CN109369012A - Furnace transmutation glaze and its preparation process - Google Patents

Furnace transmutation glaze and its preparation process Download PDF

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Publication number
CN109369012A
CN109369012A CN201811518507.0A CN201811518507A CN109369012A CN 109369012 A CN109369012 A CN 109369012A CN 201811518507 A CN201811518507 A CN 201811518507A CN 109369012 A CN109369012 A CN 109369012A
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CN
China
Prior art keywords
parts
glaze
component
furnace transmutation
frit
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811518507.0A
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Chinese (zh)
Inventor
童新田
谢少元
张支清
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HUNAN DEXING CERAMICS CO Ltd
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HUNAN DEXING CERAMICS CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by HUNAN DEXING CERAMICS CO Ltd filed Critical HUNAN DEXING CERAMICS CO Ltd
Priority to CN201811518507.0A priority Critical patent/CN109369012A/en
Publication of CN109369012A publication Critical patent/CN109369012A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/02Frit compositions, i.e. in a powdered or comminuted form
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • C03C8/18Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing free metals
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/32Burning methods
    • C04B33/34Burning methods combined with glazing
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/85Coating or impregnation with inorganic materials
    • C04B41/86Glazes; Cold glazes
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/658Atmosphere during thermal treatment
    • C04B2235/6583Oxygen containing atmosphere, e.g. with changing oxygen pressures

Abstract

The invention discloses a kind of furnace transmutation glaze and its preparation process, the component and each component mass parts contained in glaze used in furnace transmutation glaze is as follows: potassium feldspar: 20-22 parts;Albite: 20-22 parts;Quartz: 8-10 parts;Calcite: 30-32 parts;Guizhou clay: 8-10 parts;Frit: 4-5 parts;Aluminium powder: 8-10 parts;Black pigment: 10-12 parts.Glaze surface of the present invention floating is uneven, has the effect of just as chiseling and carving.

Description

Furnace transmutation glaze and its preparation process
Technical field
The present invention relates to a kind of furnace transmutation glaze and its preparation processes.
Background technique
Currently, the moulding of porcelain billet is the basis of quality product in porcelain industry, the allotment of glaze keeps porcelain more gorgeous Colorful, the porcelain billet of same moulding often because of the difference of glaze paint, and generates different influences to the vision of consumer.
Summary of the invention
The technical problem to be solved by the present invention is to overcome the deficiencies of existing technologies, a kind of furnace transmutation glaze is provided, its glaze surface Floating is uneven, has the effect of just as chiseling and carving.
In order to solve the above-mentioned technical problem, the technical scheme is that a kind of furnace transmutation glaze, contain in glaze used in it Some components and each component mass parts are as follows:
Potassium feldspar: 20-22 parts;
Albite: 20-22 parts;
Quartz: 8-10 parts;
Calcite: 30-32 parts;
Guizhou clay: 8-10 parts;
Frit: 4-5 parts;
Aluminium powder: 8-10 parts;
Black pigment: 10-12 parts.
The present invention also provides a kind of furnace transmutation glaze, the component and each component mass parts contained in glaze used in it is such as Under:
Potassium feldspar: 28-30 parts;
Quartz: 20-22 parts;
Calcite: 10-12 parts;
Guizhou clay: 6-8 parts;
Frit: 10-12 parts;
Aluminium powder: 8-10 parts;
Zirconium dioxide: 8-10 parts.
Further, the component of the frit and each component mass parts are as follows: feldspar powder: 20~25 parts;Lithium carbonate: 25 parts~ 30 parts;Borax: 20 parts~30 parts;Silica flour: 25 parts~30 parts.
The present invention also provides a kind of preparation process of furnace transmutation glaze, the step of technique in contain:
S1: it stocks up according to the component and each component mass parts of glaze;
S2: glaze: ball: mass ratio=1:1:(1.4~1.6 of water is pressed), wet ball grinding 15~18 hours, the glaze after ball milling Material is sieved and removes iron, then is tuned into the glaze slip of 40~45 Baume degrees;
S3: after the chinaware body for taking appearance bright and clean immerses the glaze slip, through being fired under 1200 DEG C -1300 DEG C of oxidizing atmospheres Product.
After above-mentioned technical proposal, using the formula of furnace transmutation glaze of the invention, after firing, surface floating is uneven, Have the effect of just as chiseling and carving.
Specific embodiment
In order that the present invention can be more clearly and readily understood, below according to specific embodiment, to the present invention make into One step detailed description.
Embodiment one
A kind of furnace transmutation glaze, the component and each component mass parts contained in glaze used in it are as follows:
Potassium feldspar: 20 parts;
Albite: 20 parts;
Quartz: 8 parts;
Calcite: 30 parts;
Guizhou clay: 8 parts;
Frit: 4 parts;
Aluminium powder: 8 parts;
Black pigment: 10 parts.
The component and each component mass parts of the frit are as follows: feldspar powder: 20 parts;Lithium carbonate: 25 parts;Borax: 20 parts;Stone Ying Fen: 25 parts.
Contain in the step of preparation process of the furnace transmutation glaze, technique:
S1: it stocks up according to the component and each component mass parts of glaze;
S2: glaze: ball: mass ratio=1:1:1.4 of water is pressed, wet ball grinding 15 hours, the glaze after ball milling was sieved and removes Iron, then it is tuned into the glaze slip of 40~45 Baume degrees;
S3: after the chinaware body for taking appearance bright and clean immerses the glaze slip, through being fired under 1200 DEG C -1300 DEG C of oxidizing atmospheres Product.
Embodiment two
A kind of furnace transmutation glaze, the component and each component mass parts contained in glaze used in it are as follows:
Potassium feldspar: 22 parts;
Albite: 22 parts;
Quartz: 10 parts;
Calcite: 32 parts;
Guizhou clay: 10 parts;
Frit: 5 parts;
Aluminium powder: 10 parts;
Black pigment: 12 parts.
The component and each component mass parts of the frit are as follows: feldspar powder: 25 parts;Lithium carbonate: 30 parts;Borax: 30 parts;Stone Ying Fen: 30 parts.
Contain in the step of preparation process of the furnace transmutation glaze, technique:
S1: it stocks up according to the component and each component mass parts of glaze;
S2: glaze: ball: mass ratio=1:1:1.6 of water is pressed, wet ball grinding 18 hours, the glaze after ball milling was sieved and removes Iron, then it is tuned into the glaze slip of 40~45 Baume degrees;
S3: after the chinaware body for taking appearance bright and clean immerses the glaze slip, through being fired under 1200 DEG C -1300 DEG C of oxidizing atmospheres Product.
Embodiment three
A kind of furnace transmutation glaze, the component and each component mass parts contained in glaze used in it are as follows:
Potassium feldspar: 21 parts;
Albite: 21 parts;
Quartz: 9 parts;
Calcite: 31 parts;
Guizhou clay: 9 parts;
Frit: 4 parts;
Aluminium powder: 9 parts;
Black pigment: 11 parts.
The component and each component mass parts of the frit are as follows: feldspar powder: 23 parts;Lithium carbonate: 26 parts;Borax: 25 parts;Stone Ying Fen: 27 parts.
Contain in the step of preparation process of the furnace transmutation glaze, technique:
S1: it stocks up according to the component and each component mass parts of glaze;
S2: glaze: ball: mass ratio=1:1:1.5 of water is pressed, wet ball grinding 16 hours, the glaze after ball milling was sieved and removes Iron, then it is tuned into the glaze slip of 40~45 Baume degrees;
S3: after the chinaware body for taking appearance bright and clean immerses the glaze slip, through being fired under 1200 DEG C -1300 DEG C of oxidizing atmospheres Product.
Example IV
A kind of furnace transmutation glaze, the component and each component mass parts contained in glaze used in it are as follows:
Potassium feldspar: 28 parts;
Quartz: 20 parts;
Calcite: 10 parts;
Guizhou clay: 6 parts;
Frit: 10 parts;
Aluminium powder: 8 parts;
Zirconium dioxide: 8 parts.
The component and each component mass parts of the frit are as follows: feldspar powder: 20 parts;Lithium carbonate: 25 parts;Borax: 20 parts;Stone Ying Fen: 25 parts.
Contain in the step of preparation process of the furnace transmutation glaze, technique:
S1: it stocks up according to the component and each component mass parts of glaze;
S2: glaze: ball: mass ratio=1:1:1.4 of water is pressed, wet ball grinding 15 hours, the glaze after ball milling was sieved and removes Iron, then it is tuned into the glaze slip of 40~45 Baume degrees;
S3: after the chinaware body for taking appearance bright and clean immerses the glaze slip, through being fired under 1200 DEG C -1300 DEG C of oxidizing atmospheres Product.
Embodiment five
A kind of furnace transmutation glaze, the component and each component mass parts contained in glaze used in it are as follows:
Potassium feldspar: 30 parts;
Quartz: 22 parts;
Calcite: 12 parts;
Guizhou clay: 8 parts;
Frit: 12 parts;
Aluminium powder: 10 parts;
Zirconium dioxide: 10 parts.
The component and each component mass parts of the frit are as follows: feldspar powder: 25 parts;Lithium carbonate: 30 parts;Borax: 30 parts;Stone Ying Fen: 30 parts.
Contain in the step of preparation process of the furnace transmutation glaze, technique:
S1: it stocks up according to the component and each component mass parts of glaze;
S2: glaze: ball: mass ratio=1:1:1.6 of water is pressed, wet ball grinding 18 hours, the glaze after ball milling was sieved and removes Iron, then it is tuned into the glaze slip of 40~45 Baume degrees;
S3: after the chinaware body for taking appearance bright and clean immerses the glaze slip, through being fired under 1200 DEG C -1300 DEG C of oxidizing atmospheres Product.
Embodiment six
A kind of furnace transmutation glaze, the component and each component mass parts contained in glaze used in it are as follows:
Potassium feldspar: 29 parts;
Quartz: 21 parts;
Calcite: 11 parts;
Guizhou clay: 7 parts;
Frit: 11 parts;
Aluminium powder: 9 parts;
Zirconium dioxide: 9 parts.
The component and each component mass parts of the frit are as follows: feldspar powder: 22 parts;Lithium carbonate: 27 parts;Borax: 25 parts;Stone Ying Fen: 27 parts.
Contain in the step of preparation process of the furnace transmutation glaze, technique:
S1: it stocks up according to the component and each component mass parts of glaze;
S2: glaze: ball: mass ratio=1:1:1.5 of water is pressed, wet ball grinding 18 hours, the glaze after ball milling was sieved and removes Iron, then it is tuned into the glaze slip of 40~45 Baume degrees;
S3: after the chinaware body for taking appearance bright and clean immerses the glaze slip, through being fired under 1200 DEG C -1300 DEG C of oxidizing atmospheres Product.
The furnace transmutation glaze that above six embodiments are prepared, by it has been observed that the equal floating injustice of its glaze paint, all has shape With the effect chiseled and carved, meet design requirement.
Particular embodiments described above, pair present invention solves the technical problem that, technical scheme and beneficial effects carry out It is further described, it should be understood that the above is only a specific embodiment of the present invention, is not limited to this Invention, all within the spirits and principles of the present invention, any modification, equivalent substitution, improvement and etc. done should be included in this hair Within bright protection scope.

Claims (4)

1. a kind of furnace transmutation glaze, which is characterized in that the component and each component mass parts contained in glaze used in it is as follows:
Potassium feldspar: 20-22 parts;
Albite: 20-22 parts;
Quartz: 8-10 parts;
Calcite: 30-32 parts;
Guizhou clay: 8-10 parts;
Frit: 4-5 parts;
Aluminium powder: 8-10 parts;
Black pigment: 10-12 parts.
2. a kind of furnace transmutation glaze, which is characterized in that the component and each component mass parts contained in glaze used in it is as follows:
Potassium feldspar: 28-30 parts;
Quartz: 20-22 parts;
Calcite: 10-12 parts;
Guizhou clay: 6-8 parts;
Frit: 10-12 parts;
Aluminium powder: 8-10 parts;
Zirconium dioxide: 8-10 parts.
3. furnace transmutation glaze according to claim 1 or 2, it is characterised in that: the component and each component mass parts of the frit are such as Under: feldspar powder: 20~25 parts;Lithium carbonate: 25 parts~30 parts;Borax: 20 parts~30 parts;Silica flour: 25 parts~30 parts.
4. a kind of preparation process of the furnace transmutation glaze as described in claims 1 or 2 or 3, it is characterised in that: contain in the step of technique Have:
S1: it stocks up according to the component and each component mass parts of glaze;
S2: glaze: ball: mass ratio=1:1:(1.4~1.6 of water is pressed), wet ball grinding 15~18 hours, the glaze mistake after ball milling It sieves and removes iron, then be tuned into the glaze slip of 40~45 Baume degrees;
S3: after the chinaware body for taking appearance bright and clean immerses the glaze slip, through firing finished product under 1200 DEG C -1300 DEG C of oxidizing atmospheres.
CN201811518507.0A 2018-12-12 2018-12-12 Furnace transmutation glaze and its preparation process Pending CN109369012A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
CN201811518507.0A CN109369012A (en) 2018-12-12 2018-12-12 Furnace transmutation glaze and its preparation process

Publications (1)

Publication Number Publication Date
CN109369012A true CN109369012A (en) 2019-02-22

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110790509A (en) * 2019-12-12 2020-02-14 醴陵市湘润陶瓷制造有限公司 Grid grain glaze and preparation method thereof
CN110937814A (en) * 2019-12-12 2020-03-31 醴陵市湘润陶瓷制造有限公司 Matte color transmutation glaze and preparation method thereof
CN111233332A (en) * 2020-03-02 2020-06-05 醴陵玉茶瓷业有限公司 Combined glaze for teabowl and preparation method thereof
CN113979638A (en) * 2021-11-19 2022-01-28 醴陵市观前瓷业有限公司 Preparation method of protruded blood vessel-shaped transmutation glaze and transmutation glaze porcelain

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103274600A (en) * 2013-05-24 2013-09-04 醴陵陶润实业发展有限公司 Decoration production method capable of producing concave-convex relief on glaze and glaze material adopted by same
CN108911509A (en) * 2018-07-14 2018-11-30 醴陵陶润实业发展有限公司 Transmutation coper green glaze and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103274600A (en) * 2013-05-24 2013-09-04 醴陵陶润实业发展有限公司 Decoration production method capable of producing concave-convex relief on glaze and glaze material adopted by same
CN108911509A (en) * 2018-07-14 2018-11-30 醴陵陶润实业发展有限公司 Transmutation coper green glaze and preparation method thereof

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110790509A (en) * 2019-12-12 2020-02-14 醴陵市湘润陶瓷制造有限公司 Grid grain glaze and preparation method thereof
CN110937814A (en) * 2019-12-12 2020-03-31 醴陵市湘润陶瓷制造有限公司 Matte color transmutation glaze and preparation method thereof
CN111233332A (en) * 2020-03-02 2020-06-05 醴陵玉茶瓷业有限公司 Combined glaze for teabowl and preparation method thereof
CN113979638A (en) * 2021-11-19 2022-01-28 醴陵市观前瓷业有限公司 Preparation method of protruded blood vessel-shaped transmutation glaze and transmutation glaze porcelain

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Application publication date: 20190222