CN107032832A - A kind of Ceramic Tiles with color changeable effect and preparation method thereof - Google Patents
A kind of Ceramic Tiles with color changeable effect and preparation method thereof Download PDFInfo
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- CN107032832A CN107032832A CN201710220875.6A CN201710220875A CN107032832A CN 107032832 A CN107032832 A CN 107032832A CN 201710220875 A CN201710220875 A CN 201710220875A CN 107032832 A CN107032832 A CN 107032832A
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- Prior art keywords
- color changeable
- ceramic tiles
- changeable effect
- glaze
- discoloration
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- 239000000919 ceramic Substances 0.000 title claims abstract description 57
- 230000000694 effects Effects 0.000 title claims abstract description 39
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 30
- 238000002845 discoloration Methods 0.000 claims abstract description 18
- PLDDOISOJJCEMH-UHFFFAOYSA-N neodymium(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Nd+3].[Nd+3] PLDDOISOJJCEMH-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910021332 silicide Inorganic materials 0.000 claims abstract description 16
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 15
- 239000002904 solvent Substances 0.000 claims abstract description 10
- 239000002270 dispersing agent Substances 0.000 claims abstract description 9
- 238000007792 addition Methods 0.000 claims abstract description 7
- 238000003756 stirring Methods 0.000 claims abstract description 6
- 238000010438 heat treatment Methods 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims description 16
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium monoxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 10
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 10
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 7
- 238000000498 ball milling Methods 0.000 claims description 6
- 229920002545 silicone oil Polymers 0.000 claims description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N AI2O3 Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 5
- KGBXLFKZBHKPEV-UHFFFAOYSA-N Boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 5
- 210000003298 Dental Enamel Anatomy 0.000 claims description 5
- 239000004327 boric acid Substances 0.000 claims description 5
- 229910052593 corundum Inorganic materials 0.000 claims description 5
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 5
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 5
- QEFYFXOXNSNQGX-UHFFFAOYSA-N Neodymium Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 claims description 4
- 229910052779 Neodymium Inorganic materials 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 125000004435 hydrogen atoms Chemical class [H]* 0.000 claims description 3
- 229910052681 coesite Inorganic materials 0.000 claims description 2
- 229910052906 cristobalite Inorganic materials 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 claims description 2
- 229910052904 quartz Inorganic materials 0.000 claims description 2
- 238000007650 screen-printing Methods 0.000 claims description 2
- 238000002791 soaking Methods 0.000 claims description 2
- 239000004328 sodium tetraborate Substances 0.000 claims description 2
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 2
- 239000007790 solid phase Substances 0.000 claims description 2
- 229910052682 stishovite Inorganic materials 0.000 claims description 2
- 229910052905 tridymite Inorganic materials 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims 2
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims 1
- 239000001768 carboxy methyl cellulose Substances 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims 1
- 238000005516 engineering process Methods 0.000 abstract description 3
- 230000015572 biosynthetic process Effects 0.000 abstract description 2
- 238000005755 formation reaction Methods 0.000 abstract description 2
- 238000009776 industrial production Methods 0.000 abstract description 2
- 238000005303 weighing Methods 0.000 abstract 1
- 239000011449 brick Substances 0.000 description 7
- -1 silicon neodymium Chemical compound 0.000 description 6
- 239000002002 slurry Substances 0.000 description 6
- 239000002245 particle Substances 0.000 description 4
- 239000003086 colorant Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000005034 decoration Methods 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 230000004907 flux Effects 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- KDJOAYSYCXTQGG-UHFFFAOYSA-N disilicic acid Chemical compound O[Si](O)(O)O[Si](O)(O)O KDJOAYSYCXTQGG-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 230000004438 eyesight Effects 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 230000037308 hair color Effects 0.000 description 1
- 230000004301 light adaptation Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000006011 modification reaction Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 230000002194 synthesizing Effects 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
Abstract
The invention discloses a kind of Ceramic Tiles with color changeable effect, it is made up of ceramic body layer, cover coat, glazed colour layer and transparent glaze layer from bottom to top, wherein glazed colour layer is mixed by discoloration fancy glaze and common fancy glaze, and the discoloration fancy glaze is mixed by Nd silicide and the component of low-temperature solvent two.Its preparation method includes weighing silica and neodymia according to a certain percentage, the appropriate mineralizer and dispersant of addition, it is dry blended stir after high-temperature heat treatment, obtain Nd silicide, obtained Nd silicide is mixed with low-temperature solvent, dispersant and stamp-pad ink again, discoloration fancy glaze is obtained.The present invention using the Nd silicide with high-temperature stable crystal formation as discoloration fancy glaze principle active component, become apparent from its colour generation and color changeable effect, the glazed colour layer that charity is formed in Ceramic Tiles after the discoloration fancy glaze and common fancy glaze are compounded, has the advantages that glaze quality is good, color changeable effect is notable, chromophoric characteristic is stable.Preparation technology of the present invention is simple, is conducive to large-scale industrial production.
Description
Technical field
The present invention relates to building decoration ceramic field, more particularly to a kind of Ceramic Tiles and its preparation side with color changeable effect
Method.
Background technology
Ceramic tile is in the home decoration in occupation of critically important part, and it is other that the ceramic tile combinations of different patterns can assign house fitting-up
The elegance of sample, gives the beautiful enjoyment of vision.With the development of Ceramic Tiles inkjet technology, the pattern of ceramic brick surface is rich
Richness, fine and smooth degree is obtained for great lifting, and in the market occurs in that the vivid and true to nature imitation wood line and imitative stone material of various quality
Ceramic Tiles, the sales volume of glazed tile obtained being also accumulated from large quantities of production glaze for glazed tile in the development of blowout, industry
Producer.Some problems are also brought simultaneously, it is all machine-made product that such as in the market, which is presented in face of consumer, it is current simple
Dependence layout it is less great to the lifting meaning of Ceramic Tiles, only pass through and develop personalized ceramic brick product
The growing demand of consumer could be met.
Color-change ceramic brick is to apply a kind of off-color material and ceramic brick surface, after high temperature is burnt till, can be in difference
Light under show the Ceramic Tiles of different colours., can be by combining based on this color changeable effect below different light
Layout, by controlling different light, realizes the changeable of Ceramic Tiles decoration style, lifts the personalization of Ceramic Tiles.China
Patent CN103693992A discloses a kind of changing colour enamal ceramics and its production method, this method by neodymia directly and some raw materials
Be mixed into camouflage paint, be then added to according to certain ratio among base glaze and changing colour enamal is made, then by spray or
Person pours to apply is made discoloration glazed tile in ceramic brick surface.Chinese patent CN104326739B discloses a kind of disilicic acid neodymium high temperature pottery
Porcelain color and preparation method thereof, the patent is prepared for the disilicic acid neodymium high temperature decorating colour with color changeable effect, and the colorant is in sunshine
It is down purple, is under fluorescent light blueness.The application example of existing color-change ceramic brick, is that neodymia is applied directly into glaze
In, it is primarily present problems with：First, the carbon dioxide in the easy moisture absorption of rare-earth oxidation neodymium, easy absorption air, by neodymia system
Into changing colour enamal, in sintering process, glaze easily bubbles, and has a strong impact on the quality of glaze；Secondly, neodymia easily with its in glaze
He reacts at composition, the glaze color developments of different systems not easy-regulating；Finally, directly using neodymia, its hair color effect is poor.
The content of the invention
It is an object of the invention to for above-mentioned the deficiencies in the prior art there is provided a kind of Ceramic Tiles with color changeable effect and
Its preparation method.
The technical solution used in the present invention is：A kind of Ceramic Tiles with color changeable effect, it is from bottom to top by ceramic blank
Body layer, cover coat, glazed colour layer and transparent glaze layer composition, wherein glazed colour layer is mixed by discoloration fancy glaze and common fancy glaze, described
Discoloration fancy glaze is mixed by Nd silicide and the component of low-temperature solvent two.
As the further improvement of such scheme, the Nd silicide accounts for color-changing flower based on material quality percentage composition
The 1 ~ 50% of glaze solid phase composition.
As the further improvement of such scheme, the low-temperature solvent is according to the weight percentage of raw materials by 40.51 ~ 49.32%
SiO2, 7.50 ~ 11.32% Al2O3, 9.38 ~ 16.10% CaO, 3.58 ~ 7.39% MgO, 1.05 ~ 5.60% K2O and
7.35 ~ 10.27% ZnO compositions.
A kind of preparation method of the Ceramic Tiles as described above with color changeable effect, it is comprised the technical steps that：
1）Silica and neodymia are weighed according to a certain percentage, appropriate mineralizer and dispersant is added, and dry blended stirring is equal
Even rear high-temperature heat treatment, obtains Nd silicide；
2）Obtained Nd silicide is mixed with low-temperature solvent, dispersant and stamp-pad ink and is placed in ball-milling treatment in ball mill, mistake
Sieve, obtains discoloration fancy glaze；
3）Discoloration fancy glaze and common fancy glaze are needed to carry out mixing toning according to design, and printed by screen printing or roller
Colored mode charity is being had been coated with the ceramic body of cover-coat enamel, forms glazed colour layer, then charity clear frit on glazed colour layer again, after
Through drying, burn till, obtain the Ceramic Tiles with color changeable effect.
Wherein, step 3）Described common fancy glaze needs to allocate according to design to be formed, in general practical operation
Can by common colorant with print cream, after stamp-pad ink mixing and ball milling certain time through sieving processing obtain common fancy glaze.
It is used as the further improvement of such scheme, step 1）Described in silica be according to mol ratio with neodymia
2.5~4:2 mixing.Yet further, the particle diameter of silica and neodymia is 20 ~ 100nm, and it is conducive to efficiently synthesizing knot
The high Nd silicide of brilliant degree.
It is used as the further improvement of such scheme, step 1）Described in mineralizer in boric acid and borax at least one
Kind, its addition is the 1 ~ 4% of silica and neodymia gross mass.
It is used as the further improvement of such scheme, step 1）Described in dispersant be containing hydrogen silicone oil, its addition be two
The 0.3 ~ 0.5% of silica and neodymia gross mass.Containing hydrogen silicone oil is added in the present invention as dry-mixed dispersant, can effectively be reduced
The reunion caking of Nd silicide, so as to further improve the stability of glaze layer after charity.
It is used as the further improvement of such scheme, step 1）Described in heat treatment process in control temperature 1150 ~
In the range of 1350 DEG C, soaking time is 1 ~ 3h.
It is used as the further improvement of such scheme, step 2）Described in dispersant to be selected from sodium tripolyphosphate and carboxymethyl fine
At least one of plain sodium of dimension, its addition is the 0.1 ~ 0.5% of Nd silicide and low-temperature solvent gross mass.
It is used as the further improvement of such scheme, step 2）Middle to require that discoloration fancy glaze crosses 325 mesh sieves without tailing over, its proportion is
1.3~2.2g/cm2。
It is used as the further improvement of such scheme, step 3）In firing temperature be 1150 ~ 1290 DEG C.
The beneficial effects of the invention are as follows：The present invention regard the Nd silicide with high-temperature stable crystal formation as discoloration fancy glaze
Principle active component, becomes apparent from its colour generation and color changeable effect, by charity after the discoloration fancy glaze and common fancy glaze compounding in ceramics
The glazed colour layer formed on brick, has the advantages that glaze quality is good, color changeable effect is notable, chromophoric characteristic is stable.The present invention prepares work
Skill is simple, is conducive to large-scale industrial production.
Embodiment
The present invention is specifically described with reference to embodiment, in order to art personnel to the present invention
Understand.It is necessary that herein the present invention will be further described it is emphasized that embodiment is only intended to, it is impossible to be interpreted as to this
The limitation of invention protection domain, art person skilled in the art, the non-intrinsically safe made according to foregoing invention content to the present invention
The modifications and adaptations of property, should still fall within protection scope of the present invention.Simultaneously following mentioned raw materials are unspecified, are
Commercially available prod；The processing step or preparation method not referred in detail be processing step known to a person skilled in the art or
Preparation method.
Embodiment 1
A kind of preparation method of the Ceramic Tiles with color changeable effect, it is comprised the technical steps that：
1）Silica 1 2g, 100nm that particle diameter is 20nm neodymia 33.6g are weighed, boric acid 1.82g and 0.23g is added hydrogeneous
Silicone oil, dry-mixed stirring 1h, then will be dry-mixed after material be placed in electric furnace, be heat-treated and be incubated after 3h in 1150 DEG C of high temperatures and take
Go out cooling, and grind and obtain silicon neodymium compound；
2）It is SiO to weigh mass percent composition2：40.51%, Al2O3：11.32%, CaO：9.38%, MgO：7.39%：K2O：
2.1%, ZnO：7.35% low temperature flux 198g, adds step 1）Middle silicon neodymium compound 10g, adds 1.52g sodium tripolyphosphates
With 80g stamp-pad ink, ball milling mixing 30min, slurry crosses 325 mesh sieves, and the proportion for the regulation and control slurry that adds water is 1.3g/cm2, obtain color-changing flower
Glaze；
3）On the ceramic body for having applied cover-coat enamel, first apply common fancy glaze, then apply changing colour enamal again, form glazed colour layer, afterwards
Cover layer of transparent glaze again, enter kiln dry after 1250 DEG C burn till, obtain the Ceramic Tiles with color changeable effect.
The prepared Ceramic Tiles with color changeable effect obtained of embodiment 1, from bottom to top by ceramic body layer, cover coat, coloured silk
Glaze layer and transparent glaze layer composition, it has color changeable effect substantially, in colour-stable, the good characteristic of glaze quality.
Embodiment 2
A kind of preparation method of the Ceramic Tiles with color changeable effect, it is comprised the technical steps that：
1）Silica 1 2g, 100nm that particle diameter is 50nm neodymia 33.6g are weighed, boric acid 0.36g and 0.11g is added hydrogeneous
Silicone oil, dry-mixed stirring 1h, then will be dry-mixed after material be placed in electric furnace, be heat-treated and be incubated after 1h in 1350 DEG C of high temperatures and take
Go out cooling, and grind and obtain silicon neodymium compound；
2）It is SiO to weigh mass percent composition2：49.32%, Al2O3：7.50%, CaO：9.38%, MgO：16.10%：K2O：
3.58%, ZnO：5.60% low temperature flux 40g, adds step 1）Middle silicon neodymium compound 40g, adds 2.38g sodium tripolyphosphates
With 60g stamp-pad ink, ball milling mixing 30min, slurry crosses 325 mesh sieves, and the proportion for the regulation and control slurry that adds water is 2.2g/cm2, obtain color-changing flower
Glaze；
3）On the ceramic body for having applied cover-coat enamel, first apply common fancy glaze, then apply changing colour enamal again, form glazed colour layer, afterwards
Cover layer of transparent glaze again, enter kiln dry after 1290 DEG C burn till, obtain the Ceramic Tiles with color changeable effect.
The prepared Ceramic Tiles with color changeable effect obtained of embodiment 2, from bottom to top by ceramic body layer, cover coat, coloured silk
Glaze layer and transparent glaze layer composition, it has color changeable effect substantially, in colour-stable, the good characteristic of glaze quality.
Embodiment 3
A kind of preparation method of the Ceramic Tiles with color changeable effect, it is comprised the technical steps that：
1）Silica 1 2g, 100nm that particle diameter is 20nm neodymia 33.6g are weighed, boric acid 1.21g and 0.18g is added hydrogeneous
Silicone oil, dry-mixed stirring 1h, then will be dry-mixed after material be placed in electric furnace, be heat-treated and be incubated after 1.5h in 1300 DEG C of high temperatures
Cooling is taken out, and grinds and obtains silicon neodymium compound；
2）It is SiO to weigh mass percent composition2：45.67%, Al2O3：9.38%, CaO：12.45%, MgO：6.34%：K2O：
2.1%, ZnO：7.35% low temperature flux 198g, adds step 1）Middle silicon neodymium compound 10g, adds 1.52g sodium tripolyphosphates
With 80g stamp-pad ink, ball milling mixing 30min, slurry crosses 325 mesh sieves, and the proportion for the regulation and control slurry that adds water is 1.3g/cm2, obtain color-changing flower
Glaze；
3）On the ceramic body for having applied cover-coat enamel, first apply common fancy glaze, then apply changing colour enamal again, form glazed colour layer, afterwards
Cover layer of transparent glaze again, enter kiln dry after 1250 DEG C burn till, obtain the Ceramic Tiles with color changeable effect.
The prepared Ceramic Tiles with color changeable effect obtained of embodiment 3, from bottom to top by ceramic body layer, cover coat, coloured silk
Glaze layer and transparent glaze layer composition, it has color changeable effect substantially, in colour-stable, the good characteristic of glaze quality.
Above-described embodiment is the preferred embodiments of the present invention, all with similar technique of the invention and the equivalence changes made,
The protection category of the present invention all should be belonged to.
Claims (10)
1. a kind of Ceramic Tiles with color changeable effect, it is characterised in that：From bottom to top by ceramic body layer, cover coat, glazed colour layer
With transparent glaze layer composition, wherein glazed colour layer is mixed by discoloration fancy glaze and common fancy glaze, and the discoloration fancy glaze is closed by neodymium silication
Thing and the component of low-temperature solvent two are mixed.
2. a kind of Ceramic Tiles with color changeable effect according to claim 1, it is characterised in that：The Nd silicide is pressed
Material quality percentage composition meter accounts for the 1 ~ 50% of discoloration fancy glaze solid phase composition.
3. a kind of Ceramic Tiles with color changeable effect according to claim 1, it is characterised in that：The low-temperature solvent is by original
Expect percentage by weight meter by 40.51 ~ 49.32% SiO2, 7.50 ~ 11.32% Al2O3, 9.38 ~ 16.10% CaO, 3.58 ~
7.39% MgO, 1.05 ~ 5.60% K2O and 7.35 ~ 10.27% ZnO compositions.
4. a kind of preparation method of Ceramic Tiles with color changeable effect as described in any one of claim 1 ~ 3, it is characterised in that
Comprise the technical steps that：
1）Silica and neodymia are weighed according to a certain percentage, appropriate mineralizer and dispersant is added, and dry blended stirring is equal
Even rear high-temperature heat treatment, obtains Nd silicide；
2）Obtained Nd silicide is mixed with low-temperature solvent, dispersant and stamp-pad ink and is placed in ball-milling treatment in ball mill, mistake
Sieve, obtains discoloration fancy glaze；
3）Discoloration fancy glaze and common fancy glaze are needed to carry out mixing toning according to design, and printed by screen printing or roller
Colored mode charity is being had been coated with the ceramic body of cover-coat enamel, forms glazed colour layer, then the charity clear frit on glazed colour layer, after
Through drying, burn till, obtain the Ceramic Tiles with color changeable effect.
5. a kind of Ceramic Tiles with color changeable effect according to claim 4, it is characterised in that：Step 1）Described in two
Silica is 2.5 ~ 4 according to mol ratio with neodymia:2 mixing.
6. a kind of Ceramic Tiles with color changeable effect according to claim 4, it is characterised in that：Step 1）Described in ore deposit
Agent is selected from least one of boric acid and borax, and its addition is the 1 ~ 4% of silica and neodymia gross mass.
7. a kind of Ceramic Tiles with color changeable effect according to claim 4, it is characterised in that：Step 1）Described in point
Powder is containing hydrogen silicone oil, and its addition is the 0.3 ~ 0.5% of silica and neodymia gross mass.
8. a kind of Ceramic Tiles with color changeable effect according to claim 4, it is characterised in that：Step 1）Described in heat
Control temperature in the range of 1150 ~ 1350 DEG C in processing procedure, soaking time is 1 ~ 3h.
9. a kind of Ceramic Tiles with color changeable effect according to claim 4, it is characterised in that：Step 2）Described in point
Powder is selected from least one of sodium tripolyphosphate and sodium carboxymethylcellulose, and its addition is Nd silicide and low-temperature solvent
The 0.1 ~ 0.5% of gross mass.
10. a kind of Ceramic Tiles with color changeable effect according to claim 4, it is characterised in that：Step 3）In burn till
Temperature is 1150 ~ 1290 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710220875.6A CN107032832A (en) | 2017-04-06 | 2017-04-06 | A kind of Ceramic Tiles with color changeable effect and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710220875.6A CN107032832A (en) | 2017-04-06 | 2017-04-06 | A kind of Ceramic Tiles with color changeable effect and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN107032832A true CN107032832A (en) | 2017-08-11 |
Family
ID=59533991
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710220875.6A Pending CN107032832A (en) | 2017-04-06 | 2017-04-06 | A kind of Ceramic Tiles with color changeable effect and preparation method thereof |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108191235A (en) * | 2018-03-15 | 2018-06-22 | 河南城建学院 | A kind of Bone China Glaze, glaze slip and preparation method |
| CN108624089A (en) * | 2018-07-20 | 2018-10-09 | 安徽东阳矿业科技有限公司 | The preparation method of the quartz products of high-purity content |
| CN109251013A (en) * | 2018-10-29 | 2019-01-22 | 长沙浩然医疗科技有限公司 | A kind of production technology of foamed ceramics |
| CN109437978A (en) * | 2018-11-21 | 2019-03-08 | 朱宝山 | Low-temp ceramics base glaze directly prints glaze ink and its application and ceramic |
| CN110436936A (en) * | 2019-08-09 | 2019-11-12 | 东莞市唯美陶瓷工业园有限公司 | A kind of photochromic Ceramic Tiles of decorative pattern and preparation method thereof |
| CN110981198A (en) * | 2019-11-21 | 2020-04-10 | 佛山欧神诺陶瓷有限公司 | Photochromic ceramic tile and preparation method thereof |
| CN111559904A (en) * | 2020-05-26 | 2020-08-21 | 蒙娜丽莎集团股份有限公司 | Whole-body color-changing light-transmitting ceramic tile and preparation method thereof |
| CN112960963A (en) * | 2021-03-05 | 2021-06-15 | 福建省德化艺囧瓷业有限公司 | Diatom porcelain product with strong water absorption and preparation method thereof |
| CN114907101A (en) * | 2021-02-08 | 2022-08-16 | Oppo广东移动通信有限公司 | Shell assembly, preparation method and electronic equipment |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101508598A (en) * | 2009-03-13 | 2009-08-19 | 白皓 | Rare earth neodymium red flambe glaze pigment and method of producing the same |
| CN106348594A (en) * | 2016-08-31 | 2017-01-25 | 广东金意陶陶瓷有限公司 | Whitening glaze suitable for silk screening and ceramic tile prepared from whitening glaze |
-
2017
- 2017-04-06 CN CN201710220875.6A patent/CN107032832A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101508598A (en) * | 2009-03-13 | 2009-08-19 | 白皓 | Rare earth neodymium red flambe glaze pigment and method of producing the same |
| CN106348594A (en) * | 2016-08-31 | 2017-01-25 | 广东金意陶陶瓷有限公司 | Whitening glaze suitable for silk screening and ceramic tile prepared from whitening glaze |
Non-Patent Citations (1)
| Title |
|---|
| 柯善军: "焦硅酸钕变色陶瓷色料及其墨水的制备与性能研究", 《中国博士学位论文全文数据库 工程科技Ⅰ辑》 * |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108191235A (en) * | 2018-03-15 | 2018-06-22 | 河南城建学院 | A kind of Bone China Glaze, glaze slip and preparation method |
| CN108624089A (en) * | 2018-07-20 | 2018-10-09 | 安徽东阳矿业科技有限公司 | The preparation method of the quartz products of high-purity content |
| CN109251013A (en) * | 2018-10-29 | 2019-01-22 | 长沙浩然医疗科技有限公司 | A kind of production technology of foamed ceramics |
| CN109437978A (en) * | 2018-11-21 | 2019-03-08 | 朱宝山 | Low-temp ceramics base glaze directly prints glaze ink and its application and ceramic |
| CN110436936A (en) * | 2019-08-09 | 2019-11-12 | 东莞市唯美陶瓷工业园有限公司 | A kind of photochromic Ceramic Tiles of decorative pattern and preparation method thereof |
| CN110436936B (en) * | 2019-08-09 | 2022-01-11 | 东莞市唯美陶瓷工业园有限公司 | Photochromic ceramic tile with decorative patterns and preparation method thereof |
| CN110981198A (en) * | 2019-11-21 | 2020-04-10 | 佛山欧神诺陶瓷有限公司 | Photochromic ceramic tile and preparation method thereof |
| CN110981198B (en) * | 2019-11-21 | 2022-08-16 | 佛山欧神诺陶瓷有限公司 | Photochromic ceramic tile and preparation method thereof |
| CN111559904A (en) * | 2020-05-26 | 2020-08-21 | 蒙娜丽莎集团股份有限公司 | Whole-body color-changing light-transmitting ceramic tile and preparation method thereof |
| CN114907101A (en) * | 2021-02-08 | 2022-08-16 | Oppo广东移动通信有限公司 | Shell assembly, preparation method and electronic equipment |
| CN112960963A (en) * | 2021-03-05 | 2021-06-15 | 福建省德化艺囧瓷业有限公司 | Diatom porcelain product with strong water absorption and preparation method thereof |
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