CN109133647A - Starry sky reacts blue glaze and preparation method thereof - Google Patents

Starry sky reacts blue glaze and preparation method thereof Download PDF

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Publication number
CN109133647A
CN109133647A CN201811152921.4A CN201811152921A CN109133647A CN 109133647 A CN109133647 A CN 109133647A CN 201811152921 A CN201811152921 A CN 201811152921A CN 109133647 A CN109133647 A CN 109133647A
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parts
coat enamel
component
ground coat
glaze
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CN201811152921.4A
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CN109133647B (en
Inventor
谢泉英
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HUNAN EKA CERAMICS CO Ltd
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HUNAN EKA CERAMICS CO Ltd
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • C03C8/20Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/02Frit compositions, i.e. in a powdered or comminuted form
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/89Coating or impregnation for obtaining at least two superposed coatings having different compositions

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Structural Engineering (AREA)
  • Compositions Of Oxide Ceramics (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of starry sky to react blue glaze and preparation method thereof, starry sky reacts blue glaze and contains ground coat enamel and overglaze, the component and each component mass parts that ground coat enamel material contains used in the ground coat enamel are as follows: 40~45 parts of feldspar powder, 40~50 parts of Shi porcelain billet mud, 18~20 parts of iron oxide, 5~7 parts of manganese carbonate, 5~8 parts of wollastonite;Cobalt oxide and millesimal copper oxide that mass percent is 3/1000ths~6 are also added in the ground coat enamel material;The component and each component mass parts that glaze material used in the overglaze contains are as follows: 35~40 parts of low temperature frit, 30~35 parts of quartz calcines 25~30 parts of spodumene, 10~12 parts of calcite, 3~6 parts of Guizhou clay, 2~4 parts of Jiepai clay, 5~10 parts of calcinated talc powder, 8~12 parts of titanium dioxide.Its glaze paint generates indistinct starry sky orchid effect, looks at a glance boundless, and people is allowed to generate unlimited reverie.

Description

Starry sky reacts blue glaze and preparation method thereof
Technical field
The present invention relates to a kind of starry sky to react blue glaze and preparation method thereof.
Background technique
Currently, the moulding of porcelain billet is the basis of quality product in porcelain industry, the allotment of glaze keeps porcelain more gorgeous Colorful, the porcelain billet of same moulding often because of the difference of glaze paint, and generates different influences to the vision of consumer.
Summary of the invention
The technical problem to be solved by the present invention is to overcome the deficiencies of existing technologies, a kind of blue glaze of starry sky reaction is provided, it Glaze paint generate indistinct starry sky orchid effect, look at a glance boundless, people allowed to generate unlimited reverie.
In order to solve the above-mentioned technical problem, the technical scheme is that a kind of starry sky reacts blue glaze, it contain ground coat enamel and Overglaze, the component and each component mass parts that ground coat enamel material used in the ground coat enamel contains are as follows:
40~45 parts of feldspar powder, 40~50 parts of Shi porcelain billet mud, 18~20 parts of iron oxide, 5~7 parts of manganese carbonate, wollastonite 5~ 8 parts;Cobalt oxide and millesimal copper oxide that mass percent is 3/1000ths~6 are also added in the ground coat enamel material;
The component and each component mass parts that glaze material used in the overglaze contains are as follows:
35~40 parts of low temperature frit, 30~35 parts of quartz, 25~30 parts of spodumene of calcining, 10~12 parts of calcite, Guizhou 3~6 parts, 2~4 parts of Jiepai clay, 5~10 parts of calcinated talc powder, 8~12 parts of titanium dioxide of soil.
Further, the component of the low temperature frit and the mass parts of each component are as follows: feldspar powder: 26~30 parts;Calcite: 20~25 parts;Borax: 25~30 parts;Silica flour: 20~25 parts;Talcum powder: 20~25 parts;Potassium nitrate: 20~25 parts.
Further, the calcining spodumene is calcined using spodumene by 1350 DEG C~1400 DEG C of temperature environment.
The present invention also provides the preparation method that a kind of starry sky reacts blue glaze, the step of method in contain:
S1: ground coat enamel slurry and overglaze slurry are prepared respectively;Wherein, the preparation process that the preparation process of ground coat enamel slurry and overglaze are starched is such as Under: it stocks up respectively according to the mass parts of each component and each component;According to material: ball: mass ratio=1:1.5:0.5 of water, wet process ball Then mill 6~10 hours crosses 160 mesh screens, then be tuned into the glaze slip that concentration is 25-30 Baume degrees;
S2: ground coat enamel is applied on biscuit using ground coat enamel slurry, then spray plane glaze is starched using overglaze, enters kiln after dry, by 1160- 1200 DEG C of temperature environment burns finished product.
After above-mentioned technical proposal, starry sky glaze paint of the invention generates indistinct starry sky orchid effect, hopes at a glance It goes boundless, people is allowed to generate unlimited reverie.
Specific embodiment
In order that the present invention can be more clearly and readily understood, below according to specific embodiment, to the present invention make into One step detailed description.
Embodiment one
A kind of starry sky reacts blue glaze, it contains ground coat enamel and overglaze, ground coat enamel material contains used in the ground coat enamel component and Each component mass parts are as follows:
40 parts of feldspar powder, 40 parts of Shi porcelain billet mud, 18 parts of iron oxide, 5 parts of manganese carbonate, 5 parts of wollastonite;In the ground coat enamel material also Add cobalt oxide and millesimal copper oxide that mass percent is 3/1000ths;
The component and each component mass parts that glaze material used in the overglaze contains are as follows:
35 parts of low temperature frit, 30 parts of quartz, 25 parts of spodumene of calcining, 10 parts of calcite, 3 parts of Guizhou clay, 2 parts of Jiepai clay, 5 parts of calcinated talc powder, 8 parts of titanium dioxide.
The component of the low temperature frit and the mass parts of each component are as follows: feldspar powder: 26 parts;Calcite: 20 parts;Borax: 25 parts;Silica flour: 20 parts;Talcum powder: 20 parts;Potassium nitrate: 20 parts.
The calcining spodumene is calcined using spodumene by 1350 DEG C~1400 DEG C of temperature environment.
Contain in the step of preparation method of the blue glaze of starry sky reaction, method:
S1: ground coat enamel slurry and overglaze slurry are prepared respectively;Wherein, the preparation process that the preparation process of ground coat enamel slurry and overglaze are starched is such as Under: it stocks up respectively according to the mass parts of each component and each component;According to material: ball: mass ratio=1:1.5:0.5 of water, wet process ball Then mill 6 hours crosses 160 mesh screens, then be tuned into the glaze slip that concentration is 25-30 Baume degrees;
S2: ground coat enamel is applied on biscuit using ground coat enamel slurry, then spray plane glaze is starched using overglaze, enters kiln after dry, by 1160- 1200 DEG C of temperature environment burns finished product.
Embodiment two
A kind of starry sky reacts blue glaze, it contains ground coat enamel and overglaze, ground coat enamel material contains used in the ground coat enamel component and Each component mass parts are as follows:
45 parts of feldspar powder, 50 parts of Shi porcelain billet mud, 20 parts of iron oxide, 7 parts of manganese carbonate, 8 parts of wollastonite;In the ground coat enamel material also Add cobalt oxide and millesimal copper oxide that mass percent is 6/1000ths;
The component and each component mass parts that glaze material used in the overglaze contains are as follows:
40 parts of low temperature frit, 35 parts of quartz, 30 parts of spodumene of calcining, 12 parts of calcite, 6 parts of Guizhou clay, 4 parts of Jiepai clay, 10 parts of calcinated talc powder, 12 parts of titanium dioxide.
The component of the low temperature frit and the mass parts of each component are as follows: feldspar powder: 30 parts;Calcite: 25 parts;Borax: 30 parts;Silica flour: 25 parts;Talcum powder: 25 parts;Potassium nitrate: 25 parts.
The calcining spodumene is calcined using spodumene by 1350 DEG C~1400 DEG C of temperature environment.
Contain in the step of preparation method of the blue glaze of starry sky reaction, method:
S1: ground coat enamel slurry and overglaze slurry are prepared respectively;Wherein, the preparation process that the preparation process of ground coat enamel slurry and overglaze are starched is such as Under: it stocks up respectively according to the mass parts of each component and each component;According to material: ball: mass ratio=1:1.5:0.5 of water, wet process ball Then mill 10 hours crosses 160 mesh screens, then be tuned into the glaze slip that concentration is 25-30 Baume degrees;
S2: ground coat enamel is applied on biscuit using ground coat enamel slurry, then spray plane glaze is starched using overglaze, enters kiln after dry, by 1160- 1200 DEG C of temperature environment burns finished product.
Embodiment three
A kind of starry sky reacts blue glaze, it contains ground coat enamel and overglaze, ground coat enamel material contains used in the ground coat enamel component and Each component mass parts are as follows:
42 parts of feldspar powder, 45 parts of Shi porcelain billet mud, 19 parts of iron oxide, 6 parts of manganese carbonate, 7 parts of wollastonite;In the ground coat enamel material also Add cobalt oxide and millesimal copper oxide that mass percent is 5/1000ths;
The component and each component mass parts that glaze material used in the overglaze contains are as follows:
37 parts of low temperature frit, 32 parts of quartz, 26 parts of spodumene of calcining, 11 parts of calcite, 4 parts of Guizhou clay, 3 parts of Jiepai clay, 7 parts of calcinated talc powder, 10 parts of titanium dioxide.
The component of the low temperature frit and the mass parts of each component are as follows: feldspar powder: 27 parts;Calcite: 22 parts;Borax: 27 parts;Silica flour: 22 parts;Talcum powder: 22 parts;Potassium nitrate: 22 parts.
The calcining spodumene is calcined using spodumene by 1350 DEG C~1400 DEG C of temperature environment.
Contain in the step of preparation method of the blue glaze of starry sky reaction, method:
S1: ground coat enamel slurry and overglaze slurry are prepared respectively;Wherein, the preparation process that the preparation process of ground coat enamel slurry and overglaze are starched is such as Under: it stocks up respectively according to the mass parts of each component and each component;According to material: ball: mass ratio=1:1.5:0.5 of water, wet process ball Then mill 8 hours crosses 160 mesh screens, then be tuned into the glaze slip that concentration is 25-30 Baume degrees;
S2: ground coat enamel is applied on biscuit using ground coat enamel slurry, then spray plane glaze is starched using overglaze, enters kiln after dry, by 1160- 1200 DEG C of temperature environment burns finished product.
The starry sky that three above embodiment is prepared reacts blue glaze, and it is blue to generate indistinct starry sky on glaze surface Effect meets design requirement.
Particular embodiments described above, pair present invention solves the technical problem that, technical scheme and beneficial effects carry out It is further described, it should be understood that the above is only a specific embodiment of the present invention, is not limited to this Invention, all within the spirits and principles of the present invention, any modification, equivalent substitution, improvement and etc. done should be included in this hair Within bright protection scope.

Claims (4)

1. a kind of starry sky reacts blue glaze, it is characterised in that it contains ground coat enamel and overglaze, and ground coat enamel material used in the ground coat enamel contains Component and each component mass parts it is as follows:
40~45 parts of feldspar powder, 40~50 parts of Shi porcelain billet mud, 18~20 parts of iron oxide, 5~7 parts of manganese carbonate, 5~8 parts of wollastonite; Cobalt oxide and millesimal copper oxide that mass percent is 3/1000ths~6 are also added in the ground coat enamel material;
The component and each component mass parts that glaze material used in the overglaze contains are as follows:
35~40 parts of low temperature frit, 30~35 parts of quartz, 25~30 parts of spodumene of calcining, 10~12 parts of calcite, Guizhou clay 3~ 6 parts, 2~4 parts of Jiepai clay, 5~10 parts of calcinated talc powder, 8~12 parts of titanium dioxide.
2. starry sky according to claim 1 reacts blue glaze, it is characterised in that: the component of the low temperature frit and each component Mass parts are as follows: feldspar powder: 26~30 parts;Calcite: 20~25 parts;Borax: 25~30 parts;Silica flour: 20~25 parts;Talcum Powder: 20~25 parts;Potassium nitrate: 20~25 parts.
3. starry sky according to claim 1 reacts blue glaze, it is characterised in that: the calcining spodumene is passed through using spodumene 1350 DEG C~1400 DEG C of temperature environment is calcined.
4. the preparation method that a kind of starry sky according to any one of claims 1 to 3 reacts blue glaze, it is characterised in that method Contain in step:
S1: ground coat enamel slurry and overglaze slurry are prepared respectively;Wherein, the preparation process of ground coat enamel slurry and the preparation process of overglaze slurry are as follows: It stocks up respectively according to the mass parts of each component and each component;According to material: ball: mass ratio=1:1.5:0.5 of water, wet ball grinding 6 ~10 hours, 160 mesh screens are then crossed, then are tuned into the glaze slip that concentration is 25-30 Baume degrees;
S2: ground coat enamel is applied on biscuit using ground coat enamel slurry, then spray plane glaze is starched using overglaze, enters kiln after dry, by 1160-1200 DEG C temperature environment burn finished product.
CN201811152921.4A 2018-09-30 2018-09-30 Starry sky reaction blue glaze and preparation method thereof Active CN109133647B (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110790509A (en) * 2019-12-12 2020-02-14 醴陵市湘润陶瓷制造有限公司 Grid grain glaze and preparation method thereof
CN110790506A (en) * 2019-12-18 2020-02-14 湖南华联瓷业股份有限公司 Granular double-layer reaction glaze and preparation method thereof
CN111233331A (en) * 2020-02-25 2020-06-05 湖南省华智瓷业有限公司 Double-layer pearl reaction glaze and preparation method thereof
CN111960672A (en) * 2020-07-08 2020-11-20 湖南省醴陵市特种电瓷电器有限公司 Glaze for 95 porcelain surface, 95 porcelain and manufacturing method

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CN104529553A (en) * 2014-12-08 2015-04-22 广东宏陶陶瓷有限公司 Glazed tile manufactured by using ceramic waste and having broken diamond sand flashing starlight on surface, and preparation method thereof
CN106673438A (en) * 2016-12-28 2017-05-17 广东宏陶陶瓷有限公司 Magic star stone glazed brick with surface aventurine effect and preparation method thereof
CN108314321A (en) * 2018-02-25 2018-07-24 醴陵嘉华瓷业制造有限公司 The double-deck glaze and preparation method thereof that reaction glaze is combined with metal glaze

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RU2035411C1 (en) * 1992-07-27 1995-05-20 Дулевский красочный завод Turquoise ceramic pigment for overglazed and underglazed dyes
CN101973788A (en) * 2010-10-26 2011-02-16 陕西科技大学 Preparation method of phase-separation peacock blue glaze
CN104529553A (en) * 2014-12-08 2015-04-22 广东宏陶陶瓷有限公司 Glazed tile manufactured by using ceramic waste and having broken diamond sand flashing starlight on surface, and preparation method thereof
CN106673438A (en) * 2016-12-28 2017-05-17 广东宏陶陶瓷有限公司 Magic star stone glazed brick with surface aventurine effect and preparation method thereof
CN108314321A (en) * 2018-02-25 2018-07-24 醴陵嘉华瓷业制造有限公司 The double-deck glaze and preparation method thereof that reaction glaze is combined with metal glaze

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110790509A (en) * 2019-12-12 2020-02-14 醴陵市湘润陶瓷制造有限公司 Grid grain glaze and preparation method thereof
CN110790506A (en) * 2019-12-18 2020-02-14 湖南华联瓷业股份有限公司 Granular double-layer reaction glaze and preparation method thereof
CN111233331A (en) * 2020-02-25 2020-06-05 湖南省华智瓷业有限公司 Double-layer pearl reaction glaze and preparation method thereof
CN111960672A (en) * 2020-07-08 2020-11-20 湖南省醴陵市特种电瓷电器有限公司 Glaze for 95 porcelain surface, 95 porcelain and manufacturing method

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