CN103332965B - Golden yellow crystallized dry-granular glaze and using method thereof - Google Patents
Golden yellow crystallized dry-granular glaze and using method thereof Download PDFInfo
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- CN103332965B CN103332965B CN201310272968.5A CN201310272968A CN103332965B CN 103332965 B CN103332965 B CN 103332965B CN 201310272968 A CN201310272968 A CN 201310272968A CN 103332965 B CN103332965 B CN 103332965B
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- glaze
- golden yellow
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- crystallized
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- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 title claims abstract description 22
- 238000000034 method Methods 0.000 title claims abstract description 14
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000000498 ball milling Methods 0.000 claims abstract description 12
- 239000013078 crystal Substances 0.000 claims abstract description 9
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 8
- 238000000227 grinding Methods 0.000 claims abstract description 8
- 239000011787 zinc oxide Substances 0.000 claims abstract description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000001035 drying Methods 0.000 claims abstract description 5
- 238000002156 mixing Methods 0.000 claims abstract description 5
- 238000001354 calcination Methods 0.000 claims abstract description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 4
- 238000007580 dry-mixing Methods 0.000 claims abstract description 4
- 239000010433 feldspar Substances 0.000 claims abstract description 4
- 239000010453 quartz Substances 0.000 claims abstract description 4
- 238000007873 sieving Methods 0.000 claims abstract description 4
- 239000002002 slurry Substances 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims description 17
- 238000002425 crystallisation Methods 0.000 claims description 13
- 230000008025 crystallization Effects 0.000 claims description 13
- 239000000758 substrate Substances 0.000 claims description 8
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 claims description 6
- 238000002386 leaching Methods 0.000 claims description 4
- 238000005507 spraying Methods 0.000 claims description 4
- 238000010422 painting Methods 0.000 claims description 3
- 238000010583 slow cooling Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 abstract 2
- 238000005303 weighing Methods 0.000 abstract 2
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 abstract 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 1
- 238000010791 quenching Methods 0.000 abstract 1
- 230000000171 quenching effect Effects 0.000 abstract 1
- 239000000919 ceramic Substances 0.000 description 9
- 238000010304 firing Methods 0.000 description 3
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 238000010923 batch production Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000004534 enameling Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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Abstract
The invention provides golden yellow crystallized dry-granular glaze and a using method thereof. The using method comprises the following steps of: (1) weighing the following compositions in percentage by weight: 15%-22% of feldspar, 20%-40% of quartz, 6%-15% of calcium carbonate, 6%-15% of barium carbonate, 22%-50% of zinc oxide, 0.7%-2.2% of CuO, and 0.7%-2.2% of Fe2O3, evenly mixing and grinding, and sieving to obtain crystallized glaze; (2) weighing the following compositions in percentage by weight: 20%-78% of activated silicon and 22%-80% of zinc oxide, evenly dry-mixing, then calcinating at 1100 DEG C for 5-10 hours, and conducting water quenching to obtain a seed crystal; (3) evenly mixing and grinding the crystallized glaze in the step (1) and the seed crystal in the step (2) to obtain golden yellow crystallized dry-granular glaze, preparing the crystallized glaze and water as well as ball milling into slurry according to proportion in use, and evenly applying to the surface of a blank; drying and burning at 1200 DEG C-1350 DEG C for 5-7 hours. The glaze is brightly golden yellow, even and complete in crystal flowers, and the glaze is very attractive, and strong in adaptability.
Description
Technical field
The present invention relates to construction sanitary ceramic decoration technique field, especially relate to a kind of golden yellow crystallization dry granular glaze and using method thereof.
Background technology
Along with ceramic enters huge numbers of families, ceramic glaze is that pottery manufactures indispensable secondary raw material, has very important impact to the performance of ceramic and quality.Existing ceramic glaze according to ceramic glaze according to classification and purposes can rough classification as follows: 1, lead glaze and leadless glaze; 2, raw glaze and fritted glaze; 3, once-firing or twice firing glaze; 4, ceramic tile, tableware, snitaryware and electroceramics glaze; 5, by enameling method divide leaching glaze, glaze spraying, water glaze; 6, high melting glaze and low temperature glaze; 7, high expansion glaze and Low Thermal Expantion Glaze; 8, firing atmosphere oxydizing flame, neutral flame and reducing flame; 9, coloured glaze and colourless glaze; 10, transparent and opaque glaze; 11, bright glaze, matt glaze, semi-mat glaze or figure glaze etc.; 12, function glaze, as fluorescence glaze, metal-lustrous glaze, crystalline glaze etc.Wherein crystalline glaze ceramic tile is due to its beautiful appearance exquisiteness, liking extensively by human consumer.Produce abundant species, crystalline glaze beautiful in colour, become the target that pottery producer of China is pursued.
Summary of the invention
The object of the invention is to solve the problems of the prior art, and provide a kind of in the golden yellow crystallization dry granular glaze colour-stable, ceramic industry production requirement can be met and using method thereof.
The technical solution adopted in the present invention is such: a kind of golden yellow crystallization dry granular glaze, comprises the following steps:
(1), by weight percentage by the feldspar of 15% ~ 22%, the quartz of 20% ~ 40%, calcium carbonate, the barium carbonate of 6% ~ 15%, the zinc oxide, 0.7% ~ 2.2% of 22% ~ 50% of 6% ~ 15%
with 0.7% ~ 2.2%
, after taking each material, mixed grinding evenly, sieving obtains crystalline glaze material;
(2), by weight percentage by the activated silica of 20% ~ 78% and the zinc oxide of 22% ~ 80%, after mixing dry mixing evenly after taking each material, then after 5 ~ 10 hours, after shrend, crystal seed is obtained through 1100 DEG C of calcinings;
(3) crystal seed, by crystalline glaze material obtained for step (1) and step (2) obtained, both mixed grindings evenly can obtain golden yellow crystallization dry granular glaze.
Preferably, the fineness of described crystalline glaze material is for be less than 2% through 10000-hole sieve excess.
A using method for golden yellow crystallization dry granular glaze, (1), by obtained golden yellow crystallization dry granular glaze and water, ball milling, 1:(0.9 ~ 1 in proportion): (0.6 ~ 0.8) is through ball milling slurrying; (2), by gained slurry, adopt leaching glaze, painting glaze or glaze spraying mode to base substrate glazing, glazing thickness is 1 ~ 1.5mm, after the body drying after glazing, 5 ~ 7 hours are fired, with the base substrate obtaining golden yellow brilliant flower face after stove Slow cooling at 1200 DEG C ~ 1350 DEG C.
By adopting preceding solution, the invention has the beneficial effects as follows: this crystalline glaze presents gorgeous golden yellow, crystalline substance is spent evenly complete, and glaze paint entirety is intact, very attractive in appearance, and can be applicable to the glaze decorating of multiple base substrate, strong adaptability.During use, by this crystalline glaze material and water, ball milling, 1:(0.9 ~ 1 in proportion): (0.6 ~ 0.8) makes slip, evenly imposes on billet surface; Wherein ball milling is the diameter of the ball of zirconium white or aluminum oxide material, the fineness of the diameter value corresponding meeting ectocrine abrasive lapping of different ball milling.At 1200 DEG C ~ 1350 DEG C, fire 5 ~ 7 hours after drying, fire the base substrate that can obtain golden yellow brilliant flower face respectively; Method technique is simple, and cost is low, is applicable to batch production demand.
Embodiment
Describe the present invention particularly with embodiment below, scope of the present invention is not by the restriction of embodiment.
Embodiment 1
(1), by weight percentage by the feldspar of 21%, the quartz of 30%, calcium carbonate, the barium carbonate of 12%, the zinc oxide, 1.5% of 29% of 8%
with 2.5%
, after taking each material, mixed grinding evenly, sieving obtains crystalline glaze material, and the fineness of crystalline glaze material is for be less than 2% through 10000-hole sieve excess;
(2), by weight percentage by the activated silica of 50% and the zinc oxide of 50%, after mixing dry mixing evenly after taking each material, then after 5 ~ 10 hours, after shrend, crystal seed is obtained through 1100 DEG C of calcinings;
(3) crystal seed, by crystalline glaze material obtained for step (1) and step (2) obtained, both mixed grindings evenly can obtain golden yellow crystallization dry granular glaze.
A kind of using method of golden yellow crystallization dry granular glaze, (1), by obtained golden yellow crystallization dry granular glaze and water, ball milling, wherein ball milling is the diameter of the ball of zirconium white or aluminum oxide material, the fineness of the diameter value corresponding meeting ectocrine abrasive lapping of different ball milling, entirety is 1:(0.9 ~ 1 in proportion): (0.6 ~ 0.8) is through ball milling slurrying; (2) by gained slurry, adopt leaching glaze, painting glaze or glaze spraying mode to base substrate glazing, glazing thickness is 1 ~ 1.5mm, after body drying after glazing, 5 ~ 7 hours are fired at 1200 DEG C ~ 1350 DEG C, with the base substrate obtaining golden yellow brilliant flower face after stove Slow cooling, cost is low, suitability is high and very attractive in appearance.
Above-described, be only preferred embodiment of the present invention, scope of the invention process can not be limited, every equalization change of doing according to the present patent application the scope of the claims and decoration, all should still belong in scope that the present invention contains.
Claims (1)
1. a using method for golden yellow crystallization dry granular glaze, is characterized in that: comprise the following steps:
(1), by weight percentage by the feldspar of 15% ~ 22%, 20% ~ 40% quartz, 6% ~
The Fe of the calcium carbonate of 15%, the barium carbonate of 6% ~ 15%, the zinc oxide of 22% ~ 50%, the CuO of 0.7% ~ 2.2% and 0.7% ~ 2.2%
2o
3, after taking each material, mixed grinding evenly, sieving obtains crystalline glaze material;
(2), by weight percentage by the activated silica of 20% ~ 78% and the zinc oxide of 22% ~ 80%, after mixing dry mixing evenly after taking each material, then after 5 ~ 10 hours, after shrend, crystal seed is obtained through 1100 DEG C of calcinings;
(3) crystal seed, by crystalline glaze material obtained for step (1) and step (2) obtained, both mixed grindings evenly can obtain golden yellow crystallization dry granular glaze;
(4), by obtained golden yellow crystallization dry granular glaze and water, ball milling, in proportion 1: (0.9 ~ 1): (0.6 ~ 0.8) is through ball milling slurrying;
(5), by gained slurry, adopt leaching glaze, painting glaze or glaze spraying mode to base substrate glazing, glazing thickness is 1 ~ 1.5mm, after the body drying after glazing, 5 ~ 7 hours are fired, with the base substrate obtaining golden yellow brilliant flower face after stove Slow cooling at 1200 DEG C ~ 1350 DEG C.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310272968.5A CN103332965B (en) | 2013-07-02 | 2013-07-02 | Golden yellow crystallized dry-granular glaze and using method thereof |
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| CN201310272968.5A CN103332965B (en) | 2013-07-02 | 2013-07-02 | Golden yellow crystallized dry-granular glaze and using method thereof |
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| Publication Number | Publication Date |
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| CN103332965A CN103332965A (en) | 2013-10-02 |
| CN103332965B true CN103332965B (en) | 2015-01-21 |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106587627B (en) * | 2016-12-16 | 2019-01-29 | 大宋官窑股份有限公司 | A kind of crystalline glaze glaze, crystalline glaze pottery and preparation method thereof |
| CN109809836A (en) * | 2018-12-13 | 2019-05-28 | 江苏新嘉理生态环境材料股份有限公司 | A kind of production method of special-shaped cube of pottery curtain wall terra-cotta |
| CN113105114A (en) * | 2021-04-06 | 2021-07-13 | 广东欧文莱陶瓷有限公司 | Crystalline dry grain face rock plate and preparation method thereof |
| CN113651607B (en) * | 2021-08-12 | 2022-12-23 | 广东宏宇新型材料有限公司 | Ceramic tile with night sky and river decoration effect |
| CN114804627B (en) * | 2022-04-24 | 2023-11-14 | 江苏省陶瓷研究所有限公司 | Reduction firing phase separation induced palace Huang Yuzi crystal fancy glaze and preparation method thereof |
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|---|---|---|---|---|
| CN102173869A (en) * | 2011-01-19 | 2011-09-07 | 江苏高淳陶瓷股份有限公司 | Preparation method of non-ferrous tea dust crystalline glaze |
| CN102173873A (en) * | 2011-01-27 | 2011-09-07 | 上海高诚艺术包装有限公司 | Transmutation glaze material and glazing process |
| CN102249739A (en) * | 2011-05-26 | 2011-11-23 | 山西高陶瓷业有限责任公司 | Preparation method of carbon-golden metallic luster crystalline glaze |
| CN102936156A (en) * | 2012-10-30 | 2013-02-20 | 佛山市道氏陶瓷技术服务有限公司 | Glaze material of high temperature fast firing crystal glaze archaized brick and preparation process thereof |
-
2013
- 2013-07-02 CN CN201310272968.5A patent/CN103332965B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102173869A (en) * | 2011-01-19 | 2011-09-07 | 江苏高淳陶瓷股份有限公司 | Preparation method of non-ferrous tea dust crystalline glaze |
| CN102173873A (en) * | 2011-01-27 | 2011-09-07 | 上海高诚艺术包装有限公司 | Transmutation glaze material and glazing process |
| CN102249739A (en) * | 2011-05-26 | 2011-11-23 | 山西高陶瓷业有限责任公司 | Preparation method of carbon-golden metallic luster crystalline glaze |
| CN102936156A (en) * | 2012-10-30 | 2013-02-20 | 佛山市道氏陶瓷技术服务有限公司 | Glaze material of high temperature fast firing crystal glaze archaized brick and preparation process thereof |
Non-Patent Citations (1)
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| 吴从若.硅酸锌基系列结晶釉试验及样品制作.《江苏陶瓷》.2001,第34卷(第4期),第15-17页. * |
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Effective date of registration: 20240115 Address after: Office Building 55, West Industrial Zone, Dapu Village, Cizao Town, Jinjiang City, Quanzhou City, Fujian Province, 362000 Patentee after: Quanzhou Omico New Material Technology Co.,Ltd. Address before: 362000 first floor, comprehensive building of advanced manufacturing technology service base, detai Road, economic and Technological Development Zone, Quanzhou City, Fujian Province Patentee before: QUANZHOU OUMIKE ECOLOGY MATERIALS TECHNOLOGY Co.,Ltd. |
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