CN107572788A - The colour mixture glaze and enameling method of a kind of pottery - Google Patents

The colour mixture glaze and enameling method of a kind of pottery Download PDF

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CN107572788A
CN107572788A CN201710892692.9A CN201710892692A CN107572788A CN 107572788 A CN107572788 A CN 107572788A CN 201710892692 A CN201710892692 A CN 201710892692A CN 107572788 A CN107572788 A CN 107572788A
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glaze
pellet
parts
colour mixture
inner core
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CN107572788B (en
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王现锋
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Yuzhou City Is Jade Jun Co Ltd
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Abstract

The colour mixture glaze and enameling method of a kind of pottery, the colour mixture glaze includes internal layer glaze and outer layer glaze, internal layer glaze is made up of the first clear frit and colour mixture pellet, and outer layer glaze is made up of the second clear frit, and colour mixture pellet includes the shell formed by calcium carbonate and the inner core formed by various colouring agent powders;Enameling method is as follows:The glaze slip of the first clear frit, the glaze slip of the second clear frit, colour mixture pellet are prepared respectively, and colour mixture pellet is dispersed in the glaze slip of the first clear frit, it is then coated with plain tire surface, it is put into kiln and sinters, burn and take out the glaze slip for being coated with the second clear frit after finishing cooling, it is put into kiln and sinters, cooling can completes the enameling method of the colour mixture glaze of pottery.The present invention, so as to which the pottery colour mixture glaze with Colourful World be made, makes pottery product have more changeable color by applying colour mixture internal layer glaze and transparent outer layer glaze on plain tire, more ornamental.

Description

The colour mixture glaze and enameling method of a kind of pottery
Technical field
The present invention relates to ceramic technology field, the colour mixture glaze and enameling method of specifically a kind of pottery.
Background technology
Pottery is originated in the Eastern Han Dynasty, is one of five big kiln porcelain of Song Dynasty, the treasure in Han nationality's tradition technology in producing porcelain, is referred to as National treasure, rarity, it is world-famous for the transmutation art of uniqueness, is known as " the valuable an ancient unit of weight of gold is priceless " and " there is ten thousand strings of cash in family, not as pottery One " good reputation, be the exclusive national treasure porcelain in Countermeasure In Yuzhou City of Henan Province god Hou towns, by its simple and unsophisticated moulding, consummate technique, multiple The miscellaneous change nothing such as magical transmutation, the beautiful scenery of lakes and mountains, rosy clouds fog, people's beast flower, bird, insect, and fish with glaze, " it is color to enter kiln kiln discharge ten thousand of the same colour " Poor figure color and marvellous charm, it is described as first of Chinese " five big porcelain ".
Glazing, also referred to as glazing, refer to the operation that one layer of glaze is covered in billet surface, and the glazing of pottery refers to utilize plain tire Water imbibition, using different operating methods, in plain one layer of chun glaze frost boiling of tire implements surface attachment.In recent decades, permitted both at home and abroad More ceramic research persons have extensively studied different colorant, atmosphere and glaze layer microstructure by modern analysis and test method The influence to pottery enamel such as pattern, and further inquired into transmutation mechanism.For example, micro cobalt blue conduct is added in glaze Colouring agent, reddish black or sky blue pottery can be made under oxidizing atmosphere;Under reducing atmosphere due to the cupric oxide quilt in glaze Partial reduction makes pottery that red be presented for cuprous oxide.With people's living standard raising and science and technology it is at full speed The change of development, traditional pottery colour generation and moulding far can not meet the requirement of pottery fan.Therefore, develop new an ancient unit of weight Glaze and products thereof can promote the further development of pottery or even whole ceramic industry energetically.
The content of the invention
The invention aims to solve the deficiency of above-mentioned technical problem, the present invention proposes a kind of colour mixture glaze of pottery And enameling method, by applying colour mixture internal layer glaze and transparent outer layer glaze on plain tire, so as to which the pottery with Colourful World be made With colour mixture glaze, make pottery product that there is more changeable color, it is more ornamental.
The present invention is for the insufficient technical scheme that uses for solving above-mentioned technical problem:A kind of colour mixture glaze of pottery, The colour mixture glaze includes internal layer glaze and outer layer glaze, and the internal layer glaze is made up of the first clear frit and colour mixture pellet, the outer layer glaze It is made up of the second clear frit, the thickness of the internal layer glaze is 0.5 ~ 0.8mm, and the thickness of the outer layer glaze is 0.3 ~ 0.5mm.
Preferably, in parts by weight, first clear frit includes 25~30 parts of potassium feldspars, 20 ~ 25 parts of albites, 8~ 12 parts of calcites, 10 ~ 15 parts of calcined kaolins, 2~5 parts of quartz, 5~8 parts of talcums.
Preferably, in parts by weight, second clear frit include 30 ~ 40 parts albite, 50 ~ 60 parts of quartz, 10 ~ 15 parts of calcites, 15 ~ 20 parts of calcined kaolins, 12 ~ 15 parts of spodumene, 5 ~ 8 parts of talcum powder and 2 ~ 3 parts of tin oxide.
Preferably, the colour mixture pellet includes the shell formed by calcium carbonate and the inner core formed by colouring agent powder, institute State colour mixture pellet and be divided into red pellet, green pellet, blue pellet, brown pellet, purple pellet and yellow pellet.
Preferably, the red pellet includes the shell formed by calcium carbonate and the inner core formed by croci, institute The green pellet stated includes the shell formed by calcium carbonate and the inner core formed by chromium oxide powder, and described blue pellet includes The shell formed by calcium carbonate and the inner core formed by cupric oxide powder, described brown pellet are outer including being formed by calcium carbonate Shell and the inner core formed by manganese oxide powder, described purple pellet include the shell formed by calcium carbonate and by nickel oxide powders The inner core of formation, described yellow pellet include the shell formed by calcium carbonate and the inner core formed by titanium dioxide powder.
A kind of enameling method of the colour mixture glaze of pottery, comprises the following steps:
(1)The various raw materials of above-mentioned first clear frit are put into ball mill plus water carries out 5 ~ 6h of wet-milling, first is obtained after sieving The glaze slip of clear frit, it is standby;
(2)The various raw materials of above-mentioned second clear frit are put into ball mill plus water carries out 5 ~ 6h of wet-milling, outer layer is obtained after sieving The glaze slip of glaze, it is standby;
(3)Take iron oxide fines, chromium oxide fine powder, oxidation copper fine powder, manganese oxide fine powder, oxidation nickel fine powder and titanium oxide thin successively Powder, particle diameter is made into respectively and is 0.03 ~ 0.05mm spherical inner core, then one layer of calcium carbonate slurry is wrapped up in outside spherical inner core, put Entering, red pellet, green pellet, blue pellet, brown pellet, purple pellet and Huang can be made respectively after being dried in drying box Colorant ball;
(4)Step is taken respectively(3)Red pellet, green pellet, blue pellet, brown pellet, purple pellet and the yellow of preparation Pellet, then it is dispersed to step(1)In the glaze slip of preparation, you can obtain internal layer glaze;
(5)By step(4)Obtained internal layer glaze is applied on biscuit, and glazed thickness is 0.5 ~ 0.8mm, kiln-firing after drying, kiln Stove uses oxidizing atmosphere, and 150 ~ 170 DEG C of programming rate is increased to 850 ~ 890 DEG C on an hourly basis, is fired by glaze, in sintering procedure Calcium carbonate in the shell of colour mixture pellet decomposes between 850 ~ 890 DEG C, exposes inner core, be cooled to after room temperature take out it is standby;
(6)By step(2)The glaze slip of preparation is coated in step(5)Base substrate on, the thickness of glaze layer is 0.3 ~ 0.5mm, dry after Kiln-firing, kiln use oxidizing atmosphere, and 150 ~ 170 DEG C of programming rate is increased to 900 ~ 920 DEG C on an hourly basis, then adopts With reducing atmosphere, by temperature, 150 ~ 170 DEG C of programming rate continues to be increased to 1250 ~ 1300 DEG C on an hourly basis, and insulation 20 ~ Room temperature is cooled to after 30min, completes the glazing of pottery colour mixture glaze.
The beneficial effects of the invention are as follows:
The present invention is to provide the colour mixture glaze and enameling method of a kind of pottery, wherein colour mixture glaze includes internal layer glaze and outer layer Glaze, internal layer glaze are used for being formed the colour mixture of glaze layer, and outer layer glaze is used for protecting the color of internal layer glaze, while improves its glossiness;It is interior Layer glaze is made up of the first clear frit and colour mixture pellet, and colour mixture pellet is divided into red pellet, green pellet, blue pellet, brown material Ball, purple pellet and yellow pellet, red pellet include the shell formed by calcium carbonate and the inner core formed by croci, Green pellet includes the shell formed by calcium carbonate and the inner core formed by chromium oxide powder, and blue pellet is included by calcium carbonate shape Into shell and the inner core that is formed by cupric oxide powder, brown pellet include the shell formed by calcium carbonate and by manganese oxide powder The inner core of formation, purple pellet include the shell formed by calcium carbonate and the inner core formed by nickel oxide powder, yellow pellet bag The shell formed by calcium carbonate and the inner core formed by titanium dioxide powder are included, also can add different colouring agents according to being actually needed Forming the inner core that varies in color, the calcium carbonate in shell, when temperature reaches 850 ~ 890 DEG C, decomposes in glaze sintering procedure, So as to expose inner core, inner core melts by the color divergence generative forces of heaven and earth in it in glaze at high temperature, is formed naturally in glaze layer The lines and decorative pattern to vary in color, compared with common pottery, the advantages of having pottery concurrently, while there is more bright and more beautiful, splendid color, Great ornamental value;
The enameling method of the colour mixture glaze of the present invention is simple and convenient, is divided into internal layer glaze and outer layer glaze, first by obtained colour mixture pellet Mixed in the first transparent glaze slip, be then coated with firing on plain tire, you can the glazing process of internal layer glaze is completed, in the process In, color, the ratio of colour mixture pellet that can also be according to needed for being allocated the production requirement of reality, to control the tone of glaze, technique Simply, controllability is high, it is ensured that with a batch of each finished product glaze on tone it is consistent, but still keep each product each Characteristic, as the pottery art work, there is high appreciation and reserve value;After internal layer glaze has been applied, one layer is coated on its surface Outer layer glaze, outer layer glaze are clear frit, can repair the flatness of internal layer glaze, play protection internal layer glaze, improve the work of its glossiness With;
In summary, the colour mixture glaze and enameling method of pottery provided by the invention, by applying colour mixture internal layer glaze on plain tire With transparent outer layer glaze, the change of traditional pottery colour generation and moulding is not only increased, makes pottery product that there is more changeable color, It is more ornamental, the requirement of pottery fan is greatly met, and with technique is simple, overall cost is relatively low, is easy to reality The advantages of existing.
Embodiment
With reference to specific embodiment, the present invention is further elaborated.
Its specific embodiment is:
A kind of colour mixture glaze of pottery, the colour mixture glaze include internal layer glaze and outer layer glaze, the internal layer glaze by the first clear frit and Colour mixture pellet forms, and the outer layer glaze is made up of the second clear frit, and the thickness of the internal layer glaze is 0.5 ~ 0.8mm, the outer layer The thickness of glaze is 0.3 ~ 0.5mm.
Preferably, in parts by weight, first clear frit includes 25~30 parts of potassium feldspars, 20 ~ 25 parts of albites, 8~ 12 parts of calcites, 10 ~ 15 parts of calcined kaolins, 2~5 parts of quartz, 5~8 parts of talcums.
Preferably, in parts by weight, second clear frit include 30 ~ 40 parts albite, 50 ~ 60 parts of quartz, 10 ~ 15 parts of calcites, 15 ~ 20 parts of calcined kaolins, 12 ~ 15 parts of spodumene, 5 ~ 8 parts of talcum powder and 2 ~ 3 parts of tin oxide.
Preferably, the colour mixture pellet includes the shell formed by calcium carbonate and the inner core formed by colouring agent powder, institute State colour mixture pellet and be divided into red pellet, green pellet, blue pellet, brown pellet, purple pellet and yellow pellet.
Preferably, the red pellet includes the shell formed by calcium carbonate and the inner core formed by croci, institute The green pellet stated includes the shell formed by calcium carbonate and the inner core formed by chromium oxide powder, and described blue pellet includes The shell formed by calcium carbonate and the inner core formed by cupric oxide powder, described brown pellet are outer including being formed by calcium carbonate Shell and the inner core formed by manganese oxide powder, described purple pellet include the shell formed by calcium carbonate and by nickel oxide powders The inner core of formation, described yellow pellet include the shell formed by calcium carbonate and the inner core formed by titanium dioxide powder.
A kind of enameling method of the colour mixture glaze of pottery, comprises the following steps:
(1)The various raw materials of above-mentioned first clear frit are put into ball mill plus water carries out 5 ~ 6h of wet-milling, first is obtained after sieving The glaze slip of clear frit, it is standby;
(2)The various raw materials of above-mentioned second clear frit are put into ball mill plus water carries out 5 ~ 6h of wet-milling, outer layer is obtained after sieving The glaze slip of glaze, it is standby;
(3)Take iron oxide fines, chromium oxide fine powder, oxidation copper fine powder, manganese oxide fine powder, oxidation nickel fine powder and titanium oxide thin successively Powder, particle diameter is made into respectively and is 0.03 ~ 0.05mm spherical inner core, then one layer of calcium carbonate slurry is wrapped up in outside spherical inner core, put Entering, red pellet, green pellet, blue pellet, brown pellet, purple pellet and Huang can be made respectively after being dried in drying box Colorant ball;
(4)Step is taken respectively(3)Red pellet, green pellet, blue pellet, brown pellet, purple pellet and the yellow of preparation Pellet, then it is dispersed to step(1)In the glaze slip of preparation, you can obtain internal layer glaze;
(5)By step(4)Obtained internal layer glaze is applied on biscuit, and glazed thickness is 0.5 ~ 0.8mm, kiln-firing after drying, kiln Stove uses oxidizing atmosphere, and 150 ~ 170 DEG C of programming rate is increased to 850 ~ 890 DEG C on an hourly basis, is fired by glaze, in sintering procedure Calcium carbonate in the shell of colour mixture pellet decomposes between 850 ~ 890 DEG C, exposes inner core, be cooled to after room temperature take out it is standby;
(6)By step(2)The glaze slip of preparation is coated in step(5)Base substrate on, the thickness of glaze layer is 0.3 ~ 0.5mm, dry after Kiln-firing, kiln use oxidizing atmosphere, and 150 ~ 170 DEG C of programming rate is increased to 900 ~ 920 DEG C on an hourly basis, then adopts With reducing atmosphere, by temperature, 150 ~ 170 DEG C of programming rate continues to be increased to 1250 ~ 1300 DEG C on an hourly basis, and insulation 20 ~ Room temperature is cooled to after 30min, completes the glazing of pottery colour mixture glaze.
Embodiment 1
A kind of colour mixture glaze of pottery, including internal layer glaze and outer layer glaze, the thickness of the internal layer glaze is 0.5 ~ 0.8mm, described outer The thickness of layer glaze is 0.3 ~ 0.5mm;The internal layer glaze is made up of the first clear frit and colour mixture pellet, and the outer layer glaze is saturating by second Bright glaze composition;The colour mixture pellet includes the shell formed by calcium carbonate and the inner core formed by colouring agent powder, the colour mixture Pellet is divided into red pellet, green pellet, blue pellet, brown pellet, purple pellet and yellow pellet;The red pellet bag The shell formed by calcium carbonate and the inner core formed by croci are included, described green pellet includes what is formed by calcium carbonate Shell and the inner core formed by chromium oxide powder, described blue pellet include the shell formed by calcium carbonate and by cupric oxide powders The inner core that end is formed, described brown pellet include the shell formed by calcium carbonate and the inner core formed by manganese oxide powder, institute The purple pellet stated includes the shell formed by calcium carbonate and the inner core formed by nickel oxide powder, and described yellow pellet includes The shell formed by calcium carbonate and the inner core formed by titanium dioxide powder.
A kind of enameling method of the colour mixture glaze of pottery, comprises the following steps:
(1)In parts by weight, 25~30 parts of potassium feldspars, 20 ~ 25 parts of albites, 8~12 parts of calcites, 10 ~ 15 parts of calcining height are taken Ridge soil, 2~5 parts of quartz, 5~8 parts of talcums, above-mentioned various raw materials are put into ball mill plus water carries out 5 ~ 6h of wet-milling, after sieving The glaze slip of the first clear frit is obtained, it is standby;
(2)In parts by weight, take 30 ~ 40 parts of albite, 50 ~ 60 parts of quartz, 10 ~ 15 parts of calcites, 15 ~ 20 parts of calcinings high Ridge soil, 12 ~ 15 parts of spodumene, 5 ~ 8 parts of talcum powder and 2 ~ 3 parts of tin oxide, above-mentioned various raw materials are put into ball mill and add water 5 ~ 6h of wet-milling is carried out, the glaze slip of outer layer glaze is obtained after sieving, it is standby;
(3)Take iron oxide fines, chromium oxide fine powder, oxidation copper fine powder, manganese oxide fine powder, oxidation nickel fine powder and titanium oxide thin successively Powder, particle diameter is made into respectively and is 0.03 ~ 0.05mm spherical inner core, then one layer of calcium carbonate slurry is wrapped up in outside spherical inner core, put Entering, red pellet, green pellet, blue pellet, brown pellet, purple pellet and Huang can be made respectively after being dried in drying box Colorant ball;
(4)It is 5 by weight:1:1:1:5:1 takes step respectively(3)The red pellet of preparation, green pellet, blue pellet, palm fibre Colorant ball, purple pellet and yellow pellet, are then dispersed to step(1)In the glaze slip of preparation, you can obtain internal layer glaze;
(5)By step(4)Obtained internal layer glaze is applied on biscuit, and glazed thickness is 0.5 ~ 0.8mm, kiln-firing after drying, kiln Stove uses oxidizing atmosphere, and 150 ~ 170 DEG C of programming rate is increased to 850 ~ 890 DEG C on an hourly basis, is fired by glaze, in sintering procedure Calcium carbonate in the shell of colour mixture pellet decomposes between 850 ~ 890 DEG C, exposes inner core, be cooled to after room temperature take out it is standby;It is interior Core melts by the color divergence generative forces of heaven and earth in it in glaze at high temperature, due to red pellet, green pellet, blue pellet, palm fibre The weight ratio 5 of colorant ball, purple pellet and yellow pellet:1:1:1:5:1, red pellet, purple pellet account for large scale, make glaze Layer forms the bright-colored color using red color tone as dominant hue;
(6)By step(2)The glaze slip of preparation is coated in step(5)Base substrate on, the thickness of glaze layer is 0.3 ~ 0.5mm, to internal layer Glaze is protected, while improves its glossiness, and kiln-firing after drying, kiln uses oxidizing atmosphere, 150 ~ 170 DEG C on an hourly basis Programming rate be increased to 900 ~ 920 DEG C, then using reducing atmosphere, by temperature 150 ~ 170 DEG C of programming rate on an hourly basis Continue to be increased to 1250 ~ 1300 DEG C, be cooled to room temperature after being incubated 20 ~ 30min, complete the glazing of pottery colour mixture glaze.
Embodiment 2
A kind of colour mixture glaze of pottery, including internal layer glaze and outer layer glaze, the thickness of the internal layer glaze is 0.5 ~ 0.8mm, described outer The thickness of layer glaze is 0.3 ~ 0.5mm;The internal layer glaze is made up of the first clear frit and colour mixture pellet, and the outer layer glaze is saturating by second Bright glaze composition;The colour mixture pellet includes the shell formed by calcium carbonate and the inner core formed by colouring agent powder, the colour mixture Pellet is divided into red pellet, green pellet, blue pellet, brown pellet, purple pellet and yellow pellet;The red pellet bag The shell formed by calcium carbonate and the inner core formed by croci are included, described green pellet includes what is formed by calcium carbonate Shell and the inner core formed by chromium oxide powder, described blue pellet include the shell formed by calcium carbonate and by cupric oxide powders The inner core that end is formed, described brown pellet include the shell formed by calcium carbonate and the inner core formed by manganese oxide powder, institute The purple pellet stated includes the shell formed by calcium carbonate and the inner core formed by nickel oxide powder, and described yellow pellet includes The shell formed by calcium carbonate and the inner core formed by titanium dioxide powder.
A kind of enameling method of the colour mixture glaze of pottery, comprises the following steps:
(1)In parts by weight, 25~30 parts of potassium feldspars, 20 ~ 25 parts of albites, 8~12 parts of calcites, 10 ~ 15 parts of calcining height are taken Ridge soil, 2~5 parts of quartz, 5~8 parts of talcums, above-mentioned various raw materials are put into ball mill plus water carries out 5 ~ 6h of wet-milling, after sieving The glaze slip of the first clear frit is obtained, it is standby;
(2)In parts by weight, take 30 ~ 40 parts of albite, 50 ~ 60 parts of quartz, 10 ~ 15 parts of calcites, 15 ~ 20 parts of calcinings high Ridge soil, 12 ~ 15 parts of spodumene, 5 ~ 8 parts of talcum powder and 2 ~ 3 parts of tin oxide, above-mentioned various raw materials are put into ball mill and add water 5 ~ 6h of wet-milling is carried out, the glaze slip of outer layer glaze is obtained after sieving, it is standby;
(3)Take iron oxide fines, chromium oxide fine powder, oxidation copper fine powder, manganese oxide fine powder, oxidation nickel fine powder and titanium oxide thin successively Powder, particle diameter is made into respectively and is 0.03 ~ 0.05mm spherical inner core, then one layer of calcium carbonate slurry is wrapped up in outside spherical inner core, put Entering, red pellet, green pellet, blue pellet, brown pellet, purple pellet and Huang can be made respectively after being dried in drying box Colorant ball;
(4)It is 1 by weight:5:5:1:1:1 takes step respectively(3)The red pellet of preparation, green pellet, blue pellet, palm fibre Colorant ball, purple pellet and yellow pellet, are then dispersed to step(1)In the glaze slip of preparation, you can obtain internal layer glaze;
(5)By step(4)Obtained internal layer glaze is applied on biscuit, and glazed thickness is 0.5 ~ 0.8mm, kiln-firing after drying, kiln Stove uses oxidizing atmosphere, and 150 ~ 170 DEG C of programming rate is increased to 850 ~ 890 DEG C on an hourly basis, is fired by glaze, in sintering procedure Calcium carbonate in the shell of colour mixture pellet decomposes between 850 ~ 890 DEG C, exposes inner core, be cooled to after room temperature take out it is standby;It is interior Core melts by the color divergence generative forces of heaven and earth in it in glaze at high temperature, due to red pellet, green pellet, blue pellet, palm fibre The weight ratio 1 of colorant ball, purple pellet and yellow pellet:5:5:1:1:1, green pellet, blue pellet account for large scale, make glaze Layer forms the bright-colored color that dominant hue is adjusted to blue-green;
(6)By step(2)The glaze slip of preparation is coated in step(5)Base substrate on, the thickness of glaze layer is 0.3 ~ 0.5mm, to internal layer Glaze is protected, while improves its glossiness, and kiln-firing after drying, kiln uses oxidizing atmosphere, 150 ~ 170 DEG C on an hourly basis Programming rate be increased to 900 ~ 920 DEG C, then using reducing atmosphere, by temperature 150 ~ 170 DEG C of programming rate on an hourly basis Continue to be increased to 1250 ~ 1300 DEG C, be cooled to room temperature after being incubated 20 ~ 30min, complete the glazing of pottery colour mixture glaze.
Embodiment 3
A kind of colour mixture glaze of pottery, including internal layer glaze and outer layer glaze, the thickness of the internal layer glaze is 0.5 ~ 0.8mm, described outer The thickness of layer glaze is 0.3 ~ 0.5mm;The internal layer glaze is made up of the first clear frit and colour mixture pellet, and the outer layer glaze is saturating by second Bright glaze composition;The colour mixture pellet includes the shell formed by calcium carbonate and the inner core formed by colouring agent powder, the colour mixture Pellet is divided into red pellet, green pellet, blue pellet, brown pellet, purple pellet and yellow pellet;The red pellet bag The shell formed by calcium carbonate and the inner core formed by croci are included, described green pellet includes what is formed by calcium carbonate Shell and the inner core formed by chromium oxide powder, described blue pellet include the shell formed by calcium carbonate and by cupric oxide powders The inner core that end is formed, described brown pellet include the shell formed by calcium carbonate and the inner core formed by manganese oxide powder, institute The purple pellet stated includes the shell formed by calcium carbonate and the inner core formed by nickel oxide powder, and described yellow pellet includes The shell formed by calcium carbonate and the inner core formed by titanium dioxide powder.
A kind of enameling method of the colour mixture glaze of pottery, comprises the following steps:
(1)In parts by weight, 25~30 parts of potassium feldspars, 20 ~ 25 parts of albites, 8~12 parts of calcites, 10 ~ 15 parts of calcining height are taken Ridge soil, 2~5 parts of quartz, 5~8 parts of talcums, above-mentioned various raw materials are put into ball mill plus water carries out 5 ~ 6h of wet-milling, after sieving The glaze slip of the first clear frit is obtained, it is standby;
(2)In parts by weight, take 30 ~ 40 parts of albite, 50 ~ 60 parts of quartz, 10 ~ 15 parts of calcites, 15 ~ 20 parts of calcinings high Ridge soil, 12 ~ 15 parts of spodumene, 5 ~ 8 parts of talcum powder and 2 ~ 3 parts of tin oxide, above-mentioned various raw materials are put into ball mill and add water 5 ~ 6h of wet-milling is carried out, the glaze slip of outer layer glaze is obtained after sieving, it is standby;
(3)Take iron oxide fines, chromium oxide fine powder, oxidation copper fine powder, manganese oxide fine powder, oxidation nickel fine powder and titanium oxide thin successively Powder, particle diameter is made into respectively and is 0.03 ~ 0.05mm spherical inner core, then one layer of calcium carbonate slurry is wrapped up in outside spherical inner core, put Entering, red pellet, green pellet, blue pellet, brown pellet, purple pellet and Huang can be made respectively after being dried in drying box Colorant ball;
(4)It is 1 by weight:1:5:1:1:5 take step respectively(3)The red pellet of preparation, green pellet, blue pellet, palm fibre Colorant ball, purple pellet and yellow pellet, are then dispersed to step(1)In the glaze slip of preparation, you can obtain internal layer glaze;
(5)By step(4)Obtained internal layer glaze is applied on biscuit, and glazed thickness is 0.5 ~ 0.8mm, kiln-firing after drying, kiln Stove uses oxidizing atmosphere, and 150 ~ 170 DEG C of programming rate is increased to 850 ~ 890 DEG C on an hourly basis, is fired by glaze, in sintering procedure Calcium carbonate in the shell of colour mixture pellet decomposes between 850 ~ 890 DEG C, exposes inner core, be cooled to after room temperature take out it is standby;It is interior Core melts by the color divergence generative forces of heaven and earth in it in glaze at high temperature, due to red pellet, green pellet, blue pellet, palm fibre The weight ratio 1 of colorant ball, purple pellet and yellow pellet:1:5:1:1:5, brown pellet, yellow pellet account for large scale, make glaze Layer forms the bright-colored color that dominant hue is adjusted to yellowish-brown;
(6)By step(2)The glaze slip of preparation is coated in step(5)Base substrate on, the thickness of glaze layer is 0.3 ~ 0.5mm, to internal layer Glaze is protected, while improves its glossiness, and kiln-firing after drying, kiln uses oxidizing atmosphere, 150 ~ 170 DEG C on an hourly basis Programming rate be increased to 900 ~ 920 DEG C, then using reducing atmosphere, by temperature 150 ~ 170 DEG C of programming rate on an hourly basis Continue to be increased to 1250 ~ 1300 DEG C, be cooled to room temperature after being incubated 20 ~ 30min, complete the glazing of pottery colour mixture glaze.
Embodiment 4
A kind of colour mixture glaze of pottery, including internal layer glaze and outer layer glaze, the thickness of the internal layer glaze is 0.5 ~ 0.8mm, described outer The thickness of layer glaze is 0.3 ~ 0.5mm;The internal layer glaze is made up of the first clear frit and colour mixture pellet, and the outer layer glaze is saturating by second Bright glaze composition;The colour mixture pellet includes the shell formed by calcium carbonate and the inner core formed by colouring agent powder, the colour mixture Pellet is divided into green pellet, blue pellet, purple pellet;Described green pellet includes the shell formed by calcium carbonate and by oxygen Change the inner core that chromium powder end is formed, in described blue pellet includes the shell that is formed by calcium carbonate and formed by cupric oxide powder Core, described purple pellet include the shell formed by calcium carbonate and the inner core formed by nickel oxide powder.
A kind of enameling method of the colour mixture glaze of pottery, comprises the following steps:
(1)In parts by weight, 25~30 parts of potassium feldspars, 20 ~ 25 parts of albites, 8~12 parts of calcites, 10 ~ 15 parts of calcining height are taken Ridge soil, 2~5 parts of quartz, 5~8 parts of talcums, above-mentioned various raw materials are put into ball mill plus water carries out 5 ~ 6h of wet-milling, after sieving The glaze slip of the first clear frit is obtained, it is standby;
(2)In parts by weight, take 30 ~ 40 parts of albite, 50 ~ 60 parts of quartz, 10 ~ 15 parts of calcites, 15 ~ 20 parts of calcinings high Ridge soil, 12 ~ 15 parts of spodumene, 5 ~ 8 parts of talcum powder and 2 ~ 3 parts of tin oxide, above-mentioned various raw materials are put into ball mill and add water 5 ~ 6h of wet-milling is carried out, the glaze slip of outer layer glaze is obtained after sieving, it is standby;
(3)Chromium oxide fine powder, oxidation copper fine powder, oxidation nickel fine powder are taken successively, and it is 0.03 ~ 0.05mm's to be made into particle diameter respectively Spherical inner core, then one layer of calcium carbonate slurry is wrapped up in outside spherical inner core, being put into after being dried in drying box, green material can be made respectively Ball, blue pellet and purple pellet;
(4)It is 1 by weight:1:1 takes step respectively(3)Green pellet, blue pellet, the purple pellet of preparation, then by it It is dispersed to step(1)In the glaze slip of preparation, you can obtain internal layer glaze;
(5)By step(4)Obtained internal layer glaze is applied on biscuit, and glazed thickness is 0.5 ~ 0.8mm, kiln-firing after drying, kiln Stove uses oxidizing atmosphere, and 150 ~ 170 DEG C of programming rate is increased to 850 ~ 890 DEG C on an hourly basis, is fired by glaze, in sintering procedure Calcium carbonate in the shell of colour mixture pellet decomposes between 850 ~ 890 DEG C, exposes inner core, be cooled to after room temperature take out it is standby;It is interior Core melts by the color divergence generative forces of heaven and earth in it in glaze at high temperature, because internal layer glaze is only containing blue pellet, green pellet With purple pellet, after Decomposition of Calcium Carbonate, the color exposed is blueness, green and purple, glaze layer is formed based on cool tone The bright-colored color of tone;
(6)By step(2)The glaze slip of preparation is coated in step(5)Base substrate on, the thickness of glaze layer is 0.3 ~ 0.5mm, to internal layer Glaze is protected, while improves its glossiness, and kiln-firing after drying, kiln uses oxidizing atmosphere, 150 ~ 170 DEG C on an hourly basis Programming rate be increased to 900 ~ 920 DEG C, then using reducing atmosphere, by temperature 150 ~ 170 DEG C of programming rate on an hourly basis Continue to be increased to 1250 ~ 1300 DEG C, be cooled to room temperature after being incubated 20 ~ 30min, complete the glazing of pottery colour mixture glaze.
Embodiment 5
A kind of colour mixture glaze of pottery, including internal layer glaze and outer layer glaze, the thickness of the internal layer glaze is 0.5 ~ 0.8mm, described outer The thickness of layer glaze is 0.3 ~ 0.5mm;The internal layer glaze is made up of the first clear frit and colour mixture pellet, and the outer layer glaze is saturating by second Bright glaze composition;The colour mixture pellet includes the shell formed by calcium carbonate and the inner core formed by colouring agent powder, the colour mixture Pellet is divided into red pellet, brown pellet and yellow pellet;The red pellet includes the shell formed by calcium carbonate and by oxygen Change the inner core that iron powder is formed, in described brown pellet includes the shell that is formed by calcium carbonate and formed by manganese oxide powder Core, described yellow pellet include the shell formed by calcium carbonate and the inner core formed by titanium dioxide powder.
A kind of enameling method of the colour mixture glaze of pottery, comprises the following steps:
(1)In parts by weight, 25~30 parts of potassium feldspars, 20 ~ 25 parts of albites, 8~12 parts of calcites, 10 ~ 15 parts of calcining height are taken Ridge soil, 2~5 parts of quartz, 5~8 parts of talcums, above-mentioned various raw materials are put into ball mill plus water carries out 5 ~ 6h of wet-milling, after sieving The glaze slip of the first clear frit is obtained, it is standby;
(2)In parts by weight, take 30 ~ 40 parts of albite, 50 ~ 60 parts of quartz, 10 ~ 15 parts of calcites, 15 ~ 20 parts of calcinings high Ridge soil, 12 ~ 15 parts of spodumene, 5 ~ 8 parts of talcum powder and 2 ~ 3 parts of tin oxide, above-mentioned various raw materials are put into ball mill and add water 5 ~ 6h of wet-milling is carried out, the glaze slip of outer layer glaze is obtained after sieving, it is standby;
(3)Iron oxide fines, manganese oxide fine powder and titanium oxide fine powder are taken successively, and it is 0.03 ~ 0.05mm to be made into particle diameter respectively Spherical inner core, then one layer of calcium carbonate slurry is wrapped up in outside spherical inner core, red can be made respectively by being put into after being dried in drying box Pellet, brown pellet and yellow pellet;
(4)It is 1 by weight:1:1 takes step respectively(3)Red pellet, brown pellet and the yellow pellet of preparation, then by it It is dispersed to step(1)In the glaze slip of preparation, you can obtain internal layer glaze;
(5)By step(4)Obtained internal layer glaze is applied on biscuit, and glazed thickness is 0.5 ~ 0.8mm, kiln-firing after drying, kiln Stove uses oxidizing atmosphere, and 150 ~ 170 DEG C of programming rate is increased to 850 ~ 890 DEG C on an hourly basis, is fired by glaze, in sintering procedure Calcium carbonate in the shell of colour mixture pellet decomposes between 850 ~ 890 DEG C, exposes inner core, be cooled to after room temperature take out it is standby;It is interior Core melts by the color divergence generative forces of heaven and earth in it in glaze at high temperature, because internal layer glaze is only containing red pellet, brown pellet With yellow pellet, after Decomposition of Calcium Carbonate, the color exposed is red, brown and yellow, glaze layer is formed based on warm tones The bright-colored color of tone;
(6)By step(2)The glaze slip of preparation is coated in step(5)Base substrate on, the thickness of glaze layer is 0.3 ~ 0.5mm, to internal layer Glaze is protected, while improves its glossiness, and kiln-firing after drying, kiln uses oxidizing atmosphere, 150 ~ 170 DEG C on an hourly basis Programming rate be increased to 900 ~ 920 DEG C, then using reducing atmosphere, by temperature 150 ~ 170 DEG C of programming rate on an hourly basis Continue to be increased to 1250 ~ 1300 DEG C, be cooled to room temperature after being incubated 20 ~ 30min, complete the glazing of pottery colour mixture glaze.
The foregoing description of the disclosed embodiments, only for enabling professional and technical personnel in the field to realize or using this Invention.A variety of modifications to these embodiments will be apparent for those skilled in the art, institute herein The General Principle of definition can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore, The present invention is not intended to be limited to the embodiments shown herein, and is to fit to special with principles disclosed herein and novelty The consistent most wide scope of point.

Claims (6)

  1. A kind of 1. colour mixture glaze of pottery, it is characterised in that the colour mixture glaze includes internal layer glaze and outer layer glaze, the internal layer glaze by First clear frit and colour mixture pellet composition, the outer layer glaze is made up of the second clear frit, the thickness of the internal layer glaze for 0.5 ~ 0.8mm, the thickness of the outer layer glaze is 0.3 ~ 0.5mm.
  2. 2. the colour mixture glaze of a kind of pottery as claimed in claim 1, it is characterised in that in parts by weight, described first is transparent Glaze includes 25~30 parts of potassium feldspars, 20 ~ 25 parts of albites, 8~12 parts of calcites, 10 ~ 15 parts of calcined kaolins, 2~5 parts of stones English, 5~8 parts of talcums.
  3. 3. the colour mixture glaze of a kind of pottery as claimed in claim 1, it is characterised in that in parts by weight, described second is transparent Glaze include 30 ~ 40 parts albite, 50 ~ 60 parts of quartz, 10 ~ 15 parts of calcites, 15 ~ 20 parts of calcined kaolins, 12 ~ 15 parts Spodumene, 5 ~ 8 parts of talcum powder and 2 ~ 3 parts of tin oxide.
  4. 4. the colour mixture glaze of a kind of pottery as claimed in claim 1, it is characterised in that the colour mixture pellet is included by calcium carbonate The shell of formation and the inner core formed by colouring agent powder, the colour mixture pellet are divided into red pellet, green pellet, blue Ball, brown pellet, purple pellet and yellow pellet.
  5. 5. the colour mixture glaze of a kind of pottery as claimed in claim 4, it is characterised in that the red pellet is included by calcium carbonate The shell of formation and the inner core formed by croci, described green pellet include the shell formed by calcium carbonate and by oxygen Change the inner core that chromium powder end is formed, in described blue pellet includes the shell that is formed by calcium carbonate and formed by cupric oxide powder Core, described brown pellet include the shell formed by calcium carbonate and the inner core formed by manganese oxide powder, described purple material Ball includes the shell formed by calcium carbonate and the inner core formed by nickel oxide powder, and described yellow pellet is included by calcium carbonate shape Into shell and the inner core that is formed by titanium dioxide powder.
  6. 6. the enameling method of the colour mixture glaze of a kind of pottery as claimed in claim 1, it is characterised in that comprise the following steps:
    (1)The various raw materials of above-mentioned first clear frit are put into ball mill plus water carries out 5 ~ 6h of wet-milling, first is obtained after sieving The glaze slip of clear frit, it is standby;
    (2)The various raw materials of above-mentioned second clear frit are put into ball mill plus water carries out 5 ~ 6h of wet-milling, outer layer is obtained after sieving The glaze slip of glaze, it is standby;
    (3)Take iron oxide fines, chromium oxide fine powder, oxidation copper fine powder, manganese oxide fine powder, oxidation nickel fine powder and titanium oxide thin successively Powder, particle diameter is made into respectively and is 0.03 ~ 0.05mm spherical inner core, then one layer of calcium carbonate slurry is wrapped up in outside spherical inner core, put Entering, red pellet, green pellet, blue pellet, brown pellet, purple pellet and Huang can be made respectively after being dried in drying box Colorant ball;
    (4)Step is taken respectively(3)Red pellet, green pellet, blue pellet, brown pellet, purple pellet and the yellow of preparation Pellet, then it is dispersed to step(1)In the glaze slip of preparation, you can obtain internal layer glaze;
    (5)By step(4)Obtained internal layer glaze is applied on biscuit, and glazed thickness is 0.5 ~ 0.8mm, kiln-firing after drying, kiln Stove uses oxidizing atmosphere, and 150 ~ 170 DEG C of programming rate is increased to 850 ~ 890 DEG C on an hourly basis, is fired by glaze, in sintering procedure Calcium carbonate in the shell of colour mixture pellet decomposes between 850 ~ 890 DEG C, exposes inner core, be cooled to after room temperature take out it is standby;
    (6)By step(2)The glaze slip of preparation is coated in step(5)Base substrate on, the thickness of glaze layer is 0.3 ~ 0.5mm, dry after Kiln-firing, kiln use oxidizing atmosphere, and 150 ~ 170 DEG C of programming rate is increased to 900 ~ 920 DEG C on an hourly basis, then adopts With reducing atmosphere, by temperature, 150 ~ 170 DEG C of programming rate continues to be increased to 1250 ~ 1300 DEG C on an hourly basis, and insulation 20 ~ Room temperature is cooled to after 30min, completes the glazing of pottery colour mixture glaze.
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CN108585767A (en) * 2018-04-17 2018-09-28 安徽青花坊瓷业股份有限公司 A kind of high-toughness wear-resistant porcelain and its manufacture craft
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CN111548011A (en) * 2020-05-20 2020-08-18 福建省德化县瓷言坊陶瓷工艺有限公司 Purple-color green-point kiln-changing porcelain and preparation process thereof
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