CN103588506B - Formula of black-matrix silver-strip streak ceramic glaze and preparation method thereof - Google Patents
Formula of black-matrix silver-strip streak ceramic glaze and preparation method thereof Download PDFInfo
- Publication number
- CN103588506B CN103588506B CN201310437267.2A CN201310437267A CN103588506B CN 103588506 B CN103588506 B CN 103588506B CN 201310437267 A CN201310437267 A CN 201310437267A CN 103588506 B CN103588506 B CN 103588506B
- Authority
- CN
- China
- Prior art keywords
- black
- ceramic glaze
- streak
- matrix silver
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Abstract
The present invention relates to formula of a kind of black-matrix silver-strip streak ceramic glaze and preparation method thereof, particularly this ceramic glaze colours has unique artistic effect and good physical and chemical.Present invention employs following technical scheme: a kind of formula of black-matrix silver-strip streak ceramic glaze, described formula is made up of by weight following raw material: potassium felspar sand 60 ~ 75%, calcium carbonate 1 ~ 3%, quartz 3 ~ 5.7%, clay 3 ~ 5.7%, Manganse Dioxide 16 ~ 30%, ferric oxide 0.6 ~ 2%, cobalt oxide 0.8 ~ 5%.Black-matrix silver-strip streak ceramic glaze, produces natural texture artistic effect, simultaneously physics and chemistry stable in properties.Black-matrix silver-strip streak ceramic glaze range of application is for very extensive: can be applied on external wall pottery, upholstery pottery, vessel tableware pottery, not containing heavy metals such as plumbous chromium, environmental protection, does not injure human body.
Description
Technical field
The present invention relates to formula of a kind of black-matrix silver-strip streak ceramic glaze and preparation method thereof, particularly this ceramic glaze colours has unique artistic effect and good physical and chemical.
Background technology
Ceramic glaze is ceramic making a kind of important source material that must use when producing, and has very strong provide protection to the base substrate of pottery, and the physical property of silicate makes the glass enamel of ceramic surface can the corrosion of effective antiacid alkali simultaneously, has fine germ resistance.Common ceramic colour glaze is by adding metallochrome in glass enamel, reach the effect reaching color development in the process fired, such glaze colours often color is single, can not give prominence to the special artistic effect produced in the aesthetic of ceramic colour glaze self and high-temperature firing process.Black-matrix silver-strip streak ceramic glaze effectively overcomes ceramic glaze deficiency in these areas, produces natural texture artistic effect, simultaneously physics and chemistry stable in properties.Black-matrix silver-strip streak ceramic glaze range of application is very extensive: can be applied on external wall pottery, upholstery pottery, vessel tableware pottery, not containing heavy metals such as plumbous chromium, environmental protection, does not injure human body.Mineral raw material and non-ferrous metal raw material distinguish the time of ball milling by preparation technology, the hair color effect of non-ferrous metal better, more stable.
Summary of the invention
The object of this invention is to provide formula of a kind of black-matrix silver-strip streak ceramic glaze and preparation method thereof, the technical problem that solve is the metal paillette grain effect allowing ceramic enamel black surface form silver color, reaches the physics and chemistry stable in properties of ceramic glaze simultaneously.
Present invention employs following technical scheme: a kind of formula of black-matrix silver-strip streak ceramic glaze, described formula is made up of by weight following raw material: potassium felspar sand 60 ~ 75%, calcium carbonate 1 ~ 3%, quartz 3 ~ 5.7%, clay 3 ~ 5.7%, Manganse Dioxide 16 ~ 30%, ferric oxide 0.6 ~ 2%, cobalt oxide 0.8 ~ 5%.
Formula of the present invention is made up of by weight following raw material: potassium felspar sand 65.8%, calcium carbonate 1%, quartz 5.7%, clay 5.7%, Manganse Dioxide 20.4%, ferric oxide 0.6%, cobalt oxide 0.8%.
Formula of the present invention is made up of by weight following raw material: potassium felspar sand 60%, calcium carbonate 3%, quartz 5.7%, clay 5.7%, Manganse Dioxide 22%, ferric oxide 1.8%, cobalt oxide 1.8%.
Formula of the present invention is made up of by weight following raw material: potassium felspar sand 70%, calcium carbonate 1%, quartz 3%, clay 3%, Manganse Dioxide 20%, ferric oxide 1%, cobalt oxide 2%.
A kind of preparation method of black-matrix silver-strip streak ceramic glaze: comprise the following steps: by weight; by potassium felspar sand 60 ~ 75%, calcium carbonate 1 ~ 3%, quartz 3 ~ 5.7%, clay 3 ~ 5.7%, participate in pure water by the 1:1 of quality, put in Quick ball grinder; rotating speed 450rpm, time 2 ~ 3.5h; Add Manganse Dioxide 16 ~ 30%, ferric oxide 0.6 ~ 2%, cobalt oxide 0.8 ~ 5%, rotating speed 450rpm, time 1 ~ 2h.
Method of the present invention: glaze is through the sieved filter of 600 ~ 800 object ceramic filter after grinding, and in process of production, room temp controls more than 0 DEG C, obtains liquid ceramic glaze.
Compared with prior art, owing to adding excessive saturated metal Manganse Dioxide and the stable cobalt oxide of hair color effect, make ceramic glaze obtain a kind of black matrix look, surface presentation goes out the special-effect of the paillette of argentine gloss in the present invention.Potassium felspar sand 60 ~ 75%, quartz 3 ~ 5.7% makes glass-ceramic glaze phase surface physics and chemistry stable in properties, is fired into power high, has both been applicable to the art pottery and has prepared a small amount of glaze, is applicable to again a large amount of process scale of large size ceramic manufacturing enterprise and produces.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in further detail.Formula of the present invention is made up of by weight following raw material: potassium felspar sand 60 ~ 75%, calcium carbonate 1 ~ 3%, quartz 3 ~ 5.7%, clay 3 ~ 5.7%, Manganse Dioxide 16 ~ 30%, ferric oxide 0.6 ~ 2%, cobalt oxide 0.8 ~ 5%.
Wherein potassium felspar sand, these two kinds of materials of quartz are the main raw materials forming ceramic glaze Watch glass glaze phase, its effect makes ceramic surface form the stable glass glaze phase surface of one deck, the corrosion of effective antiacid alkali can form the physics and chemistry of stable ceramic glaze.The ratio of potassium felspar sand 60 ~ 75%, make glass glaze phase surface smooth, brightness is high.Calcium carbonate and clay serve the effect reducing firing temperature, have saved fuel.Manganse Dioxide, ferric oxide, cobalt oxide serve the effect of color development, and experiment proves hair color effect obviously and very stable.
Example 1, formula: potassium felspar sand 65.8%, calcium carbonate 1%, quartz 5.7%, clay 5.7%, Manganse Dioxide 20.4%, ferric oxide 0.6%, cobalt oxide 0.8%.
Preparation method: according to formula ratio, first puts into potassium felspar sand, calcium carbonate, quartz, clay in HYB-I type Quick ball grinder, pours the water of identical weight simultaneously in the ratio of 1:1 into, with the rotating speed of 450rpm, and ball milling 3h.After ball milling, add metal Manganse Dioxide, ferric oxide, cobalt oxide ball milling 1.5h.After ball milling terminates, by 800 object ceramic filter sieves, obtain liquid state ceramic glaze.
Result is fired in experiment: example 1 is filled a prescription, and background color is chocolate, and there is argentine sheet spot 3 × 3mm on surface, and spot is evenly distributed in experiment test piece, produces strong reflection and metalluster effect in solar radiation situation.
Example 2, potassium felspar sand 60%, calcium carbonate 3%, quartz 5.7%, clay 5.7%, Manganse Dioxide 22%, ferric oxide 1.8%, cobalt oxide 1.8%.
Preparation method: according to formula ratio, first puts into potassium felspar sand, calcium carbonate, quartz, clay in HYB-I type Quick ball grinder, pours the water of identical weight simultaneously in the ratio of 1:1 into, with the rotating speed of 450rpm, and ball milling 2.5h.After ball milling, add metal Manganse Dioxide, ferric oxide, cobalt oxide ball milling 1h.After ball milling terminates, by 600 object ceramic filter sieves, obtain liquid state ceramic glaze
Result is fired in experiment: example 1 is filled a prescription, and background color is black, and there is argentine sheet spot 4 × 4mm on surface, and spot is evenly distributed in experiment test piece, produces strong reflection and metalluster effect in solar radiation situation.
Example 3, potassium felspar sand 70%, calcium carbonate 1%, quartz 3%, clay 3%, Manganse Dioxide 20%, ferric oxide 1%, cobalt oxide 2%.
Preparation method: according to formula ratio, first puts into potassium felspar sand, calcium carbonate, quartz, clay in HYB-I type Quick ball grinder, pours the water of identical weight simultaneously in the ratio of 1:1 into, with the rotating speed of 450rpm, and ball milling 3h.After ball milling, add metal Manganse Dioxide, ferric oxide, cobalt oxide ball milling 2h.After ball milling terminates, by 600 object ceramic filter sieves, obtain liquid state ceramic glaze
Result is fired in experiment: example 1 is filled a prescription, and background color is aterrimus, and there is argentine sheet spot 2.5 × 2.5mm on surface, and spot is evenly distributed in experiment test piece, produces strong reflection and metalluster effect in solar radiation situation.
Comparison example 1 and example 2 add Manganse Dioxide and ferric oxide content, effectively can increase the size of metal paillette in color glaze.The content adding cobalt oxide can increase the weight of the color of background color, has chocolate to become black.Comparison example 2 and example 3, the content argentine sheet spot decreasing Manganse Dioxide reduces obviously.The content increasing cobalt oxide makes background color more black.
Claims (5)
1. a black-matrix silver-strip streak ceramic glaze, is characterized in that: be made up of by weight following raw material: potassium felspar sand 60 ~ 75%, calcium carbonate 1 ~ 3%, quartz 3 ~ 5.7%, clay 3 ~ 5.7%, Manganse Dioxide 16 ~ 30%, ferric oxide 0.6 ~ 2%, cobalt oxide 0.8 ~ 5%.
2. black-matrix silver-strip streak ceramic glaze according to claim 1, is characterized in that: be made up of by weight following raw material: potassium felspar sand 65.8%, calcium carbonate 1%, quartz 5.7%, clay 5.7%, Manganse Dioxide 20.4%, ferric oxide 0.6%, cobalt oxide 0.8%.
3. black-matrix silver-strip streak ceramic glaze according to claim 1, is characterized in that: be made up of by weight following raw material: potassium felspar sand 60%, calcium carbonate 3%, quartz 5.7%, clay 5.7%, Manganse Dioxide 22%, ferric oxide 1.8%, cobalt oxide 1.8%.
4. black-matrix silver-strip streak ceramic glaze according to claim 1, is characterized in that: be made up of by weight following raw material: potassium felspar sand 70%, calcium carbonate 1%, quartz 3%, clay 3%, Manganse Dioxide 20%, ferric oxide 1%, cobalt oxide 2%.
5. the preparation method of a kind of black-matrix silver-strip streak ceramic glaze as claimed in claim 1: comprise the following steps: by weight; by potassium felspar sand 60 ~ 75%, calcium carbonate 1 ~ 3%, quartz 3 ~ 5.7%, clay 3 ~ 5.7%; pure water is participated in by the 1:1 of quality; put in Quick ball grinder; rotating speed 450rpm, time 2 ~ 3.5h; Add Manganse Dioxide 16 ~ 30%, ferric oxide 0.6 ~ 2%, cobalt oxide 0.8 ~ 5%, rotating speed 450rpm, time 1 ~ 2h.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310437267.2A CN103588506B (en) | 2013-09-24 | 2013-09-24 | Formula of black-matrix silver-strip streak ceramic glaze and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310437267.2A CN103588506B (en) | 2013-09-24 | 2013-09-24 | Formula of black-matrix silver-strip streak ceramic glaze and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103588506A CN103588506A (en) | 2014-02-19 |
| CN103588506B true CN103588506B (en) | 2015-12-23 |
Family
ID=50078869
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310437267.2A Expired - Fee Related CN103588506B (en) | 2013-09-24 | 2013-09-24 | Formula of black-matrix silver-strip streak ceramic glaze and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103588506B (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105086553B (en) * | 2014-05-16 | 2018-10-23 | 康存良 | A kind of Faience pottery coloured drawing pigment |
| CN105837042A (en) * | 2016-03-25 | 2016-08-10 | 江苏宜翔陶瓷科技有限公司 | Black nap texture glaze and preparation method thereof |
| CN106430973B (en) * | 2016-10-20 | 2019-07-09 | 沈阳建筑大学 | A kind of sodium pyroborate iron oxide black crystalline glaze and preparation method thereof |
| CN106904834A (en) * | 2017-03-30 | 2017-06-30 | 井冈山大学 | The preparation method and application method of the dark orchid color wood leaf clay glaze in unregistered land |
| CN107619190A (en) * | 2017-10-13 | 2018-01-23 | 沈阳建筑大学 | Tin ash darkviolet point-like metallic crystal ceramic glaze and preparation method thereof |
| CN107915407A (en) * | 2017-11-30 | 2018-04-17 | 南宁市生润科技有限公司 | A kind of black glazed tiles glaze |
| CN115140941B (en) * | 2022-07-25 | 2023-11-21 | 景德镇欧神诺陶瓷有限公司 | Full raw material silver gray metallic luster glaze, foundation wall brick and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103304273A (en) * | 2013-06-08 | 2013-09-18 | 浙江工业大学之江学院工业研究院 | Black crystal glaze material and firing method thereof |
-
2013
- 2013-09-24 CN CN201310437267.2A patent/CN103588506B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103304273A (en) * | 2013-06-08 | 2013-09-18 | 浙江工业大学之江学院工业研究院 | Black crystal glaze material and firing method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103588506A (en) | 2014-02-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103588506B (en) | Formula of black-matrix silver-strip streak ceramic glaze and preparation method thereof | |
| CN104529548B (en) | A kind of erythema crystalline glaze and adopt the ceramic preparation of this glaze | |
| CN106986540B (en) | Formula for making sunken and peeled marble glaze | |
| CN104016719B (en) | Reactive crystallization glaze with sagging effect and preparation method thereof | |
| EP3318541B1 (en) | Glaze resistant to wax block bonding, ceramic resistant to wax block bonding and preparation process thereof | |
| CN102936156B (en) | Glaze material of high temperature fast firing crystal glaze archaized brick and preparation process thereof | |
| CN102731168B (en) | Preparation method of white body ice crackle vitreous enamel and products produced from white body ice crackle vitreous enamel | |
| CN103951466A (en) | Double-layer reaction glaze and producing method thereof | |
| CN101462895A (en) | Golden yellow metal lustre glaze and preparation thereof | |
| CN106396638B (en) | Low temperature lightweight lime gradual change glaze ceramics and its manufacture craft | |
| CN106082662B (en) | A kind of clear frit and manufacture craft | |
| CN103601534A (en) | High-whiteness under-glaze colorful low-temperature ceramic and preparation method thereof | |
| CN103332966A (en) | Preparation method of composite opaque glaze | |
| CN105315015A (en) | Preparation method for architectural decoration flambe art ceramic tile | |
| CN104058789A (en) | Starlight enamel glaze material and application technique thereof | |
| CN105272153A (en) | Preparation method of blue-and-white Nixing ceramic | |
| CN104891808A (en) | Brown crystal glaze composition | |
| CN104193411B (en) | A kind of sanitary ceramic ware crystalline glaze and preparation technology thereof | |
| CN107244908B (en) | High-whiteness jade-like polished tile adobe and tile preparation method thereof | |
| CN103332965B (en) | Golden yellow crystallized dry-granular glaze and using method thereof | |
| CN103553715A (en) | Oxidation reaction glaze material | |
| CN107010922A (en) | The preparation method of furnace transmutation glaze boccaro fine earthenware | |
| CN104261880B (en) | A kind of sand crystal glaze and preparation technology thereof utilizing iron mica | |
| CN104829269A (en) | Low-temperature fast firing blue crystalline glaze composition | |
| CN103880476A (en) | Cold ceramic glaze with sterilization and antibacterial functions and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20151223 Termination date: 20160924 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |