CN103588506A - Formula of black-matrix silver-strip streak ceramic glaze and preparation method thereof - Google Patents

Formula of black-matrix silver-strip streak ceramic glaze and preparation method thereof Download PDF

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CN103588506A
CN103588506A CN201310437267.2A CN201310437267A CN103588506A CN 103588506 A CN103588506 A CN 103588506A CN 201310437267 A CN201310437267 A CN 201310437267A CN 103588506 A CN103588506 A CN 103588506A
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ceramic glaze
formula
clay
matrix silver
calcium carbonate
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CN103588506B (en
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沈海泳
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Shenyang Jianzhu University
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Shenyang Jianzhu University
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Abstract

The invention relates to a formula of black-matrix silver-strip streak ceramic glaze and a preparation method thereof. Particularly, the ceramic glaze has unique artistic effects and good physical properties and chemical properties. The technical scheme is as follows: the formula of black-matrix silver-strip streak ceramic glaze consists of the following raw materials in percentage by weight: 60-75% of potassium feldspar, 1-3% of calcium carbonate, 3-5.7% of quartz, 3-5.7% of clay, 16-30% of manganese dioxide, 0.6-2% of iron oxide and 0.8-5% of cobalt oxide. The black-matrix silver-strip streak ceramic glaze generates natural texture artistic effects while realizing stable physical and chemical properties. The black-matrix silver-strip streak ceramic glaze is remarkably widely applicable to building exterior wall ceramics, indoor decoration ceramics and utensil and tableware ceramics, does not contain heavy metals such as lead, chromium and the like, is environment-friendly, and prevents harm to human bodies.

Description

Formula of black matrix silver strip line ceramic glaze and preparation method thereof
Technical field
The present invention relates to formula of a kind of black matrix silver strip line ceramic glaze and preparation method thereof, particularly this pottery glaze colours has unique artistic effect and good physical and chemical.
Background technology
Ceramic glaze is a kind of important source material that ceramic making must be used while producing, and ceramic base substrate is had to very strong provide protection, and the physical property of silicate makes the corrosion that the glass enamel of ceramic surface can effective antiacid alkali simultaneously, has fine germ resistance.Common ceramic colour glaze is by add metallochrome in glass enamel, reach the effect that reaches color development in the process of firing, such glaze colours often color is single, can not give prominence to the special artistic effect producing in the aesthetic of ceramic colour glaze self and high-temperature firing process.Black matrix silver strip line ceramic glaze has effectively overcome ceramic glaze deficiency in these areas, produces natural texture artistic effect, simultaneously physics and chemistry stable in properties.Black matrix silver strip line ceramic glaze range of application is very extensive: can be applied on external wall pottery, upholstery pottery, vessel tableware pottery, not contain the heavy metals such as plumbous chromium, environmental protection, to not injury of human body.Mineral raw material and non-ferrous metal raw material are distinguished to the time of ball milling, the color development better effects if of non-ferrous metal, more stable in preparation technology.
  
Summary of the invention
The object of this invention is to provide formula of a kind of black matrix silver strip line ceramic glaze and preparation method thereof, the technical problem that solve is to allow ceramic enamel black surface form the metal paillette grain effect of silver color, reaches the physics and chemistry stable in properties of ceramic glaze simultaneously.
The present invention has adopted following technical scheme: a kind of formula of black matrix silver strip line ceramic glaze, described formula consists of by weight following raw material: potassium felspar sand 60~75%, calcium carbonate 1~3%, quartz 3~5.7%, clay 3~5.7%, Manganse Dioxide 16~30%, ferric oxide 0.6~2%, cobalt oxide 0.8~5%.
Formula of the present invention consists of by weight following raw material: potassium felspar sand 65.8%, calcium carbonate 1%, quartz 5.7%, clay 5.7%, Manganse Dioxide 20.4%, ferric oxide 0.6%, cobalt oxide 0.8%.
Formula of the present invention consists of by weight following raw material: potassium felspar sand 60%, calcium carbonate 3%, quartz 5.7%, clay 5.7%, Manganse Dioxide 22%, ferric oxide 1.8%, cobalt oxide 1.8%.
Formula of the present invention consists of by weight following raw material: potassium felspar sand 70%, calcium carbonate 1%, quartz 3%, clay 3%, Manganse Dioxide 20%, ferric oxide 1%, cobalt oxide 2%.
A kind of preparation method of black matrix silver strip line ceramic glaze: comprise the following steps: by weight; by potassium felspar sand 60~75%, calcium carbonate 1~3%, quartzy 3~5.7%, clay 3~5.7%,, by the 1:1 of quality, participate in pure water, put in Quick ball grinder; rotating speed 450rpm, time 2~3.5h; Add Manganse Dioxide 16~30%, ferric oxide 0.6~2%, cobalt oxide 0.8~5%, rotating speed 450rpm, time 1~2h.
Method of the present invention: glaze filters through 600~800 object ceramic filter sieves after grinding, and in process of production, room temp is controlled at more than 0 ℃, obtains liquid ceramic glaze.
The present invention compared with prior art, owing to having added the cobalt oxide of excessive saturated metal Manganse Dioxide and color development effect stability, makes ceramic glaze obtain a kind of black matrix look, and surface presents the special-effect of the paillette of argentine gloss.Potassium felspar sand 60~75%, quartzy 3~5.7% make glass-ceramic glaze phase surface physics and chemistry stable in properties, are fired into power high, have both been applicable to the art pottery and have prepared a small amount of glaze, are applicable to again a large amount of process scale of large size ceramic manufacturing enterprise and produce.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in further detail.Formula of the present invention consists of by weight following raw material: potassium felspar sand 60~75%, calcium carbonate 1~3%, quartz 3~5.7%, clay 3~5.7%, Manganse Dioxide 16~30%, ferric oxide 0.6~2%, cobalt oxide 0.8~5%.
Wherein potassium felspar sand, quartzy these two kinds of materials are the main raw materials that form ceramic glaze Watch glass glaze phase, its effect is to make ceramic surface form the stable glass glaze phase surface of one deck, and corrosion that can effective antiacid alkali forms the physics and chemistry of stable ceramic glaze.The ratio of potassium felspar sand 60~75%, makes glass glaze phase surface smooth, and brightness is high.Calcium carbonate and clay have played the effect that reduces firing temperature, have saved fuel.Manganse Dioxide, ferric oxide, cobalt oxide have played the effect of color development, experimental results show that color development successful and very stable.
Example 1, formula: potassium felspar sand 65.8%, calcium carbonate 1%, quartz 5.7%, clay 5.7%, Manganse Dioxide 20.4%, ferric oxide 0.6%, cobalt oxide 0.8%.
Preparation method: according to formula ratio, first potassium felspar sand, calcium carbonate, quartz, clay are put in HYB-I type Quick ball grinder, in the ratio of 1:1, poured into the water of identical weight simultaneously, with the rotating speed of 450rpm, ball milling 3h.After ball milling, add metal Manganse Dioxide, ferric oxide, cobalt oxide ball milling 1.5h.After ball milling finishes, by 800 object ceramic filter sieves, obtain liquid state ceramic glaze.
Result is fired in experiment: example 1 formula, and background color is chocolate, and there is argentine sheet spot 3 * 3mm on surface, and spot is evenly distributed in experiment test piece, produces strong reflection and metalluster effect in solar radiation situation.
Example 2, potassium felspar sand 60%, calcium carbonate 3%, quartz 5.7%, clay 5.7%, Manganse Dioxide 22%, ferric oxide 1.8%, cobalt oxide 1.8%.
Preparation method: according to formula ratio, first potassium felspar sand, calcium carbonate, quartz, clay are put in HYB-I type Quick ball grinder, in the ratio of 1:1, poured into the water of identical weight simultaneously, with the rotating speed of 450rpm, ball milling 2.5h.After ball milling, add metal Manganse Dioxide, ferric oxide, cobalt oxide ball milling 1h.After ball milling finishes, by 600 object ceramic filter sieves, obtain liquid state ceramic glaze
Result is fired in experiment: example 1 formula, and background color is black, and there is argentine sheet spot 4 * 4mm on surface, and spot is evenly distributed in experiment test piece, produces strong reflection and metalluster effect in solar radiation situation.
Example 3, potassium felspar sand 70%, calcium carbonate 1%, quartz 3%, clay 3%, Manganse Dioxide 20%, ferric oxide 1%, cobalt oxide 2%.
Preparation method: according to formula ratio, first potassium felspar sand, calcium carbonate, quartz, clay are put in HYB-I type Quick ball grinder, in the ratio of 1:1, poured into the water of identical weight simultaneously, with the rotating speed of 450rpm, ball milling 3h.After ball milling, add metal Manganse Dioxide, ferric oxide, cobalt oxide ball milling 2h.After ball milling finishes, by 600 object ceramic filter sieves, obtain liquid state ceramic glaze
Result is fired in experiment: example 1 formula, and background color is aterrimus, and there is argentine sheet spot 2.5 * 2.5mm on surface, and spot is evenly distributed in experiment test piece, produces strong reflection and metalluster effect in solar radiation situation.
Comparison example 1 and example 2 increased Manganse Dioxide and ferric oxide content, can effectively increase the size of metal paillette in color glaze.The content that has increased cobalt oxide can increase the weight of the color of background color, has chocolate to become black.Comparison example 2 and example 3, the content argentine sheet spot that has reduced Manganse Dioxide dwindles obviously.The content that increases cobalt oxide makes background color more black.

Claims (7)

1. a formula for black matrix silver strip line ceramic glaze, is characterized in that: described formula consists of by weight following raw material: potassium felspar sand 60~75%, calcium carbonate 1~3%, quartz 3~5.7%, clay 3~5.7%, Manganse Dioxide 16~30%, ferric oxide 0.6~2%, cobalt oxide 0.8~5%.
2. the formula of black matrix silver strip line ceramic glaze according to claim 1, is characterized in that: described formula consists of by weight following raw material: potassium felspar sand 65.8%, calcium carbonate 1%, quartz 5.7%, clay 5.7%, Manganse Dioxide 20.4%, ferric oxide 0.6%, cobalt oxide 0.8%.
3. the formula of black matrix silver strip line ceramic glaze according to claim 1, is characterized in that: described formula consists of by weight following raw material: potassium felspar sand 60%, calcium carbonate 3%, quartz 5.7%, clay 5.7%, Manganse Dioxide 22%, ferric oxide 1.8%, cobalt oxide 1.8%.
4. the formula of black matrix silver strip line ceramic glaze according to claim 1, is characterized in that: described formula consists of by weight following raw material: potassium felspar sand 70%, calcium carbonate 1%, quartz 3%, clay 3%, Manganse Dioxide 20%, ferric oxide 1%, cobalt oxide 2%.
5. the preparation method of a kind of black matrix silver strip line ceramic glaze as claimed in claim 1: comprise the following steps: by weight; by potassium felspar sand 60~75%, calcium carbonate 1~3%, quartzy 3~5.7%, clay 3~5.7%; 1:1 by quality participates in pure water; put in Quick ball grinder; rotating speed 450rpm, time 2~3.5h; Add Manganse Dioxide 16~30%, ferric oxide 0.6~2%, cobalt oxide 0.8~5%, rotating speed 450rpm, time 1~2h.
6. according to the preparation method of the black matrix silver strip line ceramic glaze described in right 5: it is characterized in that: to described raw material ball milling be sequentially, first ball milling potassium felspar sand 60~75%, calcium carbonate 1~3%, quartz 3~5.7%, clay 3~5.7%, the metal oxides such as rear ball milling Manganse Dioxide 16~30%, ferric oxide 0.6~2%, cobalt oxide 0.8~5%.
7. according to the preparation method of the black matrix silver strip line ceramic glaze described in right 5: it is characterized in that: the time of ball milling is: by potassium felspar sand 60~75%, calcium carbonate 1~3%, quartz 3~5.7%, clay 3~5.7%, rotating speed 450rpm, time 2~3.5h; Manganse Dioxide 16~30%, ferric oxide 0.6~2%, cobalt oxide 0.8~5%, rotating speed 450rpm, time 1~2h.
CN201310437267.2A 2013-09-24 2013-09-24 Formula of black-matrix silver-strip streak ceramic glaze and preparation method thereof Expired - Fee Related CN103588506B (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105086553A (en) * 2014-05-16 2015-11-25 康存良 Colored drawing pigment for painted pottery
CN105837042A (en) * 2016-03-25 2016-08-10 江苏宜翔陶瓷科技有限公司 Black nap texture glaze and preparation method thereof
CN106430973A (en) * 2016-10-20 2017-02-22 沈阳建筑大学 Sodium pyroborate iron black crystalline glaze and preparation method thereof
CN106904834A (en) * 2017-03-30 2017-06-30 井冈山大学 The preparation method and application method of the dark orchid color wood leaf clay glaze in unregistered land
CN107619190A (en) * 2017-10-13 2018-01-23 沈阳建筑大学 Tin ash darkviolet point-like metallic crystal ceramic glaze and preparation method thereof
CN107915407A (en) * 2017-11-30 2018-04-17 南宁市生润科技有限公司 A kind of black glazed tiles glaze
CN115140941A (en) * 2022-07-25 2022-10-04 景德镇欧神诺陶瓷有限公司 Full-raw silver gray metallic luster glaze, foundation wall brick and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103304273A (en) * 2013-06-08 2013-09-18 浙江工业大学之江学院工业研究院 Black crystal glaze material and firing method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103304273A (en) * 2013-06-08 2013-09-18 浙江工业大学之江学院工业研究院 Black crystal glaze material and firing method thereof

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105086553A (en) * 2014-05-16 2015-11-25 康存良 Colored drawing pigment for painted pottery
CN105086553B (en) * 2014-05-16 2018-10-23 康存良 A kind of Faience pottery coloured drawing pigment
CN105837042A (en) * 2016-03-25 2016-08-10 江苏宜翔陶瓷科技有限公司 Black nap texture glaze and preparation method thereof
CN106430973A (en) * 2016-10-20 2017-02-22 沈阳建筑大学 Sodium pyroborate iron black crystalline glaze and preparation method thereof
CN106430973B (en) * 2016-10-20 2019-07-09 沈阳建筑大学 A kind of sodium pyroborate iron oxide black crystalline glaze and preparation method thereof
CN106904834A (en) * 2017-03-30 2017-06-30 井冈山大学 The preparation method and application method of the dark orchid color wood leaf clay glaze in unregistered land
CN107619190A (en) * 2017-10-13 2018-01-23 沈阳建筑大学 Tin ash darkviolet point-like metallic crystal ceramic glaze and preparation method thereof
CN107915407A (en) * 2017-11-30 2018-04-17 南宁市生润科技有限公司 A kind of black glazed tiles glaze
CN115140941A (en) * 2022-07-25 2022-10-04 景德镇欧神诺陶瓷有限公司 Full-raw silver gray metallic luster glaze, foundation wall brick and preparation method thereof
CN115140941B (en) * 2022-07-25 2023-11-21 景德镇欧神诺陶瓷有限公司 Full raw material silver gray metallic luster glaze, foundation wall brick and preparation method thereof

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