CN111453992A - Refractory mortar titanium dioxide reaction glaze and preparation method thereof - Google Patents
Refractory mortar titanium dioxide reaction glaze and preparation method thereof Download PDFInfo
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- CN111453992A CN111453992A CN202010189042.XA CN202010189042A CN111453992A CN 111453992 A CN111453992 A CN 111453992A CN 202010189042 A CN202010189042 A CN 202010189042A CN 111453992 A CN111453992 A CN 111453992A
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- glaze
- titanium dioxide
- dioxide reaction
- refractory mortar
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
The invention discloses a refractory clay titanium dioxide reaction glaze, which comprises the following components in parts by mass: 50-60 parts of spodumene; 8-13 parts of dolomite; 5-10 parts of calcite; 2-3 parts of lithium carbonate; 4-6 parts of titanium oxide; 5-7 parts of barium carbonate. The glaze has high heat resistance by matching with refractory clay, can be directly made on refractory ceramics, is directly baked to 500 ℃ on open fire and is directly added with cold water without cracking, and the series of products have very excellent thermal shock resistance and are suitable for cooking soup, cooking noodles and the like in daily life.
Description
Technical Field
The invention relates to a refractory mortar titanium dioxide reaction glaze and a preparation method thereof.
Background
At present, in the lithium porcelain industry, common matte glaze is mainly used, the lithium porcelain product without reaction property is more available in the market, and the lithium oxide content is high, so that the adjustable method is few.
Disclosure of Invention
The technical problem to be solved by the invention is to overcome the defects of the prior art, and provide a refractory clay titanium dioxide reaction glaze, which is matched with refractory clay to ensure that the product has high heat resistance, the glaze can be directly made on refractory ceramic, cold water is directly added without cracking when the glaze is baked to 500 ℃ on open fire, and the series of products have very excellent thermal shock resistance and are suitable for cooking soup, boiling noodles and the like in daily life.
In order to solve the technical problems, the technical scheme of the invention is as follows: the refractory mortar titanium dioxide reaction glaze comprises the following components in parts by mass:
50-60 parts of spodumene; 8-13 parts of dolomite; 5-10 parts of calcite; 2-3 parts of lithium carbonate; 4-6 parts of titanium oxide; 5-7 parts of barium carbonate.
The invention also provides a preparation method of the refractory mortar titanium dioxide reaction glaze, which comprises the following steps:
preparing the components according to the mass parts of the components;
according to the reference: ball: the mass ratio of water is 1:1.6:0.7, wet ball milling is carried out for 12-14 hours, the ball-milled glaze passes through a 160-mesh sieve, and glaze slurry with the Baume degree of 51-53 is prepared for later use;
taking a clean blank body, and spraying glaze slurry;
and firing the blank body sprayed with the glaze slip in a drawer kiln at 1290 ℃.
After the technical scheme is adopted, the product prepared by the formula of the reaction glaze and the high-lithium refractory clay has high heat resistance, the glaze-prepared refractory ceramic can be directly baked on open fire to 500 ℃ and directly added with cold water without cracking, and the series of products have very excellent thermal shock resistance and are suitable for cooking soup, cooking noodles and the like in daily life.
Detailed Description
The invention provides a refractory mortar titanium dioxide reaction glaze and a preparation method thereof, and a person skilled in the art can appropriately improve process parameters by referring to the content. It is expressly intended that all such similar substitutes and modifications apparent to those skilled in the art are deemed to be within the scope of the invention. While the methods and applications of this invention have been described in terms of preferred embodiments, it will be apparent to those of ordinary skill in the art that variations and modifications in the methods and applications described herein, as well as other suitable variations and combinations, may be made to implement and use the techniques of this invention without departing from the spirit and scope of the invention.
The refractory mortar titanium dioxide reaction glaze comprises the following components in parts by mass:
50-60 parts of spodumene; 8-13 parts of dolomite; 5-10 parts of calcite; 2-3 parts of lithium carbonate; 4-6 parts of titanium oxide; 5-7 parts of barium carbonate.
The preparation method of the refractory mortar titanium dioxide reaction glaze comprises the following steps:
preparing the components according to the mass parts of the components;
according to the reference: ball: the mass ratio of water is 1:1.6:0.7, wet ball milling is carried out for 12-14 hours, the ball-milled glaze passes through a 160-mesh sieve, and glaze slurry with the Baume degree of 51-53 is prepared for later use;
taking a clean blank body, and spraying glaze slurry;
and firing the blank body sprayed with the glaze slip in a drawer kiln at 1290 ℃.
The product prepared by the formula of the reaction glaze and the high-lithium refractory clay has high heat resistance, can be directly baked to 500 ℃ on open fire and directly added with cold water without cracking, has very excellent thermal shock resistance, and is suitable for cooking soup, boiling noodles and the like in daily life.
In order that the present invention may be more clearly understood, the following detailed description of the present invention is given with reference to specific examples.
Comparative example 1
The refractory mortar titanium dioxide reaction glaze comprises the following components in parts by mass:
30 parts of spodumene; potassium feldspar: 15 parts of dolomite and 13 parts of dolomite; 10 parts of calcite; 4 parts of titanium oxide; and 5 parts of barium carbonate.
The preparation method of the refractory mortar titanium dioxide reaction glaze comprises the following steps:
preparing the components according to the mass parts of the components;
according to the reference: ball: the mass ratio of water is 1:1.6:0.7, wet ball milling is carried out for 12-14 hours, the ball-milled glaze passes through a 160-mesh sieve, and glaze slurry with the Baume degree of 51-53 is prepared for later use;
taking a clean blank body, and spraying glaze slurry;
and firing the blank body sprayed with the glaze slip in a drawer kiln at 1290 ℃.
The product prepared by the glaze formula of the comparative example has cracks, and the product does not crack when being added into cold water after being dried and burned to 200 ℃ by open fire, but the product has water seepage caused by the surface cracks.
Comparative example No. two
The refractory mortar titanium dioxide reaction glaze comprises the following components in parts by mass:
70 parts of spodumene; 8 parts of dolomite; 5 parts of calcite; 2 parts of lithium carbonate; 4 parts of titanium oxide; and 5 parts of barium carbonate.
The glaze surface of the product fired by the glaze formula of the comparative example II has pinhole, and the product is not cracked when being added into cold water after being dried and burned to 500 ℃ by open fire.
Example one
The refractory mortar titanium dioxide reaction glaze comprises the following components in parts by mass:
50 parts of spodumene; 8 parts of dolomite; 5 parts of calcite; 2 parts of lithium carbonate; 4 parts of titanium oxide; and 5 parts of barium carbonate.
The preparation method of the refractory mortar titanium dioxide reaction glaze comprises the following steps:
preparing the components according to the mass parts of the components;
according to the reference: ball: the mass ratio of water is 1:1.6:0.7, ball milling is carried out for 12 hours by a wet method, the ball milled glaze passes through a 160-mesh sieve, and glaze slurry with the Baume degree of 51-53 is prepared for standby;
taking a clean blank body, and spraying glaze slurry;
and firing the blank body sprayed with the glaze slip in a drawer kiln at 1290 ℃.
Example two
The refractory mortar titanium dioxide reaction glaze comprises the following components in parts by mass:
60 parts of spodumene; 13 parts of dolomite; 10 parts of calcite; 3 parts of lithium carbonate; 6 parts of titanium oxide; and 7 parts of barium carbonate.
The preparation method of the refractory mortar titanium dioxide reaction glaze comprises the following steps:
preparing the components according to the mass parts of the components;
according to the reference: ball: the mass ratio of water is 1:1.6:0.7, the wet ball milling is carried out for 14 hours, the ball milled glaze is sieved by a 160-mesh sieve, and the glaze slurry with the Baume degree of 51-53 is prepared for standby;
taking a clean blank body, and spraying glaze slurry;
and firing the blank body sprayed with the glaze slip in a drawer kiln at 1290 ℃.
EXAMPLE III
The refractory mortar titanium dioxide reaction glaze comprises the following components in parts by mass:
55 parts of spodumene; 10 parts of dolomite; 7 parts of calcite; 2 parts of lithium carbonate; 5 parts of titanium oxide; 6 parts of barium carbonate.
The preparation method of the refractory mortar titanium dioxide reaction glaze comprises the following steps:
preparing the components according to the mass parts of the components;
according to the reference: ball: the mass ratio of water is 1:1.6:0.7, ball milling is carried out for 13 hours by a wet method, the ball milled glaze is sieved by a 160-mesh sieve, and glaze slip with 51-53 Baume degrees is prepared for standby;
taking a clean blank body, and spraying glaze slurry;
and firing the blank body sprayed with the glaze slip in a drawer kiln at 1290 ℃.
The glaze surface of the product fired by the glaze formula of the three embodiments has no pinhole, is not cracked when being added into cold water after being dried and fired by open fire to 500 ℃, has no crack on the surface after being repeatedly tested for 20 times, does not seep water, and meets the design requirement.
The above embodiments are described in further detail to solve the technical problems, technical solutions and advantages of the present invention, and it should be understood that the above embodiments are only examples of the present invention and are not intended to limit the present invention, and any modifications, equivalent substitutions, improvements and the like made within the spirit and principle of the present invention should be included in the protection scope of the present invention.
Claims (2)
1. The refractory mortar titanium dioxide reaction glaze is characterized in that the glaze used by the refractory mortar titanium dioxide reaction glaze comprises the following components in parts by mass:
50-60 parts of spodumene; 8-13 parts of dolomite; 5-10 parts of calcite; 2-3 parts of lithium carbonate; 4-6 parts of titanium oxide; 5-7 parts of barium carbonate.
2. The method for preparing the refractory mortar titanium dioxide reaction glaze according to claim 1, which is characterized by comprising the following steps:
preparing the components according to the mass parts of the components;
according to the reference: ball: the mass ratio of water is 1:1.6:0.7, wet ball milling is carried out for 12-14 hours, the ball-milled glaze passes through a 160-mesh sieve, and glaze slurry with the Baume degree of 51-53 is prepared for later use;
taking a clean blank body, and spraying glaze slurry;
and firing the blank body sprayed with the glaze slip in a drawer kiln at 1290 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010189042.XA CN111453992A (en) | 2020-03-18 | 2020-03-18 | Refractory mortar titanium dioxide reaction glaze and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010189042.XA CN111453992A (en) | 2020-03-18 | 2020-03-18 | Refractory mortar titanium dioxide reaction glaze and preparation method thereof |
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| CN111453992A true CN111453992A (en) | 2020-07-28 |
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| CN101659567A (en) * | 2009-09-04 | 2010-03-03 | 黄建平 | Furnace transmutation decoration glazed brick and production technology |
| CN101857373A (en) * | 2010-06-03 | 2010-10-13 | 香港福山实业有限公司 | Microcrystal glass tube and preparation method thereof |
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Application publication date: 20200728 |
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