CN101289595A - Process for adhering tourmaline powder on surface of objects - Google Patents

Process for adhering tourmaline powder on surface of objects Download PDF

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Publication number
CN101289595A
CN101289595A CN 200810106903 CN200810106903A CN101289595A CN 101289595 A CN101289595 A CN 101289595A CN 200810106903 CN200810106903 CN 200810106903 CN 200810106903 A CN200810106903 A CN 200810106903A CN 101289595 A CN101289595 A CN 101289595A
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China
Prior art keywords
tourmaline powder
water
paper
material surface
ultra
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CN 200810106903
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Chinese (zh)
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方东波
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Individual
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Individual
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Priority to CN 200810106903 priority Critical patent/CN101289595A/en
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  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
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Abstract

The invention relates to a method for attaching tourmaline powder to a material surface, wherein a functional material containing tourmaline powder is directly attached to a material surface and is water color ink used in spray painting or printing, or tourmaline powder slurry mixed with water; and different material surfaces can be the surfaces of matters such as paper, wall surface, wall paper, cloth, non-woven fabric, plastics, ceramics and dull brown ceramics. The water color ink formula containing tourmaline powder can be widely used in the surface attachment of paper, wall surface, wall paper, cloth, non-woven fabric and plastics through adopting a mode of spray painting or silk-screen printing; meanwhile, according to the method, ceramics or a dull brown product with tourmaline powder slurry coated and dried in the shade is put in a calciner, and the finished products is naturally cooled down after calcination; thus, tourmaline powder is firmly combined with the surface of the ceramics or the dull brown product like glaze. The method can make full use of the functions of tourmaline such as negative oxygen ion releasing, peculiar smell absorption, air purification and freshness keeping.

Description

The method that tourmaline powder adheres at material surface
Technical field
The present invention relates to two kinds of methods that contain the functional material of tourmaline powder in multiple different substances surface attachment, and relate to this kind method the different substances surface is adhered to after, this material is given full play to such as improving Air quality, optimize effects such as water quality.
Background technology
Tourmalinite is a kind of natural powerful energy ore, emitting far-infrared except having, the micro-stripping feature, its the most notable attribute be to have permanent charging property, in invention disclosed patent, often tourmaline powder is joined in the starting material of goods, as the paper pulp of papermaking, the clay of pottery, make shaping with product producing process then.Do the consumption of wayward tourmaline powder like this,, might make tourmaline powder under the parcel of other feed particles, be difficult to effectively bring into play its function if ratio is lower; If ratio is higher, not only can influence the physicals of goods itself, as the folding endurance decline of paper, ceramic is frangible etc.Also cause simultaneously the waste of precious resources tourmaline powder, improved the cost of tourmalinite product.
Summary of the invention
The objective of the invention is in order to overcome above-mentioned deficiency, and two kinds of invention contain the functional materials of tourmaline powder and they method in multiple unlike material surface attachment, thereby can bring into play every function of tourmaline powder to greatest extent, reduce production costs simultaneously.
Concrete technical scheme of the present invention is as follows:
One, a kind of attachment means that contains tourmaline powder at paper, metope, wallpaper, cloth, non-woven fabrics, frosting is just earlier with containing the method for adhering to of the water color ink of tourmaline powder at paper, metope, wallpaper, cloth, non-woven fabrics, frosting.
This water-soluble printing ink formula that contains tourmaline powder does not contain the poisonous and hazardous material of human body, can adopt the spraying or the mode of silk screen printing to be widely used in adhering to of paper, metope, wallpaper, cloth, non-woven fabrics, frosting according to actual needs, can give full play to tourmalinite and discharge negative oxygen ion, absorb peculiar smell, purify air multinomial function such as fresh-keeping.
Water color ink of the present invention is made by mixed stirring of following raw material by weight percentage.
Ultra-fine tourmaline powder 10-20%
Water-based polyamine fat resin 30-40%
Trolamine 1-5%
Mill base 0.5-2%
0.5-1% such as defoamer, thickening material, stablizer
Water 30-40%
The preparation method of water color ink is: earlier the water-based versamid 900 of 30-40%, the auxiliary agents such as defoamer of 15% trolamine 0.5-1%, the water of 30-40% are mixed, adopt homogenizer to stir 15-30 minute down, and the pH value of adjusting mixed solution is between 8-8.5 at 70-80 ℃.Then the ultra-fine tourmaline powder of the 10-20% of particle fineness between 0.05-5 μ m and the mill base of 0.5-2% are blended in the above-mentioned mixed liquid, promptly make the finished product water color ink through stirring.
Need adopt spraying or screen printing mode to be attached to the unlike material surface with border factually this kind water color ink.
Two. a kind of tourmaline powder slurry that is directly used in pottery and boccaro surface coated, fires
1. the ultra-fine tourmaline powder of grain diameter between 0.05-5 μ m and water are mixed with into weight percent and contain ultra-fine electric powder slurry for 10-30%.
2. above-mentioned slurry evenly is sprayed at the surface of pottery or boccaro goods, under natural temperature, dries in the shade.
3. above-mentioned pottery or boccaro goods coated and that dry in the shade are put into calcining furnace, be fired to 900-1020 ℃, be incubated after 4-5 hour naturally cooling and promptly make finished product.Tourmaline powder just can be combined in the surface of pottery or boccaro goods securely as glaze.
The method that tourmaline powder of the present invention adheres at material surface, owing to the positive and negative electric charge of tourmalinite does not overlap, and the spontaneous polarization phenomenon that produces.Under envrionment temperature, pressure changing, can cause tourmalinite crystalline potential difference.In air, can make ambient air generation ionization, the electron attachment that discharges makes it be converted into negative aeroion on contiguous water and oxygen molecule, i.e. negative oxygen ion.These negative oxygen ions move in air, on it with negative charge can combine with airborne bacterium, dust, smoke particles, thereby reach the purpose that purifies air; In water, the ion that discharges the macromolecular mass of water can be chopped on the one hand minimum molecule to or unit molecule, strengthen the activity of water.On the other hand, can the ionizing water molecule, reaction generates hydrogen and overflow a part of H from water +Form bioactive molecule H with water molecules 3O +, it can absorb the impurity in the combination water, and dirt plays the effect that purifies water, simultaneously, OH -Become H with water molecules 3O -, its amount increases, and makes water be weakly alkaline, makes it be easier to be absorbed by human body, more is of value to the health of human body.
The water-soluble printing ink formula that the present invention contains tourmaline powder does not contain the poisonous and hazardous material of human body, can adopt the spraying or the mode of silk screen printing to be widely used in adhering to of paper, metope, wallpaper, cloth, non-woven fabrics, frosting according to actual needs, the present invention simultaneously puts into calcining furnace with pottery or boccaro goods coated and that dry in the shade, and calcining back naturally cooling gets final product.Tourmaline powder just can be combined in the surface of pottery or boccaro goods securely as glaze.Multinomial functions such as the present invention can give full play to tourmalinite and discharge negative oxygen ion, absorbs peculiar smell, purifies air, and is fresh-keeping.
Specific embodiment
Embodiment 1
Water-based versamid 900 with 30%, 2% trolamine, total amount are that 0.5% auxiliary agents such as defoamer, 40% water mix, and adopt homogenizer to stir 20 minutes down at 80 ℃, and the pH value of adjusting mixed solution are 8.5.Then particle fineness is blended in the above-mentioned mixed liquid at 10% the ultra-fine tourmaline powder of 2 μ m and 1% mill base, promptly makes the finished product water color ink through stirring.The mode of this kind water color ink with spraying is sprayed on the non-woven fabrics wallpaper equably, its film forming softness, hand feel and drape has good weather resisteant and anti-dried, wet rubbing, and has good release negative oxygen ion, the effect that purifies the air of a room.
Embodiment 2
Be that to be mixed with into that weight percent contains be 10% ultra-fine electric powder slurry for ultra-fine tourmaline powder and the water of 1 μ m with grain diameter.Slurry evenly is sprayed at the surface of ceramic thin slice, and under natural temperature, dries in the shade.To dry in the shade the back ceramic sheet put into calcining furnace, be fired to 1010 ℃, be incubated 4 hours subsequently after naturally cooling promptly make finished product.This finished product is put into water, can make water be weakly alkaline, and the active obviously enhancing of water, the impurity in the precipitation water purifies water, and the mouthfeel of water is obviously improved, and is of value to HUMAN HEALTH.

Claims (7)

1, a kind of tourmaline powder is characterized in that in the method that material surface adheres to: the functional material that contains tourmaline powder is directly to be attached to material surface, and the functional material that contains tourmaline powder is a kind of water color ink of spraying or printing of can be used for; Also can be a kind of tourmaline powder slurry mixed with water, described material surface can be the surface of materials such as paper, metope, wallpaper, cloth, non-woven fabrics, plastics and pottery, boccaro.
2, the water color ink that sprays or print of being used to according to claim 2 is characterized in that it being to be made by mixed stirring of following weight percentages;
Ultra-fine tourmaline powder 10-20%
Water-based polyamine fat resin 30-40%
Trolamine 1-5%
Mill base 0.5-2%
0.5-1% such as defoamer, thickening material, stablizer
Water 30-40%.
3, tourmaline powder according to claim 2 is characterized in that in the method that material surface adheres to: between the particle diameter 0.05-5 μ m of ultra-fine tourmaline powder particles.
4, tourmaline powder according to claim 2 is characterized in that in the method that material surface adheres to: auxiliary agents such as mill base and defoamer, thickening material, stablizer can increase or not add according to actual needs.
5, the tourmaline powder according to claim 2 method of adhering at material surface, it is characterized in that: contain the water color ink of ultra-fine tourmaline powder, it is characterized in that its mode that can adopt spraying or printing is attached to the surface of materials such as paper, metope, wallpaper, wall paper, non-woven fabrics, plastics.
6, a kind of tourmaline powder is characterized in that in the method that material surface adheres to: this slurry is a kind of tourmalinite slurry that mixes with water, and the ultra-fine tourmaline powder content is between 10-30%, and ultra-fine tourmaline powder particles particle diameter is between 0.05-5 μ m.
7, the tourmaline powder according to claim 6 method of adhering at material surface, it is characterized in that: this slurry can directly be sprayed at the pottery or the boccaro semifinished or finished goods surface of different shape, apparent surface situation difference, but put into calcining furnace and be fired to 900-1020 ℃ being coated with the pottery boccaro goods that make, be incubated after 4-5 hour naturally cooling and promptly make finished product; Can make tourmaline powder be combined in the surface of pottery or boccaro goods securely as glaze.
CN 200810106903 2008-06-06 2008-06-06 Process for adhering tourmaline powder on surface of objects Pending CN101289595A (en)

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Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102120042A (en) * 2010-01-12 2011-07-13 张业华 Negative ion knit, textile and nonwoven fabrics and paper and products thereof and processing method
CN102500062A (en) * 2011-11-14 2012-06-20 太原市伦嘉生态健康家居科技有限公司 Stereo energy factor generator and production method thereof
CN103334563A (en) * 2013-07-10 2013-10-02 广东玉兰装饰材料有限公司 Wallpaper with surface patterns having accumulation effect and manufacturing method thereof
CN103483910A (en) * 2013-09-27 2014-01-01 广东玉兰装饰材料有限公司 Wallpaper with hand-painting effect and manufacturing process of wallpaper
CN104031465A (en) * 2014-05-04 2014-09-10 杭州海维特化工科技有限公司 Anionic aqueous ink and preparation method thereof
CN104031466A (en) * 2014-05-04 2014-09-10 杭州海维特化工科技有限公司 Anion-foamed aqueous ink and preparation method thereof
CN104693894A (en) * 2015-03-26 2015-06-10 广东三水大鸿制釉有限公司 Anion ink for ink jet printing and preparation method and coating method thereof
CN105568753A (en) * 2016-01-30 2016-05-11 彭友 Odor removal decoration paper capable of releasing negative ions and preparation method of odor removal decoration paper
CN106703355A (en) * 2017-02-24 2017-05-24 四川金路高新材料有限公司 Production method of wall surface decoration materials capable of generating negative oxygen ions
CN106827921A (en) * 2017-03-08 2017-06-13 哈尔滨联邦智能卡技术开发有限责任公司 The preparation method of environment-friendly type macromolecule polymerization one mural painting
CN107151940A (en) * 2017-05-25 2017-09-12 常州佳饰家装饰新材料有限公司 Facing paper with negative ion releasing function and preparation method thereof
CN107435241A (en) * 2017-09-04 2017-12-05 西南大学 Far infrared silk fabric is prepared with the NMMO aqueous solution
CN107502067A (en) * 2017-08-31 2017-12-22 王雨生 A kind of high temperature sintering heating electrically conductive ink and preparation method thereof
CN107541951A (en) * 2017-09-04 2018-01-05 西南大学 Far infrared wool fabric is prepared with the NMMO aqueous solution
CN108689698A (en) * 2018-05-03 2018-10-23 广东博华陶瓷有限公司 A kind of formula and its production technology of the ecological satin glaze marble Ceramic Tiles with anion and light quantity subfunction
CN108751970A (en) * 2018-06-05 2018-11-06 广东博华陶瓷有限公司 The formula and its production technology of a kind of full porcelain marble Ceramic Tiles of ecology with anion and light quantity subfunction
CN109457497A (en) * 2019-01-09 2019-03-12 深圳市茜施尔服装有限公司 A kind of tourmaline heat generating fiber fabric and preparation method thereof
CN112248678A (en) * 2020-09-30 2021-01-22 湖北合信智能包装科技有限公司 Surface treatment method for flexographic preprinting product with air purification function
CN115521711A (en) * 2022-10-09 2022-12-27 河间市煜术玻璃制品有限公司 Spray coating material with far infrared function, preparation method and application

Cited By (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102120042A (en) * 2010-01-12 2011-07-13 张业华 Negative ion knit, textile and nonwoven fabrics and paper and products thereof and processing method
CN102500062A (en) * 2011-11-14 2012-06-20 太原市伦嘉生态健康家居科技有限公司 Stereo energy factor generator and production method thereof
CN103334563A (en) * 2013-07-10 2013-10-02 广东玉兰装饰材料有限公司 Wallpaper with surface patterns having accumulation effect and manufacturing method thereof
CN103334563B (en) * 2013-07-10 2015-07-15 广东玉兰集团股份有限公司 Wallpaper with surface patterns having accumulation effect and manufacturing method thereof
CN103483910A (en) * 2013-09-27 2014-01-01 广东玉兰装饰材料有限公司 Wallpaper with hand-painting effect and manufacturing process of wallpaper
CN104031465A (en) * 2014-05-04 2014-09-10 杭州海维特化工科技有限公司 Anionic aqueous ink and preparation method thereof
CN104031466A (en) * 2014-05-04 2014-09-10 杭州海维特化工科技有限公司 Anion-foamed aqueous ink and preparation method thereof
CN104031465B (en) * 2014-05-04 2015-12-02 杭州海维特化工科技有限公司 A kind of negative ion water color ink and preparation method thereof
CN104031466B (en) * 2014-05-04 2015-12-09 杭州海维特化工科技有限公司 A kind of negative ion frothed aqueous ink and preparation method thereof
CN104693894B (en) * 2015-03-26 2016-08-17 广东三水大鸿制釉有限公司 A kind of ink jet printing negative ion ink and preparation method thereof and coating process
CN104693894A (en) * 2015-03-26 2015-06-10 广东三水大鸿制釉有限公司 Anion ink for ink jet printing and preparation method and coating method thereof
CN105568753B (en) * 2016-01-30 2017-04-19 彭友 Odor removal decoration paper capable of releasing negative ions and preparation method of odor removal decoration paper
CN105568753A (en) * 2016-01-30 2016-05-11 彭友 Odor removal decoration paper capable of releasing negative ions and preparation method of odor removal decoration paper
CN106703355A (en) * 2017-02-24 2017-05-24 四川金路高新材料有限公司 Production method of wall surface decoration materials capable of generating negative oxygen ions
CN106703355B (en) * 2017-02-24 2020-04-14 四川金路高新材料有限公司 Method for producing negative oxygen ion wall decoration material
CN106827921A (en) * 2017-03-08 2017-06-13 哈尔滨联邦智能卡技术开发有限责任公司 The preparation method of environment-friendly type macromolecule polymerization one mural painting
CN107151940A (en) * 2017-05-25 2017-09-12 常州佳饰家装饰新材料有限公司 Facing paper with negative ion releasing function and preparation method thereof
CN107502067A (en) * 2017-08-31 2017-12-22 王雨生 A kind of high temperature sintering heating electrically conductive ink and preparation method thereof
CN107541951A (en) * 2017-09-04 2018-01-05 西南大学 Far infrared wool fabric is prepared with the NMMO aqueous solution
CN107435241A (en) * 2017-09-04 2017-12-05 西南大学 Far infrared silk fabric is prepared with the NMMO aqueous solution
CN108689698A (en) * 2018-05-03 2018-10-23 广东博华陶瓷有限公司 A kind of formula and its production technology of the ecological satin glaze marble Ceramic Tiles with anion and light quantity subfunction
CN108751970A (en) * 2018-06-05 2018-11-06 广东博华陶瓷有限公司 The formula and its production technology of a kind of full porcelain marble Ceramic Tiles of ecology with anion and light quantity subfunction
CN109457497A (en) * 2019-01-09 2019-03-12 深圳市茜施尔服装有限公司 A kind of tourmaline heat generating fiber fabric and preparation method thereof
CN109457497B (en) * 2019-01-09 2019-09-10 深圳市茜施尔服装有限公司 A kind of tourmaline heat generating fiber fabric and preparation method thereof
CN112248678A (en) * 2020-09-30 2021-01-22 湖北合信智能包装科技有限公司 Surface treatment method for flexographic preprinting product with air purification function
CN115521711A (en) * 2022-10-09 2022-12-27 河间市煜术玻璃制品有限公司 Spray coating material with far infrared function, preparation method and application

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