CN108314321A - The double-deck glaze and preparation method thereof that reaction glaze is combined with metal glaze - Google Patents

The double-deck glaze and preparation method thereof that reaction glaze is combined with metal glaze Download PDF

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Publication number
CN108314321A
CN108314321A CN201810158027.1A CN201810158027A CN108314321A CN 108314321 A CN108314321 A CN 108314321A CN 201810158027 A CN201810158027 A CN 201810158027A CN 108314321 A CN108314321 A CN 108314321A
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China
Prior art keywords
glaze
parts
metal
slurry
reaction
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CN201810158027.1A
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Chinese (zh)
Inventor
朱道林
徐冬其
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Liling Jiahua Ceramic Industry Manufacturing Co Ltd
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Liling Jiahua Ceramic Industry Manufacturing Co Ltd
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Priority to CN201810158027.1A priority Critical patent/CN108314321A/en
Publication of CN108314321A publication Critical patent/CN108314321A/en
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • C03C8/18Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing free metals
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/89Coating or impregnation for obtaining at least two superposed coatings having different compositions

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Structural Engineering (AREA)
  • Glass Compositions (AREA)

Abstract

The invention discloses a kind of double-deck glaze and preparation method thereof that reaction glaze is combined with metal glaze, containing reaction glaze and metal glaze ground-coat enamel material in glaze used in the double-deck glaze that reaction glaze is combined with metal glaze;Wherein, the component and each component mass parts that the reaction glaze contains are as follows:High boron frit:30 parts;Spodumene:30 parts;Quartz:28 parts;Calcite:10 parts;Zinc oxide:10 parts;Reactant:10 parts;Talcum:5 parts;Guizhou clay:3 parts;Iron oxide red:3 parts;Manganese powder:3 parts;The component and each component mass parts that the metal glaze ground-coat enamel material contains are as follows:Iron powder:35 parts;Metal flux:20 parts;Albite:30 parts;Spodumene:15 parts;Quartz:8 parts;Guizhou clay:2 parts;Wash mud:10 parts.The glaze of the present invention does not contain lead, and more environmentally friendly, color is gorgeous, deep to be liked by client.

Description

Double-layer glaze combining reaction glaze and metal glaze and preparation method thereof
Technical Field
The invention relates to a double-layer glaze combining reaction glaze and metal glaze and a preparation method thereof.
Background
At present, the color of the whole body of the dish product in the prior art is single, along with the improvement of the living level of people and the requirement on the living environment, the glaze of the dish product has higher decoration requirement, and because the metal decoration material has elegant and luxurious artistic effect, the glaze with metal luster is more and more popular. At present, three manufacturing methods for realizing the metallic luster glaze are available: 1 directly sputtering a molten metal coating on the blank; 2. coating a coat containing metal or metal compound powder on the glaze surface of the product, and performing reduction heat treatment to form a metallized decorative layer; 3. preparing glaze components with specific compositions, and firing to produce the metal luster imitating glaze with similar appearance of metal luster such as color tone, luster and the like. The first two technologies have high requirements on equipment and high decoration cost: in the third method, by preparing glaze components, the glaze with the metallization effect is directly formed without changing the firing system of the existing tunnel kiln. At present, the glaze is only applied to wall and floor tiles, and batch production is not seen in the field of dish products; similar studies are not ideal and the main problems are: 1. the metallic effect of the glaze is not particularly outstanding; 2. the wear resistance and corrosion resistance of the metal glaze surface are not related; 3. lead is generally used for preparing the glaze, so that the lead content of the glaze surface exceeds the standard, and the health of a human body is influenced when the glaze is used; 4. the glaze has more defects of pinholes and brown eyes.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provide the double-layer glaze combining the reaction glaze and the metal glaze, and the glaze surface of the double-layer glaze does not contain lead, is relatively environment-friendly and bright in color and is deeply favored by customers.
In order to solve the technical problems, the technical scheme of the invention is as follows: a reaction glaze and metal glaze combined double-layer glaze, wherein the glaze used in the double-layer glaze comprises a reaction glaze material and a metal glaze bottom glaze material; wherein,
the reaction glaze material comprises the following components in parts by mass:
high boron frit: 30 parts of (1);
spodumene: 30 parts of (1);
quartz: 28 parts of (1);
calcite: 10 portions of
Zinc oxide: 10 parts of (A);
the reaction agent: 10 parts of (A);
talc: 5 parts of a mixture;
guizhou soil: 3 parts of a mixture;
iron oxide red: 3 parts of a mixture;
manganese powder: 3 parts of a mixture;
the metal glaze bottom glaze material comprises the following components in parts by mass:
iron powder: 35 parts of (B);
metal flux: 20 parts of (1);
albite: 30 parts of (1);
spodumene: 15 parts of (1);
quartz: 8 parts of a mixture;
guizhou soil: 2 parts of (1);
washing mud: 10 parts.
Further, the reactant is rutile titanium dioxide.
The invention also provides a preparation method of the double-layer glaze combining the reaction glaze and the metal glaze, which comprises the following steps:
s1: respectively preparing surface glaze slurry and bottom glaze slurry; wherein the overglaze slurry is made of reactive glaze; the ground glaze slurry is made of metal ground glaze;
s2: taking a clean blank body and applying bottom glaze slurry;
s3: after the bottom glaze slurry is dried, applying surface glaze slurry;
s4: and firing the blank body coated with the overglaze slurry at 1170-1200 ℃.
Further, a method for preparing the cover slip is provided, in step S1, the method for preparing the cover slip is as follows:
preparing materials according to the components and all components of the reactive glaze;
according to the material: ball: and (3) performing wet ball milling for 12-18 hours with the mass ratio of water being 1:2:0.7, then sieving with a 250-mesh sieve, and modulating to 47-49 Baume degrees to obtain the surface glaze slurry.
Further provides a method for preparing the ground glaze slip, in step S1, the method for preparing the ground glaze slip comprises the following steps:
preparing materials according to the components of the metal glaze bottom glaze and each component;
according to the material: ball: and (3) performing wet ball milling for 12-15 hours with the mass ratio of water being 1:2:0.8, then sieving with a 250-mesh sieve, and modulating to 42-47 Baume degrees to obtain the final glaze slurry.
After the technical scheme is adopted, the metal glaze bottom glaze material adopted by the invention is the lead-free metal glaze, is relatively environment-friendly, is widely suitable for the production of household porcelain, has the sintering temperature lower than that of the traditional metal glaze, and is titanium crystal as the reaction glaze material, so that the prepared glaze is bright in color and is deeply favored by customers.
Detailed Description
In order that the present invention may be more clearly understood, the following detailed description of the present invention is given with reference to specific examples.
Example one
A reaction glaze and metal glaze combined double-layer glaze, wherein the glaze used in the double-layer glaze comprises a reaction glaze material and a metal glaze bottom glaze material; wherein,
the reaction glaze material comprises the following components in parts by mass:
high boron frit: 30 parts of (1);
spodumene: 30 parts of (1);
quartz: 28 parts of (1);
calcite: 10 portions of
Zinc oxide: 10 parts of (A);
the reaction agent: 10 parts of (A);
talc: 5 parts of a mixture;
guizhou soil: 3 parts of a mixture;
iron oxide red: 3 parts of a mixture;
manganese powder: 3 parts of a mixture;
the metal glaze bottom glaze material comprises the following components in parts by mass:
iron powder: 35 parts of (B);
metal flux: 20 parts of (1);
albite: 30 parts of (1);
spodumene: 15 parts of (1);
quartz: 8 parts of a mixture;
guizhou soil: 2 parts of (1);
washing mud: 10 parts.
The reactant is rutile titanium dioxide.
The preparation method of the double-layer glaze combining the reaction glaze and the metal glaze comprises the following steps:
s1: respectively preparing surface glaze slurry and bottom glaze slurry; wherein the overglaze slurry is made of reactive glaze; the ground glaze slurry is made of metal ground glaze;
s2: taking a clean blank body and applying bottom glaze slurry;
s3: after the bottom glaze slurry is dried, applying surface glaze slurry;
s4: and firing the blank body coated with the overglaze slurry at 1180 ℃.
In step S1, the cover slip is prepared as follows:
preparing materials according to the components and all components of the reactive glaze;
according to the material: ball: and (3) performing wet ball milling for 13 hours with the mass ratio of water being 1:2:0.7, then sieving with a 250-mesh sieve, and modulating to 47 Baume degrees to obtain the overglaze slurry.
In step S1, the method of preparing the glaze slurry is as follows:
preparing materials according to the components of the metal glaze bottom glaze and each component;
according to the material: ball: and (3) performing wet ball milling for 12 hours when the mass ratio of water is 1:2:0.8, then sieving by a 250-mesh sieve, and modulating to 42 Baume degrees to obtain the glaze slip.
Example two
The formula components of the reaction glaze and metal glaze combined double-layer glaze of the embodiment are the same as those in the first embodiment.
The preparation method of the double-layer glaze combining the reaction glaze and the metal glaze of the embodiment comprises the following steps:
s1: respectively preparing surface glaze slurry and bottom glaze slurry; wherein the overglaze slurry is made of reactive glaze; the ground glaze slurry is made of metal ground glaze;
s2: taking a clean blank body and applying bottom glaze slurry;
s3: applying the bottom glaze slurry after the bottom glaze slurry is dried;
s4: and firing the blank body coated with the ground glaze slurry at the temperature of 1190 ℃.
In step S1, the cover slip is prepared as follows:
preparing materials according to the components and all components of the reactive glaze;
according to the material: ball: and (3) performing wet ball milling for 17 hours with the mass ratio of water being 1:2:0.7, then sieving with a 250-mesh sieve, and modulating to 48 Baume degrees to obtain the overglaze slurry.
In step S1, the method of preparing the glaze slurry is as follows:
preparing materials according to the components of the metal glaze bottom glaze and each component;
according to the material: ball: and (3) performing wet ball milling for 13 hours when the mass ratio of water is 1:2:0.8, then sieving by a 250-mesh sieve, and modulating to 47 Baume degrees to obtain the glaze slip.
EXAMPLE III
The formula components of the reaction glaze and metal glaze combined double-layer glaze of the embodiment are the same as those in the first embodiment.
The preparation method of the double-layer glaze combining the reaction glaze and the metal glaze of the embodiment comprises the following steps:
s1: respectively preparing surface glaze slurry and bottom glaze slurry; wherein the overglaze slurry is made of reactive glaze; the ground glaze slurry is made of metal ground glaze;
s2: taking a clean blank body and applying bottom glaze slurry;
s3: applying the bottom glaze slurry after the bottom glaze slurry is dried;
s4: and firing the blank body coated with the ground glaze slurry at the temperature of 1170 ℃ to obtain the finished product.
In step S1, the cover slip is prepared as follows:
preparing materials according to the components and all components of the reactive glaze;
according to the material: ball: and (3) performing wet ball milling for 16 hours with the mass ratio of water being 1:2:0.7, then sieving with a 250-mesh sieve, and modulating to 48 Baume degrees to obtain the overglaze slurry.
In step S1, the method of preparing the glaze slurry is as follows:
preparing materials according to the components of the metal glaze bottom glaze and each component;
according to the material: ball: and (3) performing wet ball milling for 14 hours when the mass ratio of water is 1:2:0.8, then sieving by a 250-mesh sieve, and modulating to 45 Baume degrees to obtain the glaze slip.
The observation shows that the product of the double-layer glaze prepared by the three embodiments has bright color and meets the design requirements.
The above embodiments are described in further detail to solve the technical problems, technical solutions and advantages of the present invention, and it should be understood that the above embodiments are only examples of the present invention and are not intended to limit the present invention, and any modifications, equivalent substitutions, improvements and the like made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (5)

1. A reaction glaze and metal glaze combined double-layer glaze is characterized in that the glaze used in the reaction glaze and metal glaze combined double-layer glaze contains a reaction glaze material and a metal glaze bottom glaze material; wherein,
the reaction glaze material comprises the following components in parts by mass:
high boron frit: 30 parts of (1);
spodumene: 30 parts of (1);
quartz: 28 parts of (1);
calcite: 10 portions of
Zinc oxide: 10 parts of (A);
the reaction agent: 10 parts of (A);
talc: 5 parts of a mixture;
guizhou soil: 3 parts of a mixture;
iron oxide red: 3 parts of a mixture;
manganese powder: 3 parts of a mixture;
the metal glaze bottom glaze material comprises the following components in parts by mass:
iron powder: 35 parts of (B);
metal flux: 20 parts of (1);
albite: 30 parts of (1);
spodumene: 15 parts of (1);
quartz: 8 parts of a mixture;
guizhou soil: 2 parts of (1);
washing mud: 10 parts.
2. The reactive glaze-metal glaze combined double-layer glaze according to claim 1, wherein: the reactant is rutile titanium dioxide.
3. A process for the preparation of a double-layer glaze of the reactive glaze according to claim 1 or 2 in combination with a metallic glaze, characterized in that it comprises the steps of:
s1: respectively preparing surface glaze slurry and bottom glaze slurry; wherein the overglaze slurry is made of reactive glaze; the ground glaze slurry is made of metal ground glaze;
s2: taking a clean blank body and applying bottom glaze slurry;
s3: after the bottom glaze slurry is dried, applying surface glaze slurry;
s4: and firing the blank body coated with the overglaze slurry at 1170-1200 ℃.
4. The production method according to claim 3, characterized in that: in step S1, the cover slip is prepared as follows:
preparing materials according to the components and all components of the reactive glaze;
according to the material: ball: and (3) performing wet ball milling for 12-18 hours with the mass ratio of water being 1:2:0.7, then sieving with a 250-mesh sieve, and modulating to 47-49 Baume degrees to obtain the surface glaze slurry.
5. The production method according to claim 3, characterized in that: in step S1, the method of preparing the glaze slurry is as follows:
preparing materials according to the components of the metal glaze bottom glaze and each component;
according to the material: ball: and (3) performing wet ball milling for 12-15 hours with the mass ratio of water being 1:2:0.8, then sieving with a 250-mesh sieve, and modulating to 42-47 Baume degrees to obtain the final glaze slurry.
CN201810158027.1A 2018-02-25 2018-02-25 The double-deck glaze and preparation method thereof that reaction glaze is combined with metal glaze Pending CN108314321A (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108975699A (en) * 2018-08-17 2018-12-11 湖南德兴瓷业有限公司 Furnace transmutation glaze and preparation method thereof
CN109133647A (en) * 2018-09-30 2019-01-04 湖南益嘉瓷业有限公司 Starry sky reacts blue glaze and preparation method thereof
CN110790506A (en) * 2019-12-18 2020-02-14 湖南华联瓷业股份有限公司 Granular double-layer reaction glaze and preparation method thereof
CN111170635A (en) * 2020-01-14 2020-05-19 湖南泰鑫瓷业有限公司 Matt reaction glaze with metallic luster and preparation method thereof
CN111233330A (en) * 2020-02-21 2020-06-05 醴陵嘉诚陶瓷有限公司 Corrosion glaze and preparation method thereof
CN111453992A (en) * 2020-03-18 2020-07-28 湖南陶润会文化传播有限公司 Refractory mortar titanium dioxide reaction glaze and preparation method thereof
CN113429221A (en) * 2021-07-28 2021-09-24 广东中印陶瓷科技有限公司 Antibacterial wear-resistant glaze and preparation method thereof
CN113547869A (en) * 2021-08-04 2021-10-26 德化县新佳兴印刷有限公司 In-glaze color paper and preparation method thereof
CN114716147A (en) * 2022-04-21 2022-07-08 醴陵千汇实业有限公司 Crocodile skin-imitated glaze material formed by organic matter and preparation process thereof

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JPS56149342A (en) * 1980-04-19 1981-11-19 Nippon Fueroo Kk Low-alkali frit for enamel
KR20040102658A (en) * 2003-05-28 2004-12-08 김진학 Enamel composition for forming water drops on surface of pottery and thereof making method for pottery using the said enamel composition
CN1789205A (en) * 2005-12-23 2006-06-21 胡武强 Ceramic glaze material and method for burning ceramic glaze
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CN105753515A (en) * 2016-04-01 2016-07-13 江苏高淳陶瓷股份有限公司 Preparation method of speckled glaze
CN106045576A (en) * 2016-05-28 2016-10-26 湖南省醴陵市楚华陶瓷实业有限公司 Sand glaze and preparation method thereof
CN106242290A (en) * 2016-08-26 2016-12-21 德化县如瓷生活文化有限公司 Ferrimanganic rust glaze porcelain and processing technology thereof

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JPS56149342A (en) * 1980-04-19 1981-11-19 Nippon Fueroo Kk Low-alkali frit for enamel
KR20040102658A (en) * 2003-05-28 2004-12-08 김진학 Enamel composition for forming water drops on surface of pottery and thereof making method for pottery using the said enamel composition
CN1789205A (en) * 2005-12-23 2006-06-21 胡武强 Ceramic glaze material and method for burning ceramic glaze
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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108975699A (en) * 2018-08-17 2018-12-11 湖南德兴瓷业有限公司 Furnace transmutation glaze and preparation method thereof
CN109133647A (en) * 2018-09-30 2019-01-04 湖南益嘉瓷业有限公司 Starry sky reacts blue glaze and preparation method thereof
CN110790506A (en) * 2019-12-18 2020-02-14 湖南华联瓷业股份有限公司 Granular double-layer reaction glaze and preparation method thereof
CN111170635A (en) * 2020-01-14 2020-05-19 湖南泰鑫瓷业有限公司 Matt reaction glaze with metallic luster and preparation method thereof
CN111233330A (en) * 2020-02-21 2020-06-05 醴陵嘉诚陶瓷有限公司 Corrosion glaze and preparation method thereof
CN111453992A (en) * 2020-03-18 2020-07-28 湖南陶润会文化传播有限公司 Refractory mortar titanium dioxide reaction glaze and preparation method thereof
CN113429221A (en) * 2021-07-28 2021-09-24 广东中印陶瓷科技有限公司 Antibacterial wear-resistant glaze and preparation method thereof
CN113547869A (en) * 2021-08-04 2021-10-26 德化县新佳兴印刷有限公司 In-glaze color paper and preparation method thereof
CN114716147A (en) * 2022-04-21 2022-07-08 醴陵千汇实业有限公司 Crocodile skin-imitated glaze material formed by organic matter and preparation process thereof
CN114716147B (en) * 2022-04-21 2023-11-21 醴陵千汇实业有限公司 Crocodile-like Pi Youliao formed by organic matters and preparation process thereof

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Application publication date: 20180724