CN106348598A - Copper-red glaze and preparation method thereof - Google Patents

Copper-red glaze and preparation method thereof Download PDF

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Publication number
CN106348598A
CN106348598A CN201610833739.XA CN201610833739A CN106348598A CN 106348598 A CN106348598 A CN 106348598A CN 201610833739 A CN201610833739 A CN 201610833739A CN 106348598 A CN106348598 A CN 106348598A
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China
Prior art keywords
parts
glaze
base substrate
dried
copper
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Pending
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CN201610833739.XA
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Chinese (zh)
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崔松伟
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Individual
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/85Coating or impregnation with inorganic materials
    • C04B41/86Glazes; Cold glazes

Abstract

The invention relates to copper-red glaze and a preparation method thereof. The copper-red glaze comprises, by weight, 5-10 parts of kaolin, 18-35 parts of quartz, 10-16 parts of calcium phosphate, 15-22 parts of albite, 15-24 parts of potassium feldspar, 2-9 parts of talcum, 1-2 parts of cupric oxalate, 0.5-1.5 parts of tin oxide, 8-16 parts of calcite, 0.5-1.5 parts of zinc oxide and 10-13 parts of borax. The copper-red glaze has the advantages that the glaze is even in color and good in glossiness, and porcelain processed by the copper-red glaze is even in color and thick in glaze, has an unique artistic effect, gives an impression of depth, steadiness, dignity and elegance to people, has a bright red color and is even in glaze color distribution and high in yield.

Description

A kind of rough flambe and preparation method thereof
Technical field
The present invention relates to field is and in particular to a kind of rough flambe and preparation method thereof.
Background technology
With the continuous development and change in epoch, people constantly show to aesthetic, artistic pursuit.Coloured glaze will be native and fiery The combination of art represents incisively and vividly, is therefore increasingly favored by people.High temperature rough flambe is that Ancient Times in China is famous One of color glaze, sparkling and crystal-clear bright, moist uniformly famous with it, additionally, its good stability, reserve value height, this makes it the world A jewelly jewel in ceramic industrial art history.The burning of rough flambe is made history and can be traced back to the Tang Dynasty, famous at that time Changsha Kiln in red glaze implements occurred, but this is only accidental making, does not become a kind of universal decoration;And arrive It is decoration that an ancient unit of weight kiln of Song dynasty has then started a large amount of use copper reds.In addition, China has from ancient times to the present with redness for noble, dignified, happiness The tradition of the color of celebrating, it is increasingly paid close attention to by people in recent years.
However, the requirement to process conditions and atmosphere for the rough flambe is very strict, it is difficult to burn out in colour-stable product. Modern times have tried to fire rough flambe with oxidizing atmosphere, but colour generation is all undesirable.
Content of the invention
For the deficiencies in the prior art, the present invention provides a kind of rough flambe and preparation method thereof, have colour generation uniformly, gloss Spend, the feature of artistic effect that glaze paint is plump, unique and high yield rate.
The technical scheme is that and be achieved in that: a kind of rough flambe, it is made up of the raw material of following weight portion: Kaolin 5 ~ 10 parts, quartz 18 ~ 35 parts, 10 ~ 16 parts of calcium phosphate, 15 ~ 22 parts of albite, 15 ~ 24 parts of potassium feldspar, 2 ~ 9 parts of Talcum, cupric oxalate 1 ~ 2 part, 0.5 ~ 1.5 part of stannum oxide, 8 ~ 16 parts of calcite, 0.5 ~ 1.5 part of zinc oxide, 10 ~ 13 parts of Borax.
A kind of rough flambe, is made up of the raw material of following weight portion: 8 parts of Kaolin, 26 parts of quartz, 13 parts of calcium phosphate, sodium are long 18 parts of stone, 19 parts of potassium feldspar, 8 parts of Talcum, 1 part of cupric oxalate, 0.8 part of stannum oxide, 13 parts of calcite, 0.9 part of zinc oxide, Borax 12 Part.
The preparation method of described rough flambe comprises the following steps:
(1) above-mentioned various raw materials are carried out wet ball mill 25 ~ 30min, the ratio of material, ball and water by the ball mill being 300r/min with rotating speed Example is 1:2:0.75, crosses 250 mesh sieves afterwards, tails over and controls 0.1~0.15%, is then l ten thousand Gauss except ferrum with magnetic field intensity Device removes ferrum 5 times, prepared glaze slip;
(2) base substrate, through 900 ~ 950 DEG C of biscuitings, is dried, the glaze slip in step (1) is bestowed on dried base substrate, obtains glazing Base substrate, glazed thickness is 1 ~ 1.1mm;
(3) dried glazing base substrate is put in gas burning kiln stove and fire, fire in weak oxide atmosphere, temperature rises to 900 DEG C Fired with strongly reducing atmosphere afterwards, be fired with weakly reducing atmosphere when temperature rises to 1200 DEG C, treat that temperature rises to 1280 DEG C when stop heating, be incubated 20 ~ 30min, naturally cool to room temperature, obtain pottery finished product.
The present invention has following good effect: uniformly, glossiness is good, and the porcelain color and luster obtained by copper red glaze is equal for colour generation Even, glaze paint is plump, have the artistic effect of uniqueness, gives people the perception of deep, steady, dignified air, has more bright-coloured redness, And glaze distribution of color is uniformly, high yield rate.
Specific embodiment
Embodiment one
A kind of rough flambe, is made up of the raw material of following weight portion: 5 parts of Kaolin, 18 parts of quartz, 10 parts of calcium phosphate, albite 15 Part, 15 parts of potassium feldspar, 2 parts of Talcum, 1 part of cupric oxalate, 0.5 part of stannum oxide, 8 parts of calcite, 0.5 part of zinc oxide, 10 parts of Borax.
The preparation method of rough flambe comprises the following steps:
(1) above-mentioned various raw materials are carried out wet ball mill 25min, the ratio of material, ball and water by the ball mill being 300r/min with rotating speed For 1:2:0.75, cross 250 mesh sieves afterwards, tail over and control 0.1%, then remove ferrum 5 with the tramp iron separator that magnetic field intensity is l ten thousand Gauss Secondary, prepared glaze slip;
(2) base substrate, through 900 DEG C of biscuitings, is dried, the glaze slip in step (1) is bestowed on dried base substrate, obtains glazing base substrate, Glazed thickness is 1mm;
(3) dried glazing base substrate is put in gas burning kiln stove and fire, fire in weak oxide atmosphere, temperature rises to 900 DEG C Fired with strongly reducing atmosphere afterwards, be fired with weakly reducing atmosphere when temperature rises to 1200 DEG C, treat that temperature rises to 1280 DEG C when stop heating, be incubated 20min, naturally cool to room temperature, obtain pottery finished product.
Embodiment two
A kind of rough flambe, is made up of the raw material of following weight portion: 8 parts of Kaolin, 26 parts of quartz, 13 parts of calcium phosphate, albite 18 Part, 19 parts of potassium feldspar, 8 parts of Talcum, 1 part of cupric oxalate, 0.8 part of stannum oxide, 13 parts of calcite, 0.9 part of zinc oxide, 12 parts of Borax.
The preparation method of described rough flambe comprises the following steps:
(1) above-mentioned various raw materials are carried out wet ball mill 30min, the ratio of material, ball and water by the ball mill being 300r/min with rotating speed For 1:2:0.75, cross 250 mesh sieves afterwards, tail over and control 0.15%, then remove ferrum 5 with the tramp iron separator that magnetic field intensity is l ten thousand Gauss Secondary, prepared glaze slip;
(2) base substrate, through 920 DEG C of biscuitings, is dried, the glaze slip in step (1) is bestowed on dried base substrate, obtains glazing base substrate, Glazed thickness is 1mm;
(3) dried glazing base substrate is put in gas burning kiln stove and fire, fire in weak oxide atmosphere, temperature rises to 900 DEG C Fired with strongly reducing atmosphere afterwards, be fired with weakly reducing atmosphere when temperature rises to 1200 DEG C, treat that temperature rises to 1280 DEG C when stop heating, be incubated 30min, naturally cool to room temperature, obtain pottery finished product.
Embodiment three
A kind of rough flambe, is made up of the raw material of following weight portion: 10 parts of Kaolin, 35 parts of quartz, 16 parts of calcium phosphate, albite 22 Part, 24 parts of potassium feldspar, 9 parts of Talcum, 2 parts of cupric oxalate, 1.5 parts of stannum oxide, 16 parts of calcite, 1.5 parts of zinc oxide, 13 parts of Borax.
The preparation method of rough flambe comprises the following steps:
(1) above-mentioned various raw materials are carried out wet ball mill 30min, the ratio of material, ball and water by the ball mill being 300r/min with rotating speed For 1:2:0.75, cross 250 mesh sieves afterwards, tail over and control 0.15%, then remove ferrum 5 with the tramp iron separator that magnetic field intensity is l ten thousand Gauss Secondary, prepared glaze slip;
(2) base substrate, through 950 DEG C of biscuitings, is dried, the glaze slip in step (1) is bestowed on dried base substrate, obtains glazing base substrate, Glazed thickness is 1.1mm;
(3) dried glazing base substrate is put in gas burning kiln stove and fire, fire in weak oxide atmosphere, temperature rises to 900 DEG C Fired with strongly reducing atmosphere afterwards, be fired with weakly reducing atmosphere when temperature rises to 1200 DEG C, treat that temperature rises to 1280 DEG C when stop heating, be incubated 30min, naturally cool to room temperature, obtain pottery finished product.
Uniformly, glossiness is good for colour generation, and porcelain uniform color obtained by copper red glaze, glaze paint is plump, have the skill of uniqueness Art effect, gives people the perception of deep, steady, dignified air, has more bright-coloured redness, and glaze distribution of color is uniformly, yield rate High.

Claims (3)

1. a kind of rough flambe it is characterised in that: be made up of the raw material of following weight portion: 5 ~ 10 parts of Kaolin, quartz 18 ~ 35 parts, 10 ~ 16 parts of calcium phosphate, 15 ~ 22 parts of albite, 15 ~ 24 parts of potassium feldspar, 2 ~ 9 parts of Talcum, 1 ~ 2 part of cupric oxalate, stannum oxide 0.5 ~ 1.5 Part, 8 ~ 16 parts of calcite, 0.5 ~ 1.5 part of zinc oxide, 10 ~ 13 parts of Borax.
2. a kind of rough flambe it is characterised in that: be made up of the raw material of following weight portion: 8 parts of Kaolin, quartzy 26 parts, calcium phosphate 13 parts, 18 parts of albite, 19 parts of potassium feldspar, 8 parts of Talcum, 1 part of cupric oxalate, 0.8 part of stannum oxide, 13 parts of calcite, zinc oxide 0.9 Part, 12 parts of Borax.
3. a kind of preparation method of rough flambe as claimed in claim 1 or 2 it is characterised in that: the preparation of described rough flambe Method comprises the following steps:
(1) above-mentioned various raw materials are carried out wet ball mill 25 ~ 30min, the ratio of material, ball and water by the ball mill being 300r/min with rotating speed Example is 1:2:0.75, crosses 250 mesh sieves afterwards, tails over and controls 0.1~0.15%, is then l ten thousand Gauss except ferrum with magnetic field intensity Device removes ferrum 5 times, prepared glaze slip;
(2) base substrate, through 900 ~ 950 DEG C of biscuitings, is dried, the glaze slip in step (1) is bestowed on dried base substrate, obtains glazing Base substrate, glazed thickness is 1 ~ 1.1mm;
(3) dried glazing base substrate is put in gas burning kiln stove and fire, fire in weak oxide atmosphere, temperature rises to 900 DEG C Fired with strongly reducing atmosphere afterwards, be fired with weakly reducing atmosphere when temperature rises to 1200 DEG C, treat that temperature rises to 1280 DEG C when stop heating, be incubated 20 ~ 30min, naturally cool to room temperature, obtain pottery finished product.
CN201610833739.XA 2016-09-20 2016-09-20 Copper-red glaze and preparation method thereof Pending CN106348598A (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106746655A (en) * 2016-12-06 2017-05-31 许昌学院 A kind of method that imitative pottery rough flambe is fired under the conditions of oxidizing atmosphere
CN106986542A (en) * 2017-05-15 2017-07-28 晋大纳米科技(厦门)有限公司 A kind of far-infrared anti-biotic ceramic glaze and preparation method thereof
CN107226718A (en) * 2017-05-30 2017-10-03 刘新乐 Pottery health-promotion kettle and preparation method thereof
CN109384478A (en) * 2018-12-19 2019-02-26 禹州市正玉钧窑有限公司 A kind of red glaze of band spot an ancient unit of weight
CN109439019A (en) * 2018-09-17 2019-03-08 佛山市高明丰霖新型材料有限公司 A kind of environmental protection household china golden brown material
CN111138211A (en) * 2020-01-14 2020-05-12 蒙娜丽莎集团股份有限公司 Copper-colored blank particle-combined inkjet penetration decorative polished brick and preparation method thereof
CN112340992A (en) * 2020-12-01 2021-02-09 禹州市正元钧窑有限公司 Surface glazing process of Jun porcelain plate
CN112479591A (en) * 2020-12-24 2021-03-12 湖州海程塑业有限公司 Sacrificial red glaze and preparation method thereof
CN115536271A (en) * 2021-11-29 2022-12-30 四川美术学院 Copper red glaze ceramic and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102731066A (en) * 2012-07-06 2012-10-17 河南白玉陶瓷有限公司 Porcelain with Junyu glaze and manufacturing method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102731066A (en) * 2012-07-06 2012-10-17 河南白玉陶瓷有限公司 Porcelain with Junyu glaze and manufacturing method thereof

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106746655A (en) * 2016-12-06 2017-05-31 许昌学院 A kind of method that imitative pottery rough flambe is fired under the conditions of oxidizing atmosphere
CN106986542A (en) * 2017-05-15 2017-07-28 晋大纳米科技(厦门)有限公司 A kind of far-infrared anti-biotic ceramic glaze and preparation method thereof
CN107226718A (en) * 2017-05-30 2017-10-03 刘新乐 Pottery health-promotion kettle and preparation method thereof
CN109439019A (en) * 2018-09-17 2019-03-08 佛山市高明丰霖新型材料有限公司 A kind of environmental protection household china golden brown material
CN109384478A (en) * 2018-12-19 2019-02-26 禹州市正玉钧窑有限公司 A kind of red glaze of band spot an ancient unit of weight
CN111138211A (en) * 2020-01-14 2020-05-12 蒙娜丽莎集团股份有限公司 Copper-colored blank particle-combined inkjet penetration decorative polished brick and preparation method thereof
CN111138211B (en) * 2020-01-14 2022-05-06 蒙娜丽莎集团股份有限公司 Copper-colored blank particle-combined inkjet penetration decorative polished brick and preparation method thereof
CN112340992A (en) * 2020-12-01 2021-02-09 禹州市正元钧窑有限公司 Surface glazing process of Jun porcelain plate
CN112340992B (en) * 2020-12-01 2022-08-02 禹州市正元钧窑有限公司 Surface glazing process of Jun porcelain plate
CN112479591A (en) * 2020-12-24 2021-03-12 湖州海程塑业有限公司 Sacrificial red glaze and preparation method thereof
CN115536271A (en) * 2021-11-29 2022-12-30 四川美术学院 Copper red glaze ceramic and preparation method thereof

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Application publication date: 20170125