CN114804627B - Reduction firing phase separation induced palace Huang Yuzi crystal fancy glaze and preparation method thereof - Google Patents
Reduction firing phase separation induced palace Huang Yuzi crystal fancy glaze and preparation method thereof Download PDFInfo
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- CN114804627B CN114804627B CN202210433551.1A CN202210433551A CN114804627B CN 114804627 B CN114804627 B CN 114804627B CN 202210433551 A CN202210433551 A CN 202210433551A CN 114804627 B CN114804627 B CN 114804627B
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- 239000013078 crystal Substances 0.000 title claims abstract description 57
- 238000010304 firing Methods 0.000 title claims abstract description 35
- 238000005191 phase separation Methods 0.000 title claims abstract description 35
- 230000009467 reduction Effects 0.000 title claims abstract description 34
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 239000000919 ceramic Substances 0.000 claims abstract description 18
- 239000007791 liquid phase Substances 0.000 claims abstract description 12
- 239000000203 mixture Substances 0.000 claims description 19
- 238000000498 ball milling Methods 0.000 claims description 14
- 238000004040 coloring Methods 0.000 claims description 14
- 239000008139 complexing agent Substances 0.000 claims description 14
- 239000002994 raw material Substances 0.000 claims description 14
- 239000010453 quartz Substances 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 230000015572 biosynthetic process Effects 0.000 claims description 6
- 230000006698 induction Effects 0.000 claims description 6
- 238000007598 dipping method Methods 0.000 claims description 5
- 238000005507 spraying Methods 0.000 claims description 5
- 229910015902 Bi 2 O 3 Inorganic materials 0.000 claims description 4
- 229910021532 Calcite Inorganic materials 0.000 claims description 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 4
- 239000001506 calcium phosphate Substances 0.000 claims description 4
- 229910000389 calcium phosphate Inorganic materials 0.000 claims description 4
- 235000011010 calcium phosphates Nutrition 0.000 claims description 4
- 238000007599 discharging Methods 0.000 claims description 4
- 239000010433 feldspar Substances 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 229910052744 lithium Inorganic materials 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 239000002689 soil Substances 0.000 claims description 4
- 238000003786 synthesis reaction Methods 0.000 claims description 4
- 235000012222 talc Nutrition 0.000 claims description 4
- 239000000454 talc Substances 0.000 claims description 4
- 229910052623 talc Inorganic materials 0.000 claims description 4
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 3
- 230000001105 regulatory effect Effects 0.000 claims description 3
- 238000007873 sieving Methods 0.000 claims description 2
- 238000001354 calcination Methods 0.000 claims 1
- 230000000087 stabilizing effect Effects 0.000 claims 1
- 238000005303 weighing Methods 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 19
- 238000002425 crystallisation Methods 0.000 abstract description 7
- 230000008025 crystallization Effects 0.000 abstract description 7
- 239000011521 glass Substances 0.000 abstract description 5
- 239000007788 liquid Substances 0.000 abstract description 5
- 238000000926 separation method Methods 0.000 abstract description 5
- 238000005245 sintering Methods 0.000 abstract description 5
- 239000002131 composite material Substances 0.000 abstract description 3
- 229910052723 transition metal Inorganic materials 0.000 abstract description 3
- 238000013329 compounding Methods 0.000 abstract description 2
- 238000005034 decoration Methods 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000002955 isolation Methods 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 241000721047 Danaus plexippus Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000006103 coloring component Substances 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- OJYBUGUSFDKJEX-UHFFFAOYSA-N tungsten zirconium Chemical compound [Zr].[W].[W] OJYBUGUSFDKJEX-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Abstract
The invention relates to a ceramic glaze, in particular to a palace Huang Yuzi crystal fancy glaze induced by reduction firing phase separation and a preparation method thereof. The crystal fancy glaze for imperial target Huang Yuzi through reduction sintering phase separation includes 15-25% of color crystal nucleus compounding agent and 75-85% of liquid phase separation functional environment group. The reduction firing phase separation induced imperial Huang Yuzi crystal fancy glaze provided by the invention has the advantages that the reduction firing phase separation induced imperial Huang Yuzi crystal fancy glaze is stably and controllably realized under the reduction firing condition by adopting transition metal element color-developing crystal nucleus composite steady-state preset treatment and the selective enrichment effect of two-liquid separation isolated relative crystallization color-developing components of the glaze glass, so that the novel crystal artistic glaze which can be fired under the conventional reduction condition is obtained.
Description
Technical Field
The invention relates to a ceramic glaze, in particular to a palace Huang Yuzi crystal fancy glaze induced by reduction firing phase separation and a preparation method thereof.
Background
According to the search, no related technical content report of reduction firing phase separation induction of imperial Huang Yuzi crystal fancy glaze exists at home and abroad at present. As an adjacent crystallization glaze technology, the appearance effect is realized by severely depending on the harsh process of quenching and long-time heat preservation on firing, and even so, the controllability of the decoration effect is still poor, and the method cannot be applied to the stable production of mass products. The ideal effect can not be achieved under the severe atmosphere condition of reduction firing.
The grain and phase-splitting precursor crystal fancy glaze disclosed in Chinese patent CN102887729B has controllable crystal fancy effect and easy realization by applying the dual precursor actions of the grain presetting and the base glaze phase-splitting technology, and avoids the severe sintering requirement to a great extent, but has no crystal fancy form and color effect peculiar to the palace Huang Yuzi crystal in appearance effect and cannot be sintered under the reducing condition. It can be seen that the existing ceramic glaze technology is substantially different from the reduction firing phase separation induction palace Huang Yuzi crystal fancy glaze of the invention in artistic effect and formation mechanism. So far, under the condition of reduction firing, no ideal crystal flower artistic glaze exists, and the further development of the reduction firing artistic ceramic product is restricted.
Disclosure of Invention
In order to solve the problems, the invention provides a novel crystal artistic glaze effect which can be sintered under the conventional reduction condition and has high and noble appearance and honour imperial effect by adopting the integrated steady-state preset treatment of transition element color-forming crystal nucleus, the two-liquid separation and isolation of glaze glass, relative crystallization and the selective enrichment effect of color-forming components, so that the stereoscopic crystal effect of the palace-like yellow roe on the glaze can be stably and controllably realized under the reduction sintering condition. The artistic space and the added value of the ceramic product are greatly expanded. The specific technical scheme is as follows:
the crystal fancy glaze for imperial target Huang Yuzi through reduction sintering phase separation includes 15-25% of color crystal nucleus compounding agent and 75-85% of liquid phase separation functional environment group.
Preferably, the coloring crystal nucleus complexing agent consists of the following raw materials in parts by weight: WO (WO) 3 ：18-22％、Bi 2 O 3 ：10-13％、TiO 2 ：20-30％、Fe 2 O 3 ：12-18％、MgCO 3 ：8-12％、ZrO 2 :10-15%, quartz: 7-10%.
Preferably, the liquid phase separation functional environmental group consists of the following raw materials in weight: lithium feldspar: 38-44%, quartz: 10-14%, suzhou soil: 6-10% BaCO 3 ：2-6％、SrCO 3 :5-6%, calcium phosphate: 6-10% of TiO 2 :3-5 percent of calcite: 5-8% of talcum: 10-16%.
The preparation method of the crystal fancy glaze for the palace Huang Yuzi by reduction firing phase separation induction comprises the following steps:
preparation of a coloring crystal nucleus complexing agent: the raw materials of the coloring crystal nucleus complexing agent are respectively weighed and then added into a ball mill, ball milling and mixing are carried out according to the material water ratio of 1:0.8, the mixture is sieved by a 60-mesh sieve, the mixture is calcined at 1100 ℃ in a kiln after being dried, stable synthesis is carried out, and the mixture is subjected to ball milling and 80-mesh standby.
Preparing a liquid phase separation functional environment group and a finished glaze: the raw materials of the liquid phase separation functional environment groups are respectively weighed and then added into a ball mill, ball milling is carried out according to the material water ratio of 1:0.8, the color crystal nucleus complexing agent is added according to the proportion for 2 hours before ball discharging, the mixture is ball milled together, and the mixture is sieved by a 100-mesh sieve, and the concentration is regulated to be 50-55 Baume degrees for standby.
A firing method for reducing and firing phase separation induction imperial court Huang Yuzi crystal fancy glaze adopts a glaze dipping or glaze spraying method to decorate the surface of a ceramic blank with the reducing and firing phase separation induction imperial court Huang Yuzi crystal fancy glaze, and the ceramic blank is subjected to reducing and firing at 1260-1280 ℃ after drying.
Compared with the prior art, the invention has the following beneficial effects:
the reduction firing phase separation induced imperial Huang Yuzi crystal fancy glaze provided by the invention has the advantages that the reduction firing phase separation induced imperial Huang Yuzi crystal fancy glaze is stably and controllably realized under the reduction firing condition by adopting transition metal element color-developing crystal nucleus composite steady-state preset treatment and the selective enrichment effect of two-liquid separation isolated relative crystallization color-developing components of the glaze glass, so that the novel crystal artistic glaze which can be fired under the conventional reduction condition is obtained.
The mechanism is as follows: the transition metal element coloring and crystal nucleus components are preset through the composite stabilization of the tungsten-zirconium crystal, so that the coloring and crystal nucleus components can play a role stably and controllably under the common reduction sintering condition, and the bottleneck interference problem of the reducing atmosphere on crystallization and coloring is fundamentally solved; the unique glazed glass composition enables the isolated relative color development of the two-liquid separation area and the selective enrichment effect of the crystallization group component, thereby enabling the glaze to present the unique palace yellow roe-shaped three-dimensional crystal flower effect, highlighting the noble and most noble monarch gas and filling the blank of reduction firing of high-grade crystalline glaze.
The product of the invention is a high-grade novel artistic glaze for ceramic decoration. When in use, the finished glaze of the invention can be decorated on the surface of a ceramic blank by adopting a glaze dipping or glaze spraying method, and is reduced and burned in a shuttle gas kiln at 1260-1280 ℃ after being dried. The product of the invention has conventional preparation process, is suitable for decoration of high-grade artistic ceramics and daily ceramics, has novel and unique decoration effect, and is a novel artistic glaze material with special formation mechanism for ceramic decoration.
Drawings
FIG. 1 is a schematic diagram of reduction firing phase separation induced imperial Huang Yuzi crystal flower glaze firing orange;
fig. 2 is a schematic diagram of reduction firing phase separation induced imperial Huang Yuzi crystal flower glaze firing golden yellow.
Detailed Description
The invention will now be further described with reference to the accompanying drawings.
The invention provides a method for realizing steady-state presetting treatment of transition element coloring crystal nucleus integration, and selective enrichment effect of glaze glass two-liquid separation and isolation relative crystallization and coloring components, so that the effect of palace-yellow roe-shaped three-dimensional crystal flower on the glaze surface can be stably and controllably realized under the condition of reduction firing, and the novel crystal artistic glaze effect which can be fired under the conventional reduction condition is obtained, and the imperial gas with noble appearance and honour is obtained. The artistic space and the added value of the ceramic product are greatly expanded. The invention of the ceramic artistic glaze opens up a new way for the development of high-grade ceramic artistic glaze and has the meaning of methodology.
Example 1
As shown in fig. 1, reduction firing phase separation induced imperial Huang Yuzi crystal fancy glaze, wherein the color is yellow (orange) with warm color:
the content of the coloring crystal nucleus complexing agent is as follows:
liquid phase separation functional environment group and finished glaze content:
a coloring crystal nucleus complexing agent: WO (WO) 3 ：22％、Bi 2 O 3 ：13％、TiO 2 ：21％、Fe 2 O 3 ：18％、MgCO 3 ：8％、ZrO 2 :9% of quartz.
The raw materials are respectively weighed and then added into a ball mill, ball milling and mixing are carried out according to the water ratio of 1:0.8, the mixture is sieved by a 60-mesh sieve, the mixture is calcined at 1100 ℃ in a kiln after being dried, stable synthesis is carried out, and the mixture is subjected to ball milling and 80-mesh standby.
Liquid phase separation functional environment groups and finished glaze: lithium feldspar: 38%, quartz: 12%, suzhou soil: 6%, baCO 3 ：5％、SrCO 3 :6%, calcium phosphate 8%, tiO 2 :3%, calcite: 8%, talc: 14%. The raw materials are respectively weighed and then added into a ball mill, ball milling is carried out according to the water ratio of 1:0.8, and the weight ratio is 75 after 2 hours before ball discharging: 25 proportion of the coloring crystal nucleus complexing agent is added, ball milling is carried out, a 100-mesh sieve is adopted, and the concentration is regulated to 50-55 Baume degrees for standby.
The finished glaze is decorated on the surface of the ceramic blank by adopting a glaze dipping or glaze spraying method, and is reduced and sintered in a shuttle gas kiln at 1260-1280 ℃ after being dried.
Example two
As shown in fig. 2, reduction firing phase separation induced imperial Huang Yuzi crystal fancy glaze, wherein the color is a yellow system with cold tone (golden yellow):
a coloring crystal nucleus complexing agent:
WO 3 ：18％、Bi 2 O 3 ：10％、TiO 2 ：28％、Fe 2 O 3 ：12％、MgCO 3 ：11％、ZrO 2 :11% and 10% of quartz. The raw materials are respectively weighed and then added into a ball mill, ball milling and mixing are carried out according to the water ratio of 1:0.8, the mixture is sieved by a 60-mesh sieve, the mixture is calcined at 1100 ℃ in a kiln after being dried, stable synthesis is carried out, and the mixture is subjected to ball milling and 80-mesh standby.
Liquid phase separation functional environment groups and finished glaze: lithium feldspar: 44. quartz: 14%, suzhou soil: 8%, baCO 3 ：2％、SrCO 3 :5% of calcium phosphate: 6% TiO 2 :5% calcite: 5% of talcum: 11%.
The raw materials are respectively weighed and then added into a ball mill, ball milling is carried out according to the feed water of 1:0.8, the weight ratio is 86 after 2 hours before ball discharging: 14 proportion of coloring crystal nucleus complexing agent, ball milling, sieving with 100 mesh sieve, and adjusting concentration to 50-55 Baume degree for standby.
The finished glaze is decorated on the surface of the ceramic blank by adopting a glaze dipping or glaze spraying method, and is reduced and sintered in a shuttle gas kiln at 1260-1280 ℃ after being dried.
The technical principle of the present invention is described above in connection with the specific embodiments. The description is made for the purpose of illustrating the general principles of the invention and should not be taken in any way as limiting the scope of the invention. Other embodiments of the invention will occur to those skilled in the art from consideration of the specification and practice of the invention without the need for inventive faculty, and are within the scope of the claims.
Claims (3)
1. The reduction firing phase separation induced imperial Huang Yuzi crystal fancy glaze is characterized by comprising 15-25% of a coloring crystal nucleus complexing agent and 75-85% of a liquid phase separation functional environment group
The color-developing crystal nucleus complexing agent consists of the following raw materials in parts by weight:
WO 3 ：18-22%、Bi 2 O 3 ：10-13%、TiO 2 ：20-30%、Fe 2 O 3 ：12-18%、MgCO 3 ：8-12%、ZrO 2 :10-15%, quartz: 7-10%;
the liquid phase separation functional environment group consists of the following raw materials in weight:
lithium feldspar: 38-44%, quartz: 10-14%, suzhou soil: 6-10% BaCO 3 ：2-6%、SrCO 3 :5-6%, calcium phosphate: 6-10% of TiO 2 :3-5 percent of calcite: 5-8% of talcum: 10-16%.
2. The method for preparing the crystal fancy glaze of palace Huang Yuzi by reduction firing phase separation induction according to claim 1, which is characterized by comprising the following steps:
preparation of a coloring crystal nucleus complexing agent: respectively weighing raw materials of the color nucleus complexing agent, adding the raw materials into a ball mill, ball-milling and mixing the raw materials with water in a ratio of 1:0.8, sieving the mixture with a 60-mesh sieve, drying the mixture, calcining the mixture in a kiln at 1100 ℃, stabilizing the mixture for synthesis, and ball-milling the mixture with 80 meshes for later use;
preparing a liquid phase separation functional environment group and a finished glaze: the raw materials of the liquid phase separation functional environment groups are respectively weighed and then added into a ball mill, ball milling is carried out according to the material water ratio of 1:0.8, the color crystal nucleus complexing agent is added according to the proportion for 2 hours before ball discharging, the mixture is ball milled together, and the mixture is sieved by a 100-mesh sieve, and the concentration is regulated to be 50-55 Baume degrees for standby.
3. The method for firing a reduced firing phase separation induced imperial Huang Yuzi crystal glazing according to claim 1, wherein,
the ceramic body is decorated with a reduction firing phase separation induced imperial Huang Yuzi crystal fancy glaze by adopting a glaze dipping or glaze spraying method, and is subjected to reduction firing at 1260-1280 ℃ after drying.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210433551.1A CN114804627B (en) | 2022-04-24 | 2022-04-24 | Reduction firing phase separation induced palace Huang Yuzi crystal fancy glaze and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210433551.1A CN114804627B (en) | 2022-04-24 | 2022-04-24 | Reduction firing phase separation induced palace Huang Yuzi crystal fancy glaze and preparation method thereof |
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| CN114804627A CN114804627A (en) | 2022-07-29 |
| CN114804627B true CN114804627B (en) | 2023-11-14 |
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| CN106116695A (en) * | 2016-05-06 | 2016-11-16 | 福建省德化县万益陶瓷有限公司 | Sapphire blue spun gold iron wire glaze porcelain and preparation method |
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| CN114163127A (en) * | 2021-12-06 | 2022-03-11 | 佛山市金舵陶瓷有限公司 | Preparation method of porcelain tile with special micro-drilling particle distribution effect |
-
2022
- 2022-04-24 CN CN202210433551.1A patent/CN114804627B/en active Active
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| US5268339A (en) * | 1986-09-17 | 1993-12-07 | Lanxide Technology Company, Lp | Method for in situ tailoring the component of ceramic articles |
| US6012304A (en) * | 1991-09-30 | 2000-01-11 | Loxley; Ted A. | Sintered quartz glass products and methods for making same |
| CN1887147A (en) * | 2005-06-27 | 2007-01-03 | 江苏省陶瓷研究所有限公司 | Western tableware of iron and ceramic and its making process |
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| CN114163127A (en) * | 2021-12-06 | 2022-03-11 | 佛山市金舵陶瓷有限公司 | Preparation method of porcelain tile with special micro-drilling particle distribution effect |
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| CN114804627A (en) | 2022-07-29 |
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