CN103332965A - Golden yellow crystallized dry-granular glaze and using method thereof - Google Patents
Golden yellow crystallized dry-granular glaze and using method thereof Download PDFInfo
- Publication number
- CN103332965A CN103332965A CN2013102729685A CN201310272968A CN103332965A CN 103332965 A CN103332965 A CN 103332965A CN 2013102729685 A CN2013102729685 A CN 2013102729685A CN 201310272968 A CN201310272968 A CN 201310272968A CN 103332965 A CN103332965 A CN 103332965A
- Authority
- CN
- China
- Prior art keywords
- glaze
- golden yellow
- crystallization
- dry granular
- evenly
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 title claims abstract description 24
- 238000000034 method Methods 0.000 title claims abstract description 14
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000000498 ball milling Methods 0.000 claims abstract description 12
- 239000013078 crystal Substances 0.000 claims abstract description 9
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 8
- 238000000227 grinding Methods 0.000 claims abstract description 8
- 238000005303 weighing Methods 0.000 claims abstract description 8
- 239000011787 zinc oxide Substances 0.000 claims abstract description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000001035 drying Methods 0.000 claims abstract description 5
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 claims abstract description 4
- 238000001354 calcination Methods 0.000 claims abstract description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 4
- 238000007580 dry-mixing Methods 0.000 claims abstract description 4
- 239000010433 feldspar Substances 0.000 claims abstract description 4
- 239000010453 quartz Substances 0.000 claims abstract description 4
- 238000007873 sieving Methods 0.000 claims abstract description 4
- 239000002002 slurry Substances 0.000 claims abstract description 4
- 238000002425 crystallisation Methods 0.000 claims description 25
- 230000008025 crystallization Effects 0.000 claims description 25
- 239000000463 material Substances 0.000 claims description 8
- 239000000758 substrate Substances 0.000 claims description 8
- 238000005507 spraying Methods 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 1
- 238000010791 quenching Methods 0.000 abstract 1
- 230000000171 quenching effect Effects 0.000 abstract 1
- 239000000919 ceramic Substances 0.000 description 9
- 238000010304 firing Methods 0.000 description 3
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 238000010923 batch production Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000004534 enameling Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Abstract
The invention provides golden yellow crystallized dry-granular glaze and a using method thereof. The using method comprises the following steps of: (1) weighing the following compositions in percentage by weight: 15%-22% of feldspar, 20%-40% of quartz, 6%-15% of calcium carbonate, 6%-15% of barium carbonate, 22%-50% of zinc oxide, 0.7%-2.2% of CuO, and 0.7%-2.2% of Fe2O3, evenly mixing and grinding, and sieving to obtain crystallized glaze; (2) weighing the following compositions in percentage by weight: 20%-78% of activated silicon and 22%-80% of zinc oxide, evenly dry-mixing, then calcinating at 1100 DEG C for 5-10 hours, and conducting water quenching to obtain a seed crystal; (3) evenly mixing and grinding the crystallized glaze in the step (1) and the seed crystal in the step (2) to obtain golden yellow crystallized dry-granular glaze, preparing the crystallized glaze and water as well as ball milling into slurry according to proportion in use, and evenly applying to the surface of a blank; drying and burning at 1200 DEG C-1350 DEG C for 5-7 hours. The glaze is brightly golden yellow, even and complete in crystal flowers, and the glaze is very attractive, and strong in adaptability.
Description
Technical field
The present invention relates to construction sanitary ceramic decoration technique field, especially relate to a kind of golden yellow crystallization dry granular glaze and using method thereof.
Background technology
Along with ceramic enters huge numbers of families, ceramic glaze is that pottery is made indispensable secondary raw material, and performance and the quality of ceramic had very important influence.Existing ceramic glaze is can rough classification as follows according to classification and purposes according to ceramic glaze: 1, lead glaze and leadless glaze; 2, raw glaze and fritted glaze; 3, once-firing or twice firing glaze; 4, ceramic tile, tableware, snitaryware and electroceramics glaze; 5, soak glaze, glaze spraying, water glaze by what enameling method was divided; 6, high melting glaze and low temperature glaze; 7, high expansion glaze and low bulk glaze; 8, firing atmosphere oxydizing flame, neutral flame and reducing flame; 9, coloured glaze and colourless glaze; 10, transparent and opaque glaze; 11, bright glaze, matt glaze, semi-mat glaze or figure glaze etc.; 12, function glaze is as fluorescence glaze, metal-lustrous glaze, crystalline glaze etc.Wherein the crystalline glaze ceramic tile is because its beautiful appearance exquisiteness extensively is subjected to liking of human consumer.Produce abundant, the beautiful in colour crystalline glaze of kind, become the target that China pottery producer is pursued.
Summary of the invention
The objective of the invention is to solve the problems of the prior art, and a kind of golden yellow crystallization dry granular glaze and using method thereof that is colour-stable, can satisfies the ceramic industry production requirement is provided.
The technical solution adopted in the present invention is such: a kind of golden yellow crystallization dry granular glaze may further comprise the steps:
(1), by weight percentage with 15%～22% feldspar, 20%～40% quartz, 6%～15% calcium carbonate, 6%～15% barium carbonate, 22%～50% zinc oxide, 0.7%～2.2%
With 0.7%～2.2%
, take by weighing that mixed grinding evenly behind each material, sieving obtains the crystallization glaze;
(2), by weight percentage with 20%～78% activated silica and 22%～80% zinc oxide, take by weighing mix dry mixing evenly behind each material after, after 5～10 hours, after shrend, obtain crystal seed through 1100 ℃ of calcinings again;
(3), the crystal seed that makes of crystallization glaze that step (1) is made and step (2), both mixed grindings evenly can make golden yellow crystallization dry granular glaze.
Preferably, the fineness of described crystallization glaze is less than 2% through the 10000-hole sieve excess.
A kind of using method of golden yellow crystallization dry granular glaze, (1), the golden yellow crystallization dry granular glaze that will make and water, ball milling, 1:(0.9～1 in proportion): (0.6～0.8) is through ball milling slurrying; (2), with the gained slurry, employing soaks glaze, be coated with glaze or glaze spraying mode to the base substrate glazing, and glazing thickness is 1～1.5mm, behind the body drying after the glazing, under 1200 ℃～1350 ℃, fired 5～7 hours, slowly obtain the golden yellow brilliant base substrate of spending face after the cooling with stove.
By adopting the aforementioned techniques scheme, the invention has the beneficial effects as follows: this crystalline glaze presents gorgeous golden yellow, and crystalline substance is spent evenly complete, and glaze integral body is intact, and is very attractive in appearance, and can be applicable to the glaze decoration of multiple base substrate, and adaptability is strong.During use, with this crystallization glaze and water, ball milling, 1:(0.9～1 in proportion): (0.6～0.8) makes slip, evenly imposes on billet surface; Wherein ball milling is the diameter of the ball of zirconium white or aluminum oxide material, the fineness of the corresponding meeting of the diameter value of different ball milling ectocrine abrasive lapping.Drying was fired 5～7 hours under 1200 ℃～1350 ℃, fired the base substrate that can obtain golden yellow brilliant flower face respectively; Method technology is simple, and cost is low, is fit to the batch process demand.
Embodiment
Describe the present invention particularly with embodiment below, scope of the present invention is not subjected to the restriction of embodiment.
Embodiment 1
(1), by weight percentage with 21% feldspar, 30% quartz, 8% calcium carbonate, 12% barium carbonate, 29% zinc oxide, 1.5%
With 2.5%
, taking by weighing that mixed grinding is evenly behind each material, sieving obtains the crystallization glaze, the fineness of crystallization glaze is less than 2% through the 10000-hole sieve excess;
(2), by weight percentage with 50% activated silica and 50% zinc oxide, take by weighing mix dry mixing evenly behind each material after, after 5～10 hours, after shrend, obtain crystal seed through 1100 ℃ of calcinings again;
(3), the crystal seed that makes of crystallization glaze that step (1) is made and step (2), both mixed grindings evenly can make golden yellow crystallization dry granular glaze.
A kind of using method of golden yellow crystallization dry granular glaze, the golden yellow crystallization dry granular glaze that (1), will make and water, ball milling, wherein ball milling is the diameter of the ball of zirconium white or aluminum oxide material, the fineness of the corresponding meeting of the diameter value of different ball milling ectocrine abrasive lapping, integral body is 1:(0.9～1 in proportion): (0.6～0.8) is through ball milling slurrying; (2) with the gained slurry, employing soaks glaze, be coated with glaze or glaze spraying mode to the base substrate glazing, glazing thickness is 1～1.5mm, behind the body drying after the glazing, under 1200 ℃～1350 ℃, fired 5～7 hours, slowly obtain the base substrate of golden yellow brilliant flower face after the cooling with stove, cost is low, suitability is high and very attractive in appearance.
Above-described, only be preferred embodiment of the present invention, can not limit scope of the invention process, every equalization of doing according to the present patent application claim changes and decorates, and all should still belong in the scope that the present invention contains.
Claims (3)
1. golden yellow crystallization dry granular glaze is characterized in that: may further comprise the steps:
(1), by weight percentage with 15%～22% feldspar, 20%～40% quartz, 6%～15% calcium carbonate, 6%～15% barium carbonate, 22%～50% zinc oxide, 0.7%～2.2%
With 0.7%～2.2%
, take by weighing that mixed grinding evenly behind each material, sieving obtains the crystallization glaze;
(2), by weight percentage with 20%～78% activated silica and 22%～80% zinc oxide, take by weighing mix dry mixing evenly behind each material after, after 5～10 hours, after shrend, obtain crystal seed through 1100 ℃ of calcinings again;
(3), the crystal seed that makes of crystallization glaze that step (1) is made and step (2), both mixed grindings evenly can make golden yellow crystallization dry granular glaze.
2. a kind of golden yellow crystallization dry granular glaze according to claim 1 is characterized in that: the fineness of described crystallization glaze for through the 10000-hole sieve excess less than 2%.
3. the using method of a kind of golden yellow crystallization dry granular glaze according to claim 1 and 2, it is characterized in that: (1), the golden yellow crystallization dry granular glaze that will make and water, ball milling, 1:(0.9～1 in proportion): (0.6～0.8) is through ball milling slurrying; (2), with the gained slurry, employing soaks glaze, be coated with glaze or glaze spraying mode to the base substrate glazing, and glazing thickness is 1～1.5mm, behind the body drying after the glazing, under 1200 ℃～1350 ℃, fired 5～7 hours, slowly obtain the golden yellow brilliant base substrate of spending face after the cooling with stove.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310272968.5A CN103332965B (en) | 2013-07-02 | 2013-07-02 | Golden yellow crystallized dry-granular glaze and using method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310272968.5A CN103332965B (en) | 2013-07-02 | 2013-07-02 | Golden yellow crystallized dry-granular glaze and using method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103332965A true CN103332965A (en) | 2013-10-02 |
| CN103332965B CN103332965B (en) | 2015-01-21 |
Family
ID=49241193
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310272968.5A Active CN103332965B (en) | 2013-07-02 | 2013-07-02 | Golden yellow crystallized dry-granular glaze and using method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103332965B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106587627A (en) * | 2016-12-16 | 2017-04-26 | 河南大宋官窑股份有限公司 | Crystalline glaze material, crystalline glaze Jun porcelain and preparation methods thereof |
| CN109809836A (en) * | 2018-12-13 | 2019-05-28 | 江苏新嘉理生态环境材料股份有限公司 | A kind of production method of special-shaped cube of pottery curtain wall terra-cotta |
| CN113105114A (en) * | 2021-04-06 | 2021-07-13 | 广东欧文莱陶瓷有限公司 | Crystalline dry grain face rock plate and preparation method thereof |
| CN113651607A (en) * | 2021-08-12 | 2021-11-16 | 广东宏宇新型材料有限公司 | Ceramic tile with night sky and river decoration effect |
| CN114804627A (en) * | 2022-04-24 | 2022-07-29 | 江苏省陶瓷研究所有限公司 | Reduction-sintering phase-separation-induced palace yellow croaker seed crystal glaze and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102173873A (en) * | 2011-01-27 | 2011-09-07 | 上海高诚艺术包装有限公司 | Transmutation glaze material and glazing process |
| CN102173869A (en) * | 2011-01-19 | 2011-09-07 | 江苏高淳陶瓷股份有限公司 | Preparation method of non-ferrous tea dust crystalline glaze |
| CN102249739A (en) * | 2011-05-26 | 2011-11-23 | 山西高陶瓷业有限责任公司 | Preparation method of carbon-golden metallic luster crystalline glaze |
| CN102936156A (en) * | 2012-10-30 | 2013-02-20 | 佛山市道氏陶瓷技术服务有限公司 | Glaze material of high temperature fast firing crystal glaze archaized brick and preparation process thereof |
-
2013
- 2013-07-02 CN CN201310272968.5A patent/CN103332965B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102173869A (en) * | 2011-01-19 | 2011-09-07 | 江苏高淳陶瓷股份有限公司 | Preparation method of non-ferrous tea dust crystalline glaze |
| CN102173873A (en) * | 2011-01-27 | 2011-09-07 | 上海高诚艺术包装有限公司 | Transmutation glaze material and glazing process |
| CN102249739A (en) * | 2011-05-26 | 2011-11-23 | 山西高陶瓷业有限责任公司 | Preparation method of carbon-golden metallic luster crystalline glaze |
| CN102936156A (en) * | 2012-10-30 | 2013-02-20 | 佛山市道氏陶瓷技术服务有限公司 | Glaze material of high temperature fast firing crystal glaze archaized brick and preparation process thereof |
Non-Patent Citations (1)
| Title |
|---|
| 吴从若: "硅酸锌基系列结晶釉试验及样品制作", 《江苏陶瓷》 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106587627A (en) * | 2016-12-16 | 2017-04-26 | 河南大宋官窑股份有限公司 | Crystalline glaze material, crystalline glaze Jun porcelain and preparation methods thereof |
| CN106587627B (en) * | 2016-12-16 | 2019-01-29 | 大宋官窑股份有限公司 | A kind of crystalline glaze glaze, crystalline glaze pottery and preparation method thereof |
| CN109809836A (en) * | 2018-12-13 | 2019-05-28 | 江苏新嘉理生态环境材料股份有限公司 | A kind of production method of special-shaped cube of pottery curtain wall terra-cotta |
| CN113105114A (en) * | 2021-04-06 | 2021-07-13 | 广东欧文莱陶瓷有限公司 | Crystalline dry grain face rock plate and preparation method thereof |
| CN113651607A (en) * | 2021-08-12 | 2021-11-16 | 广东宏宇新型材料有限公司 | Ceramic tile with night sky and river decoration effect |
| CN114804627A (en) * | 2022-04-24 | 2022-07-29 | 江苏省陶瓷研究所有限公司 | Reduction-sintering phase-separation-induced palace yellow croaker seed crystal glaze and preparation method thereof |
| CN114804627B (en) * | 2022-04-24 | 2023-11-14 | 江苏省陶瓷研究所有限公司 | Reduction firing phase separation induced palace Huang Yuzi crystal fancy glaze and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103332965B (en) | 2015-01-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102249739B (en) | Preparation method of carbon-golden metallic luster crystalline glaze | |
| CN103102178B (en) | Purple matt glaze and preparation method thereof | |
| CN102249738B (en) | Furnace transmutation glaze dolomitic pottery and preparation technique thereof | |
| CN105330158A (en) | Glaze of brunet ceramic and preparation method of glaze | |
| CN103332965B (en) | Golden yellow crystallized dry-granular glaze and using method thereof | |
| CN105753321B (en) | A kind of molybdenum system metallic luster crystalline glaze and preparation method thereof | |
| CN103332861A (en) | Preparation method of metallic luster glaze | |
| CN102173875B (en) | Preparation method of B2O3-TiO2 series fambe ceramic crystalline glaze | |
| CN106396638B (en) | Low temperature lightweight lime gradual change glaze ceramics and its manufacture craft | |
| CN103588506B (en) | Formula of black-matrix silver-strip streak ceramic glaze and preparation method thereof | |
| CN103319158A (en) | Method for preparing Nixing pottery through calcining | |
| CN104058789A (en) | Starlight enamel glaze material and application technique thereof | |
| CN102432342A (en) | Preparation method of vanadium-titanium-iron system golden crystal glaze | |
| CN110316968B (en) | Fast-fired polycrystalline multicolor crystal glaze and preparation method and application thereof | |
| CN103396166A (en) | Method for preparing zinc metasilicate crystal glaze by taking granite as parent glaze raw material | |
| CN106186696A (en) | Introduce ultra-fine alumina or the throwing glazed brick of ultrafine aluminium hydroxide raising glaze wearability and preparation method thereof | |
| CA2984659A1 (en) | Glaze resistant to wax block bonding, ceramic resistant to wax block bonding and preparation process thereof | |
| CN101607786B (en) | Chinese red ceramic glaze and glaze technology thereof | |
| CN107721179B (en) | Preparation method of Jun porcelain bluish-blue glaze | |
| CN100450977C (en) | Method of manufacturing starlight glaze | |
| CN109748506B (en) | Metal crystal glaze, ceramic tile and preparation method thereof | |
| CN106316127B (en) | Medium-temperature golden plum crystal glaze and preparation method thereof | |
| CN102557754A (en) | Formula of opacified glaze | |
| CN107601898B (en) | Preparation method of Jun porcelain blue glaze | |
| CN107663022B (en) | Celeste jun porcelain glaze and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20240115 Address after: Office Building 55, West Industrial Zone, Dapu Village, Cizao Town, Jinjiang City, Quanzhou City, Fujian Province, 362000 Patentee after: Quanzhou Omico New Material Technology Co.,Ltd. Address before: 362000 first floor, comprehensive building of advanced manufacturing technology service base, detai Road, economic and Technological Development Zone, Quanzhou City, Fujian Province Patentee before: QUANZHOU OUMIKE ECOLOGY MATERIALS TECHNOLOGY Co.,Ltd. |
|
| TR01 | Transfer of patent right |