CN101659567A - Furnace transmutation decoration glazed brick and production technology - Google Patents
Furnace transmutation decoration glazed brick and production technology Download PDFInfo
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- CN101659567A CN101659567A CN200910192069A CN200910192069A CN101659567A CN 101659567 A CN101659567 A CN 101659567A CN 200910192069 A CN200910192069 A CN 200910192069A CN 200910192069 A CN200910192069 A CN 200910192069A CN 101659567 A CN101659567 A CN 101659567A
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Abstract
The invention relates to a furnace transmutation decoration glazed brick and a production technique thereof. The furnace transmutation decoration glazed brick is prepared from the following componentsin percentage by weight: 10-30% of albite, 3-10% of spodumene, 5-10% of kaoline Al2O3.2SiO2.2H2O, 8-30% of zinc oxide ZnO, 3-10% of talc 3MgO.4SiO2.H2O, 0-20% of titanium TiO2, 3-10% of zirconite ZrSiO, and 1-10% of coloring metallic oxide MnO2, V2O5, Fe2O3 and CoO2. The production technique of the furnace transmutation decoration glazed brick comprises the following steps: (1) shaping the substrate of the furnace transmutation decoration glazed wall and floor bricks; (2) decorating the wall and floor brick substrate surface or anti-abrasion transparent glaze layers and drying; and (3) sintering the furnace transmutation decoration glazed wall and floor bricks once in a high-temperature roller kiln.
Description
Technical field
The present invention relates to a kind of furnace transmutation decoration glazed brick that mass-producing is fired in roller kiln and production technique.
Background technology
Along with the application of ceramic industry novel process, novel material, new installation, product innovation continues to bring out; In the decoration field of ceramic wall and floor bricks, stamp, ooze the flower and multitube cloth decoration brick greatly enriched ceramic wall and floor bricks market; Should see that these products all are the collocation that rely on the color of glaze color or powder, produce pattern effect by multi color printing or multitube cloth, the variation that its pattern is single, lack color.Transmutation glaze, crystalline glaze are traditional decoration glaze, be in sintering process by improving firing temperature, prolonging soaking time and cooling at a slow speed, the decorative pattern and the crystallization flower that make it in kiln, to change, crystallization form; The firing process of high temperature, burning, slow cooling has slowly limited the expansion of its range of application, and its Application Areas only is to rest on the ceramic of decorative art class.
CN200610036552.3 (Main classification number: C04B41/86) disclose " a kind of be used for the glaze that ceramic tile surface has transmutation glaze effect ".Its purpose provides a kind of under existing ceramic tile working condition, and promptly 120 ± 20 ℃ of firing temperatures, firing period can make ceramic tile surface that the glaze of traditional ceramics artistic glaze transmutation glaze effect is arranged in the time of 50~120 minutes.Its technology constitutes: describedly be used for the glaze that ceramic tile surface has transmutation glaze effect, by raw mineral materials such as clay or ball clay or calcination clay, zirconium silicate, porcelain stone powder or pottery stone powder, silica powder, Wingdale, rhombspar, zinc oxide, calcium phosphate, wollastonite, barium carbonate, aluminum oxide powder, titanium dioxide, triphane, Feldspar Powder and burn talcum powder etc. and flux frit and coloring oxide or coloring compound or mineral dye of low temperature constitutes through uniform mixing specifically adopts following feed composition and proportioning: 1.0~25 weight part Li2o/Na20/K20,0~20 weight part CaO, 0~10 weight part Mgo, 50~85 weight part SiO2,2.0~20 weight part Al
2O
3, 0.5~30 weight part B
2O
3, 0~25 weight part ZrO
2, 0~30 weight part TiO
2, 0.5~50 weight part ZnO, 2~15 weight part BaO, 0~20 weight part P
2O
5, 0~50 weight part PbO, 0.5~30 weight part coloring oxide or coloring compound or mineral dye.Its weak point is, adds low temperature and contain lead frit in the transmutation glaze, and this means overglaze wear resistance, chemical resistance variation for tile product, and therefore the use range of the product of ceramic wall and floor bricks is restricted.
CN200710028882.2 (Main classification C04B41/86) discloses a kind of " Blazing heronsbill furnace transmulation glaze and manufacture method thereof ", its goal of the invention provides a kind of transmutation glaze, can separate out circular discrete safflower, and association has golden yellow crystallization, become the heronsbill effect and form credit, and burn out the method that this kind has the transmutation glaze of credit change heronsbill (or being called circular discrete safflower).Its technology constitutes: described Blazing heronsbill furnace transmulation glaze, contain following chemical constitution and weight percent: KNaO4~8.5%, SiO
250~56%, MgO1.5~7.5%, Fe
2O
310~16%, ALl
2O
311.5 P~15.5%,
2O
54~18%, CaO2~9%, B
2O
31~6%, TiO
20~0.5%, C 0~1%, MnO
20.1~0.6% and the impurity of other content and temperature of glaze firing under the chemical ingredients of decomposing or volatilizing.Its weak point is that this glaze adopts and burns till for twice, and burns till the heating-up time at least more than 12 hours, is cooled to naturally cooling, is traditional furnace transmutation decoration artistic glaze, and this glaze can not be applied to modernized wall floor tile production technology.
200610098258.5 (Main classification number: C04B41/86) disclose a kind of " ceramic scarlet-variable glaze and application method thereof ", its goal of the invention provide a kind of with wrap up bright red colorant show signs of anger the base the transmutation glaze, because bright red occlusion pigment adds and plays strong fluxing action in the basic glaze, the beginning fusing point of glaze water is reduced, cause glaze to seal too early, make base glaze gas in oxidising process be difficult for discharging, in addition because the glaze bubble appears in the hot stage that is reduced in of glaze water bulk temperature easily, defectives such as pin hole, for overcoming the above problems, the present invention adopts basestocks is selected, and obtains by orthogonal test that glaze is bright and clean to burn till stable scarlet-variable glaze.Its technology constitutes: described ceramic scarlet-variable glaze, comprise red glaze and titanium enamel, and the chemical constitution of described red glaze is: SiO
253~58%, Al
2O
310~11%, K
2O 4~4.5%, Na
2O:1~1.2%, MgO:0.1~0.12%, CaO:11.5~12.5%, ZnO:5~7%, Fe
2O
3: 0.5~1%, bright red parcel pigment: 9~11%; Described chemical group of admiring white glaze is: SiO
252~56%, Al
2O
3: 10~11%, K
2O:4.5~5%, Na
2O:1.3~1.5%, CaO:9~10%, TiO
2: 11~13%, BaO:5~6%, P
2O
5: 0.5~0.7%, MgO:0.4~0.6%, Fe
2O
3: 0.23~0.28%.This invention is adopted and is burnt till for twice, promptly on 950 ℃ of biscuit ware base substrates, burns till through 1230~1250 ℃; Having given prominence to high temperature wraps up the low hole that causes of bright red colorant melt temperature, hole defect increase and makes the parcel large red have the feature of transmutation.
CN200810070152.3 (Main classification C03C8/12) discloses " a kind of manufacturing process of furnace transmutation enamel ".Its goal of the invention provides a kind of manufacturing process of furnace transmutation enamel, employing ferrotitanium content is higher, reserves abundant and cheap china clay inferior and secondary clay is that main material production becomes vitreous enamel, not only can solve the unavailable problem of the idle waste of a large amount of high-Fe-Ti china clay, and do not need china clay is carried out selected and removes ironworking, saved production cost, and the change vitreous enamel of producing is elegant in appearance, practical, has good economic outlook.Its technology constitutes: the manufacturing process of described furnace transmutation enamel may further comprise the steps: a. base: choose Fe
2O
3Content greater than 1%, TiO
2Content is greater than 0.2% china clay, and the china clay fragmentation is fine ground, ball milling, press filtration then, and the fineness requirement of ball milling: 10000-hole sieve is surplus between 0.2%~1.0%; Secondary clay is added water, stir, treat after the disintegration to mix, add admire oxide compound and account for the thulium of total mass below 1.0% of iron, be pressed into base substrate with china clay after the press filtration; B. enamel frit makeing: 1. make ground-coat enamel: it is fine ground to make the ground-coat enamel raw material crushing, and add the iron oxide compound of admiring and add water for ball milling, the fineness requirement of ball milling: 10000-hole sieve is surplus between 0.1%~0.5%, and it is stand-by to stir; 2. make cover-coat enamel: it is fine ground to make the cover-coat enamel raw material crushing, adds to account for raw material total mass 1.0% following thulium, and add water for ball milling then, fineness requirement: 10000-hole sieve is surplus between 0.1%~0.5%, and it is stand-by to stir; C. moulding: base substrate is carried out forming processes according to the design needs; D. glazing: at normal temperatures, base substrate is left standstill, treat to carry out glazing treatment behind the body drying, with ground-coat enamel dipping or spraying, spray cover-coat enamel more earlier; E. fire: under 1230 ℃~1250 ℃ temperature, in reducing atmosphere, fire.Its weak point is: be to be main raw material with china clay inferior and secondary clay, by adding iron titanium oxide and rare-earth oxide, burnt till in reducing atmosphere 8 hours.
Summary of the invention
The objective of the invention is to overcome above-mentioned weak point of the prior art, provide a kind of on the basis that high temperature burns till, avoid the introducing of plumbous PbO, boron 2O3, increase the wear-resisting composition of prescription, be applicable to the furnace transmutation decoration glazed brick of the extensive firing ceramics wall of roller kiln floor tile.Another object of the present invention is: be applied to the big production of modernization for making traditional decorative art glaze, guarantee wall ground brick product overglaze wear resistance and chemical resistance, execute the wear-resisting transparent of one deck on furnace transmutation decoration glaze surface or at the surface decoration transmutation glaze of wear-resisting transparent, make transmutation glaze product not only have good wear-resisting, erosion resistance, also given prominence to three-dimensional, exquisitely carved, the decorative effect of transmutation glaze and the furnace transmutation decoration glazed brick of wall ground brick product functions of use more; A further object of the present invention is the furnace transmutation decoration glazed brick production technique that provides described furnace transmutation decoration glaze wall floor tile to fire in roller kiln.
Purpose of the present invention can reach by following measure:
This furnace transmutation decoration glazed brick, its special character is: the glaze layer of described furnace transmutation decoration glazed brick is made up of the furnace transmutation decoration glaze of bottom and the wear-resisting transparent of surface layer;
Described furnace transmutation decoration glaze said composition by weight percentage is made up of following component:
Albite 10%~30%
Triphane 3%~10%
Kaolin Al
2O
32SiO
22H
2O 5%~10%
Zinc oxide ZnO 8%~30%
Talcum 3MgO4SiO
2H
2O 3%~10%
Titanium dioxide TiO
210%~20%
Zircon ZrSiO
43%~10%
Coloring metal oxide M nO
2, V
2O
5, Fe
2O
3, CoO
21%~10%;
Described wear-resisting transparent said composition by weight percentage is made up of following component:
Barium carbonate 10%~20%
Feldspar 10%~20%
Talcum 3%~10%
Rhombspar 5%~10%
Calcite 10%~20%
Triphane 10%~20%
Kaolin 5%~15%
Aluminum oxide 5%~10%.
Purpose of the present invention can also reach by following measure:
This furnace transmutation decoration glazed brick, its special character is: the glaze layer of described furnace transmutation decoration glazed brick is made up of the wear-resisting transparent of bottom and the furnace transmutation decoration glaze of surface layer;
Described wear-resisting transparent said composition by weight percentage is made up of following component:
Barium carbonate 10%~20%
Feldspar 10%~20%
Talcum 3%~10%
Rhombspar 5%~10%
Calcite 10%~20%
Triphane 10%~20%
Kaolin 5%~15%
Aluminum oxide 5%~10%;
Described furnace transmutation decoration glaze said composition by weight percentage is made up of following component:
Albite 10%~30%
Triphane 3%~10%
Kaolin Al
2O
32SiO
22H
2O 5%~10%
Zinc oxide ZnO 8%~30%
Talcum 3MgO4SiO
2H
2O 3%~10%
Titanium dioxide TiO
210%~20%
Zircon ZrSiO
43%~10%
Coloring metal oxide M nO
2, V
2O
5, Fe
2O
3, CoO
21%~10%.
Purpose of the present invention can also reach by following measure:
The production technique of this furnace transmutation decoration glazed brick, its special character is, is made up of following steps:
(1) moulding furnace transmutation decoration glaze wall floor tile matrix and dry;
(2) at wall floor tile matrix surface or execute the enterprising luggage of wear-resisting transparent layer decorations;
(3) furnace transmutation decoration glaze wall floor tile is through high temperature roller kiln once-firing.
Described operation (1) further comprises:
(1.1) various components being gone into ball mill adds the water wet-milling and becomes mud;
(1.2) the spray-dried preparation powder of mud;
(1.3) repressed plane or the concavo-convex face wall floor tile matrix of being shaped to of powder;
(1.4) plane or concavo-convex face wall floor tile matrix are gone into roller-way dry kiln drying.
Described operation (2) further comprises:
(2.1) preparation furnace transmutation decoration glaze;
(2.1.1) go into ball mill and add the water wet-milling and become glaze slip, be prepared into according to enameling method and drench glaze slip, glaze spraying slurry or printing glaze by the various raw materials of proportioning weighing
(2.2) prepare wear-resisting transparent:
(2.2.2) go into ball mill and add the water wet-milling and become glaze slip, be prepared into according to enameling method and drench glaze slip, glaze spraying slurry or printing glaze by the various raw materials of proportioning weighing;
(2.3) furnace transmutation decoration glaze trailing:
(2.3.1) on ceramic matrix or wear-resisting transparent, spray, drench, get rid of or print the furnace transmutation decoration glaze;
(2.3.2) by the pattern that designs in advance, the integrated use decorative technique forms spot or the pattern of transmutation texture and the combination of pattern texture of all kinds with transmutation texture.
Described operation (3) furnace transmutation decoration glaze wall floor tile further comprises through high temperature roller kiln once-firing:
(3.1) described calcination equipment is roller kiln, is moved by the isometrical roller carrying goods of arranging on the same horizontal plane, finishes the sintering of goods by preheating zone, clinkering zone and the cooling zone of kiln casing;
(3.2) described furnace transmutation decoration glaze wall floor tile roller kiln once-firing, its firing temperature is 1220 ℃~1260 ℃, and high fiery soaking time is 5~10 minutes, and firing period is 60~70 minutes.
The present invention has following advantage compared to existing technology:
1, furnace transmutation decoration glaze wall ground brick product adopts matrix, furnace transmutation decoration glaze layer and wear-resisting glaze layer once-firing, and firing period is short, and energy consumption is low, be suitable for the large-scale production of modern wall floor tile roller kiln.
2, the ornament layer of furnace transmutation decoration glaze wall floor tile covers with wear-resisting transparent layer, has strengthened the decorative effect of decorating glaze, makes that the transmutation fancy glaze is exquisitely carved, stereoscopic sensation is strong, and wall floor tile product surface is wear-resisting, and use occasion is unrestricted.
3, decorate with the transmutation glaze on the ceramic adobe surface of executing wear-resisting transparent, high temperature is down because both fusion effect and physical reaction make the wear resistance of product well also ornamental strong.
4, traditional transmutation artistic glaze is applied to the decoration of wall ground brick product, has increased the decoration technique means of ceramic tile product, make the pattern of ceramic product, decorative content abundanter.
5, its raw material sources of production of furnace transmutation decoration glaze wall ground brick product are extensive, and polished tile requires lower to raw materials quality relatively.
6, alumina content height in the wear-resisting transparent, under the high temperature in the glaze layer content of mullite many; Overglaze fastness to rubbing height, good corrosion resistance.
Description of drawings
Fig. 1 is the schematic diagram of fabrication technology of furnace transmutation decoration glaze wall floor tile of the present invention.
Fig. 2 is the roller kiln sintering curve figure of furnace transmutation decoration glaze wall floor tile of the present invention.
Embodiment
Embodiment:
The present invention is described in further detail below in conjunction with embodiment and accompanying drawing:
See also shown in Figure 1ly, the manufacturing process of furnace transmutation decoration glaze wall floor tile of the present invention comprises:
(1) described ceramic tile matrix compression moulding, its matrix is made up of following component:
Porcelain sand 59%~80%
Black, white clay 15%~40%
Additive 0.5%~5%
(1.1) various raw materials being gone into ball mill adds the water wet-milling and becomes mud;
(1.2) mud is through the dry preparation of spray tower powder;
(1.3) matrix of powder repressed moulding becoming furnace transmutation decoration glaze wall floor tile;
(1.4) drying is carried out in the matrix adobe.
(2) preparation of described furnace transmutation decoration glaze and wear-resisting transparent, its transmutation glaze and wear-resisting transparent are made up of following component:
Material name | The furnace transmutation decoration glaze is formed | Wear-resisting transparent is formed |
Feldspar KNaO.Al 2O 3.6SiO 2 | ??10%~30% | ??10%-20% |
Triphane | ??3%-10% | ??10%-20% |
Kaolin Al 2O 3.2SiO 2.2H 2O | ??5%~10% | ??5%-10% |
Zinc oxide ZnO | ??8%~30% | ??0-10% |
Talcum 3MgO.4SiO 2.H 2O | ??3%~10% | ??3%-10% |
Titanium dioxide TiO 2 | ??10%-20% | ??-- |
Zircon ZrSiO 4 | ??3%-10% | ??-- |
??MnO 2、V 2O 5、Fe 2O 3、CoO 2 | ??1%-10% | ??-- |
Barium carbonate BaCO 3 | ??-- | ??10%-20% |
Rhombspar CaCO 3.MgCO 3 | ??-- | ??5%-10% |
Calcite CaCO 3 | ??-- | ??10%-20% |
Aluminium oxide Al 2O 3 | ??-- | ??5%-10% |
(2.1) preparation furnace transmutation decoration glaze and wear-resisting transparent glaze slip:
With furnace transmutation decoration glaze and wear-resisting transparent precentagewise weighing, go into ball mill and add water and carry out ball milling, wherein: material: ball: water=1: 2: 0.5~0.6; Ball milling fineness: 0.1~0.5% (325 mesh screen residue);
(2.2) prepare the transmutation glaze according to trailing and decorate glaze and wear-resisting transparent;
(2.2.1) glaze spraying is decorated: proportion 1.20~1.70g/ml;
(2.2.2) drenching glaze decorates: 1.70~1.90g/ml;
(2.2.3) silk screen coating and printing or stamp: will decorate glaze slip thickening material thickening, and make the printing glaze that is suitable for silk screen or adopt the rubber roll stamp.
(3) described transmutation glaze is decorated, and its trailing is as follows:
(3.1) on matrix surface, spray, get rid of the furnace transmutation decoration glaze;
(3.2) carry out transmutation pattern decorative according to the pattern that designs in advance with silk screen or rubber roll stamp at matrix surface or wear-resisting transparent laminar surface.
(4) the described method of executing wear-resisting transparent can be glaze spraying, pouring glaze and printing coating process:
(4.1) spray glazing: be the wear-resisting glaze slip that preparation meets the processing parameter requirement to be made it atomizing spraying through pressure pump generate wear-resisting glaze layer to matrix surface.
(4.2) waterfall process: be with pump the glaze slip that preparation meets the processing parameter requirement to be beaten to buffer tank, make slip form successive slurry curtain on bell jar by pulp feeding pipe mouth, dashpot, adobe is tiled on the matrix by the successive curtain.
(4.3) silk screen printing: wear-resisting transparent glaze slip is suitable for screen printing with the thickening material thickening, wear-resisting glaze layer is coated on the matrix.
(4.4) will decorate adobe and carry out drying;
(5) described roller kiln once-firing:
(5.1) its roller kiln structure: be by the isometrical roller rod of arranging on the same horizontal plane, its roller rod carrying goods move, and finish the sintering of goods by preheating zone, clinkering zone and the cooling zone of kiln casing;
(5.2) burning till of goods, its calcining system comprises: temperature schedule, pressure regime and firing atmosphere (referring to sintering curve shown in Figure 2).
The above only is preferred embodiment of the present invention, and all equalizations of being done according to claim scope of the present invention change and modify, and all should belong to the covering scope of claim of the present invention.
Claims (6)
1, a kind of furnace transmutation decoration glazed brick is characterized in that: the glaze layer of described furnace transmutation decoration glazed brick is made up of the furnace transmutation decoration glaze of bottom and the wear-resisting transparent of surface layer;
Described furnace transmutation decoration glaze said composition by weight percentage is made up of following component:
Albite 10%~30%
Triphane 3%~10%
Kaolin Al
2O
32SiO
22H
2O 5%~10%
Zinc oxide ZnO 8%~30%
Talcum 3MgO4SiO
2H
2O 3%~10%
Titanium dioxide TiO
210%~20%
Zircon ZrSiO
43%~10%
Coloring metal oxide M nO
2, V
2O
5, Fe
2O
3, CoO
21%~10%
Described wear-resisting transparent said composition by weight percentage is made up of following component:
Barium carbonate 10%~20%
Zinc oxide 0~10%
Feldspar 10%~20%
Talcum 3%~10%
Rhombspar 5%~10%
Calcite 10%~20%
Triphane 10%~20%
Kaolin 5%~15%
Aluminum oxide 5%~10%.
2, a kind of furnace transmutation decoration glazed brick is characterized in that: the glaze layer of described furnace transmutation decoration glazed brick is made up of the wear-resisting transparent of bottom and the furnace transmutation decoration glaze of surface layer;
Described wear-resisting transparent said composition by weight percentage is made up of following component:
Barium carbonate 10%~20%
Zinc oxide 0~10%
Feldspar 10%~20%
Talcum 3%~10%
Rhombspar 5%~10%
Calcite 10%~20%
Triphane 10%~20%
Kaolin 5%~15%
Aluminum oxide 5%~10%;
Described furnace transmutation decoration glaze said composition by weight percentage is made up of following component:
Albite 10%~30%
Triphane 3%~10%
Kaolin Al
2O
32SiO
22H
2O 5%~10%
Zinc oxide ZnO 8%~30%
Talcum 3MgO4SiO
2H
2O 3%~10%
Titanium dioxide TiO
210%~20%
Zircon ZrSiO
43%~10%
Coloring metal oxide M nO
2, V
2O
5, Fe
2O
3, CoO
21%~10%.
3,, it is characterized in that forming by following steps according to the production technique of the described furnace transmutation decoration glazed brick of claim 1:
(1) moulding furnace transmutation decoration glaze wall floor tile matrix and dry;
(2) at wall floor tile matrix surface or execute the enterprising luggage of wear-resisting transparent layer decorations;
(3) furnace transmutation decoration glaze wall floor tile is through high temperature roller kiln once-firing.
4, according to the production technique of the described furnace transmutation decoration glazed brick of claim 3, it is characterized in that: described operation (1) further comprises:
(1.1) various components being gone into ball mill adds the water wet-milling and becomes mud;
(1.2) the spray-dried preparation powder of mud;
(1.3) repressed plane or the concavo-convex face wall floor tile matrix of being shaped to of powder;
(1.4) plane or concavo-convex face wall floor tile matrix are gone into roller-way dry kiln drying.
5, according to the production technique of the described furnace transmutation decoration glazed brick of claim 3, it is characterized in that: described operation (2) further comprises:
(2.1) preparation furnace transmutation decoration glaze;
(2.1.1) go into ball mill and add the water wet-milling and become glaze slip, be prepared into according to enameling method and drench glaze slip, glaze spraying slurry or printing glaze by the various raw materials of proportioning weighing;
(2.2) prepare wear-resisting transparent:
(2.2.2) go into ball mill and add the water wet-milling and become glaze slip, be prepared into according to enameling method and drench glaze slip, glaze spraying slurry or printing glaze by the various raw materials of proportioning weighing;
(2.3) furnace transmutation decoration glaze trailing:
(2.3.1) on ceramic matrix surface or wear-resisting transparent layer, spray, drench, get rid of or print the furnace transmutation decoration glaze;
(2.3.2) by the pattern that designs in advance, the integrated use decorative technique forms spot or the pattern of transmutation texture and the combination of pattern texture of all kinds with transmutation texture.
6, according to the production technique of the described furnace transmutation decoration glazed brick of claim 3, it is characterized in that: described operation (3) furnace transmutation decoration glaze wall floor tile further comprises through high temperature roller kiln once-firing:
(3.1) described calcination equipment is roller kiln, is moved by the isometrical roller carrying goods of arranging on the same horizontal plane, finishes the sintering of goods by preheating zone, clinkering zone and the cooling zone of kiln casing;
(3.2) described furnace transmutation decoration glaze wall floor tile roller kiln once-firing, its firing temperature is 1220 ℃~1260 ℃, and high fiery soaking time is 5~10 minutes, and firing period is 60~70 minutes.
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