CN108751970A - The formula and its production technology of a kind of full porcelain marble Ceramic Tiles of ecology with anion and light quantity subfunction - Google Patents
The formula and its production technology of a kind of full porcelain marble Ceramic Tiles of ecology with anion and light quantity subfunction Download PDFInfo
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Abstract
Embodiment of the present invention discloses a kind of formula and its production technology of the full porcelain marble Ceramic Tiles of the ecology with anion and light quantity subfunction.Including component：Potassium feldspar, earth burning, kaolin, calcium phosphate, silica flour, burns aluminium, colour former, tourmaline at albite；So that the crystal phase structure of ceramics changes under high-temperature firing, the trace element of inventive formulation raw material can be promoted to excite, it is easier to discharge anion, there is light quantum effect.
Description
Technical field
The present invention relates to ceramic tile field more particularly to a kind of full porcelain marbles of ecology with anion and light quantity subfunction
The formula and its production technology of Ceramic Tiles.
Background technology
Marble is a kind of lithotome, and natural wash landscape painting can be formed by splitting, therefore the modern times melt marble
Enter in Ceramic Tiles technique so that the characteristic that Ceramic Tiles have marble grain, quality hard.
The characteristic of full porcelain Ceramic Tiles is bright as new, and when ceramic brick surface is worn, but inside can also keep bright as new,
Whole perception is not influenced.
In this field, how the technique of marble, full porcelain etc. is merged uniquely, be the direction that technical staff should research and develop.
Invention content
Embodiment of the present invention provides a kind of full porcelain marble Ceramic Tiles of the ecology with anion and light quantity subfunction
Formula and its production technology.
To solve the above problems, the full porcelain marble of a kind of ecology with anion and light quantity subfunction provided by the invention
The formula of Ceramic Tiles, the full porcelain marble ceramics include the component calculated in parts by weight：
Potassium feldspar is 20-25, albite 35-38, earth burning 10-12, kaolin 5-8, calcium phosphate (PC02-2) are
0.5-0.8, silica flour 20-22, burning aluminium are 1-2, colour former 2-3, tourmaline are 1~1.5；
Wherein, percentage of every parts by weight correspondence containing following chemical composition of said components is：
The proportion of the tourmaline is 3.03-3.25, hardness 6.5-7.0, granularity are≤20 mesh.
The present invention also provides a kind of production works of the full porcelain marble Ceramic Tiles of the ecology with anion and light quantity subfunction
Skill is made with the Ceramic Tiles being formulated described in claim 1, calculates raw material in parts by weight, include the following steps：
By the potassium feldspar of 20-25 parts by weight, the albite of 35-38 parts by weight, the earth burning of 10-12 parts by weight, 5-8 weight
The kaolin of part, the calcium phosphate of 0.5-0.8 parts by weight, the silica flour of 20-22 parts by weight, the burning aluminium of 1-2 parts by weight, 2-3 weight
The colour former of part is homogenized as idiosome formula, ball milling, powder processed, aging, press compacting, dry, leaching ground-coat enamel, stamp, sprays spherical surface
Glaze, high-temperature firing；
The raw material of the spray spherical surface glaze is the tourmaline of 1~1.5 parts by weight；
The high-temperature firing is that temperature is fired at 1000~2000 DEG C.
Preferably, before the ball milling, first by the potassium feldspar, albite, earth burning, kaolin, calcium phosphate, silica flour,
Burn aluminium, colour former is ground to granularity as 100~300 mesh.
Preferably, the tourmaline is by prefabricated, described prefabricated to be specially：It is placed in HIGH TEMPERATURE PURGE in steam chamber, high temperature
Drying, is ground up, sieved.
Preferably, the proportion of the tourmaline is 3.10~3.20, hardness 6.8-7.0, and granularity is≤20 mesh.
Preferably, the proportion of the tourmaline is 3.18, hardness 7.0, and granularity is≤20 mesh.
Preferably, it is 1.35 that the full porcelain marble ceramics, which include the tourmaline calculated in parts by weight,.
Preferably, the high-temperature firing temperature is 1850 DEG C.
Preferably, it calculates in parts by weight, potassium feldspar 20.5, albite 36, earth burning 12, kaolin 5, calcium phosphate
For 0.6, silica flour 21.8, burn aluminium be 1.3, colour former 2.8.
Preferably, the colour former is LXJ-815.
As can be seen from the above technical solutions, embodiment of the present invention has the following advantages：
The full porcelain marble Ceramic Tiles formula of ecology of the present invention has used tourmaline as negative ion powder, and negative ion powder is main
For the boron sikicate aluminums such as elbaite, dravite or iron, sodium complexing ores in one or more composite materials, when bear from
When sub- powder and the other components of the present invention are sintered, the chemical reaction encouraged when calcium-aluminium-silicon-phosphorus liquid phase, intermolecular knot are formed
Structure becomes secured and stablizes, and the lithium ion, sodium ion, magnesium ion, the activity of iron ion in manufactured Ceramic Tiles are very strong, these
It is exposed to the active ion of ceramic tile surface or gap inner wall, radiation that can be by micro element when being contacted with air and discharge process,
It has an effect with air molecule, air molecule loses electronics, forms free ion, which is combined i.e. with neutral gas
Anion.
Furthermore, it is understood that in the sintering process of this full porcelain marble Ceramic Tiles, using 1000~2000 DEG C of high temperature, make
Ceramic crystal phase structure changes so that potassium feldspar, earth burning, kaolin, silica flour, burns aluminium and tourmaline at albite
Crystal phase structure changes, and the trace element of inventive formulation raw material can be promoted to excite, it is easier to discharge anion, have light quantity
Sub- effect.
Specific implementation mode
Embodiment of the present invention provides a kind of full porcelain marble Ceramic Tiles of the ecology with anion and light quantity subfunction
Formula and its production technology.
A kind of formula of the full porcelain marble Ceramic Tiles of ecology with anion and light quantity subfunction, the full porcelain marble
Ceramics include the component calculated in parts by weight：
Potassium feldspar is 20-25, albite 35-38, earth burning 10-12, kaolin 5-8, calcium phosphate 0.5-0.8,
Silica flour is 20-22, burning aluminium is 1-2, colour former 2-3, tourmaline are 1~1.5；
Wherein, percentage of every parts by weight correspondence containing following chemical composition of said components is：
The proportion of the tourmaline is 3.03-3.25, hardness 6.5-7.0, granularity are≤20 mesh.
Wherein, the chemical composition contained by each ingredient is as it appears from the above, for example：Potassium feldspar contain 70.39% Si (silicon),
15.96%Al (aluminium), 0.06%Fe (iron), 0.01%Ti (titanium), 0.52%Ca (calcium), 0.03%Mg (magnesium), 8.85%K
(potassium), 3.21%Na (sodium), 0.77%I.L.Other ingredients are identical, herein not burdensome explanation.Indicate that it contains when less than 100%
There are other impurities.
The present invention also has a kind of production technology of the full porcelain marble Ceramic Tiles of the ecology with anion and light quantity subfunction,
It is made with the Ceramic Tiles being formulated described in claim 1, calculates raw material in parts by weight, include the following steps：
By the potassium feldspar of 20-25 parts by weight, the albite of 35-38 parts by weight, the earth burning of 10-12 parts by weight, 5-8 weight
The kaolin of part, the calcium phosphate of 0.5-0.8 parts by weight, the silica flour of 20-22 parts by weight, the burning aluminium of 1-2 parts by weight, 2-3 weight
The colour former of part is homogenized as idiosome formula, ball milling, powder processed, aging, press compacting, dry, leaching ground-coat enamel, stamp, sprays spherical surface
Glaze, high-temperature firing；
The raw material of the spray spherical surface glaze is the tourmaline of 1~1.5 parts by weight；
The high-temperature firing is that temperature is fired at 1000~2000 DEG C.
Preferably, before the ball milling, first by the potassium feldspar, albite, earth burning, kaolin, calcium phosphate, silica flour,
Burn aluminium, colour former is ground to granularity as 100~300 mesh.
Preferably, the tourmaline is by prefabricated, described prefabricated to be specially：It is placed in HIGH TEMPERATURE PURGE in steam chamber, high temperature
Drying, is ground up, sieved.
Preferably, the proportion of the tourmaline is 3.10~3.20, hardness 6.8-7.0, and granularity is≤20 mesh.
Preferably, the proportion of the tourmaline is 3.18, hardness 7.0, and granularity is≤20 mesh.
Preferably, it is 1.35 that the full porcelain marble ceramics, which include the tourmaline calculated in parts by weight,.
Preferably, the high-temperature firing temperature is 1850 DEG C.
Preferably, it calculates in parts by weight, potassium feldspar 20.5, albite 36, earth burning 12, kaolin 5, calcium phosphate
For 0.6, silica flour 21.8, burn aluminium be 1.3, colour former 2.8.
Preferably, the colour former is LXJ-815.
Above-mentioned production technology is described with specific implementation mode now：
Choose potassium feldspar be 20.5Kg, albite 36Kg, earth burning 12Kg, kaolin 5Kg, calcium phosphate 0.6Kg,
Silica flour is 21.8Kg, burning aluminium is 1.3Kg, colour former 2.8Kg, and be sieved 200 mesh, and ball milling is homogenized, powder processed, aging, press
Compacting, dry, leaching ground-coat enamel, stamp.
Tourmaline 1.35Kg is chosen, proportion 3.10, hardness 6.8, granularity is 20 mesh, prefabricated to be placed in steam chamber
HIGH TEMPERATURE PURGE, high temperature drying, is ground up, sieved.
Spherical surface glaze is sprayed, that is, spray tourmaline is fired as overglaze at 1850 DEG C, and Ceramic Tiles are made.
Below by multiple embodiments, the present invention will be described in detail：
Embodiment 1
Take 20Kg potassium feldspars, 35Kg albites, 10Kg earth burnings, 5Kg kaolin, 0.5Kg calcium phosphate, 20Kg silica flours, 1Kg
The colour former of aluminium, 2Kg are burnt as idiosome formula, and ball milling is homogenized, powder processed, aging, press compacting, drying, drenches ground-coat enamel, stamp；
It applies 1.35Kg and applies tourmaline glaze (proportion is 3.20 or so, hardness is 6.8 or so, granularity is 20 mesh), 1850
High-temperature firing at DEG C；
The full porcelain marble Ceramic Tiles of ecology with anion and light quantity subfunction are made.
Embodiment 2
Take 20.5Kg potassium feldspars, 36Kg albites, 12Kg earth burnings, 5Kg kaolin, 0.6Kg calcium phosphate, 21.8Kg quartz
Powder, 1.3Kg burn the colour former of aluminium, 2.8Kg as idiosome formula, and ball milling is homogenized, powder processed, aging, press compacting, drying, drenches bottom
Glaze, stamp；
It applies 1.35Kg and applies tourmaline glaze (proportion is 3.20 or so, hardness is 6.8 or so, granularity is 20 mesh), 1850
High-temperature firing at DEG C；
The full porcelain marble Ceramic Tiles of ecology with anion and light quantity subfunction are made.
Embodiment 3
Take 23Kg potassium feldspars, 37Kg albites, 11Kg earth burnings, 5Kg kaolin, 0.6Kg calcium phosphate, 21Kg silica flours, 1Kg
The colour former of aluminium, 2Kg are burnt as idiosome formula, and ball milling is homogenized, powder processed, aging, press compacting, drying, drenches ground-coat enamel, stamp；
It applies 1.35Kg and applies tourmaline glaze (proportion is 3.20 or so, hardness is 6.8 or so, granularity is 20 mesh), 1850
High-temperature firing at DEG C；
The full porcelain marble Ceramic Tiles of ecology with anion and light quantity subfunction are made.
Embodiment 4
Take 25Kg potassium feldspars, 38Kg albites, 12Kg earth burnings, 5Kg kaolin, 0.6Kg calcium phosphate, 22Kg silica flours,
1Kg burns the colour former of aluminium, 3Kg as idiosome formula, and ball milling is homogenized, powder processed, aging, press compacting, drying, leaching ground-coat enamel, prints
Flower；
It applies 1.35Kg and applies tourmaline glaze (proportion is 3.20 or so, hardness is 6.8 or so, granularity is 20 mesh), 1850
High-temperature firing at DEG C；
The full porcelain marble Ceramic Tiles of ecology with anion and light quantity subfunction are made.
Wherein, the ball milling of Examples 1 to 4, be homogenized, the compacting of powder processed, aging, press, dry, leaching ground-coat enamel, stamp, apply it is electrical
Stone glaze is fired, and is controlled and is carried out in same baking furnace, to reduce various factors to the full porcelain marble Ceramic Tiles of the ecology of generation
Influence.
The full porcelain marble Ceramic Tiles of ecology made of Example 1~4, measure the concentration of each ceramic tile autonomous production anion
For：Release concentration >=1500/cm 1. anion is averaged3；2. at 1 meter of ceramic brick surface, it is average to measure its anion
Release concentration >=1000/cm3.As it can be seen that Ceramic Tiles prepared by the present invention, can be released effectively a large amount of anion, and negative
Ion concentration is higher.
The above, embodiment of above and embodiment are merely illustrative of the technical solution of the present invention, rather than its limitations；
Although with reference to aforementioned embodiments and embodiment, invention is explained in detail, and those skilled in the art should
Understand：It still can be with technical scheme described in the above embodiments is modified, or to which part technical characteristic
Carry out equivalent replacement；And these modifications or replacements, each embodiment of the present invention that it does not separate the essence of the corresponding technical solution
With the spirit and scope of embodiment technical solution.
Claims (10)
1. a kind of formula of the full porcelain marble Ceramic Tiles of ecology with anion and light quantity subfunction, which is characterized in that described
Full porcelain marble ceramics include the component calculated in parts by weight：
Potassium feldspar is 20-25, albite 35-38, earth burning 10-12, kaolin 5-8, calcium phosphate 0.5-0.8, quartz
Powder is 20-22, burning aluminium is 1-2, colour former 2-3, tourmaline are 1~1.5；
Wherein, percentage of every parts by weight correspondence containing following chemical composition of said components is：
The proportion of the tourmaline is 3.03-3.25, hardness 6.5-7.0, granularity are≤20 mesh.
2. a kind of production technology of the full porcelain marble Ceramic Tiles of ecology with anion and light quantity subfunction, which is characterized in that
It is made with the Ceramic Tiles being formulated described in claim 1, calculates raw material in parts by weight, include the following steps：
By the potassium feldspar of 20-25 parts by weight, the albite of 35-38 parts by weight, the earth burning of 10-12 parts by weight, 5-8 parts by weight height
The hair of ridge soil, the burning aluminium of the calcium phosphate of 0.5-0.8 parts by weight, the silica flour of 20-22 parts by weight, 1-2 parts by weight, 2-3 parts by weight
Toner is homogenized as idiosome formula, ball milling, powder processed, aging, press compacting, dry, leaching ground-coat enamel, stamp, sprays spherical surface glaze, high temperature
It fires；
The raw material of the spray spherical surface glaze is the tourmaline of 1~1.5 parts by weight；
The high-temperature firing is that temperature is fired at 1000~2000 DEG C.
3. the production work of the full porcelain marble Ceramic Tiles of the ecology according to claim 2 with anion and light quantity subfunction
Skill, which is characterized in that before the ball milling, first by the potassium feldspar, albite, earth burning, kaolin, calcium phosphate, silica flour, burning
It is 100~300 mesh that aluminium, colour former, which are ground to granularity,.
4. the production work of the full porcelain marble Ceramic Tiles of the ecology according to claim 3 with anion and light quantity subfunction
Skill, which is characterized in that the tourmaline is described prefabricated to be specially by prefabricated：It is placed in HIGH TEMPERATURE PURGE in steam chamber, high temperature dries
It is dry, it is ground up, sieved.
5. the full porcelain marble of the ecology with anion and light quantity subfunction according to any one of Claims 1 to 4
The production technology of Ceramic Tiles, which is characterized in that the proportion of the tourmaline is 3.10~3.20, hardness 6.8-7.0, granularity
For≤20 mesh.
6. the full porcelain marble of the ecology with anion and light quantity subfunction according to any one of Claims 1 to 4
The production technology of Ceramic Tiles, which is characterized in that the proportion of the tourmaline is 3.18, hardness 7.0, and granularity is≤20 mesh.
7. the full porcelain marble of the ecology with anion and light quantity subfunction according to any one of Claims 1 to 4
The production technology of Ceramic Tiles, which is characterized in that the full porcelain marble ceramics include that the tourmaline calculated in parts by weight is 1.35.
8. the full porcelain marble of the ecology with anion and light quantity subfunction according to any one of Claims 1 to 4
The production technology of Ceramic Tiles, which is characterized in that the high-temperature firing temperature is 1850 DEG C.
9. the full porcelain marble of the ecology with anion and light quantity subfunction according to any one of Claims 1 to 4
The production technology of Ceramic Tiles, which is characterized in that calculate in parts by weight, potassium feldspar 20.5, albite 36, earth burning 12, height
Ridge soil is 5, calcium phosphate 0.6, silica flour 21.8, burn aluminium be 1.3, colour former 2.8.
10. the full porcelain marble of the ecology with anion and light quantity subfunction according to any one of Claims 1 to 4
The production technology of Ceramic Tiles, which is characterized in that the colour former is LXJ-815.
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