CN108264782A - A kind of Dry powder type shell powder coating and preparation method thereof - Google Patents

A kind of Dry powder type shell powder coating and preparation method thereof Download PDF

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Publication number
CN108264782A
CN108264782A CN201810006481.5A CN201810006481A CN108264782A CN 108264782 A CN108264782 A CN 108264782A CN 201810006481 A CN201810006481 A CN 201810006481A CN 108264782 A CN108264782 A CN 108264782A
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shell
shell powder
coating
dry powder
dry
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CN201810006481.5A
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Chinese (zh)
Inventor
张辉
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Heilongjiang Bess Eel Environmental Protection Technology Co Ltd
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Heilongjiang Bess Eel Environmental Protection Technology Co Ltd
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Priority to CN201810006481.5A priority Critical patent/CN108264782A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/006Anti-reflective coatings
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/32Radiation-absorbing paints

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

A kind of Dry powder type shell powder coating and preparation method thereof, including oyster shell whiting, plant adhesive and inorganic pigment, wherein, the weight ratio of the shell powder paint is oyster shell whiting 80%, plant adhesive 5%, environment friendly inorganic pigment 2%;Kaolin 5%, nano silicon dioxide 3%, gold redrock nano-titanium dioxide 2%, magnesia 3%;The smell and indoor miscellaneous taste that the Dry powder type shell powder coating can distribute indoor smoke, infant, patient, pet, mould all have the advantageous effect effectively dispelled, the advantageous effect of carbon monoxide and dust Capacity with suction-operated especially distributed indoors to cigarette;Plant adhesive in shell powder paint is to be extracted the binding material for having sedimentation and flocculating function in cotton core and paper pulp using extraction method, adds reagent without any harmful chemicals, has reached natural harmless advantageous effect;Environment friendly inorganic pigment is applied can play the advantageous effects such as cooling energy-saving, durability are good, colour retention is good in coating.

Description

A kind of Dry powder type shell powder coating and preparation method thereof
Technical field
The present invention relates to technical field of coatings, it is especially a kind of using oyster shell whiting as major ingredient, plant adhesive, inorganic pigment, Kaolin, nano silicon dioxide, gold redrock nano-titanium dioxide and magnesia are the green of auxiliary material, a kind of dry-type shellfish of environmental protection Shell powder coating and preparation method thereof.
Background technology
In today of people's pay attention to day by day environmental protection, with the deterioration of atmospheric environment and goods and materials improvement of living standard, people Requirement for the air quality of indoor environment is also increasingly stringenter;Current interior decoration largely uses emulsion paint, paint, compound The materials such as plank, leather, foam insert, plastic facing, it is serious dirty containing a large amount of volatility toxic compounds in material Dye living and working environment, the health for endangering people;The dope for inner wall of architecture used in the market is mainly emulsion paint, and emulsion paint is universal There is the shortcomings of paint film is soft, drying time is long, bin stability is poor, emulsion paint class coating after being moistened, easily grows bacterium, Phenomena such as generation comes off, changes colour seriously affects service life and indoor beauty;At present, environment-friendly type coating emerges in an endless stream, it is recognized that Most environmentally friendly coating one be water paint, second is that powdery paints;Powdery paints is even more to have the advantages that absolutely to form a film, But really just it can accomplish pure natural no pollution from raw material, while the coating of adsorption-decomposition function pollutions such as formaldehyde within doors, market It is upper actually rare, therefore, using natural material be made powdery paints by be following interior wall coating development trend.
Invention content
For overcome the deficiencies in the prior art, the present invention provides a kind of Dry powder type shell powder coating and preparation method thereof, A kind of oyster shell whiting in the Dry powder type shell powder coating and preparation method thereof by shell by high-temperature calcination, crush after be made, Its component part is the calcified materials such as calcium carbonate, calcium oxide, calcium hydroxide, this has absorption, decomposes first as porous helical The harmful substances such as aldehyde, benzene, it is antibacterial, sterilization, anlistatig function, reached adjusting air humidity, eliminate peculiar smell, instead of wallpaper, The purpose of traditional coating such as emulsion paint, diatom ooze.
The technical solution used in the present invention is a kind of Dry powder type shell powder coating, including oyster shell whiting, plant adhesive, Inorganic pigment, kaolin, nano silicon dioxide, gold redrock nano-titanium dioxide and magnesia, wherein, the shell powder paint Weight ratio for oyster shell whiting 80%, plant adhesive 5%, environment friendly inorganic pigment 2%;Kaolin 5%, nano silicon dioxide 3%, gold Red stone nano-titanium dioxide 2%, magnesia 3%;
The application method of the Dry powder type shell powder coating is:Because contain various impurity, therefore, the oyster shell whiting in tap water Pure water is used when coating dilutes;Mixer is added in after pure water is weighed first, the shell powder paint addition after weighing is matched It is mixed in charging basket with pure water, wherein, the weight ratio of pure water and shell powder paint is 5:1, it stirs 10 minutes clockwise manually Afterwards, it static 10 minutes, stays in after the shell powder paint in mixer fully dissolves water, according to the needs of wall color effect, adds Enter food coloring to mix colours, be further continued for stirring 10 minutes so that oyster shell whiting in mixer and pure water, food coloring it is mixed It closes object to be more uniformly distributed, direct first pass spraying or roller coating on metope, metope carries out the time drying of half a day after the completion of application, does Metope after dry carries out second time spraying or application can be completed in roller coating;Coating it is diluted during requirement in strict accordance with water with The proportion of shell powder paint is diluted, in order to avoid causing aberration, the coating after dilution requires to be finished in one hour, Yi Mianzao It is precipitated into shell powder paint, paint film is uneven;Requirement uniformly sprays or roller coating in coating process, in order to avoid cause film thickness not One, influence overall effect.
A kind of preparation method of Dry powder type shell powder coating, the specific steps are:It is prepared by oyster shell whiting preparation → plant adhesive → mixture mixing → drying → crushing → sieving → packaging;The oyster shell whiting is prepared as cleaning shell → immersion → height Warm calcining → cooling → grinding;The plant adhesive is prepared as the binding material by being extracted in cotton core and paper pulp;Institute It is by oyster shell whiting, plant adhesive, environment friendly inorganic pigment and kaolin, nano silicon dioxide, gold that the mixture stated, which is mixed, Red stone nano-titanium dioxide, magnesia and a certain proportion of pure water input blender are sufficiently stirred to obtain mixture;Described It dries and is dried for obtained mixture is put into dryer, obtain dry matter mixture;The crushing is after drying Mixture dry powder is obtained after being crushed in dry matter mixture input pulverizer;The sieving is to do the mixture after crushing Powder obtains standard compliant shell powder paint dry powder after being screened via 1200 mesh;Described is packaged as shell powder paint Dry powder is by packaging production line quantitative package;
The beneficial effects of the invention are as follows:The compound of calcium is chiefly used in eliminating smell agent in life, and oyster shell whiting is to lead to natural shell Manufactured powdered substance after high-temperature calcination, grinding is crossed, component part is the calcified materials such as calcium carbonate, calcium oxide, calcium hydroxide, This has the function of absorption, decomposing formaldehyde, benzene, TVOC, ammonia and adjusting air humidity, eliminates peculiar smell as porous helical Function, therefore, shell powder paint can be to smell that indoor smoke, infant, patient, pet, mould are distributed and interiors Miscellaneous taste all has the advantageous effect effectively dispelled, and the carbon monoxide and dust Capacity especially distributed indoors to cigarette has The advantageous effect of suction-operated;Plant adhesive in shell powder paint is that will have sedimentation in cotton core and paper pulp using extraction method It is extracted with the binding material of flocculating function, adds reagent without any harmful chemicals, reached natural harmless beneficial effect Fruit;Environment friendly inorganic pigment is applied can play the advantageous effects such as cooling energy-saving, durability are good, colour retention is good in coating;Nanometer Silica adds and forms shielding action to coating in coating, has excellent self-cleaning performance and adhesive force, has extremely strong Ultraviolet radiation absorption and infrared resistant reflection performance, improve the finish and anti-aging property of figure layer, reach uvioresistant Aging and the advantageous effect of heat ageing;Gold redrock nano-titanium dioxide, the aging of film are substantially reduced, and screen is played to ultraviolet light The effect of covering has reached the advantageous effect for being effectively protected film;Zinc oxide can improve the weatherability and resistance to chalking of film Ability has reached fire-retardant advantageous effect.
Specific embodiment:
The present invention specific embodiment be:
A kind of Dry powder type shell powder coating, including oyster shell whiting, plant adhesive, inorganic pigment, kaolin, nano silicon dioxide, Gold redrock nano-titanium dioxide and magnesia, wherein, the weight ratio of the shell powder paint is oyster shell whiting 80%, plant is glued Mixture 5%, environment friendly inorganic pigment 2%;Kaolin 5%, nano silicon dioxide 3%, gold redrock nano-titanium dioxide 2%, magnesia 3%;
The application method of the Dry powder type shell powder coating is:Because contain various impurity, therefore, the oyster shell whiting in tap water Pure water is used when coating dilutes;Mixer is added in after pure water is weighed first, the shell powder paint addition after weighing is matched It is mixed in charging basket with pure water, wherein, the weight ratio of pure water and shell powder paint is 5:1, it stirs 10 minutes clockwise manually Afterwards, it static 10 minutes, stays in after the shell powder paint in mixer fully dissolves water, according to the needs of wall color effect, adds Enter food coloring to mix colours, be further continued for stirring 10 minutes so that oyster shell whiting in mixer and pure water, food coloring it is mixed It closes object to be more uniformly distributed, direct first pass spraying or roller coating on metope, metope carries out the time drying of half a day after the completion of application, does Metope after dry carries out second time spraying or application can be completed in roller coating;Coating it is diluted during requirement in strict accordance with water with The proportion of shell powder paint is diluted, in order to avoid causing aberration, the coating after dilution requires to be finished in one hour, Yi Mianzao It is precipitated into shell powder paint, paint film is uneven;Requirement uniformly sprays or roller coating in coating process, in order to avoid cause film thickness not One, influence overall effect.
VOC < 1g/kg in the Dry powder type shell powder coating;
Benzene+toluene+ethylbenzene+dimethylbenzene < 50mg/kg in the Dry powder type shell powder coating;
Formaldehyde < 5mg/kg in the Dry powder type shell powder coating;
Soluble heavy metal in the Dry powder type shell powder coating(Lead, chromium < 2.5;Cadmium < 0.5;Mercury < 0.1)mg/kg;
A kind of preparation method of Dry powder type shell powder coating, the specific steps are:
1)It is prepared by oyster shell whiting:
A, shell is cleaned with clear water, it is spare after the residues such as shellfish meat to remove on shell;
B, the shell after cleaning is put into acid solution and impregnated, it is spare after desalination ungrease treatment to carry out, it is acid molten The pH value of liquid is 3, and soaking time is 120 minutes;
C, the shell after immersion is put into high-temperature calcination stove and calcined, calcination temperature is 1500 degrees Celsius, and calcination time is 60 points Clock;
D, the shell after calcining, which is transported to after cooling equipment cooling in grinder, to be ground, and the shell after grinding is in powder Last shape is to get for use to oyster shell whiting;
2)It is prepared by plant adhesive:The binding material with sedimentation and flocculating function is extracted in cotton core and paper pulp using extraction method It is spare as plant adhesive;
3)Mixture is mixed:By spare oyster shell whiting, plant adhesive, environment friendly inorganic pigment and kaolin, nano-silica SiClx, gold redrock nano-titanium dioxide, magnesia and a certain proportion of pure water input blender are sufficiently stirred to obtain mixture, Mixing time is 25 minutes;
4)Drying:Obtained mixture is put into dryer and is dried, obtains dry matter mixture, the temperature of drying is taken the photograph for 1400 Family name's degree, the time of drying is 30 minutes;
5)It crushes:Mixture dry powder is obtained after being crushed in dry matter mixture input pulverizer after drying;
6)Sieving:Standard compliant shell powder paint is obtained after obtained mixture dry powder is screened via 1200 mesh to do Powder;
7)Packaging;Described is packaged as shell powder paint dry powder by packaging production line quantitative package, as finished product dry-type shellfish Shell powder coating.

Claims (7)

1. a kind of Dry powder type shell powder coating, including oyster shell whiting, plant adhesive, inorganic pigment, kaolin, nanometer titanium dioxide Silicon, gold redrock nano-titanium dioxide and magnesia, it is characterized in that:The weight ratio of the shell powder paint for oyster shell whiting 80%, Plant adhesive 5%, environment friendly inorganic pigment 2%;Kaolin 5%, nano silicon dioxide 3%, gold redrock nano-titanium dioxide 2%, oxidation Magnesium 3%.
2. a kind of Dry powder type shell powder coating according to claim 1, it is characterized in that:The Dry powder type shell powder coating Application method be:Because therefore, pure water is used when which dilutes containing various impurity in tap water;First Mixer is added in after pure water is weighed, the shell powder paint after weighing is added in mixer and is mixed with pure water, wherein, it is pure The weight ratio of water purification and shell powder paint is 5:1, stirring after ten minutes, static 10 minutes, is stayed in mixer clockwise manually Shell powder paint fully dissolve water after, according to the needs of wall color effect, add in food coloring and mix colours, be further continued for stirring It mixes 10 minutes so that the mixture of oyster shell whiting and pure water, food coloring in mixer is more uniformly distributed, direct on metope A time spraying or roller coating, metope carries out the time drying of half a day after the completion of application, dried metope carry out second time spraying or Application can be completed in roller coating;Requirement carries out dilute in strict accordance with the proportion of water and shell powder paint during coating is diluted It releases, in order to avoid causing aberration, the coating after dilution requires to be finished in one hour, in order to avoid shell powder paint is caused to precipitate, paint film is not Uniformly;Requirement uniformly sprays or roller coating in coating process, in order to avoid film thickness is caused to differ, influences overall effect.
3. a kind of Dry powder type shell powder coating according to claim 1, it is characterized in that:The Dry powder type shell powder coating Middle VOC < 1g/kg.
4. a kind of Dry powder type shell powder coating according to claim 1, it is characterized in that:The Dry powder type shell powder coating Middle benzene+toluene+ethylbenzene+dimethylbenzene < 50mg/kg.
5. a kind of Dry powder type shell powder coating according to claim 1, it is characterized in that:The Dry powder type shell powder coating Middle formaldehyde < 5mg/kg.
6. a kind of Dry powder type shell powder coating according to claim 1, it is characterized in that:The Dry powder type shell powder coating Middle soluble heavy metal(Lead, chromium < 2.5;Cadmium < 0.5;Mercury < 0.1)mg/kg.
7. a kind of preparation method of Dry powder type shell powder coating, the specific steps are:
1)It is prepared by oyster shell whiting:
A, shell is cleaned with clear water, it is spare after the residues such as shellfish meat to remove on shell;
B, the shell after cleaning is put into acid solution and impregnated, it is spare after desalination ungrease treatment to carry out, it is acid molten The pH value of liquid is 3, and soaking time is 120 minutes;
C, the shell after immersion is put into high-temperature calcination stove and calcined, calcination temperature is 1500 degrees Celsius, and calcination time is 60 points Clock;
D, the shell after calcining, which is transported to after cooling equipment cooling in grinder, to be ground, and the shell after grinding is in powder Last shape is to get for use to oyster shell whiting;
2)It is prepared by plant adhesive:The binding material with sedimentation and flocculating function is extracted in cotton core and paper pulp using extraction method It is spare as plant adhesive;
3)Mixture is mixed:By spare oyster shell whiting, plant adhesive, environment friendly inorganic pigment and kaolin, nano-silica SiClx, gold redrock nano-titanium dioxide, magnesia and a certain proportion of pure water input blender are sufficiently stirred to obtain mixture, Mixing time is 25 minutes;
4)Drying:Obtained mixture is put into dryer and is dried, obtains dry matter mixture, the temperature of drying is taken the photograph for 1400 Family name's degree, the time of drying is 30 minutes;
5)It crushes:Mixture dry powder is obtained after being crushed in dry matter mixture input pulverizer after drying;
6)Sieving:Standard compliant shell powder paint is obtained after obtained mixture dry powder is screened via 1200 mesh to do Powder;
7)Packaging;Described is packaged as shell powder paint dry powder by packaging production line quantitative package, as finished product dry-type shellfish Shell powder coating.
CN201810006481.5A 2018-01-04 2018-01-04 A kind of Dry powder type shell powder coating and preparation method thereof Pending CN108264782A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109177337A (en) * 2018-08-28 2019-01-11 扬中市惠丰包装有限公司 A kind of efficient gravure coating technique of corrugated board
CN109266073A (en) * 2018-09-12 2019-01-25 吉林省金贝壳新材料科技有限公司 A kind of dry powder paint based on the modified conch meal in surface
CN109880490A (en) * 2019-03-25 2019-06-14 秦皇岛美博士新型材料科技有限公司 A kind of water soluble negative ion conch meal and its manufacture craft
CN110396310A (en) * 2019-07-30 2019-11-01 河北威曼斯新材料科技有限公司 A kind of release negative ion antibiotic removes the shell powder, preparation method thereof of aldehyde

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109177337A (en) * 2018-08-28 2019-01-11 扬中市惠丰包装有限公司 A kind of efficient gravure coating technique of corrugated board
CN109266073A (en) * 2018-09-12 2019-01-25 吉林省金贝壳新材料科技有限公司 A kind of dry powder paint based on the modified conch meal in surface
CN109880490A (en) * 2019-03-25 2019-06-14 秦皇岛美博士新型材料科技有限公司 A kind of water soluble negative ion conch meal and its manufacture craft
CN110396310A (en) * 2019-07-30 2019-11-01 河北威曼斯新材料科技有限公司 A kind of release negative ion antibiotic removes the shell powder, preparation method thereof of aldehyde

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Application publication date: 20180710