CN108689698A - A kind of formula and its production technology of the ecological satin glaze marble Ceramic Tiles with anion and light quantity subfunction - Google Patents

A kind of formula and its production technology of the ecological satin glaze marble Ceramic Tiles with anion and light quantity subfunction Download PDF

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CN108689698A
CN108689698A CN201810412482.XA CN201810412482A CN108689698A CN 108689698 A CN108689698 A CN 108689698A CN 201810412482 A CN201810412482 A CN 201810412482A CN 108689698 A CN108689698 A CN 108689698A
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parts
weight
anion
ecological
subfunction
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林家生
王志强
李宣营
于智深
邹达旋
谢扬光
梁勇海
杨思龙
吴建洲
陈炒
陆月星
朱岸权
吴云平
黄金保
李继新
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BOHUA CERAMIC Co Ltd GUANGDONG
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BOHUA CERAMIC Co Ltd GUANGDONG
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Abstract

Embodiment of the present invention discloses a kind of formula and its production technology of the ecological satin glaze marble Ceramic Tiles with anion and light quantity subfunction, it is exposed to the active ion of ceramic tile surface or gap inner wall, it has an effect with air molecule when being contacted with air, forms anion.The present invention includes the component calculated in parts by weight:Potassium feldspar is 33, barium carbonate 17, albite 6, zinc oxide 5, water-washed kaoline 10, dolomite 15, calcined kaolin 7, burns that talcum is 8, calcite 3, tourmaline are 1~1.5;The proportion of tourmaline is 3.03-3.25, hardness 6.5-7.0, granularity are≤20 mesh, raw material by ball milling, be homogenized, powder processed, aging, press compacting, dry, leaching ground-coat enamel, stamp, spray spherical surface glaze, high-temperature firing form the Ceramic Tiles.

Description

A kind of ecological satin glaze marble Ceramic Tiles with anion and light quantity subfunction Formula and its production technology
Technical field
The present invention relates to ceramic tile field more particularly to a kind of ecological satin glaze with anion and light quantity subfunction are big The formula and its production technology of reason stone Ceramic Tiles.
Background technology
Ceramic tile is widely used in various finishings, derives a kind of satin glaze in recent years.
As its name suggests, quality is thick close and smooth, can visually experience its submissive exquisiteness, can be experienced when stroking for satin glaze Its submissive quality, the form of expression can be a variety of, be such as made it is well arranged highlight luxurious, ripples lines is for another example made But there is silk as silks and satins to slide texture simultaneously.
The structure of satin glaze is very submissive, and prospect for sales is good, and how to enhance the characteristic of satin glaze is that those skilled in the art answer The direction of research and development.
Invention content
Embodiment of the present invention provides a kind of ecological satin glaze Dali feldspar with anion and light quantity subfunction The formula and its production technology of brick.
To solve the above problems, a kind of ecological satin glaze with anion and light quantity subfunction provided by the invention is big The formula of reason stone Ceramic Tiles, satin glaze Dali feldspar include the component calculated in parts by weight:
Potassium feldspar is 33, barium carbonate 17, albite 6, zinc oxide 5, water-washed kaoline 10, dolomite 15, Calcined kaolin is 7, burning talcum is 8, calcite 3, tourmaline are 1~1.5;
Wherein, percentage of every parts by weight correspondence containing following chemical composition of said components is:
The proportion of the tourmaline is 3.03-3.25, hardness 6.5-7.0, granularity are≤20 mesh.
The present invention also provides a kind of productions of the ecological satin glaze marble Ceramic Tiles with anion and light quantity subfunction Technique is made the Ceramic Tiles with formula described above, calculates raw material in parts by weight, include the following steps:
By the potassium feldspar of 33 parts by weight, the barium carbonate of 17 parts by weight, the albite of 6 parts by weight, 5 parts by weight zinc oxide, The water-washed kaoline of 10 parts by weight, the dolomite of 15 parts by weight, the calcined kaolin of 7 parts by weight, the burning talcum of 8 parts by weight, 3 The calcite of parts by weight is homogenized as idiosome formula, ball milling, powder processed, aging, press compacting, drying, drenches ground-coat enamel, stamp, spray Spherical surface glaze, high-temperature firing;The raw material of the spray spherical surface glaze is the tourmaline of 1~1.5 parts by weight;
The high-temperature firing is that temperature is fired at 1000~2000 DEG C.
Preferably, before the ball milling, first by the potassium feldspar, barium carbonate, albite, zinc oxide, water-washed kaoline, It is 100~300 mesh that dolomite, calcined kaolin, burning talcum, calcite, which are ground to granularity,.
Preferably, the tourmaline is by prefabricated, described prefabricated to be specially:It is placed in HIGH TEMPERATURE PURGE in steam chamber, high temperature Drying, is ground up, sieved.
Preferably, the proportion of the tourmaline is 3.10~3.20, hardness 6.8-7.0, and granularity is≤20 mesh.
Preferably, the proportion of the tourmaline is 3.18, hardness 7.0, and granularity is≤20 mesh.
Preferably, it is 1.35 that satin glaze Dali feldspar, which includes the tourmaline calculated in parts by weight,.
Preferably, the high-temperature firing temperature is 1850 DEG C.
As can be seen from the above technical solutions, embodiment of the present invention has the following advantages:The ecological satin glaze of the present invention Marble Ceramic Tiles formula has used tourmaline as negative ion powder, negative ion powder be mainly elbaite, dravite or One or more composite materials in the complexing ores of the boron sikicate aluminums such as iron, sodium, when other groups of negative ion powder and the present invention When dividing sintering, the chemical reaction encouraged when calcium-aluminium-silicon-phosphorus liquid phase is formed, intermolecular structure becomes secured and stablizes, system At Ceramic Tiles in lithium ion, sodium ion, magnesium ion, iron ion activity it is very strong, these are exposed to ceramic tile surface or sky The active ion of gap inner wall, radiation that can be by micro element when being contacted with air and discharge process, make with air molecule With air molecule loses electronics, forms free ion, which is combined i.e. anion with neutral gas.
Furthermore, it is understood that in the sintering process of ceramics, 1000~2000 DEG C of high temperature is used so that ceramic crystalline phase Structure changes, and crystal phase structure variation can promote the trace element of inventive formulation raw material to excite, it is easier to discharge Anion has light quantum effect.
Specific implementation mode
Embodiment of the present invention provides a kind of ecological satin glaze Dali feldspar with anion and light quantity subfunction The formula and its production technology of brick.
Wherein, satin glaze Dali feldspar includes the component calculated in parts by weight:
Potassium feldspar is 33, barium carbonate 17, potassium feldspar 6, zinc oxide 5, water-washed kaoline 10, dolomite 15, Calcined kaolin is 7, burning talcum is 8, calcite 3, tourmaline are 1~1.5;
Wherein, percentage of every parts by weight correspondence containing following chemical composition of said components is:
The proportion of the tourmaline is 3.03-3.25, hardness 6.5-7.0, granularity are≤20 mesh.
Specifically, satin glaze Dali feldspar is by following components:The carbonic acid of the potassium feldspar of 33 parts by weight, 17 parts by weight Barium, the albite of 6 parts by weight, the zinc oxide of 5 parts by weight, the water-washed kaoline of 10 parts by weight, the dolomite of 15 parts by weight, 7 weights Measure the calcined kaolin of part, the tourmaline composition for burning talcum, the calcite of 3 parts by weight, 1~1.5 parts by weight of 8 parts by weight.
Wherein, shown in the chemical composition table as above contained by each ingredient, such as:Potassium feldspar contains 61.47% Si (silicon), 15.85%Al (aluminium), 0.08%Fe (iron), 0.03%Ti (titanium), 0.93%Ca (calcium), 0.01%Mg (magnesium), 11.36%K (potassium), 1.99%Na (sodium), 0.63%I.L.Other ingredients are identical, herein not burdensome explanation.
The production work of also a kind of ecological satin glaze marble Ceramic Tiles with anion and light quantity subfunction of the present invention Skill is made the Ceramic Tiles with formula described above, calculates raw material in parts by weight, include the following steps:
By the potassium feldspar of 33 parts by weight, the barium carbonate of 17 parts by weight, the albite of 6 parts by weight, 5 parts by weight zinc oxide, The water-washed kaoline of 10 parts by weight, the dolomite of 15 parts by weight, the calcined kaolin of 7 parts by weight, the burning talcum of 8 parts by weight, 3 The calcite of parts by weight is homogenized as idiosome formula, ball milling, powder processed, aging, press compacting, drying, drenches ground-coat enamel, stamp, spray Spherical surface glaze, high-temperature firing;
The raw material of the spray spherical surface glaze is the tourmaline of 1~1.5 parts by weight;
The high-temperature firing is that temperature is fired at 1000~2000 DEG C.
Ball milling described herein, be homogenized, powder processed, aging, press compacting, dry, leaching ground-coat enamel, stamp, firing, with routine Technology is identical, therefore is not described in detail herein.
From not unlike firing temperature, firing temperature of the present invention controls at 1000~2000 DEG C, preferably 1850 ℃。
Preferably, before the ball milling, first by the potassium feldspar, barium carbonate, albite, zinc oxide, water-washed kaoline, It is 100~300 mesh that dolomite, calcined kaolin, burning talcum, calcite, which are ground to granularity,.
Preferably, the tourmaline is by prefabricated, described prefabricated to be specially:It is placed in HIGH TEMPERATURE PURGE in steam chamber, high temperature Drying, is ground up, sieved.
Preferably, the proportion of the tourmaline is 3.10~3.20, hardness 6.8-7.0, and granularity is≤20 mesh.
Preferably, the proportion of the tourmaline is 3.18, hardness 7.0, and granularity is≤20 mesh.
Preferably, it is 1.35 that satin glaze Dali feldspar, which includes the tourmaline calculated in parts by weight,.
Preferably, the high-temperature firing temperature is 1850 DEG C.
Specifically, take 33 parts of potassium feldspars, 17 parts of barium carbonates, 6 parts of albites, 5 parts of zinc oxide, 10 parts of water-washed kaolines, 15 parts of dolomites, 7 parts of calcined kaolins, 8 parts burn talcums, 3 parts of calcites as idiosome formula, by ball milling, be homogenized, powder processed, Aging, press compacting, dry, leaching ground-coat enamel, stamp, spray 1~1.5 part of tourmaline glaze (proportion 3.03-3.25, hardness 6.5- 7.0, granularity be≤20 mesh), fire, obtain the ecological satin glaze marble Ceramic Tiles with anion and light quantity subfunction.
Below by multiple embodiments, the present invention will be described in detail:
Embodiment 1
Take 3.3Kg potassium feldspars, 1.7Kg barium carbonates, 0.6Kg albites, 0.5Kg zinc oxide, 1Kg water-washed kaolines, 1.5Kg dolomites, 0.7Kg calcined kaolins, 0.8Kg burn talcum, 0.3Kg calcites as idiosome formula, by ball milling, Change, powder processed, aging, press compacting, dry, leaching ground-coat enamel, stamp, applying 1 part of tourmaline glaze, (proportion is 3.20 or so, hardness is 6.8 or so, granularity is 20 mesh), be 1850 DEG C in temperature at fire, obtain can with anion and light quantity subfunction life State satin glaze marble Ceramic Tiles.
Embodiment 2
Take 3.3Kg potassium feldspars, 1.7Kg barium carbonates, 0.6Kg albites, 0.5Kg zinc oxide, 1Kg water-washed kaolines, 1.5Kg dolomites, 0.7Kg calcined kaolins, 0.8Kg burn talcum, 0.3Kg calcites as idiosome formula, by ball milling, Change, powder processed, aging, press compacting, dry, leaching ground-coat enamel, stamp, applying 1.5 parts of tourmaline glaze, (proportion is 3.03 or so, hardness is 6.5 or so, granularity is 20 mesh), be 1850 DEG C in temperature at fire, obtain the ecology with anion and light quantity subfunction Satin glaze marble Ceramic Tiles.
Embodiment 3
Take 3.3Kg potassium feldspars, 1.7Kg barium carbonates, 0.6Kg albites, 0.5Kg zinc oxide, 1Kg water-washed kaolines, 1.5Kg dolomites, 0.7Kg calcined kaolins, 0.8Kg burn talcum, 0.3Kg calcites as idiosome formula, by ball milling, Change, powder processed, aging, press compacting, dry, leaching ground-coat enamel, stamp, applying 1.35 parts of tourmaline glaze, (proportion is 3.25 or so, hardness Be 20 mesh for 7.0 or so, granularity), be 1850 DEG C in temperature at fire, obtain the life with anion and light quantity subfunction State satin glaze marble Ceramic Tiles.
Embodiment 4
Take 3.3Kg potassium feldspars, 1.7Kg barium carbonates, 0.6Kg albites, 0.5Kg zinc oxide, 1Kg water-washed kaolines, 1.5Kg dolomites, 0.7Kg calcined kaolins, 0.8Kg burn talcum, 0.3Kg calcites as idiosome formula, by ball milling, Change, powder processed, aging, press compacting, dry, leaching ground-coat enamel, stamp, applying 1.35 parts of tourmaline glaze, (proportion is 3.25 or so, hardness Be 20 mesh for 7.0 or so, granularity), be 1850 DEG C in temperature at fire, obtain the life with anion and light quantity subfunction State satin glaze marble Ceramic Tiles.
Wherein, the ball milling of Examples 1 to 4, be homogenized, the compacting of powder processed, aging, press, it is dry, leaching ground-coat enamel, stamp, apply electricity Gas stone glaze is fired, and is controlled and is carried out in same baking furnace, to reduce ecological satin glaze marble of the various factors to generation The influence of Ceramic Tiles.
Ecological satin glaze marble Ceramic Tiles, measure each ceramic tile autonomous production anion made of Example 1~4 It is a concentration of:Release concentration >=1500/cm 1. anion is averaged3;2. at 1 meter of ceramic brick surface, its anion is measured Average release concentration >=1000/cm3.As it can be seen that Ceramic Tiles prepared by the present invention, can be released effectively a large amount of anion, and And negative ion concentration is higher.
The above, embodiment of above and embodiment are merely illustrative of the technical solution of the present invention, rather than are limited it System;Although with reference to aforementioned embodiments and embodiment, invention is explained in detail, those skilled in the art It should be understood that:It still can be with technical scheme described in the above embodiments is modified, or to which part technology Feature carries out equivalent replacement;And these modifications or replacements, the present invention that it does not separate the essence of the corresponding technical solution is each to be implemented The spirit and scope of mode and embodiment technical solution.

Claims (8)

1. a kind of formula of the ecological satin glaze marble Ceramic Tiles with anion and light quantity subfunction, which is characterized in that institute It includes the component calculated in parts by weight to state satin glaze Dali feldspar:
Potassium feldspar is 33, barium carbonate 17, albite 6, zinc oxide 5, water-washed kaoline 10, dolomite 15, calcines Kaolin is 7, burning talcum is 8, calcite 3, tourmaline are 1~1.5;
Wherein, percentage of every parts by weight correspondence containing following chemical composition of said components is:
The proportion of the tourmaline is 3.03-3.25, hardness 6.5-7.0, granularity are≤20 mesh.
2. a kind of production technology of the ecological satin glaze marble Ceramic Tiles with anion and light quantity subfunction, feature exist In, it is obtained with the Ceramic Tiles being formulated described in claim 1, raw material is calculated in parts by weight, is included the following steps:
By the potassium feldspar of 33 parts by weight, the barium carbonate of 17 parts by weight, the albite of 6 parts by weight, the zinc oxide of 5 parts by weight, 10 weights Measure the water-washed kaoline of part, the dolomite of 15 parts by weight, the calcined kaolin of 7 parts by weight, the burning talcum of 8 parts by weight, 3 parts by weight Calcite as idiosome formula, ball milling, be homogenized, powder processed, aging, press compacting, dry, leaching ground-coat enamel, stamp, spray spherical surface glaze, High-temperature firing;
The raw material of the spray spherical surface glaze is the tourmaline of 1~1.5 parts by weight;
The high-temperature firing is that temperature is fired at 1000~2000 DEG C.
3. the production of the ecological satin glaze marble Ceramic Tiles according to claim 2 with anion and light quantity subfunction Technique, which is characterized in that before the ball milling, first by the potassium feldspar, barium carbonate, albite, zinc oxide, water-washed kaoline, It is 100~300 mesh that dolomite, calcined kaolin, burning talcum, calcite, which are ground to granularity,.
4. the production of the ecological satin glaze marble Ceramic Tiles according to claim 3 with anion and light quantity subfunction Technique, which is characterized in that the tourmaline is described prefabricated to be specially by prefabricated:It is placed in HIGH TEMPERATURE PURGE in steam chamber, high temperature Drying, is ground up, sieved.
5. the ecological satin glaze Dali with anion and light quantity subfunction according to any one of Claims 1 to 4 The production technology of feldspar brick, which is characterized in that the proportion of the tourmaline is 3.10~3.20, hardness 6.8-7.0, particle Degree is≤20 mesh.
6. the ecological satin glaze Dali with anion and light quantity subfunction according to any one of Claims 1 to 4 The production technology of feldspar brick, which is characterized in that the proportion of the tourmaline is 3.18, hardness 7.0, and granularity is≤20 Mesh.
7. the ecological satin glaze Dali with anion and light quantity subfunction according to any one of Claims 1 to 4 The production technology of feldspar brick, which is characterized in that satin glaze Dali feldspar includes that the tourmaline calculated in parts by weight is 1.35。
8. the ecological satin glaze Dali with anion and light quantity subfunction according to any one of Claims 1 to 4 The production technology of feldspar brick, which is characterized in that the high-temperature firing temperature is 1850 DEG C.
CN201810412482.XA 2018-05-03 2018-05-03 A kind of formula and its production technology of the ecological satin glaze marble Ceramic Tiles with anion and light quantity subfunction Pending CN108689698A (en)

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CN110372356A (en) * 2019-08-17 2019-10-25 山东华宇国际控股有限公司 A kind of photocatalyst cleaning ceramic tile
CN110407572A (en) * 2019-08-17 2019-11-05 山东华宇国际控股有限公司 A kind of ceramic tile with nano chain skid resistance
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CN113582662B (en) * 2021-08-20 2022-11-29 佛山石湾鹰牌陶瓷有限公司 High-hardness wear-resistant satin glazed tile and preparation method thereof
CN116063105A (en) * 2023-01-14 2023-05-05 佛山市普竹陶瓷科技有限公司 Leather grain marble tile and preparation method thereof
CN116063105B (en) * 2023-01-14 2023-09-22 佛山市普竹陶瓷科技有限公司 Leather grain marble tile and preparation method thereof

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