CN105693207B - A kind of preparation method of tea dust artistic porcelain - Google Patents
A kind of preparation method of tea dust artistic porcelain Download PDFInfo
- Publication number
- CN105693207B CN105693207B CN201610025608.9A CN201610025608A CN105693207B CN 105693207 B CN105693207 B CN 105693207B CN 201610025608 A CN201610025608 A CN 201610025608A CN 105693207 B CN105693207 B CN 105693207B
- Authority
- CN
- China
- Prior art keywords
- parts
- glaze
- kaolin
- talcum
- raw material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/24—Manufacture of porcelain or white ware
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
- C04B2235/3472—Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Dispersion Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
The invention discloses a kind of tea dust artistic porcelains and preparation method thereof, belong to field of ceramic preparation technology, including green body and the glaze for being wrapped in billet surface, which is made of the raw material of following weight parts: 28~42 parts of kaolin, 12~25 parts of potassium feldspar, quartzy 8~18 parts, 12~25 parts of porcelain clay tailings, 1~3 part of talcum, 12~25 parts of beef liver stone, 1~3 part of calcite；The glaze is made of the raw material of following weight parts: 2~15 parts of kaolin, 28~45 parts of potassium feldspar, quartzy 10~25 parts, 12~25 parts of calcite, 8~20 parts of talcum, 1~3 part of tricalcium phosphate, 2~15 parts of iron oxide；The present invention is intended to provide a kind of formula science, tea dust artistic porcelain that cost is relatively low and product is of good quality and preparation method thereof；Preparation for tea dust artistic porcelain.
Description
Technical field
The present invention relates to a kind of processing of ceramic product, more specifically more particularly to a kind of preparation of tea dust artistic porcelain
Method.
Background technique
Tea-dust glaze is one of kind important in Ancient Times in China iron crystalline glaze, belongs to high temperature yellow glaze, burns through high temperature reduction flame
At.Tea-dust glaze began to burn in the Tang Dynasty, and Yao county kiln at that time was once largely fired, Tang and Song Dynasty time, Shanxi Huiyuan kiln and northern area one
The kiln for burning black glaze a bit also has burning to make.It is contained in Yongzheng's Qianrong's period, the secret glaze of Qing Dynasty's tea-dust glaze category government porcelain kiln, mostly royal noble institute
Treasure and delight in.It is furnished with yellow green crystallite on glaze, is in semimat shape, quite like tealeaves smalls, green person claims tea, and yellow person claims end, therefore and obtains
Name tealeaves small skill art glaze.It sees on the whole, tea dust artistic glaze between yellow and green, get over by this unique artistic effect
Liked to get over by people.High temperature coloured glaze kind one of of the tea dust artistic glaze as Chinese tradition, quite seemingly with its shape
Tealeaves smalls and gain the name, it is the crystallization glaze porcelain that iron content is high in glaze.Its glaze colours is yellow, and in adulterate it is green.Due to formula and
The variation of manufacture craft, glaze colours are not quite similar.Traditional tea dust artistic glaze is larger to firing condition sensibility, firing temperature pair
Tea dust crystallization and colour generation influence are very big, while traditional manufacturing technique is also harsher to formula selection, generallys use high-quality
Ceramic raw material, therefore, yield rate is low and with high costs.
Summary of the invention
It is an object of the invention in view of the above shortcomings of the prior art, provide, a kind of formula is scientific, cost is relatively low and produces
Product tea dust artistic porcelain of good quality.
Another object of the present invention is to provide a kind of methods for preparing above-mentioned tea dust artistic porcelain.
Previous technical solution of the invention is achieved in that a kind of tea dust artistic porcelain, including green body and is wrapped in base
The glaze in body surface face, the green body are made of the raw material of following weight parts: 28~42 parts of kaolin, 12~25 parts of potassium feldspar, quartz 8
~18 parts, 12~25 parts of porcelain clay tailings, 1~3 part of talcum, 12~25 parts of beef liver stone, 1~3 part of calcite；
The glaze is made of the raw material of following weight parts: 2~15 parts of kaolin, 28~45 parts of potassium feldspar, quartz 10~25
Part, 12~25 parts of calcite, 8~20 parts of talcum, 1~3 part of tricalcium phosphate, 2~15 parts of iron oxide.
In a kind of above-mentioned tea dust artistic porcelain, which is made of the raw material of following weight parts: 30~40 parts of kaolin,
15~20 parts of potassium feldspar, quartzy 10~15 parts, 15~20 parts of porcelain clay tailings, 1~2 part of talcum, 15~20 parts of beef liver stone, calcite
1~2 part；
The glaze is made of the raw material of following weight parts: 4~10 parts of kaolin, 32~42 parts of potassium feldspar, quartz 12~20
Part, 15~20 parts of calcite, 10~15 parts of talcum, 1~2 part of tricalcium phosphate, 5~12 parts of iron oxide.
Latter technique scheme of the invention is achieved in that a kind of method for preparing above-mentioned tea dust artistic porcelain, including
Following step:
(1) body preparation: after each raw material is weighed by formula ratio, being added in ball milling and grind, be then sequentially sieved, be aging,
Injection forming；Wherein when ball milling, material: ball: the ratio of water is 1:1.8~2.2:0.5~0.6；Additionally addition accounts for when grinding
The waterglass of formula material total weight 0.5%；Fineness of grind is 0.2~1.0% to be tailed over by 250 meshes；
(2) prepared by glaze: it is (a) that kaolin, potassium feldspar, quartz, calcite, talcum is fine crushing, 20 meshes are crossed, standby is dried
With；(b) kaolin, potassium feldspar, quartz, calcite and talcum after drying fine crushing are weighed by formula ratio, adds the phosphorus of formula ratio
Sour tricalcium and iron oxide are added in ball milling and grind, wherein when ball milling, material: ball: the ratio of water are as follows: 1:1.8~2.2:0.5
~1.0, fineness of grind is 0.05~0.5% to be tailed over by 250 meshes；
(3) glazing: selecting spray glazing or waterfall process or glaze method to carry out glazing according to type, glazing with a thickness of 1.2~
2mm；
(4) it is burnt into: being burnt into using reducing atmosphere or oxidizing atmosphere, moisture content is 2~4% when green body enters kiln；Firing temperature
It is 1250~1290 DEG C；Firing time is 20 minutes 7 hours~40 minutes 10 hours.
In the preparation method of above-mentioned tea dust artistic porcelain, step (3) glazing is specifically, big part and complicated type use
The multiple glaze spraying of spray glazing, thickness control are 1.2mm~2.0mm；Regular device shape uses waterfall process, and thickness control is 1.5~2mm；
Smallclothes type uses glaze method, and thickness control is 1.5~2mm.
In the preparation method of above-mentioned tea dust artistic porcelain, in step (4), when using reducing atmosphere, lighting a fire to 980 DEG C is oxygen
Change flame to be burnt into the stage, firing time is 2.5~3.5 hours, and 980 DEG C to 1250~1290 DEG C are firing with reductive flame stage, firing
Time is 3.5~4.5 hours, and 1250~1290 DEG C keep the temperature 10~20 minutes, and 1160 DEG C are then cooled in 30~50 minutes
And 1~1.5 hour is kept the temperature, final cooled to room temperature obtains finished product；Product is covered with dirty-green after burning or yellow green matt shape is micro-
It is brilliant；
When using oxidizing atmosphere, igniting to 950 DEG C the firing stage 2.5~3.5 hours, 950 DEG C to 1250~1290 DEG C
The firing stage 3~4 hours, 1250~1290 DEG C kept the temperature 20~30 minutes, and 1160 DEG C are then cooled in 30~50 minutes simultaneously
Heat preservation 1~1.5 hour, final cooled to room temperature obtains finished product；Product is covered with khaki after burning or grey khaki matt shape is micro-
It is brilliant.
The present invention is using formula and technique, in conjunction with the china clay after this area beef liver stone raw ore abundant and the exploitation of a large amount of china clay
The lower quality feedstocks such as tailing.A small amount of P can be provided by adding a small amount of tricalcium phosphate simultaneously2O5And CaO, there is preferable phase separation, energy
Promote microcrystal in the rapid aggregation of sintering process and is uniformly distributed.By scientific matching rational formula process debugging, using wound
New calcining system is finally obtained high-grade tea dust artistic glaze new product, enriches ceramic colour glaze kind.In addition, this
Invention is to the integrated application level for improving china clay mineral resources and reduces environmental pollution caused by porcelain clay tailings accumulation with very
Important meaning.
The steady production of tea dust artistic glaze is extended to the application of big product from miscellaneous goods, enriches the type of product, I
The tea dust artistic glaze technology of preparing develop, grasped can provide technical support for associated ceramic enterprise, greatly improve production effect
Rate saves the ceramic mineral resource of growing tension, produces the tea dust artistic glaze product of high-quality.Tea dust artistic glaze product
Mass production, be generalized to huge numbers of families, people can be allowed to know more about this rare enamel of tea dust, increase people to China
The understanding of porcelain and culture of porcelain.
Specific embodiment
The present invention is described in further detail combined with specific embodiments below, but does not constitute to of the invention any
Limitation.
A kind of tea dust artistic porcelain of the invention, including green body and the glaze for being wrapped in billet surface, the green body is by following
The raw materials of parts by weight forms: 28~42 parts of kaolin, 12~25 parts of potassium feldspar, 8~18 parts of quartz, 12~25 parts of porcelain clay tailings,
1~3 part of talcum, 12~25 parts of beef liver stone, 1~3 part of calcite；
The glaze is made of the raw material of following weight parts: 2~15 parts of kaolin, 28~45 parts of potassium feldspar, quartz 10~25
Part, 12~25 parts of calcite, 8~20 parts of talcum, 1~3 part of tricalcium phosphate, 2~15 parts of iron oxide.
Preferably, which is made of the raw material of following weight parts: 30~40 parts of kaolin, 15~20 parts of potassium feldspar, stone
10~15 parts of English, 15~20 parts of porcelain clay tailings, 1~2 part of talcum, 15~20 parts of beef liver stone, 1~2 part of calcite；
The glaze is made of the raw material of following weight parts: 4~10 parts of kaolin, 32~42 parts of potassium feldspar, quartz 12~20
Part, 15~20 parts of calcite, 10~15 parts of talcum, 1~2 part of tricalcium phosphate, 5~12 parts of iron oxide.
Iron oxide is main crystallizing agent and colorant, formation and the colour generation of tea dust crystallite is directly affected, with oxidation
The increase of iron content, glaze face color is from pistac to pale brown brown transition.Talcum is good fluxing agent, can widen the burning of glaze
At range, tricalcium phosphate is more suitable for tea dust artistic glaze in bone ash on year-on-year basis, and (bone ash will affect ferro element in the high glaze of iron content
Color development), in addition to providing a small amount of P2O5, a small amount of CaO is additionally provided, there is good phase separation, tea dust can be promoted micro-
Crystal rapid aggregation and is uniformly distributed in sintering process, to make tea dust artistic glaze surfacing, asterism is evenly distributed.
It is improved by formula, realizes and same burn with can stablize under the conditions of aoxidizing and restoring two kinds of different calcining systems
System.The just right introducing of the present invention is capable of forming the compound of the iron of stable chemical bond, calcium, magnesium, these three compounds are to gas
Atmosphere firing susceptibility is low, and iron oxide all only can in the green for aoxidizing the yellow shown when firing and presenting in reductive firing
Change tea dust product entirety color sensation, tea dust crystallite is still high-visible, at the same yellow and green be also we required for
Color.
A kind of method preparing tea dust artistic porcelain of the invention, includes the following steps:
(1) body preparation: after each raw material is weighed by formula ratio, being added in ball milling and grind, be then sequentially sieved, be aging,
Injection forming；Wherein when ball milling, material: ball: the ratio of water is 1:1.8~2.2:0.5~0.6；Additionally addition accounts for when grinding
The waterglass of formula material total weight 0.5%；Fineness of grind is to tail over 0.2~1.0% by 250 meshes；
(2) prepared by glaze: it is (a) that kaolin, potassium feldspar, quartz, calcite, talcum is fine crushing, 20 meshes are crossed, standby is dried
With；(b) kaolin, potassium feldspar, quartz, calcite and talcum after drying fine crushing are weighed by formula ratio, adds the phosphorus of formula ratio
Sour tricalcium and iron oxide are added in ball milling and grind, wherein when ball milling, material: ball: the ratio of water are as follows: 1:1.8~2.2:0.5
~1.0, fineness of grind is 0.05~0.5% to be tailed over by 250 meshes；
(3) glazing: selecting spray glazing or waterfall process or glaze method to carry out glazing according to type, glazing with a thickness of 1.2~
2mm；Specifically: big part and complicated type use the multiple glaze spraying of spray glazing, and thickness control is 1.2mm~2.0mm；Regular device shape is adopted
With waterfall process, thickness control is 1.5~2mm；Smallclothes type uses glaze method, and thickness control is 1.5~2mm.
(4) it is burnt into: being burnt into using reducing atmosphere or oxidizing atmosphere, moisture content is 2~4% when green body enters kiln；Firing temperature
It is 1250~1290 DEG C；Firing time are as follows: 20 minutes 7 hours~40 minutes 10 hours.
When specifically, using reducing atmosphere, igniting is burnt into the stage to 980 DEG C for oxidizing flame, and firing time is 2.5~3.5
Hour, 980 DEG C to 1250~1290 DEG C are the firing with reductive flame stage, and firing time is 3.5~4.5 hours, 1250~1290 DEG C
Then heat preservation 10~20 minutes is cooled to 1160 DEG C in 30~50 minutes and keeps the temperature 1~1.5 hour, finally naturally cools to
Room temperature obtains finished product；Product is covered with dirty-green or yellow green matt shape crystallite after burning；
When using oxidizing atmosphere, igniting to 950 DEG C of 2.5~3.5 hours firing used times in stage, 950 DEG C to 1250~
1290 DEG C of 3~4 hours firing used times in stage, 1250~1290 DEG C keep the temperature 20~30 minutes, then cooling in 30~50 minutes
To 1160 DEG C and 1~1.5 hour is kept the temperature, final cooled to room temperature obtains finished product；Product is covered with khaki or the grey colour of loess after burning
Color matt shape crystallite.
Tea dust artistic glaze heating rate in sintering process is too fast to make crystallization temperature needed for glaze improve, or oxidation is endless
Entirely, the defects of forming bubble；Cooling can be such that crystallite seems from reaching required size, glaze in single colour glaze very much fastly.Firing temperature
Too many residual Free quartz matter mixture easy to form in too low then glaze is spent, iron oxide reaction is insufficient, and glaze pin hole is more and inclined
Grey black.
Embodiment 1
Body recipe is made of the raw material of following weight parts: 28 parts of kaolin, 12 parts of potassium feldspar, quartzy 8 parts, porcelain clay tailings
12 parts, 1 part of talcum, 12 parts of beef liver stone, 1 part of calcite；
Glaze formula is made of the raw material of following weight parts: 2 parts of kaolin, 28 parts of potassium feldspar, quartzy 10 parts, calcite 12
Part, 8 parts of talcum, 1 part of tricalcium phosphate, 2 parts of iron oxide.
Preparation method: (1) body preparation: by each raw material by formula ratio weighing after, be added in ball milling and grind, then sequentially mistake
Sieve, aging, injection forming；Wherein when ball milling, material: ball: the ratio of water is 1:1.8:0.5；It additionally adds to account for when grinding and match
The waterglass of square raw material gross weight 0.5%；Fineness of grind is 0.2% to be tailed over by 250 meshes；
(2) prepared by glaze: it is (a) that kaolin, potassium feldspar, quartz, calcite, talcum is fine crushing, 20 meshes are crossed, standby is dried
With；(b) kaolin, potassium feldspar, quartz, calcite and talcum after drying fine crushing are weighed by formula ratio, adds the phosphorus of formula ratio
Sour tricalcium and iron oxide are added in ball milling and grind, wherein when ball milling, material: ball: the ratio of water are as follows: 1:1.8:0.5, grinding
Fineness is 0.05% to be tailed over by 250 meshes；
(3) glazing: big part and complicated type use the multiple glaze spraying of spray glazing, and thickness control is 1.2mm~2.0mm；Rule
Device shape uses waterfall process, and thickness control is 1.5~2mm；Smallclothes type uses glaze method, and thickness control is 1.5~2mm.
(4) it is burnt into: being burnt into using reducing atmosphere, moisture content is 2% when green body enters kiln；When firing, lighting a fire to 980 DEG C is oxygen
Change flame to be burnt into the stage, the used time 2.5 hours, 980 DEG C to 1250 DEG C are the firing with reductive flame stage, and the used time 3.5 hours, 1250 DEG C kept the temperature
10 minutes, it is then cooled to 1160 DEG C in 30 minutes and keeps the temperature 1 hour, final cooled to room temperature obtains finished product；It is produced after burning
Product are covered with dirty-green or yellow green matt shape crystallite；
Embodiment 2
Body recipe is made of the raw material of following weight parts: 42 parts of kaolin, 25 parts of potassium feldspar, quartzy 18 parts, china clay tail
25 parts of mine, 3 parts of talcum, 25 parts of beef liver stone, 3 parts of calcite；
Glaze formula is made of the raw material of following weight parts: 15 parts of kaolin, 45 parts of potassium feldspar, quartzy 25 parts, calcite
25 parts, 20 parts of talcum, 3 parts of tricalcium phosphate, 15 parts of iron oxide.
Preparation method: (1) body preparation: by each raw material by formula ratio weighing after, be added in ball milling and grind, then sequentially mistake
Sieve, aging, injection forming；Wherein when ball milling, material: ball: the ratio of water is 1:2.2:0.6；It is additional when grinding to account for formula original
Expect the waterglass of total weight 0.5%；Fineness of grind is 1.0% to be tailed over by 250 meshes；
(2) prepared by glaze: it is (a) that kaolin, potassium feldspar, quartz, calcite, talcum is fine crushing, 20 meshes are crossed, standby is dried
With；(b) kaolin, potassium feldspar, quartz, calcite and talcum after drying fine crushing are weighed by formula ratio, adds the phosphorus of formula ratio
Sour tricalcium and iron oxide are added in ball milling and grind, wherein when ball milling, material: ball: the ratio of water are as follows: 1:2.2:1, grinding are thin
Degree is 0.5% to be tailed over by 250 meshes；
(3) glazing: big part and complicated type use the multiple glaze spraying of spray glazing, and thickness control is 1.2mm~2.0mm；Rule
Device shape uses waterfall process, and thickness control is 1.5~2mm；Smallclothes type uses glaze method, and thickness control is 1.5~2mm.
(4) it is burnt into: being burnt into using oxidizing atmosphere, moisture content is 4% when green body enters kiln；When firing, lighting a fire to 950 DEG C is oxygen
Change flame to be burnt into the stage, the used time 2.5 hours, 950 DEG C to 1290 DEG C are the firing with reductive flame stage, and the used time 3 hours, 1290 DEG C kept the temperature
20 minutes, it is then cooled to 1160 DEG C in 30 minutes and keeps the temperature 1 hour, final cooled to room temperature obtains finished product；It is produced after burning
Product are covered with khaki or grey khaki matt shape crystallite.
Embodiment 3
Body recipe is made of the raw material of following weight parts: 30 parts of kaolin, 15 parts of potassium feldspar, quartzy 10 parts, china clay tail
15 parts of mine, 1 part of talcum, 15 parts of beef liver stone, 1 part of calcite；
Glaze formula is made of the raw material of following weight parts: 4 parts of kaolin, 32 parts of potassium feldspar, quartzy 12 parts, calcite 15
Part, 10 parts of talcum, 1 part of tricalcium phosphate, 5 parts of iron oxide.
Preparation method: (1) body preparation: by each raw material by formula ratio weighing after, be added in ball milling and grind, then sequentially mistake
Sieve, aging, injection forming；Wherein when ball milling, material: ball: the ratio of water is 1:1.9:0.55；It is additional when grinding to account for formula original
Expect the waterglass of total weight 0.5%；Fineness of grind is to tail over 0.5% by 250 meshes；
(2) prepared by glaze: it is (a) that kaolin, potassium feldspar, quartz, calcite, talcum is fine crushing, 20 meshes are crossed, standby is dried
With；(b) kaolin, potassium feldspar, quartz, calcite and talcum after drying fine crushing are weighed by formula ratio, adds the phosphorus of formula ratio
Sour tricalcium and iron oxide are added in ball milling and grind, wherein when ball milling, material: ball: the ratio of water are as follows: 1:2.0:0.9, grinding
Fineness is 0.3% to be tailed over by 250 meshes；
(3) glazing: big part and complicated type use the multiple glaze spraying of spray glazing, and thickness control is 1.2mm~2.0mm；Rule
Device shape uses waterfall process, and thickness control is 1.5~2mm；Smallclothes type uses glaze method, and thickness control is 1.5~2mm.
(4) it is burnt into: being burnt into using reducing atmosphere, moisture content is 3% when green body enters kiln；When firing, lighting a fire to 980 DEG C is oxygen
Change flame to be burnt into the stage, the used time 3.5 hours, 980 DEG C to 1290 DEG C are the firing with reductive flame stage, and the used time 4.5 hours, 1290 DEG C kept the temperature
20 minutes, it is then cooled to 1160 DEG C in 50 minutes and keeps the temperature 1.5 hours, final cooled to room temperature obtains finished product；After burning
Product is covered with dirty-green or yellow green matt shape crystallite；
Embodiment 4
Body recipe is made of the raw material of following weight parts: 40 parts of kaolin, 20 parts of potassium feldspar, quartzy 15 parts, china clay tail
20 parts of mine, 2 parts of talcum, 20 parts of beef liver stone, 2 parts of calcite；
Glaze formula is made of the raw material of following weight parts: 10 parts of kaolin, 42 parts of potassium feldspar, 12~20 parts of quartz, side
Solve 20 parts of stone, 15 parts of talcum, 2 parts of tricalcium phosphate, 12 parts of iron oxide.
Preparation method: (1) body preparation: by each raw material by formula ratio weighing after, be added in ball milling and grind, then sequentially mistake
Sieve, aging, injection forming；Wherein when ball milling, material: ball: the ratio of water is 1:2:0.58；It is additional when grinding to account for formula material
The waterglass of total weight 0.5%；Fineness of grind is to tail over 0.75% by 250 meshes；
(2) prepared by glaze: it is (a) that kaolin, potassium feldspar, quartz, calcite, talcum is fine crushing, 20 meshes are crossed, standby is dried
With；(b) kaolin, potassium feldspar, quartz, calcite and talcum after drying fine crushing are weighed by formula ratio, adds the phosphorus of formula ratio
Sour tricalcium and iron oxide are added in ball milling and grind, wherein when ball milling, material: ball: the ratio of water are as follows: 1:1.9:0.8, grinding
Fineness is 0.08% to be tailed over by 250 meshes；
(3) glazing: big part and complicated type use the multiple glaze spraying of spray glazing, and thickness control is 1.2mm~2.0mm；Rule
Device shape uses waterfall process, and thickness control is 1.5~2mm；Smallclothes type uses glaze method, and thickness control is 1.5~2mm.
(4) it is burnt into: being burnt into using oxidizing atmosphere, moisture content is 3.5% when green body enters kiln；When firing, light a fire is to 950 DEG C
Oxidizing flame is burnt into the stage, and the used time 3 hours, 950 DEG C to 1280 DEG C were the firing with reductive flame stage, and the used time 3.5 hours, 1280 DEG C kept the temperature
20 minutes, it is then cooled to 1160 DEG C in 40 minutes and keeps the temperature 1 hour, final cooled to room temperature obtains finished product；It is produced after burning
Product are covered with khaki or grey khaki matt shape crystallite.
Embodiment 5
Body recipe is made of the raw material of following weight parts: 35 parts of kaolin, 18 parts of potassium feldspar, quartzy 12 parts, china clay tail
12 parts of mine, 1.5 parts of talcum, 18 parts of beef liver stone, 1.5 parts of calcite；
Glaze formula is made of the raw material of following weight parts: 6 parts of kaolin, 38 parts of potassium feldspar, quartzy 16 parts, calcite 18
Part, 12 parts of talcum, 1.5 parts of tricalcium phosphate, 8 parts of iron oxide.
Preparation method: (1) body preparation: by each raw material by formula ratio weighing after, be added in ball milling and grind, then sequentially mistake
Sieve, aging, injection forming；Wherein when ball milling, material: ball: the ratio of water is 1:2.1:0.52；It is additional when grinding to account for formula original
Expect the waterglass of total weight 0.5%；Fineness of grind is 0.35% to be tailed over by 250 meshes；
(2) prepared by glaze: it is (a) that kaolin, potassium feldspar, quartz, calcite, talcum is fine crushing, 20 meshes are crossed, standby is dried
With；(b) kaolin, potassium feldspar, quartz, calcite and talcum after drying fine crushing are weighed by formula ratio, adds the phosphorus of formula ratio
Sour tricalcium and iron oxide are added in ball milling and grind, wherein when ball milling, material: ball: the ratio of water are as follows: 1:2.1:0.8, grinding
Fineness is 0.25% to be tailed over by 250 meshes；
(3) glazing: big part and complicated type use the multiple glaze spraying of spray glazing, and thickness control is 1.2mm~2.0mm；Rule
Device shape uses waterfall process, and thickness control is 1.5~2mm；Smallclothes type uses glaze method, and thickness control is 1.5~2mm.
(4) it is burnt into: being burnt into using reducing atmosphere, moisture content is 2.45% when green body enters kiln；When firing, light a fire to 980 DEG C
It is burnt into the stage for oxidizing flame, the used time 3 hours, 980 DEG C to 1280 DEG C are the firing with reductive flame stage, and the used time 4 hours, 1280 DEG C kept the temperature
10 minutes, it is then cooled to 1160 DEG C in 40 minutes and keeps the temperature 1 hour, final cooled to room temperature obtains finished product；It is produced after burning
Product are covered with dirty-green or yellow green matt shape crystallite.
Embodiment provided above is better embodiment of the invention, only is used to facilitate to illustrate the present invention, not to this
Invention makes any form of restriction, any those of ordinary skill in the art, if not departing from institute of the present invention
In the range of mentioning technical characteristic, using the equivalent embodiment for locally changing or modifying made by disclosed technology contents,
And without departing from technical feature content of the invention, in the range of still falling within the technology of the present invention feature.
Claims (3)
1. a kind of preparation method of tea dust artistic porcelain, including green body and the glaze for being wrapped in billet surface, which is characterized in that should
Green body is made of the raw material of following weight parts: 28~42 parts of kaolin, 12~25 parts of potassium feldspar, quartzy 8~18 parts, porcelain clay tailings
12~25 parts, 1~3 part of talcum, 12~25 parts of beef liver stone, 1~3 part of calcite；
The glaze is made of the raw material of following weight parts: 2~15 parts of kaolin, 28~45 parts of potassium feldspar, 10~25 parts of quartz, side
Solve 12~25 parts of stone, 8~20 parts of talcum, 1~3 part of tricalcium phosphate, 2~15 parts of iron oxide；
Preparation method includes the following steps:
(1) body preparation: after each raw material is weighed by formula ratio, being added in ball milling and grind, then sequentially sieving, aging, slip casting
Molding；Wherein when ball milling, material: ball: the ratio of water is 1:1.8~2.2:0.5~0.6；Additionally addition accounts for formula when grinding
The waterglass of raw material gross weight 0.5%；Fineness of grind is 0.2~1.0% to be tailed over by 250 meshes；
(2) prepared by glaze: it is (a) that kaolin, potassium feldspar, quartz, calcite, talcum is fine crushing, 20 meshes are crossed, and it is spare after drying；
(b) kaolin, potassium feldspar, quartz, calcite and talcum after drying fine crushing are weighed by formula ratio, adds the tricresyl phosphate of formula ratio
Calcium and iron oxide are added in ball milling and grind, wherein when ball milling, material: ball: the ratio of water are as follows: 1:1.8~2.2:0.5~
1.0, fineness of grind is 0.05~0.5% to be tailed over by 250 meshes；
(3) glazing: spray glazing or waterfall process or glaze method is selected to carry out glazing according to type, glazing is with a thickness of 1.2~2mm；
(4) it is burnt into: being burnt into using reducing atmosphere or oxidizing atmosphere, moisture content is 2~4% when green body enters kiln；Firing temperature is
1250~1290 DEG C；Firing time is 20 minutes 7 hours~40 minutes 10 hours；
When using reducing atmosphere, igniting is burnt into the stage to 980 DEG C for oxidizing flame, and firing time is 2.5~3.5 hours, and 980 DEG C extremely
1250~1290 DEG C are the firing with reductive flame stage, and firing time is 3.5~4.5 hours, and 1250~1290 DEG C keep the temperature 10~20 points
Then clock is cooled to 1160 DEG C in 30~50 minutes and keeps the temperature 1~1.5 hour, final cooled to room temperature obtains finished product；It burns
Product is covered with dirty-green or yellow green matt shape crystallite afterwards；
When using oxidizing atmosphere, igniting to 950 DEG C of firing stages, firing time is 2.5~3.5 hours, 950 DEG C to 1250~
1290 DEG C of firing stages, firing time are 3~4 hours, and 1250~1290 DEG C keep the temperature 20~30 minutes, then at 30~50 minutes
It is inside cooled to 1160 DEG C and keeps the temperature 1~1.5 hour, final cooled to room temperature obtains finished product；After burning product be covered with khaki or
Grey khaki matt shape crystallite.
2. a kind of preparation method of tea dust artistic porcelain according to claim 1, which is characterized in that the green body is by following heavy
Measure the raw material composition of part: 30~40 parts of kaolin, 10~15 parts of quartz, 15~20 parts of porcelain clay tailings, is slided 15~20 parts of potassium feldspar
1~2 part of stone, 15~20 parts of beef liver stone, 1~2 part of calcite；
The glaze is made of the raw material of following weight parts: 4~10 parts of kaolin, 32~42 parts of potassium feldspar, 12~20 parts of quartz, side
Solve 15~20 parts of stone, 10~15 parts of talcum, 1~2 part of tricalcium phosphate, 5~12 parts of iron oxide.
3. a kind of preparation method of tea dust artistic porcelain according to claim 1, which is characterized in that step (3) described glazing
Specifically, big part and complicated type use the multiple glaze spraying of spray glazing, thickness control is 1.2mm~2.0mm；Regular device shape is using leaching
Glaze method, thickness control are 1.5~2mm；Smallclothes type uses glaze method, and thickness control is 1.5~2mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610025608.9A CN105693207B (en) | 2016-01-13 | 2016-01-13 | A kind of preparation method of tea dust artistic porcelain |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610025608.9A CN105693207B (en) | 2016-01-13 | 2016-01-13 | A kind of preparation method of tea dust artistic porcelain |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105693207A CN105693207A (en) | 2016-06-22 |
| CN105693207B true CN105693207B (en) | 2019-03-01 |
Family
ID=56226580
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610025608.9A Active CN105693207B (en) | 2016-01-13 | 2016-01-13 | A kind of preparation method of tea dust artistic porcelain |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105693207B (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106630934A (en) * | 2016-08-30 | 2017-05-10 | 郏县神前传奇陶瓷钧瓷厂 | Process for firing jun porcelain by aid of temmoku brown golden glaze |
| CN106673610A (en) * | 2016-12-11 | 2017-05-17 | 吴硕 | Art porcelain and preparation method thereof |
| CN106904833B (en) * | 2017-03-16 | 2019-11-26 | 广东省大埔陶瓷工业研究所 | A kind of an ancient unit of weight fancy glaze material and the method that pottery is prepared using an ancient unit of weight fancy glaze material |
| CN108752050B (en) * | 2018-06-19 | 2020-12-15 | 张玉凤 | Ru porcelain tea dust glaze and preparation method thereof |
| CN109020219A (en) * | 2018-10-09 | 2018-12-18 | 汝州市宣和坊汝瓷有限公司 | A kind of Ruyao tea-dust glaze and preparation method thereof |
| CN111320458A (en) * | 2020-03-02 | 2020-06-23 | 福建省德化县昱晟工艺品有限责任公司 | Preparation method of tea dust glaze light porcelain |
| CN112028484A (en) * | 2020-09-04 | 2020-12-04 | 福建省春秋陶瓷实业有限公司 | Dark green transmutation glaze ceramic product and preparation method thereof |
| CN112028601A (en) * | 2020-09-07 | 2020-12-04 | 福建省德化贝思家居有限公司 | Secret color ceramic product and preparation method thereof |
| CN114276015B (en) * | 2021-12-27 | 2023-09-05 | 齐鲁工业大学 | Tea dust glaze based on yellow river mud and preparation method of tea dust glaze |
| CN115784613B (en) * | 2023-01-06 | 2023-05-30 | 山东硅元新型材料股份有限公司 | Oxidizing flame fired tea dust glaze and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101624297A (en) * | 2009-08-07 | 2010-01-13 | 陕西科技大学 | Preparation method for tea dust temmoku glaze |
| CN104016657A (en) * | 2013-03-01 | 2014-09-03 | 格丰科技材料有限公司 | Ultrahigh specific surface area ceramic material and preparation method thereof |
| CN104817343A (en) * | 2015-03-30 | 2015-08-05 | 姚瑞平 | Ru porcelain tea-dust glaze and preparation technology thereof |
-
2016
- 2016-01-13 CN CN201610025608.9A patent/CN105693207B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101624297A (en) * | 2009-08-07 | 2010-01-13 | 陕西科技大学 | Preparation method for tea dust temmoku glaze |
| CN104016657A (en) * | 2013-03-01 | 2014-09-03 | 格丰科技材料有限公司 | Ultrahigh specific surface area ceramic material and preparation method thereof |
| CN104817343A (en) * | 2015-03-30 | 2015-08-05 | 姚瑞平 | Ru porcelain tea-dust glaze and preparation technology thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105693207A (en) | 2016-06-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105693207B (en) | A kind of preparation method of tea dust artistic porcelain | |
| CN108751718B (en) | Preparation process of relief oil drop jian cup | |
| CN103232225B (en) | Method for preparing colorful leaf-temmoku porcelain and product prepared from colorful leaf-temmoku porcelain | |
| CN105884197A (en) | Method for preparing series iron-series colored glaze from iron-ore slag and decoration method based on colored glaze | |
| CN106348598A (en) | Copper-red glaze and preparation method thereof | |
| CN105218170B (en) | A kind of high-hardness, wearable exempts to polish iron microcrystalline glass in series ceramic clad plate and preparation method thereof | |
| CN105036809A (en) | Blue background and mottled spot composite Tang jun glaze and technology for preparing jun porcelain through same | |
| CN105036810A (en) | Black-base mottled composite Tang jun glaze and process for preparing jun porcelain through black-base mottled composite Tang jun glaze | |
| CN106045579A (en) | Celeste ceramic with ripple glaze and firing method of ceramic | |
| CN107032832A (en) | A kind of Ceramic Tiles with color changeable effect and preparation method thereof | |
| CN105175020A (en) | Complex Tang-dynasty jun glaze with blue spots in black and process for preparing jun porcelain by use of complex Tang-dynasty jun glaze | |
| CN109095775A (en) | A kind of clear frit and preparation method thereof suitable for high-strength ceramic whiteware | |
| CN102219562B (en) | Production method for quickly firing aventurine glaze for stoneware | |
| CN105272153A (en) | Preparation method of blue-and-white Nixing ceramic | |
| CN102173875A (en) | Preparation method of B2O3-TiO2 series fambe ceramic crystalline glaze | |
| CA2984659A1 (en) | Glaze resistant to wax block bonding, ceramic resistant to wax block bonding and preparation process thereof | |
| CN106587620B (en) | A kind of gold glaze glaze, gold glaze pottery and preparation method thereof | |
| CN105198377A (en) | Preparation method for improving firing rate of Nixing pottery | |
| CN104478482A (en) | Nansong offcial kiln cream-colored glaze transmutation formula and making technology | |
| CN109987842A (en) | A kind of pottery celeste glaze and its preparation process | |
| CN105218167A (en) | A kind of preparation method of blue and white material decoration Nixing pottery | |
| CN108046751A (en) | A kind of ceramic material and its ceramic | |
| CN106565091A (en) | High-temperature quick-burning sand crystal glaze and preparation technology thereof | |
| CN105439640A (en) | Transmutation glaze and preparation method thereof | |
| CN103992140B (en) | A kind of copper iron look sunlight becomes gold ring temmoku glaze and makes the method for household china of it |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |