| CN107384014B (en) * | 2017-09-11 | 2020-02-21 | 杭州海维特化工科技有限公司 | PVC furniture film water-based foaming ink and preparation method thereof |
| CN109021688A (en) * | 2018-07-27 | 2018-12-18 | 郑州汉东科技有限公司 | Environment-friendly water-based printing ink of one kind and preparation method thereof |
| CN109021688B (en) * | 2018-07-27 | 2021-07-16 | 广东顺德艾司科科技股份有限公司 | Environment-friendly water-based printing ink and preparation method thereof |
| CN111777905A (en) * | 2020-07-08 | 2020-10-16 | 上海德粼水性油墨有限公司 | Environment-friendly water-based coating and preparation method thereof |
| CN115386262A (en) * | 2022-09-26 | 2022-11-25 | 杭州海维特化工科技有限公司 | Gravure ink with essence and negative ions slowly released and applied to automobile interior decoration plastic film and preparation method thereof |
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Application publication date: 20140910 Assignee: Linyi Haiweite New Materials Co.,Ltd. Assignor: HANGZHOU HIWETECH CHEMICAL TECHNOLOGY Co.,Ltd. Contract record no.: X2023330000865 Denomination of invention: A negative ion water-based ink and its preparation method Granted publication date: 20151202 License type: Common License Record date: 20231120 |