CN103627261A - Dry powder type shell powder interior wall coating material and preparation method thereof - Google Patents
Dry powder type shell powder interior wall coating material and preparation method thereof Download PDFInfo
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- CN103627261A CN103627261A CN201310653982.XA CN201310653982A CN103627261A CN 103627261 A CN103627261 A CN 103627261A CN 201310653982 A CN201310653982 A CN 201310653982A CN 103627261 A CN103627261 A CN 103627261A
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- 239000000843 powder Substances 0.000 title claims abstract description 89
- 239000000463 material Substances 0.000 title claims abstract description 42
- 238000000576 coating method Methods 0.000 title claims abstract description 41
- 239000011248 coating agent Substances 0.000 title claims abstract description 40
- 238000002360 preparation method Methods 0.000 title claims description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000002245 particle Substances 0.000 claims abstract description 11
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 10
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 10
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 10
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 241000276489 Merlangius merlangus Species 0.000 claims description 49
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 42
- 229910052613 tourmaline Inorganic materials 0.000 claims description 26
- 229940070527 tourmaline Drugs 0.000 claims description 26
- 239000011032 tourmaline Substances 0.000 claims description 26
- 229920000642 polymer Polymers 0.000 claims description 18
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 17
- 230000005855 radiation Effects 0.000 claims description 11
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 9
- 229920006243 acrylic copolymer Polymers 0.000 claims description 9
- 239000001913 cellulose Substances 0.000 claims description 9
- 229920002678 cellulose Polymers 0.000 claims description 9
- HDERJYVLTPVNRI-UHFFFAOYSA-N ethene;ethenyl acetate Chemical compound C=C.CC(=O)OC=C HDERJYVLTPVNRI-UHFFFAOYSA-N 0.000 claims description 9
- 229920001038 ethylene copolymer Polymers 0.000 claims description 9
- 150000002762 monocarboxylic acid derivatives Chemical group 0.000 claims description 9
- 239000000049 pigment Substances 0.000 claims description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- 238000010276 construction Methods 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 230000000694 effects Effects 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 239000008399 tap water Substances 0.000 claims description 4
- 235000020679 tap water Nutrition 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 239000000945 filler Substances 0.000 claims description 3
- 238000003837 high-temperature calcination Methods 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 238000004381 surface treatment Methods 0.000 claims description 2
- 230000001954 sterilising effect Effects 0.000 abstract description 7
- 239000004408 titanium dioxide Substances 0.000 abstract description 6
- 241000894006 Bacteria Species 0.000 abstract description 4
- 239000011256 inorganic filler Substances 0.000 abstract description 4
- 229910003475 inorganic filler Inorganic materials 0.000 abstract description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052791 calcium Inorganic materials 0.000 abstract description 3
- 239000011575 calcium Substances 0.000 abstract description 3
- 238000005265 energy consumption Methods 0.000 abstract description 2
- 239000004575 stone Substances 0.000 abstract 2
- GUTLYIVDDKVIGB-OUBTZVSYSA-N Cobalt-60 Chemical compound [60Co] GUTLYIVDDKVIGB-OUBTZVSYSA-N 0.000 abstract 1
- 230000007547 defect Effects 0.000 abstract 1
- 230000005611 electricity Effects 0.000 abstract 1
- 230000005251 gamma ray Effects 0.000 abstract 1
- 230000000452 restraining effect Effects 0.000 abstract 1
- 230000003068 static effect Effects 0.000 abstract 1
- 239000003973 paint Substances 0.000 description 13
- 230000000844 anti-bacterial effect Effects 0.000 description 7
- HGWOWDFNMKCVLG-UHFFFAOYSA-N [O--].[O--].[Ti+4].[Ti+4] Chemical compound [O--].[O--].[Ti+4].[Ti+4] HGWOWDFNMKCVLG-UHFFFAOYSA-N 0.000 description 6
- 239000000839 emulsion Substances 0.000 description 6
- 239000000796 flavoring agent Substances 0.000 description 6
- 235000019634 flavors Nutrition 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 238000004659 sterilization and disinfection Methods 0.000 description 5
- 238000000354 decomposition reaction Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- -1 TVOC Chemical compound 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 230000002070 germicidal effect Effects 0.000 description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 2
- 239000011858 nanopowder Substances 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 238000007790 scraping Methods 0.000 description 2
- 230000035943 smell Effects 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 231100000167 toxic agent Toxicity 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 241000607142 Salmonella Species 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
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- 239000000853 adhesive Substances 0.000 description 1
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- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- JYYOBHFYCIDXHH-UHFFFAOYSA-N carbonic acid;hydrate Chemical compound O.OC(O)=O JYYOBHFYCIDXHH-UHFFFAOYSA-N 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 239000003653 coastal water Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000009313 farming Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 230000000968 intestinal effect Effects 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 230000001902 propagating effect Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
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- 231100000331 toxic Toxicity 0.000 description 1
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention relates to a dry powder type shell powder interior wall coating material which has the functions of adsorbing and decomposing harmful gas and peculiar smell, restraining bacteria, sterilizing and resisting static electricity and using shell powder, nanometer inorganic filler and high molecular powder materials as main components. The invention solves the defects of high cost, high energy consumption, pollution and incapability of purifying indoor harmful gas in the existing interior wall coating materials. The coating material uses natural or manually cultivated shell powder as basic materials; meanwhile, a certain quantity of nanometer titanium dioxide and nanometer electric stone powder radiated by cobalt-60 gamma ray and the high molecular powder materials are added; the weight percentages of all components are as follows: 30-60% of shell powder, 10-20% of calcined kaolin, 10-20% of heavy calcium, 10-20% of talcum powder, 1-5% of nanometer titanium dioxide, 1-5% of nanometer electric stone powder, and 5-20% of high molecular powder materials; the particle size of the shell powder is 200-1250 meshes.
Description
Technical field
The present invention relates to a kind of novel dry powder type interior wall coating that oyster shell whiting and nanometer inorganic filler and polymer powder material be main component of take with adsorption-decomposition function obnoxious flavour and peculiar smell, antibacterial, sterilization, anti-static function.The invention solves the shortcoming that current interior wall coating cost is high, energy consumption large, indoor harmful gas is polluted and can not purify in existence own.Prepared have have adsorption-decomposition function obnoxious flavour and peculiar smell, the coating of antibacterial, sterilizing function.
Background technology
The dope for inner wall of architecture using on market is mainly emulsion paint.Emulsion paint ubiquity the shortcomings such as paint film is soft, time of drying is long, package stability is poor, emulsion paint class coating after making moist, easy breed bacteria, produce come off, the phenomenon such as variable color, have a strong impact on work-ing life and indoor attractive in appearance.The a large amount of oil of emulsion paint class coating consumption simultaneously, due to China's oil resource shortage, needs a large amount of imports, and material cost improves year by year.Chinese society expanding economy has increased the demand of coating, and has improved the requirement of people for coating use properties.In interior decoration process, in the finishing materials such as a large amount of paint using, milky white adhesive, composition board, foam-filled thing, contain a large amount of volatility toxic compounds, these toxic compounds are the toxic and harmful serious harm mankind's of volatilization health and living environment slowly.Environmental protection and functionalization are the future thrusts of interior architecture coating, and introduce nanometer system and use natural materials also just to become the development trend that paint field is new.
Oyster shell whiting is to make by propagating artificially with natural shell by high-temperature calcination, after pulverizing.Its moiety is the calcified materials such as calcium carbonate, calcium oxide, calcium hydroxide, and this has absorption, the effect of decomposing (formaldehyde, benzene, TVOC, ammonia) and adjusting air humidity, elimination odor function as vesicular.The compound of calcium is used for deodovization agent in life, therefore the smell that oyster shell whiting can distribute indoor smoke, infant, patient, pet, mould and indoor assorted taste all have effectively dispels effect, especially cigarette is had to adsorption at indoor distributed carbon monoxide and the Dust Capacity that swims.Its composition of oyster shell whiting 100% is calcium, therefore has good antistatic performance.The oyster shell whiting of simultaneously firing and titanium dioxide and tourmalinite nano-powder have extremely strong antibacterial and germicidal action to comprising the various bacteria of intestinal bacteria, Salmonellas, yellow glucose fungus etc., and have function anticorrosion, mildew-resistant.Take oyster shell whiting as base material, then be equipped with interior wall coating that a certain amount of titanium dioxide by cobalt-60γray radiation treatment and tourmalinite nano-powder and polymer powder material makes and will there is good absorption obnoxious flavour and antibacterial, sterilization, anti-static function.Metope use have after shell powder paint film plentiful, texture is natural, firm soft and smooth, fashion is graceful.Pollution resistance is good.Its construction versatility is good, is as good as with emulsion paint, applicable to scraping, rolls, and brush, sprays various constructional methods.High comprehensive performance.
Shell powder paint " be the typical industry product of recycling economy, " resource-product-waste-renewable resources " closed loop economic process, in production and consumption process, realizes minimizing, the resource utilization and innoxious of waste.Shell is a kind of edible resource, and it,, after cannery's processing, becomes a kind of edible product.Empty shell has but become a kind of waste, is dropped and is polluting on the beach environment.The contribution of " shell powder paint " is just this waste renewable resources.The main raw material of " shell powder paint " is that shell is the byproduct that modern farming causes, and there are very long shoreline and vast marine site in China, and the Shells in the seabed, coastal waters of 1 years is almost vast equally with marine site.Because it does not use petroleum product additive, so it is nontoxic pollution-free product.Product cost is 1/10-1/20 of similar quality emulsion paint, be a kind of advanced person, with eco-friendly production key technology, it meets novel process and the new technology of recycling economy fundamental principle completely.It is the Green Revolution of coatings industry, has fabulous prospect.
Summary of the invention
The object of the invention is to provide a kind of novel dry powder type interior wall coating that oyster shell whiting and surface treated nanometer inorganic filler and polymer powder material be main component of take with adsorption-decomposition function obnoxious flavour and peculiar smell, antibacterial, sterilization, anti-static function.By the mode by cobalt-60γray radiation treatment, nano level titanium dioxide and nano level tourmaline powder being carried out to finishing can load in oyster shell whiting surface and hole, add a certain amount of macromolecular material simultaneously, form a kind of have several functions, low, the easy construction of cost, application dry powder type interior wall coating attractive in appearance.
First above-mentioned purpose of the present invention is achieved in that needs nano titanium oxide and nano-tourmaline powder to carry out finishing processing.By nano titanium oxide and nano-tourmaline powder cobalt-60γray radiation treatment, irradiation dose 20Mrad.
A kind of dry powder type interior wall coating, it is basic material that described coating be take oyster shell whiting natural or that propagate artificially, add a certain amount of nano titanium oxide and nano-tourmaline powder and polymer powder material by cobalt-60γray radiation treatment, the weight percent proportioning of its various components is simultaneously:
The polymer powder material of the oyster shell whiting of 30%-60%, the calcined kaolin of 10%-20%, the coarse whiting of 10%-20%, the talcum powder of 10%-20%, 1-5% nano titanium oxide, 1-5% nano-tourmaline powder, 5%-20%;
The particle diameter of described oyster shell whiting is 200 order-1250 orders.
Described polymer powder material serves as film forming and solidifying agent effect, its multipolymer by ethene-vinyl acetate, vinyl acetate between to for plastic-tertiary monocarboxylic acid ethylene copolymer, acrylic copolymer and natural cellulose form, and the weight percent proportioning of its various components is: the multipolymer of ethene-vinyl acetate is 20%-50%, vinyl acetate between to for plastic-tertiary monocarboxylic acid ethylene copolymer 10%-20%, acrylic copolymer 10%-40%, natural cellulose 5%-20%.
Described nano titanium oxide and tourmaline powder add in oyster shell whiting after surface treatment through carrying out with cobalt-60γray irradiation, irradiation dose 20Mrad.
Described oyster shell whiting is pulverized preparation through high-temperature calcination, and the particle diameter of oyster shell whiting is 200 order-1250 orders.
A kind of preparation method of any one dry powder type interior wall coating as previously discussed, the first step: first need nano titanium oxide and nano-tourmaline powder to carry out finishing processing, by nano titanium oxide and nano-tourmaline powder cobalt-60γray radiation treatment, irradiation dose: 20Mrad. irradiation temperature: 25 ℃; Under nitrogen protection;
Second step: prepare macromolecular material powder
The multipolymer of 20%-50% ethene-vinyl acetate is mixed for, 10%-20% vinyl acetate between to for plastic-tertiary monocarboxylic acid ethylene copolymer, 10%-40% acrylic copolymer and 5%-20% natural cellulose;
The 3rd step: site operation
During construction, the macromolecular material powder that the powder that the first step is made and second step are made and pigment and oyster shell whiting and other fillers fully mix by the weight percent of various components, then the above-mentioned dry powder type coating configuring is added to ordinary tap water by weight 1:2, after standing 4 hours, after within uniform stirring 20-30 minute, mixing, can use.
Innovation of the present invention is:
1, in coating system of the present invention, take oyster shell whiting natural or that propagate artificially is main raw, nano titanium oxide and nano-tourmaline powder and environmental protection macromolecule powder material through cobalt-60γray radiation treatment have been added, do not add any poisonous and harmful substances, there is production cost, low beautiful decoration, the simple feature of constructing simultaneously.
2, with after cobalt-60γray radiation treatment. nano level titanium dioxide and nano level tourmaline powder have higher activity, the negative oxygen ion that discharges that can be permanent purifies and germicidal treatment room air.
3, the macromolecular material powder using has environmental protection, water-soluble, cohesive strength is high.
Embodiment
That the dry powder type that the oyster shell whiting that the invention discloses the calcining of a kind of shell by natural or shell biology that propagate artificially and make and nanometer inorganic filler and polymer powder material are main component has is antibacterial, the interior wall coating of sterilization and adsorption-decomposition function obnoxious flavour and odor function and preparation method thereof.This coating by adding nano-tourmaline powder and the nano titanium oxide by cobalt-60γray radiation treatment, obtained the function with very effective antibacterial, sterilization in oyster shell whiting.By the obnoxious flavour in oyster shell whiting adsorption chamber, as formaldehyde, dimethylbenzene etc., and effectively resolved into carbonic acid gas and water under nano-tourmaline powder and nano titanium oxide catalysis.The composition of this dry powder type coating is: the polymer powdery material of the oyster shell whiting of 30%-60%, the calcined kaolin of 10%-20%, the coarse whiting of 10%-20%, the talcum powder of 10%-20%, 5%-20%, 1-5% nano titanium dioxide, 1-5% nano-tourmaline powder.Polymer powder material is the multipolymer by ethene-vinyl acetate, vinyl acetate between to for plastic-tertiary monocarboxylic acid ethylene copolymer, and acrylic copolymer, natural cellulose forms.Wherein, the multipolymer of ethene-vinyl acetate is: 20%-50%, vinyl acetate between to for plastic-tertiary monocarboxylic acid ethylene copolymer 10%-20%, acrylic copolymer 10%-40%, natural cellulose 5%-20%.
Component on site construction method: the above-mentioned dry powder type coating configuring is added to ordinary tap water by weight 1:1.5～2, after standing 4 hours, can use after mixing for uniform stirring 20-30 minute.Applicable to scraping, roll, brush, sprays various constructional methods.
The preparation method of dry powder type interior wall coating of the present invention:
The first step: first need nano titanium oxide and nano-tourmaline powder to carry out finishing processing.By nano titanium oxide and nano-tourmaline powder cobalt-60γray radiation treatment, irradiation dose: 20Mrad. irradiation temperature: 25 ℃; Under nitrogen protection.
Second step: prepare macromolecular material powder
The multipolymer of 20%-50% ethene-vinyl acetate is mixed for, 10%-20% vinyl acetate between to for plastic-tertiary monocarboxylic acid ethylene copolymer, 10%-40% acrylic copolymer, 5%-20% natural cellulose.
The 3rd step: site operation
During construction, the macromolecular material powder that the powder that the first step is made and second step are made and pigment and oyster shell whiting and other fillers fully mix by the weight percent of various components, then the above-mentioned dry powder type coating configuring is added to ordinary tap water by weight 1:2, after standing 4 hours, after within uniform stirring 20-30 minute, mixing, can use.
Embodiment mono-: in coating system, weight percent is as follows:
Oyster shell whiting (particle diameter 200 orders): 60%, calcined kaolin: 10%, coarse whiting: 10%, talcum powder: 5%, polymer powder material: 10%, nanometer titanium dioxide titanium valve: 2%, nano-tourmaline powder: 2%, pigment: 1%,
Embodiment bis-: in coating system, weight percent is as follows:
Oyster shell whiting (particle diameter 400 orders): 50%, calcined kaolin: 10%, coarse whiting: 15%, talcum powder: 5%, polymer powder material: 15%, nanometer titanium dioxide titanium valve: 2%, nano-tourmaline powder: 2%, pigment: 1%,
Embodiment tri-: in coating system, weight percent is as follows:
Oyster shell whiting (particle diameter 1250 orders): 30%, calcined kaolin: 15%, coarse whiting: 15%, talcum powder: 20%, polymer powder material: 15%, nanometer titanium dioxide titanium valve: 2%, nano-tourmaline powder: 2%, pigment: 1%,
Embodiment tetra-: in coating system, weight percent is as follows:
Oyster shell whiting (particle diameter 400 orders): 40%, calcined kaolin: 10%, coarse whiting: 10%, talcum powder: 20%, polymer powder material: 15%, nanometer titanium dioxide titanium valve: 2%, nano-tourmaline powder: 2%, pigment: 1%,
Embodiment five: in coating system, weight percent is as follows:
Oyster shell whiting (particle diameter 400 orders): 40%,
Calcined kaolin: 10%, coarse whiting: 20%, talcum powder: 10%, polymer powder material: 13%, nanometer titanium dioxide titanium valve: 5%, nano-tourmaline powder: 1%, pigment: 1%,
Embodiment six: in coating system, weight percent is as follows:
Oyster shell whiting (particle diameter 800 orders): 40%, calcined kaolin: 10%, coarse whiting: 20%, talcum powder: 10%, polymer powder material: 15%, nanometer titanium dioxide titanium valve: 1%, nano-tourmaline powder: 3%, pigment: 1%.
Claims (5)
1. a dry powder type oyster shell whiting interior wall coating, is characterized in that:
It is basic material that described coating be take oyster shell whiting natural or that propagate artificially, adds a certain amount of nano titanium oxide and nano-tourmaline powder and polymer powder material by cobalt-60γray radiation treatment simultaneously, and the weight percent proportioning of its various components is:
The polymer powder material of the oyster shell whiting of 30%-60%, the calcined kaolin of 10%-20%, the coarse whiting of 10%-20%, the talcum powder of 10%-20%, 1-5% nano titanium oxide, 1-5% nano-tourmaline powder, 5%-20%;
The particle diameter of described oyster shell whiting is 200 order-1250 orders.
2. a kind of dry powder type oyster shell whiting interior wall coating as claimed in claim 1, is characterized in that:
Described polymer powder material serves as film forming and solidifying agent effect, its multipolymer by ethene-vinyl acetate, vinyl acetate between to for plastic-tertiary monocarboxylic acid ethylene copolymer, acrylic copolymer and natural cellulose form, and the weight percent proportioning of its various components is: the multipolymer of ethene-vinyl acetate is 20%-50%, vinyl acetate between to for plastic-tertiary monocarboxylic acid ethylene copolymer 10%-20%, acrylic copolymer 10%-40%, natural cellulose 5%-20%.
3. a kind of dry powder type oyster shell whiting interior wall coating as claimed in claim 1 or 2, is characterized in that:
Described nano titanium oxide and tourmaline powder add in oyster shell whiting after surface treatment through carrying out with cobalt-60γray irradiation, irradiation dose 20Mrad.
4. a kind of dry powder type oyster shell whiting interior wall coating as claimed in claim 1 or 2, is characterized in that:
Described oyster shell whiting is pulverized preparation through high-temperature calcination, and the particle diameter of oyster shell whiting is 200 order-1250 orders.
5. a preparation method for any one dry powder type oyster shell whiting interior wall coating as described in claim 1 to 4, its special card is:
The first step: first need nano titanium oxide and nano-tourmaline powder to carry out finishing processing, by nano titanium oxide and nano-tourmaline powder cobalt-60γray radiation treatment, irradiation dose: 20Mrad. irradiation temperature: 25 ℃; Under nitrogen protection;
Second step: prepare macromolecular material powder
The multipolymer of 20%-50% ethene-vinyl acetate is mixed for, 10%-20% vinyl acetate between to for plastic-tertiary monocarboxylic acid ethylene copolymer, 10%-40% acrylic copolymer and 5%-20% natural cellulose;
The 3rd step: site operation
During construction, the macromolecular material powder that the powder that the first step is made and second step are made and pigment and oyster shell whiting and other fillers fully mix by the weight percent of various components, then the above-mentioned dry powder type coating configuring is added to ordinary tap water by weight 1:2, after standing 4 hours, after within uniform stirring 20-30 minute, mixing, can use.
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| CN201310653982.XA CN103627261B (en) | 2013-12-06 | 2013-12-06 | Dry powder type shell powder interior wall coating and preparation method thereof |
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| CN201310653982.XA CN103627261B (en) | 2013-12-06 | 2013-12-06 | Dry powder type shell powder interior wall coating and preparation method thereof |
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| CN103627261A true CN103627261A (en) | 2014-03-12 |
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Cited By (39)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104031437A (en) * | 2014-04-23 | 2014-09-10 | 佛山早稻田信息咨询有限公司 | All-weather air purification paint and preparation method thereof |
| CN104371401A (en) * | 2014-11-14 | 2015-02-25 | 昆山上艺电子有限公司 | Metallic non-metal ink |
| CN104387885A (en) * | 2014-11-11 | 2015-03-04 | 合肥不老传奇保健科技有限公司 | Natural-fiber-added anti-aging high-weather-resistance outer wall paint and preparation method thereof |
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| CN104031437A (en) * | 2014-04-23 | 2014-09-10 | 佛山早稻田信息咨询有限公司 | All-weather air purification paint and preparation method thereof |
| CN105314950A (en) * | 2014-07-10 | 2016-02-10 | 马锡奎 | Novel 3D particle paint |
| CN104387885A (en) * | 2014-11-11 | 2015-03-04 | 合肥不老传奇保健科技有限公司 | Natural-fiber-added anti-aging high-weather-resistance outer wall paint and preparation method thereof |
| CN104371401A (en) * | 2014-11-14 | 2015-02-25 | 昆山上艺电子有限公司 | Metallic non-metal ink |
| CN105062331A (en) * | 2015-08-06 | 2015-11-18 | 天长市巨龙车船涂料有限公司 | Absorption odor-less emulsion paint added with lime and crab shell powder and preparation method thereof |
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| CN105669083A (en) * | 2015-12-17 | 2016-06-15 | 张龙飞 | Indoor air purifying material and preparation method thereof |
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| CN107298878A (en) * | 2016-04-14 | 2017-10-27 | 庄少玉 | Environmental health nanometer dry powder paint |
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| CN106084891A (en) * | 2016-06-06 | 2016-11-09 | 广东贝尤安新材料科技有限公司 | A kind of modified conch meal calcine technology |
| CN106084891B (en) * | 2016-06-06 | 2018-04-03 | 广东贝尤安新材料科技有限公司 | A kind of modified oyster shell whiting calcine technology |
| CN106221313A (en) * | 2016-08-20 | 2016-12-14 | 谢裕梦 | A kind of shell powder paint and preparation method thereof |
| CN106630747A (en) * | 2016-10-18 | 2017-05-10 | 佟朝富 | Ecological shell powder embossment coating and interior wall embossment construction method |
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| CN107382227A (en) * | 2017-08-16 | 2017-11-24 | 河北卓达建材研究院有限公司 | A kind of vermiculite board for inducing anion and preparation method thereof |
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| CN107352927A (en) * | 2017-08-16 | 2017-11-17 | 河北卓达建材研究院有限公司 | A kind of perlite calcium silicate board for inducing anion and preparation method thereof |
| CN107382250A (en) * | 2017-08-16 | 2017-11-24 | 河北卓达建材研究院有限公司 | A kind of plasterboard for inducing anion and preparation method thereof |
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| CN107435427A (en) * | 2017-08-16 | 2017-12-05 | 河北卓达建材研究院有限公司 | A kind of anion imitated wood floor board and preparation method thereof |
| CN107456596A (en) * | 2017-08-16 | 2017-12-12 | 河北卓达建材研究院有限公司 | A kind of negative oxygen ion porous material |
| CN107456597A (en) * | 2017-08-16 | 2017-12-12 | 河北卓达建材研究院有限公司 | A kind of negative oxygen ion cavernous body |
| CN107365540A (en) * | 2017-08-16 | 2017-11-21 | 河北卓达建材研究院有限公司 | A kind of anion alkali-resisting primer and preparation method thereof |
| CN107556051A (en) * | 2017-08-16 | 2018-01-09 | 河北卓达建材研究院有限公司 | A kind of vermiculite calcium silicates composite plate for inducing anion and preparation method thereof |
| CN107555893A (en) * | 2017-08-16 | 2018-01-09 | 河北卓达建材研究院有限公司 | A kind of anion mortar of construction wall and preparation method thereof |
| CN107555916A (en) * | 2017-08-16 | 2018-01-09 | 河北卓达建材研究院有限公司 | A kind of calcium silicate board for inducing anion |
| CN107418264A (en) * | 2017-08-22 | 2017-12-01 | 杭州纳巍负离子科技有限公司 | Fullerene negative ion dry powder paint and application method |
| CN108300039A (en) * | 2017-09-18 | 2018-07-20 | 白山市和硅藻科技有限公司 | A kind of thermal insulation coatings of containing diatomite and preparation method thereof |
| CN107572875A (en) * | 2017-10-16 | 2018-01-12 | 江苏贝壳居新材料科技有限公司 | The preparation method of environment-friendly type shell powder paint |
| CN108264782A (en) * | 2018-01-04 | 2018-07-10 | 黑龙江贝丝鳗环保科技有限公司 | A kind of Dry powder type shell powder coating and preparation method thereof |
| CN111171723A (en) * | 2018-11-09 | 2020-05-19 | 万喜人家(北京)健康科技有限公司 | Preparation method and preparation equipment of shell powder dry powder type coating with mesh-hole polymer as film forming material |
| CN109535784A (en) * | 2018-11-27 | 2019-03-29 | 吉林日禾科技开发有限公司 | A kind of liquid shell powder interior wall paint and preparation method thereof |
| CN109705637A (en) * | 2018-12-25 | 2019-05-03 | 吉林日禾科技开发有限公司 | A kind of C60 anion shell powder interior wall paint and preparation method thereof |
| CN109705639A (en) * | 2019-01-11 | 2019-05-03 | 燕山大学 | A kind of shell powder paint and preparation method thereof |
| CN111375249A (en) * | 2020-04-22 | 2020-07-07 | 陈宁 | Air purification device applied to shell processing |
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