CN103332861B - Preparation method of metallic luster glaze - Google Patents
Preparation method of metallic luster glaze Download PDFInfo
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- CN103332861B CN103332861B CN201310273810.XA CN201310273810A CN103332861B CN 103332861 B CN103332861 B CN 103332861B CN 201310273810 A CN201310273810 A CN 201310273810A CN 103332861 B CN103332861 B CN 103332861B
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- CN
- China
- Prior art keywords
- glaze
- metal
- metallic luster
- preparation
- lustrous
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- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 239000002932 luster Substances 0.000 title abstract description 6
- 239000000203 mixture Substances 0.000 claims abstract description 16
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000002156 mixing Methods 0.000 claims abstract description 8
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 5
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 5
- 239000010433 feldspar Substances 0.000 claims abstract description 5
- 238000000227 grinding Methods 0.000 claims abstract description 5
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000010453 quartz Substances 0.000 claims abstract description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000011787 zinc oxide Substances 0.000 claims abstract description 5
- 239000000463 material Substances 0.000 claims description 10
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 claims description 8
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract description 10
- 238000000034 method Methods 0.000 abstract description 8
- 238000004519 manufacturing process Methods 0.000 abstract description 7
- 229910052751 metal Inorganic materials 0.000 abstract description 6
- 239000002184 metal Substances 0.000 abstract description 6
- 229910052697 platinum Inorganic materials 0.000 abstract description 5
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052737 gold Inorganic materials 0.000 abstract description 4
- 239000010931 gold Substances 0.000 abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- 239000011449 brick Substances 0.000 abstract description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 2
- 238000005303 weighing Methods 0.000 abstract 2
- 235000019738 Limestone Nutrition 0.000 abstract 1
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 abstract 1
- 239000010459 dolomite Substances 0.000 abstract 1
- 229910000514 dolomite Inorganic materials 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 239000006028 limestone Substances 0.000 abstract 1
- 238000010791 quenching Methods 0.000 abstract 1
- 230000000171 quenching effect Effects 0.000 abstract 1
- 238000000498 ball milling Methods 0.000 description 6
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 230000003796 beauty Effects 0.000 description 2
- 235000015895 biscuits Nutrition 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 229910052770 Uranium Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- RIVZIMVWRDTIOQ-UHFFFAOYSA-N cobalt iron Chemical compound [Fe].[Co].[Co].[Co] RIVZIMVWRDTIOQ-UHFFFAOYSA-N 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- -1 metal oxide compound Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 1
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- Glass Compositions (AREA)
Abstract
The invention provides a preparation method of a metallic luster glaze, which comprises the following steps: (1) respectively weighing the following substances in percentage by weight: 5-30% of quartz, 20-50% of feldspar, 2-20% of limestone, 2-20% of dolomite, 2-20% of barium carbonate, 2-20% of zinc oxide and 2-10% of lead silicate, and then evenly mixing; (2) fusing the mixture prepared in the step (1) at 1200-1400 DEG C, and performing water quenching to obtain a basic glaze fused block; and (3) weighing the following substances in percentage by weight: 70-90% of basic glaze fused block, 1-10% of kaolin, 1-11% of MnO2, 1-10% of TiO2, 1-10% of CuO and 1-10% of NiO, then mixing, and integrally performing coarse crushing, fine crushing and ingredient grinding sequentially; and evenly mixing to obtain the metallic luster glaze. The metallic luster glaze provided by the invention is brilliant and bright in color; platinum and gold metallic luster can be obtained by changing the composition of the metal glaze; and the method and the process are simple and are very suitable for production and manufacturing of wall bricks.
Description
Technical field
The present invention relates to construction sanitary ceramic decoration technique field, especially relate to a kind of preparation method of metal-lustrous glaze.
Background technology
In the prior art, in nineteen ninety, the research in " microstructure analysis of imitative blue or green uranium pottery " literary composition such as Shanghai Inst. of Silicate, Chinese Academy of Sciences professor Chen Xianqiu shows, its gloss derives from ferro-cobalt spinel crystallites and is being parallel to the reflectance signature in implements surface direction.This be mainly veil density larger 1,1,1} crystal face with surface perfect parallelism, strong reflection is presented to light.The grain size of these crystallites, distribution, integrated degree can affect metalluster.The cardinal principle of metal-lustrous glaze is in the raw material of certain component, adds coloring metal oxide compound, as
,
,
,
and
deng, make its when burning till cooling because of supersaturation crystallize out, produce the metalluster of various different-effect.As the patent No.: 200710008547.6, patent name is a kind of metal glaze production method, and its technique is simple, is only suitable for metal glaze Antique Imitation Tiles, but the tone of similar metal-lustrous glaze is bright-coloured not, not too applicable tone required by interior glazed tile becomes clear, bright-coloured requirement.
Summary of the invention
The object of the invention is to solve the problems of the prior art, and provide a kind of in colour-stable, bright in luster, the preparation method of the simple metal-lustrous glaze of technique.
The technical solution adopted in the present invention is such: a kind of preparation method of metal-lustrous glaze, comprises the following steps:
(1), by weight percentage by the quartz of 5% ~ 30%, 20% ~ 50% feldspar, 2% ~ 20% Wingdale, 2% ~ 20% rhombspar, the barium carbonate of 2% ~ 20%, the zinc oxide of 2% ~ 20% and 2% ~ 10% lead silicate, mix after taking each material;
(2), by the mixture obtained by step (1), carry out 1200 DEG C-1400 DEG C found after, after shrend, obtain parent glaze frit;
(3), by weight percentage by the parent glaze frit of 70% ~ 90%, 1% ~ 10% kaolin, 1% ~ 11%
, 1% ~ 10%
, 1% ~ 10%
, 1% ~ 10%
, each material takes rear mixing, and entirety is successively through coarse crushing, in small, broken bits, batching grinding; Mix and can obtain metal-lustrous glaze.
Preferably, the fineness of described metal-lustrous glaze is for be less than 2% through 10000-hole sieve excess.
By adopting preceding solution, the invention has the beneficial effects as follows: this metal-lustrous glaze can colour generation bright-coloured bright, the composition of change metal glaze can obtain the metalluster of platinum look and Gold production.By metalluster glaze, ball milling is even in proportion; And add the Xylo-Mucine of 0.3%, in glaze: ball milling value: the ratio of water=1:1.2:0.5 makes glaze slip, evenly imposes on biscuit surface, thickness 0.2-1mm; Wherein ball milling value is the diameter of the ball of zirconium white or aluminum oxide material, the fineness of the diameter value corresponding meeting ectocrine abrasive lapping of different ball milling.Through 1050-1200 DEG C after drying, firing time 1 hour, fires the Gold production and platinum non-ferrous metal gloss glaze paint that can obtain tone beauty respectively; Method technique is simple, is applicable to very much the manufacturing of wall brick.
Embodiment
Describe the present invention particularly with embodiment below, scope of the present invention is not by the restriction of embodiment.
Embodiment 1
(1), by weight percentage by the quartz of 17%, 46% feldspar, 14% Wingdale, 5% rhombspar, the barium carbonate of 4%, the zinc oxide of 6% and 8% lead silicate, mix after taking each material;
(2), by the mixture obtained by step (1), after founding through 1350 DEG C, shrend obtains base glaze frit;
(3), by weight percentage by the parent glaze frit of 78%, 5% kaolin, 10.5%
, 3%
, 1.7%
, 1.8%
, each material takes rear mixing, and entirety is successively through coarse crushing, in small, broken bits, batching grinding; Mix the metal-lustrous glaze of obtained Gold production.
Embodiment 2
(1), by weight percentage by the quartz of 17%, 46% feldspar, 14% Wingdale, 5% rhombspar, the barium carbonate of 4%, the zinc oxide of 6% and 8% lead silicate, mix after taking each material;
(2), by the mixture obtained by step (1), after founding through 1350 DEG C, shrend obtains base glaze frit;
(3), by weight percentage by the parent glaze frit of 78%, 5% kaolin, 8.5%
, 5.8%
, 1.5%
, 1.2%
, each material takes rear mixing, and entirety is successively through coarse crushing, in small, broken bits, batching grinding; Mix the metal-lustrous glaze of obtained platinum look.
Ground by ball mill Homogeneous phase mixing in proportion by above-mentioned metal-lustrous glaze, fineness is for be less than 2% through 10000-hole sieve excess; By the Xylo-Mucine of metal-lustrous glaze in conjunction with interpolation 0.3%, in glaze: ball: the ratio of water=1:1.2:0.5 makes glaze slip; It is evenly imposed on biscuit surface, ensures that the thickness of glazing is 0.2-1mm; Wherein ball milling value is the diameter of the ball of zirconium white or aluminum oxide material, the fineness of the diameter value corresponding meeting ectocrine abrasive lapping of different ball milling.Through the calcining of 1050 DEG C-1200 DEG C after drying, firing time is 1 hour, can obtain the platinum non-ferrous metal gloss glaze paint of tone beauty.
Above-described, be only preferred embodiment of the present invention, scope of the invention process can not be limited, every equalization change of doing according to the present patent application the scope of the claims and decoration, all should still belong in scope that the present invention contains.
Claims (2)
1. a preparation method for metal-lustrous glaze, is characterized in that: comprise the following steps:
(1), by weight percentage by the quartz of 5% ~ 30%, 20% ~ 50% feldspar, 2% ~ 20% Wingdale, 2% ~ 20% rhombspar, the barium carbonate of 2% ~ 20%, the zinc oxide of 2% ~ 20% and 2% ~ 10% lead silicate, mix after taking each material;
(2), by the mixture obtained by step (1), carry out 1200 DEG C-1400 DEG C found after, after shrend, obtain parent glaze frit;
(3), by weight percentage by the parent glaze frit of 70% ~ 90%, 1% ~ 10% kaolin, 1% ~ 11%
, 1% ~ 10%
, 1% ~ 10%
, 1% ~ 10%
, each material takes rear mixing, and entirety is successively through coarse crushing, in small, broken bits, batching grinding; Mix and can obtain metal-lustrous glaze.
2. the preparation method of a kind of metal-lustrous glaze according to claim 1, is characterized in that: the fineness of described metal-lustrous glaze is for be less than 2% through 10000-hole sieve excess.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310273810.XA CN103332861B (en) | 2013-07-02 | 2013-07-02 | Preparation method of metallic luster glaze |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310273810.XA CN103332861B (en) | 2013-07-02 | 2013-07-02 | Preparation method of metallic luster glaze |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103332861A CN103332861A (en) | 2013-10-02 |
| CN103332861B true CN103332861B (en) | 2015-07-08 |
Family
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|---|---|---|---|
| CN201310273810.XA Active CN103332861B (en) | 2013-07-02 | 2013-07-02 | Preparation method of metallic luster glaze |
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| Country | Link |
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| CN (1) | CN103332861B (en) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104193172A (en) * | 2014-06-30 | 2014-12-10 | 贵州省兴仁县荣凯五金搪瓷制品有限公司 | Titanium dioxide cover glaze used on gold smelting bucket and production method of titanium dioxide cover glaze |
| CN104030569A (en) * | 2014-06-30 | 2014-09-10 | 贵州省兴仁县荣凯五金搪瓷制品有限公司 | Nickel base porcelain glaze for sintered metal drum and production method thereof |
| CN105254338A (en) * | 2015-11-16 | 2016-01-20 | 德化恒瀚艺品有限公司 | Colorful glaze and manufacturing technology |
| CN106810229B (en) * | 2017-01-25 | 2020-02-11 | 欧阳琦 | Preparation process of metal glaze carpet brick and metal glaze carpet brick |
| CN107311613A (en) * | 2017-07-26 | 2017-11-03 | 贵州省旅游产品研发中心（有限合伙） | A kind of tooth boat pottery underglaze colour manufacture craft |
| CN107698152A (en) * | 2017-11-30 | 2018-02-16 | 南宁市生润科技有限公司 | A kind of golden glazed tiles glaze |
| CN108191239A (en) * | 2018-01-18 | 2018-06-22 | 武汉理工大学 | A kind of unleaded metallic luster gold glaze and preparation method thereof |
| CN108516684B (en) * | 2018-05-07 | 2021-01-15 | 湖南大学 | Inorganic bonding glaze and preparation method thereof |
| CN108863077A (en) * | 2018-08-10 | 2018-11-23 | 张家港市六福新材料科技有限公司 | A kind of preparation method of ceramet glaze |
| CN109111114A (en) * | 2018-09-15 | 2019-01-01 | 湖南高峰陶瓷制造有限公司 | Purplish red reaction glaze and preparation method thereof |
| CN109264994A (en) * | 2018-09-21 | 2019-01-25 | 醴陵市良盛陶瓷制造有限公司 | Unglazed golden metallic glaze and preparation method thereof |
| CN109133629A (en) * | 2018-09-22 | 2019-01-04 | 醴陵市良盛陶瓷制造有限公司 | Unglazed unleaded metal glaze of copper red color and preparation method thereof |
| CN112499970A (en) * | 2020-12-31 | 2021-03-16 | 卡罗比亚(中国)高新材料有限公司 | Production process of ceramic tile with decorative glaze with golden bright metal cracks |
| CN116062996B (en) * | 2022-12-21 | 2023-11-21 | 蒙娜丽莎集团股份有限公司 | Mother-of-pearl glaze, mother-of-pearl bright-grain ceramic rock plate and preparation method thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB962568A (en) * | 1960-11-11 | 1964-07-01 | Owens Illinois Glass Co | Improvements in and relating to refractory compositions |
| US20040050106A1 (en) * | 2002-08-29 | 2004-03-18 | Murnane Rand A. | Producing glass using outgassed frit |
| CN101255067B (en) * | 2007-12-28 | 2012-03-14 | 冼金源 | Preparation method of metal-imitation glaze |
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Effective date of registration: 20240111 Address after: Office Building 55, West Industrial Zone, Dapu Village, Cizao Town, Jinjiang City, Quanzhou City, Fujian Province, 362000 Patentee after: Quanzhou Omico New Material Technology Co.,Ltd. Address before: 362000 first floor, comprehensive building of advanced manufacturing technology service base, detai Road, economic and Technological Development Zone, Quanzhou City, Fujian Province Patentee before: QUANZHOU OUMIKE ECOLOGY MATERIALS TECHNOLOGY Co.,Ltd. |