CN108046751A - A kind of ceramic material and its ceramic - Google Patents

A kind of ceramic material and its ceramic Download PDF

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Publication number
CN108046751A
CN108046751A CN201711387275.5A CN201711387275A CN108046751A CN 108046751 A CN108046751 A CN 108046751A CN 201711387275 A CN201711387275 A CN 201711387275A CN 108046751 A CN108046751 A CN 108046751A
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CN
China
Prior art keywords
parts
porcelain
ceramic
mud
laterite
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Pending
Application number
CN201711387275.5A
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Chinese (zh)
Inventor
麦潮棠
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HUNAN HUALIAN CERAMICS CO Ltd
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HUNAN HUALIAN CERAMICS CO Ltd
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Priority to CN201711387275.5A priority Critical patent/CN108046751A/en
Publication of CN108046751A publication Critical patent/CN108046751A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418Silicon oxide, silicic acids or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • C04B2235/9646Optical properties
    • C04B2235/9661Colour

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

The invention discloses a kind of ceramic material and its ceramic, including 8~13 parts of laterite, 30~40 parts of porcelain sand, smart 17~27 parts of mud, 30~40 parts of porcelain mud, quartzy 1~9 part, 0.5~1 part of mineralising additive;Present invention employs the higher laterite of iron-holder, Fe in formula2O3Content is 2.0%~2.3%, it can be ensured that the color into porcelain porcelain body is in stable brown;Meanwhile the Fe having more than needed in formula2O3With reference to Heng Shan essence mud (Na2O·AL2O3·SiO2) in Na2O plays fluxing cooling effect so that product can burn (5.5~7h) soon under the conditions of medium temperature (1255~1270 DEG C) and form, and compared with traditional technology in producing porcelain, greatly reduce energy loss;With this condition, brown ceramic product water absorption rate obtained is below 1%;Meanwhile SiO in pug formula2Content more than 70%, can promote decorate glaze generate transmutation effect.

Description

A kind of ceramic material and its ceramic
Technical field
This application involves ceramic field, more particularly to a kind of ceramic material and its ceramic.
Background technology
It is suitable that existing China's production with the household china production area that brown ceramics mold makes is mainly distributed on Guangdong Chaozhou, Jiangsu Emerging and Longquan, Zhejiang Province Deng Ci areas, the produced brown greenwave in Chaozhou area are only applicable in common color glaze, are decorated with two-sided decoration technique, with Low temperature is burnt till at a slow speed, and water absorption rate is about 20% or so.The produced brown pottery (being commonly called as boccaro) in Yixing City is with pure mold face Color is made, without glaze processing, to burn till at a slow speed with low temperature, water absorption rate is about more than 2%.And dragon's fountain Deng Ci areas produce brown porcelain and (are commonly called as green grass or young crops Porcelain) it is that two-sided celadon glaze or ice-crack-like glaze decoration are equipped with brown porcelain body, using high temperature, water absorption rate is more than 1%.More than The brown ceramics in three ceramic producing regions are to burn till at a slow speed, and water absorption rate cannot arrange in pairs or groups all more than 1% with furnace transmutation glaze, energy consumption Of high cost and glaze colours decoration is single.
The content of the invention
In view of this, it is an object of the invention to propose a kind of ceramic material and its ceramic, to improve conventional ceramic In product manufacturing process the problem of high energy consumption, at the same reduce fire after ceramic water absorption rate.In addition, using made of this programme into Product ceramics tone can be in stable brown, can promote to decorate glaze generation transmutation effect.
Based on above-mentioned purpose, the present invention provides a kind of ceramic materials, which is characterized in that in parts by weight, including laterite 8 ~13 parts, 30~40 parts of porcelain sand, smart 17~27 parts of mud, 30~40 parts of porcelain mud, quartzy 1~9 part, 0.5~1 part of mineralising additive.
Preferably, laterite originates from Liling, porcelain sand originates from Youxian County, mud originates from Heng Shan to essence, porcelain mud originates from Guangxi.
Particularly, Fe in selected laterite2O3Content be more than 13.5% (parts by weight).
Wherein, by weight percentage, Fe in pug formula2O3Content for 2.0~2.3%, SiO2Content for 70~ 72%th, Al2O3Content be 19~22%.
Table 1 is the content of each component metal oxide in pug formula (each component is counted using weight as 100).
Table 1
The present invention also provides a kind of ceramics, it is characterised in that comprises the following steps:By weight by laterite 8~13 Part, 30~40 parts of porcelain sand, smart 17~27 parts of mud, 30~40 parts of porcelain mud, quartzy 1~9 part, 0.5~1 part of mineralising additive, by material, Ballstone, water ratio are 1:1.4~1.7:1.2~1.3 filling ball millings;Ball milling certain time after fineness reaches 0.1%~0.2%, is pressed Provide out ball sieving, except iron, press filt, pugging is sunk rotten spare;It chooses specific type and carries out roll forming, dry body, refine base, wash water And the operations such as glazing;It is placed in 80 meters of roller kilns and once fires.
Wherein, firing temperature is 1255~1270 DEG C, when the firing time is 5.5~7 small.
Its water absorption rate of the ceramic of gained is below 1%, and porcelain billet tire chromatic value is L after cooling:43.5 or so, a: 5.0 or so, b:7.1 or so (wherein L:Represent shading value (black and white), a:Represent red green, b represents champac color), in stable palm fibre Color tone.
As can be seen from Table 1, laterite iron-holder is higher, Fe in formula2O3Content be up to 2.0~2.3%, in itself and water After mixing fine grinding, there is micro ferrous acid to be precipitated, the thixotropy of mud can be changed, improve the plasticity of mud;It is rich in pug formula Remaining Fe2O3With reference to Heng Shan essence mud (Na2O·AL2O3·SiO2) in Na2O plays fluxing cooling effect so that ceramic energy It is enough under mesophilic condition (1255~1270 DEG C) by 5.5~7 it is small when quickly fire, and under this firing condition, system Ceramic water absorption rate is obtained below 1%.
Cr micro in moulded pottery not yet put in a kiln to bake after shaping2O3And MnO2When medium temperature is fired, generated under the action of mineralising additive a certain amount of ZnO-AL2O3-Fe2O3Spinelle colorant, then it is equipped with free iron ion more than needed and micro MnO2Colour generation is mixed, after cooling For the ceramic mold of order in stable brown tone, chromatic value is L:43.5 or so, a:5.0 or so, b:7.1 or so, and existing one As preferable ceramic whiteware chromatic value be L:87 or so, a:- 0.5 or so, b:0.5 or so;Meanwhile SiO in pug formula2Content exist More than 70%, it can promote to decorate glaze generation transmutation effect.
Specific embodiment
Understand to make the object, technical solutions and advantages of the present invention clearer, below in conjunction with specific embodiment, to this hair Bright further description.
Embodiment 1
First, accurately weighed by kind:Laterite 9kg, porcelain sand 35kg, smart mud 24kg, porcelain mud 41kg, quartz 4kg, mineralising add Add agent 0.5kg, common 113.5kg;Then, it is 1 by material, ballstone, water ratio:1.4~1.7:1.2~1.3 filling ball millings;Ball milling is certain Time, after fineness reaches 0.1%~0.2%, by provide out ball sieving, except iron, press filt, pugging is sunk rotten spare;Choose specific device Type carries out roll forming, dry body, refine base, the operations such as wash water and glazing;It is placed in once-firing in 80 meters of roller kilns, firing period For 5.5 it is small when, actual measurement maximum sintering temperature be 1255 DEG C.
Gained brown ceramic product water absorption rate test and the test of porcelain body colourity are as follows:
Wherein, table 2 is ceramic product water absorption rate test.
Table 2
Table 3 is tested for porcelain body colourity.
Table 3
Embodiment 2
First, accurately weighed by kind:Laterite 12kg, porcelain sand 41kg, smart mud 27kg, porcelain mud 37kg, quartz 6kg, mineralising Additive 0.5kg, common 123.5kg;Then, it is 1 by material, ballstone, water ratio:1.4~1.7:1.2~1.3 filling ball millings;Ball milling one Fix time, after fineness reaches 0.1%~0.2%, by provide out ball sieving, except iron, press filt, pugging is sunk rotten spare;It chooses specific Type carries out roll forming, dry body, refine base, the operations such as wash water and glazing;Once-firing in 80 meters of roller kilns is placed in, burns till week When phase is 6 small, actual measurement maximum sintering temperature is 1260 DEG C.
Gained ceramic product water absorption rate test and the test of porcelain body colourity are as follows:
Wherein, table 4 is ceramic product water absorption rate test.
Table 4
Table 5 is tested for porcelain body colourity.
Table 5
Embodiment 3
First, accurately weighed by kind:Laterite 13kg, porcelain sand 39kg, smart mud 25kg, porcelain mud 39kg, quartz 8kg, mineralising Additive 0.5kg, common 124.5kg;Then, it is 1 by material, ballstone, water ratio:1.4~1.7:1.2~1.3 filling ball millings;Ball milling one Fix time, after fineness reaches 0.1%~0.2%, by provide out ball sieving, except iron, press filt, pugging is sunk rotten spare;It chooses specific Type carries out roll forming, dry body, refine base, the operations such as wash water and glazing;Once-firing in 80 meters of roller kilns is placed in, burns till week When phase is 7 small, actual measurement maximum sintering temperature is 1270 DEG C.
Gained ceramic product water absorption rate test and the test of porcelain body colourity are as follows:
Wherein, table 6 is ceramic product water absorption rate test.
Table 6
Table 7 is tested for porcelain body colourity.
Table 7
It is understood by table 2,4,6, the different formulations in the range of, obtained ceramic water absorption rate is respectively 0.33%, 0.23%th, 0.21%, it is below 1%;Meanwhile understand that obtained sample is stable brown, wherein colourity by table 3,5,7 Value L:43.5 or so, a:5.0 or so, b:7.1 left and right;Meanwhile in sintering temperature be 1255~1270 DEG C, the time is 5.5~7 small When or so once sintered can complete, compared with traditional technology in producing porcelain, the loss of energy is greatly saved.
Those of ordinary skills in the art should understand that:The discussion of any of the above embodiment is exemplary only, not It is intended to imply that the scope of the present disclosure is limited to these examples (including claim);Under the thinking of the present invention, above example Or can also be combined between the technical characteristic in different embodiments, step can be realized with random order, and be existed such as Many other variations of the different aspect of the upper present invention, for simplicity, they are not provided in details.
The embodiment of the present invention be intended to cover fall within the broad range of appended claims it is all it is such replace, Modifications and variations.Therefore, within the spirit and principles of the invention, any omission, modification, equivalent substitution, the improvement made Deng should all be included in the protection scope of the present invention.

Claims (7)

1. a kind of ceramic material, which is characterized in that in parts by weight, including 8~13 parts of laterite, 30~40 parts of porcelain sand, smart mud 17 ~27 parts, 30~40 parts of porcelain mud, quartzy 1~9 part, 0.5~1 part of mineralising additive.
2. ceramic material according to claim 1, which is characterized in that Fe in the laterite2O3Weight ratio be more than 13.5%.
3. ceramic material according to claim 1, which is characterized in that by weight percentage, Fe in pug formula2O3's Content is 2.0~2.3%, SiO2Content for 70~72%, Al2O3Content be 19~22%.
4. a kind of ceramic, it is characterised in that comprise the following steps:By 8~13 parts of laterite, 30~40 parts of porcelain sand, smart mud 17 ~27 parts, 30~40 parts of porcelain mud, quartzy 1~9 part, 0.5~1 part of mineralising additive, be 1 by material, ballstone, water ratio:1.4~1.7: It is once fired after the operations such as ball milling after 1.2~1.3 mixing.
5. ceramic according to claim 4, which is characterized in that firing temperature is 1255~1270 DEG C, the firing time For 5.5~7 it is small when.
6. ceramic according to claim 4, which is characterized in that water absorption rate is below 1%.
7. ceramic according to claim 4, which is characterized in that porcelain billet tire chromatic value is L after cooling:43.5 left and right, a:5.0 or so, b:7.1 or so, in stable brown tone.
CN201711387275.5A 2017-12-20 2017-12-20 A kind of ceramic material and its ceramic Pending CN108046751A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108863308A (en) * 2018-08-17 2018-11-23 德阳极光文创设计有限公司 Ceramic material based on composite rock mineral
CN108911699A (en) * 2018-08-17 2018-11-30 德阳极光文创设计有限公司 The preparation method of ceramics based on composite rock mineral
CN109354406A (en) * 2018-11-14 2019-02-19 宁波联城住工科技有限公司 Anti-skidding glaze and preparation method thereof and a kind of production method of skid-resistance ceramic
CN114409374A (en) * 2022-02-23 2022-04-29 内蒙古布德民族文化发展有限责任公司 Preparation method of red mud for ceramics preparation and firing method of red mud product

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CN102093034A (en) * 2010-12-10 2011-06-15 望城县铜官泥人刘艺术陶瓷厂 Ceramic and preparation method thereof
CN106116456A (en) * 2016-06-23 2016-11-16 湖南华联瓷业股份有限公司 Warm colour glaze colour daily-use fine and preparation method thereof in one
CN106957169A (en) * 2016-01-12 2017-07-18 长沙市望城区铜官先陶美术陶瓷有限公司 A kind of manufacture craft of iron stoneware

Patent Citations (3)

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Publication number Priority date Publication date Assignee Title
CN102093034A (en) * 2010-12-10 2011-06-15 望城县铜官泥人刘艺术陶瓷厂 Ceramic and preparation method thereof
CN106957169A (en) * 2016-01-12 2017-07-18 长沙市望城区铜官先陶美术陶瓷有限公司 A kind of manufacture craft of iron stoneware
CN106116456A (en) * 2016-06-23 2016-11-16 湖南华联瓷业股份有限公司 Warm colour glaze colour daily-use fine and preparation method thereof in one

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108863308A (en) * 2018-08-17 2018-11-23 德阳极光文创设计有限公司 Ceramic material based on composite rock mineral
CN108911699A (en) * 2018-08-17 2018-11-30 德阳极光文创设计有限公司 The preparation method of ceramics based on composite rock mineral
CN109354406A (en) * 2018-11-14 2019-02-19 宁波联城住工科技有限公司 Anti-skidding glaze and preparation method thereof and a kind of production method of skid-resistance ceramic
CN114409374A (en) * 2022-02-23 2022-04-29 内蒙古布德民族文化发展有限责任公司 Preparation method of red mud for ceramics preparation and firing method of red mud product

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