CN105777204A - Aventurine metallic luster glaze and preparation method thereof - Google Patents

Aventurine metallic luster glaze and preparation method thereof Download PDF

Info

Publication number
CN105777204A
CN105777204A CN201610233580.8A CN201610233580A CN105777204A CN 105777204 A CN105777204 A CN 105777204A CN 201610233580 A CN201610233580 A CN 201610233580A CN 105777204 A CN105777204 A CN 105777204A
Authority
CN
China
Prior art keywords
parts
glaze
venus
metal
lustrous
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201610233580.8A
Other languages
Chinese (zh)
Other versions
CN105777204B (en
Inventor
王彦庆
董志军
董子红
谭瑞超
李涛
王春金
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huida Sanitary Ware Co Ltd
Original Assignee
Huida Sanitary Ware Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Huida Sanitary Ware Co Ltd filed Critical Huida Sanitary Ware Co Ltd
Priority to CN201610233580.8A priority Critical patent/CN105777204B/en
Publication of CN105777204A publication Critical patent/CN105777204A/en
Application granted granted Critical
Publication of CN105777204B publication Critical patent/CN105777204B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81—Coating or impregnation
    • C04B41/85—Coating or impregnation with inorganic materials
    • C04B41/86—Glazes; Cold glazes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Glass Compositions (AREA)

Abstract

The invention relates to aventurine metallic luster glaze and a preparation method thereof.The aventurine glaze is prepared from, by weight, the raw materials of 30-50 parts of albite, 2-10 parts of cristobalite, 5-18 parts of calcined talc, 2-8 parts of aluminium oxide, 2-7 parts of zinc oxide, 4-15 parts of boron frit, 0-6 parts of calcined kaolin, 15-30 parts of catalyst, and 8-20 parts of crystallization agent.The preparation method of the aventurine metallic luster glaze comprises the steps that the raw materials are evenly mixed in proportion to obtain the total dry material, water is added in a certain proportion to be mixed, glaze slip with the concentration of 325-335g/ 200ml is obtained, and the glaze slip with the granularity smaller than or equal to 10 microns is controlled to range from 50% to 55%.By means of reasonable adjustment of the firing process system and optimization of chemical composition of the formula, during later condensation after high-temperature firing, many micro ferric oxide crystalline granules are separated out from the glaze of the aventurine glaze produced in the invention, and many isolated flake-shaped single crystals sparkling like small gold foils are formed, so that an aventurine metallic glaze effect is shown.

Description

A kind of Venus metal-lustrous glaze and preparation method thereof
Technical field
The invention belongs to sanitary ceramics preparing technical field, be specifically related to a kind of Venus metal-lustrous glaze and preparation method thereof.
Background technology
Now with people live taste raising, sanitary ceramics glaze has been had higher finishing requirements, use value to be had ornamental value to be had.Owing to metal decorative material has artistic effect graceful, resplendent and magnificent, the glaze therefore with metallic luster is becoming increasingly popular.Goldstone glaze is the microcrystallization glaze of a class specific type, its mechanism is that crystallizing agent is when high temperature burns till later stage condensation, separate out many fine ferrum oxide crystal grains, form gold sand shape, these imperceptible goldc grains crystal are not to float on the surface of glaze, but it is imbedded under the surface of glaze, it is suspended among transparent glass basis.By the reflection to incident illumination, form the glazing effect that radiance glitters as Venus or spark.Require that effect that is higher and that burn till is unstable due to this glaze in the face of formula composition, firing process, so this glaze is only applicable on ceramic tile and the art work at present, the most do not apply in terms of sanitary ceramics.
Summary of the invention
Present invention aim at developing a kind of Venus metal-lustrous glaze and preparation method thereof (abbreviation goldstone glaze), this novel sanitary ceramics metal glaze, while ensureing glaze Venus effect, also to improve its stability.This is significant to raising product specification and quality level.
For solving above-mentioned technical problem, the present invention provides following technical scheme: a kind of Venus metal-lustrous glaze, the raw material of described goldstone glaze is by weight being made up of following material: albite 30～50 parts, cristobalite 2～10 parts, burning Talcum 5～18 parts, aluminium oxide 1～8 parts, zinc oxide 2～7 parts, boron frit 4～15 parts, burn Kaolin 0～6 parts, catalyst 15～30 parts, crystallize agent 8～20 parts.
The raw material of goldstone glaze of the present invention is by weight being made up of following material: albite 40 parts, cristobalite 3 parts, burns 12 parts of Talcum, aluminium oxide 1 part, zinc oxide 2 parts, boron frit 5 parts, burns Kaolin 5 parts, catalyst 20 parts, crystallize agent 12 parts.
Catalyst of the present invention is P-Al system mixture, its chemical composition the most such as under: burning decrement: 16～20%, SiO2: 4～6%, Al2O3: 16～20%, P2O5: 45～55%, Na2O:0.5～3%, ZnO:4～6%, the most leaded, chromium element, surplus is other inevitable impurity elements；Described crystallize agent is P-Fe system mixture, its chemical composition the most such as under: burning decrement: 20～25%, Fe2O3: 35～45%, P2O5: 35～40%, the most leaded, chromium element, surplus is other inevitable impurity elements.
Catalyst of the present invention is P-Al system mixture, its chemical composition the most such as under: burning decrement: 18.5%, SiO2: 5.5%, Al2O3: 18%, P2O5: 51%, Na2O:1.0%, ZnO:5.5%, the most leaded, chromium element, surplus is other inevitable impurity elements；Described crystallize agent is P-Fe system mixture, its chemical composition the most such as under: burning decrement: 22.2%, Fe2O3: 40.5%, P2O5: 37%, the most leaded, chromium element, surplus is other inevitable impurity elements.
SiO in the chemical composition of cristobalite of the present invention2Content >=95%.
The chemical composition of Venus metal-lustrous glaze of the present invention is as follows: SiO2: 35～45%, P2O5: 12～25%, Fe2O3: 3～10%, Al2O3: 14～22%, TiO2≤ 0.05%, CaO≤1.0%, MgO:2～4.5%, B2O3: 1～3%, K2O:0.2～2.5%, Na2O:3～6%, ZnO:3～7%.
The present invention also provides for the production method of a kind of above-mentioned Venus metal-lustrous glaze, described raw material proportionally mix homogeneously obtains total siccative, adding the mixing of a certain proportion of water, obtain the glaze slip of concentration 325～335g/200ml, granularity≤10 μm of glaze slip controls 50～55%.
Mobility V of glaze slip of the present invention0=50～90s.
Above-mentioned Venus metal-lustrous glaze is used for preparing ceramic article.
The present invention also provides for the using method of a kind of Venus metal-lustrous glaze,
1) glaze slip is prepared
Described raw material proportionally mix homogeneously obtains total siccative, adds the mixing of a certain proportion of water, obtains the glaze slip of concentration 325～335g/200ml, and granularity≤10 μm of glaze slip controls 50～55%；
2) glazing
Glaze slip is sprayed on semi-finished product base substrate, a glazing, glazing layer gross thickness 0.5～0.8mm；
3) calcining system
Firing period is 15～20 hours, and maximum sintering temperature is 1160～1220 DEG C, and temperature retention time is 20～40 minutes, once-firing.
Step 3) firing atmosphere of the present invention is oxidizing atmosphere, and burning till combustion gas is natural gas.
Use and have the beneficial effects that produced by technique scheme: 1, goldstone glaze is by Reasonable adjustment firing process system, the chemical composition of optimization of C/C composites, introduce the crystallize agent of ferrum system and the catalyst thereof of novel lead-free, so that glaze is when high temperature burns till later stage condensation, separate out many fine ferrum oxide crystal grains, sparkling single sheet shape, the diameter as little native gold that form many isolated are spent at the crystalline substance of 3～8mm, thus are presented the metal glazing effect as Venus；2, the product glaze Venus that present invention production obtains is of moderate size, and is evenly distributed, and stereovision is strong, and glaze pin hole is less, and acid-resistant corrosion is good, hardness 500Kgf/mm2Above.
Accompanying drawing explanation
Fig. 1 is the bathroom basin figure being fired into according to the present embodiment 1 formula；
Fig. 2 is the toilet illustraton of model being fired into according to the present embodiment 1 formula.
Detailed description of the invention
Below in conjunction with the accompanying drawings and specific embodiment the present invention is further detailed explanation.
Embodiment 1:
A kind of Venus metal-lustrous glaze, raw material forms by weight and is shown in Table 1, SiO in described cristobalite2Content 99.5%.
Catalyst is P-Al system mixture, its chemical composition the most such as under: burning decrement: 18.5%, SiO2: 5.5%, Al2O3: 18%, P2O5: 51%, Na2O:1.0%, ZnO:5.5%, the most leaded, chromium element, surplus is other inevitable impurity elements；Crystallize agent is P-Fe system mixture, its chemical composition the most such as under: burning decrement: 22.2%, Fe2O3: 40.5%, P2O5: 37%, the most leaded, chromium element, surplus is other inevitable impurity elements.
The production of Venus metal-lustrous glaze and using method, specifically comprise the following steps that
1) glaze slip is prepared
Raw material proportionally mix homogeneously obtains total siccative, adds the mixing of a certain proportion of water, obtains the glaze slip of concentration 325g/200ml, and granularity≤10 μm of glaze slip controls 55%, mobility V of glaze slip0=70s；
2) glazing
Glaze slip is sprayed on semi-finished product base substrate, a glazing, glazing layer gross thickness 0.8mm；
3) calcining system
Firing period is 15 hours, and maximum sintering temperature is 1220 DEG C, and temperature retention time is 25 minutes, once-firing；Firing atmosphere is oxidizing atmosphere, and combustion gas is natural gas.
Embodiment 2:
A kind of Venus metal-lustrous glaze, raw material forms by weight and is shown in Table 1, SiO in described cristobalite2Content 99.5%.
Catalyst is P-Al system mixture, its chemical composition the most such as under: burning decrement: 18.5%, SiO2: 5.5%, Al2O3: 18%, P2O5: 51%, Na2O:1.0%, ZnO:5.5%, the most leaded, chromium element, surplus is other inevitable impurity elements；Crystallize agent is P-Fe system mixture, its chemical composition the most such as under: burning decrement: 22.2%, Fe2O3: 40.5%, P2O5: 37%, the most leaded, chromium element, surplus is other inevitable impurity elements.
The production of Venus metal-lustrous glaze and using method, specifically comprise the following steps that
1) glaze slip is prepared
Raw material proportionally mix homogeneously obtains total siccative, adds the mixing of a certain proportion of water, obtains the glaze slip of concentration 335g/200ml, and granularity≤10 μm of glaze slip controls 50%, mobility V of glaze slip0=50s；
2) glazing
Glaze slip is sprayed on semi-finished product base substrate, a glazing, glazing layer gross thickness 0.5mm；
3) calcining system
Firing period is 20 hours, and maximum sintering temperature is 1160 DEG C, and temperature retention time is 40 minutes, once-firing；Firing atmosphere is oxidizing atmosphere, and combustion gas is natural gas.
Embodiment 3:
A kind of Venus metal-lustrous glaze, raw material forms by weight and is shown in Table 1, SiO in described cristobalite2Content 99.5%.
Catalyst is P-Al system mixture, its chemical composition the most such as under: burning decrement: 18.5%, SiO2: 5.5%, Al2O3: 18%, P2O5: 51%, Na2O:1.0%, ZnO:5.5%, the most leaded, chromium element, surplus is other inevitable impurity elements；Crystallize agent is P-Fe system mixture, its chemical composition the most such as under: burning decrement: 22.2%, Fe2O3: 40.5%, P2O5: 37%, the most leaded, chromium element, surplus is other inevitable impurity elements.
The production of Venus metal-lustrous glaze and using method, specifically comprise the following steps that
1) glaze slip is prepared
Raw material proportionally mix homogeneously obtains total siccative, adds the mixing of a certain proportion of water, obtains the glaze slip of concentration 330g/200ml, and granularity≤10 μm of glaze slip controls 52%, mobility V of glaze slip0=90s；
2) glazing
Glaze slip is sprayed on semi-finished product base substrate, a glazing, glazing layer gross thickness 0.6mm；
3) calcining system
Firing period is 18 hours, and maximum sintering temperature is 1200 DEG C, and temperature retention time is 30 minutes, once-firing；Firing atmosphere is oxidizing atmosphere, and combustion gas is natural gas.
Embodiment 4:
A kind of Venus metal-lustrous glaze, raw material forms by weight and is shown in Table 1, SiO in described cristobalite2Content 95%.
Catalyst is P-Al system mixture, its chemical composition the most such as under: burning decrement: 16%, SiO2: 4%, Al2O3: 16%, P2O5: 55%, Na2O:3%, ZnO:4%, the most leaded, chromium element, surplus is other inevitable impurity elements；Crystallize agent is P-Fe system mixture, its chemical composition the most such as under: burning decrement: 20%, Fe2O3: 45%, P2O5: 35%, the most leaded, chromium element, surplus is other inevitable impurity elements.Catalyst is P-Al system mixture, and crystallize agent is P-Fe system mixture, the most leaded, chromium element.
The production of Venus metal-lustrous glaze and using method, specifically comprise the following steps that
1) glaze slip is prepared
Raw material proportionally mix homogeneously obtains total siccative, adds the mixing of a certain proportion of water, obtains the glaze slip of concentration 335g/200ml, and granularity≤10 μm of glaze slip controls 53%, mobility V of glaze slip0=80s；
2) glazing
Glaze slip is sprayed on semi-finished product base substrate, a glazing, glazing layer gross thickness 0.7mm；
3) calcining system
Firing period is 16 hours, and maximum sintering temperature is 1190 DEG C, and temperature retention time is 35 minutes, once-firing；Firing atmosphere is oxidizing atmosphere, and combustion gas is natural gas.
Embodiment 5:
A kind of Venus metal-lustrous glaze, raw material forms by weight and is shown in Table 1, SiO in described cristobalite2Content 98%.
Catalyst of the present invention is P-Al system mixture, its chemical composition the most such as under: burning decrement: 20%, SiO2: 6%, Al2O3: 20%, P2O5: 45%, Na2O:0.5%, ZnO:6%, the most leaded, chromium element, surplus is other inevitable impurity elements；Described crystallize agent is P-Fe system mixture, its chemical composition the most such as under: burning decrement: 25%, Fe2O3: 35%, P2O5: 40%, the most leaded, chromium element, surplus is other inevitable impurity elements.
The production of Venus metal-lustrous glaze and using method, specifically comprise the following steps that
1) glaze slip is prepared
Raw material proportionally mix homogeneously obtains total siccative, adds the mixing of a certain proportion of water, obtains the glaze slip of concentration 332g/200ml, and granularity≤10 μm of glaze slip controls 54%, mobility V of glaze slip0=75s；
2) glazing
Glaze slip is sprayed on semi-finished product base substrate, a glazing, glazing layer gross thickness 0.6m；
3) calcining system
Firing period is 15～20 hours, and maximum sintering temperature is 1220 DEG C, and temperature retention time is 28 minutes, once-firing；Firing atmosphere is oxidizing atmosphere, and combustion gas is natural gas.
Embodiment 1-5 is burnt till product aggregative indicator and is shown in Table 2, and the performance technological parameter that goldstone glaze produces is shown in Table 3, it can be seen that, the present invention produces the product glaze Venus obtained and is of moderate size, and is evenly distributed, and stereovision is strong, glaze pin hole is less, and acid-resistant corrosion is good, hardness 500Kgf/mm2Above.
Table 1 raw material forms (part) by weight
Table 2 embodiment 1-5 burns till product aggregative indicator
The performance technological parameter that table 3 goldstone glaze produces
Above example is only in order to illustrative not limiting technical scheme, although the present invention being described in detail with reference to above-described embodiment, it will be understood by those within the art that: still the present invention can be modified or equivalent, any modification or partial replacement without departing from the spirit and scope of the present invention, it all should be contained in the middle of scope of the presently claimed invention.

Claims (10)

1. a Venus metal-lustrous glaze, it is characterized in that, the raw material of described goldstone glaze is by weight being made up of following material: albite 30～50 parts, cristobalite 2～10 parts, burning Talcum 5～18 parts, aluminium oxide 1～8 parts, zinc oxide 2～7 parts, boron frit 4～15 parts, burn Kaolin 0～6 parts, catalyst 15～30 parts, crystallize agent 8～20 parts.
A kind of Venus metal-lustrous glaze the most according to claim 1, it is characterized in that, the raw material of described goldstone glaze is by weight being made up of following material: albite 40 parts, cristobalite 3 parts, burns 12 parts of Talcum, aluminium oxide 1 part, zinc oxide 2 parts, boron frit 5 parts, burns Kaolin 5 parts, catalyst 20 parts, crystallize agent 12 parts.
A kind of Venus metal-lustrous glaze the most according to claim 1 and 2, it is characterised in that described catalyst is P-Al system mixture, its chemical composition the most such as under: burning decrement: 16～20%, SiO2: 4～6%, Al2O3: 16～20%, P2O5: 45～55%, Na2O:0.5～3%, ZnO:4～6%, the most leaded, chromium element, surplus is other inevitable impurity elements；
Described crystallize agent is P-Fe system mixture, its chemical composition the most such as under: burning decrement: 20～25%, Fe2O3: 35～45%, P2O5: 35～40%, the most leaded, chromium element, surplus is other inevitable impurity elements.
A kind of Venus metal-lustrous glaze the most according to claim 1 and 2, it is characterised in that described catalyst is P-Al system mixture, its chemical composition the most such as under: burning decrement: 18.5%, SiO2: 5.5%, Al2O3: 18%, P2O5: 51%, Na2O:1.0%, ZnO:5.5%, the most leaded, chromium element, surplus is other inevitable impurity elements；
Described crystallize agent is P-Fe system mixture, its chemical composition the most such as under: burning decrement: 22.2%, Fe2O3: 40.5%, P2O5: 37%, the most leaded, chromium element, surplus is other inevitable impurity elements.
A kind of Venus metal-lustrous glaze the most according to claim 1 and 2, it is characterised in that SiO in the chemical composition of described cristobalite2Content >=95%.
A kind of Venus metal-lustrous glaze the most according to claim 1 and 2, it is characterised in that the chemical composition of described Venus metal-lustrous glaze is as follows: SiO2: 35～45%, P2O5: 12～25%, Fe2O3: 3～10%, Al2O3: 14～22%, TiO2≤ 0.05%, CaO≤1.0%, MgO:2～4.5%, B2O3: 1～3%, K2O:0.2～2.5%, Na2O:3～6%, ZnO:3～7%.
7. production method based on a kind of Venus metal-lustrous glaze described in claim 1-6 any one, it is characterized in that, described raw material proportionally mix homogeneously obtains total siccative, add the mixing of a certain proportion of water, obtaining the glaze slip of concentration 325～335g/200ml, granularity≤10 μm of glaze slip controls 50～55%.
Production method the most according to claim 7, it is characterised in that mobility V of described glaze slip0=50～90s.
9. using method based on a kind of Venus metal-lustrous glaze described in claim 1-6 any one, it is characterised in that: described specifically used method is as follows:
1) glaze slip is prepared
Described raw material proportionally mix homogeneously obtains total siccative, adds the mixing of a certain proportion of water, obtains the glaze slip of concentration 325～335g/200ml, and granularity≤10 μm of glaze slip controls 50～55%；
2) glazing
Glaze slip is sprayed on semi-finished product base substrate, a glazing, glazing layer gross thickness 0.5～0.8mm；
3) calcining system
Firing period is 15～20 hours, and maximum sintering temperature is 1160～1220 DEG C, and temperature retention time is 20～40 minutes, once-firing.
Production method the most according to claim 8, it is characterised in that described step 3) firing atmosphere is oxidizing atmosphere, burning till combustion gas is natural gas.
CN201610233580.8A 2016-04-15 2016-04-15 A kind of Venus metal-lustrous glaze and preparation method thereof Active CN105777204B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610233580.8A CN105777204B (en) 2016-04-15 2016-04-15 A kind of Venus metal-lustrous glaze and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610233580.8A CN105777204B (en) 2016-04-15 2016-04-15 A kind of Venus metal-lustrous glaze and preparation method thereof

Publications (2)

Publication Number Publication Date
CN105777204A true CN105777204A (en) 2016-07-20
CN105777204B CN105777204B (en) 2019-01-04

Family

ID=56396508

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610233580.8A Active CN105777204B (en) 2016-04-15 2016-04-15 A kind of Venus metal-lustrous glaze and preparation method thereof

Country Status (1)

Country Link
CN (1) CN105777204B (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106495493A (en) * 2016-10-11 2017-03-15 常州市鼎日环保科技有限公司 A kind of preparation method of crystallite stone ceramic tile
CN106567078A (en) * 2016-10-21 2017-04-19 陕西科技大学 Preparation method of aventurine enamel
CN106587624A (en) * 2016-12-06 2017-04-26 钦州市高新技术产业服务中心 Metallic luster glaze and preparation method thereof
CN106746671A (en) * 2017-01-12 2017-05-31 九牧厨卫股份有限公司 A kind of preparation method of bright glaze sanitary ceramics
CN107892481A (en) * 2017-12-06 2018-04-10 九牧厨卫股份有限公司 A kind of metal glaze prepared using sanitary ceramics recovery iron tramp and its method
CN109133628A (en) * 2018-09-21 2019-01-04 醴陵市良盛陶瓷制造有限公司 yellow gold sand glaze and preparation method thereof
CN109264997A (en) * 2018-10-26 2019-01-25 张丹丹 A kind of pottery iron aventurine glaze and preparation method thereof
CN109734316A (en) * 2019-02-18 2019-05-10 西安文理学院 A kind of ceramet glaze and preparation method thereof
CN112939627A (en) * 2021-02-08 2021-06-11 湖南泰鑫瓷业有限公司 Ceramic production method for realizing metal effect on product embossment
CN113562976A (en) * 2021-09-24 2021-10-29 佛山市道氏科技有限公司 Gold foil effect particles for ceramics, preparation method of gold foil effect particles and glaze

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103086747A (en) * 2013-02-06 2013-05-08 陕西科技大学 Preparation method of flare aventurine glaze
CN103833419A (en) * 2014-01-02 2014-06-04 惠达卫浴股份有限公司 Purple bronze glaze with metallic luster and preparation method thereof
CN103896634A (en) * 2014-03-12 2014-07-02 湖南港鹏实业有限公司 High-temperature domestic porcelain metallic bright glaze and product decorated by same

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103086747A (en) * 2013-02-06 2013-05-08 陕西科技大学 Preparation method of flare aventurine glaze
CN103833419A (en) * 2014-01-02 2014-06-04 惠达卫浴股份有限公司 Purple bronze glaze with metallic luster and preparation method thereof
CN103896634A (en) * 2014-03-12 2014-07-02 湖南港鹏实业有限公司 High-temperature domestic porcelain metallic bright glaze and product decorated by same

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106495493A (en) * 2016-10-11 2017-03-15 常州市鼎日环保科技有限公司 A kind of preparation method of crystallite stone ceramic tile
CN106495493B (en) * 2016-10-11 2019-01-18 邯郸市永年区金缔陶瓷有限公司 A kind of preparation method of crystallite stone ceramic tile
CN106567078A (en) * 2016-10-21 2017-04-19 陕西科技大学 Preparation method of aventurine enamel
CN106587624A (en) * 2016-12-06 2017-04-26 钦州市高新技术产业服务中心 Metallic luster glaze and preparation method thereof
CN106746671A (en) * 2017-01-12 2017-05-31 九牧厨卫股份有限公司 A kind of preparation method of bright glaze sanitary ceramics
CN107892481A (en) * 2017-12-06 2018-04-10 九牧厨卫股份有限公司 A kind of metal glaze prepared using sanitary ceramics recovery iron tramp and its method
CN107892481B (en) * 2017-12-06 2020-06-23 九牧厨卫股份有限公司 Metal glaze prepared by recovering iron impurities from sanitary ceramics and method thereof
CN109133628A (en) * 2018-09-21 2019-01-04 醴陵市良盛陶瓷制造有限公司 yellow gold sand glaze and preparation method thereof
CN109264997A (en) * 2018-10-26 2019-01-25 张丹丹 A kind of pottery iron aventurine glaze and preparation method thereof
CN109734316A (en) * 2019-02-18 2019-05-10 西安文理学院 A kind of ceramet glaze and preparation method thereof
CN112939627A (en) * 2021-02-08 2021-06-11 湖南泰鑫瓷业有限公司 Ceramic production method for realizing metal effect on product embossment
CN113562976A (en) * 2021-09-24 2021-10-29 佛山市道氏科技有限公司 Gold foil effect particles for ceramics, preparation method of gold foil effect particles and glaze

Also Published As

Publication number Publication date
CN105777204B (en) 2019-01-04

Similar Documents

Publication Publication Date Title
CN105777204A (en) Aventurine metallic luster glaze and preparation method thereof
CN101255067B (en) Preparation method of metal-imitation glaze
CN103833419B (en) Purple bronze glaze with metallic luster and preparation method thereof
CN108455857B (en) Soft and warm moist glaze for sanitary ceramic sanitary ware and preparation process thereof
CN102249739B (en) Preparation method of carbon-golden metallic luster crystalline glaze
CN103332861B (en) Preparation method of metallic luster glaze
CN103102178B (en) Purple matt glaze and preparation method thereof
CN106977103B (en) Preparation method of sand glaze sanitary ceramic
CN107226691B (en) Green fambe flowing glaze ceramic product and manufacturing process thereof
CN102731169A (en) Fully glazed ceramic chip and preparation method thereof
CA2984659C (en) Glaze resistant to wax block bonding, ceramic resistant to wax block bonding and preparation process thereof
CN102020461B (en) High-temperature bright red ceramic and preparation method thereof
CN102173875B (en) Preparation method of B2O3-TiO2 series fambe ceramic crystalline glaze
CN104891808B (en) A kind of coffee-like crystallization enamel composition
CN102432342A (en) Preparation method of vanadium-titanium-iron system golden crystal glaze
JP2016165887A (en) Ceramic article and method for production thereof
CN107010922B (en) Preparation method of transmutation glaze purple sand fine pottery
CN103588506A (en) Formula of black-matrix silver-strip streak ceramic glaze and preparation method thereof
CN106587624A (en) Metallic luster glaze and preparation method thereof
CN108069608B (en) Alkali-resistant porcelain glaze
CN103044083A (en) Transparent glaze and manufacturing method thereof
CN109704719A (en) Heat-insulated corrosion resistant ancient architecture ceramics of one kind and preparation method thereof
CN105541112B (en) A kind of super flat glaze frit and the method for being produced from it super spar
CN106565091A (en) High-temperature quick-burning sand crystal glaze and preparation technology thereof
CN108623164B (en) Wear-resistant ceramic glaze

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant