CN109705637A - A kind of C60 anion shell powder interior wall paint and preparation method thereof - Google Patents
A kind of C60 anion shell powder interior wall paint and preparation method thereof Download PDFInfo
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- CN109705637A CN109705637A CN201811586348.8A CN201811586348A CN109705637A CN 109705637 A CN109705637 A CN 109705637A CN 201811586348 A CN201811586348 A CN 201811586348A CN 109705637 A CN109705637 A CN 109705637A
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Abstract
A kind of C60 anion shell powder interior wall paint, the coating is using natural or artificial breeding conch meal as basic material, the nano-titanium dioxide and nano-tourmaline powder and macromolecule pulverulent material with cobalt-60γray radiation treatment are added simultaneously, its component for including is calculated by weight as: 60-90 parts of water of 3-6 parts of chlorination C60 negative ion powder, 30-60 parts of conch meal, 20 parts of coarse whiting, 10 parts of kaolin, 8 parts of benzalkonium chloride, 1-5 parts of nano-titanium dioxide, 1-5 parts of nano-tourmaline powder, 5-20 parts of macromolecule pulverulent material, and the partial size of the conch meal is -1500 mesh of 500 mesh.The benzalkonium chloride is medical benzalkonium chloride.It further include 20-80 parts of phytochrome.The present invention solves common building interior wall coating existing in the prior art containing noxious material, and mildew and Dry powder type shell powder coating, the problem that Specific construction is difficult, error is big easily occur for interior wall coating.
Description
Technical field
The present invention relates to coating for wall surface fields, more particularly to a kind of C60 anion shell powder interior wall paint and its preparation
Method.
Background technique
The dope for inner wall of architecture used in the market is mainly emulsion paint.Emulsion paint is soft in the prevalence of paint film, drying time
Long, the disadvantages of storage stability is poor, emulsion paint class coating after being moistened, phenomena such as bacterium easy to breed, generation falls off, changes colour,
Seriously affect service life and indoor beauty.Emulsion paint class coating consumes bulk petroleum simultaneously, since China's oil resource lacks
It is weary, a large amount of imports are needed, the cost of raw material improves year by year.Chinese society expanding economy increases the demand of coating, and mentions
High requirements of the people for coating service performance.Indoors in fitment process, it is a large amount of using paint, milky white adhesive, composite plate,
Contain a large amount of volatility toxic compounds in the finishing materials such as foam insert, what these toxic compounds slowly volatilized has
Malicious pernicious gas seriously endangers human health and living environment.Environmental protection and functionalization are the future development of indoor architectural paints
Direction, and introduce nanometer system and also just become the new development trend of paint field using natural material.
C60 negative ion powder has stronger biocidal property, and C60 negative ion powder is almost insoluble in water, negative in order to play C60
Ion powder bioactivity first has to increase its solubility in water.The soluble derivative of C60 anion has very strong
Biocidal property.
Dry powder type shell powder coating at present on the market is relatively environmentally friendly, but still there are certain drawbacks.Dry-type shellfish
There is inconvenience in shell powder coating, because Dry powder type shell powder coating adds water and stirs sieving etc. in scene in construction, apply on Specific construction
Worker person is difficult to hold, and error is big.Therefore a kind of novel shell powder interior wall paint is needed to solve problem above.
Summary of the invention
The purpose of the present invention is to provide a kind of C60 anion shell powder interior wall paint and preparation method thereof, solve existing
There is common building interior wall coating present in technology containing noxious material, it is prone to mildew and Dry powder type shell powder coating tool
The problem that body construction is difficult, error is big.
To achieve the above object, the present invention is achieved through the following technical solutions:
A kind of C60 anion shell powder interior wall paint, the coating is with natural or artificial breeding conch meal for basic material
Material, while nano-titanium dioxide and nano-tourmaline powder and macromolecule powdery material with cobalt-60γray radiation treatment is added
Material comprising component be calculated by weight as:
Preferably, the coating is using natural or artificial breeding conch meal as basic material, while being added with cobalt -60
The nano-titanium dioxide and nano-tourmaline powder and macromolecule pulverulent material of gamma-ray irradiation processing comprising component press
Parts by weight are calculated as:
Preferably, the coating is using natural or artificial breeding conch meal as basic material, while being added with cobalt -60
The nano-titanium dioxide and nano-tourmaline powder and macromolecule pulverulent material of gamma-ray irradiation processing comprising component press
Parts by weight are calculated as:
It preferably, further include 20-80 parts of phytochrome.
A kind of preparation method of C60 anion shell powder interior wall paint, comprising the following steps:
Step 1: needing nano-titanium dioxide and nano-tourmaline powder being surface modified processing first, by nano-silica
Change titanium and nano-tourmaline powder cobalt-60γray radiation treatment, irradiation dose: 20Mrad；Irradiation temperature: 20 DEG C；In nitrogen
Under protection；
Step 2: preparing high molecular material powder
By the copolymer of 20-50 parts of ethene-vinyl acetate, 10-40 parts of acrylic copolymer and 5-20 parts it is natural
Cellulose is uniformly mixed；
Step 3: preparation chlorination C60 negative ion powder
C60 negative ion powder is subjected to chlorination
Step 4: preparing coating
Each component is sufficiently mixed in parts by weight, with blender uniform stirring 25min, revolving speed 1200r/min.
Beneficial effects of the present invention:
1, for the present invention without containing the auxiliary agents such as lotion are added in traditional coating, the raw material of selection is natural, harmless, uses
Nanoscale titanium dioxide and nanoscale tourmaline powder activity with higher after cobalt-60γray radiation treatment, can be with
The permanent negative oxygen ion that releases purifies room air, and since conch meal 100% is calcium, coating itself is prevented quiet
Electric effect is good.
2, present invention addition chlorination C60 negative ion powder, plays inhibiting effect to microbial growth capable of releasing negative ion,
Wall is inhibited to go mouldy to a certain extent.
3, the present invention can be used directly, be conducive to construct.
4, the present invention replaces preservative excitatory with benzalkonium chloride, extends the coating pot-life.
5, the coating for the different colours that the present invention can make, is applicable in a variety of environment, occasion, can satisfy modern Man's Demands.
Specific embodiment
It in order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below will be in the embodiment of the present invention
Technical solution be clearly and completely described.The person that is not specified actual conditions in embodiment, according to normal conditions or manufacturer
It is recommended that condition carry out.Production firm person is not specified in component used or instrument, is the routine that can be obtained by commercially available purchase
Product.
It is as follows that the invention will be further described below:
Bibliography
[1] Lin Xiuguang .C60The experimental study Chinese medical research magazine of bactericidal effect, 2006 (6) 7.
Embodiment one
A kind of C60 anion shell powder interior wall paint, the coating is with natural or artificial breeding conch meal for basic material
Material, while nano-titanium dioxide and nano-tourmaline powder and macromolecule powdery material with cobalt-60γray radiation treatment is added
Material comprising component be calculated by weight as:
A kind of preparation method of C60 anion shell powder interior wall paint, comprising the following steps:
Step 1: needing nano-titanium dioxide and nano-tourmaline powder being surface modified processing first, by nano-silica
Change titanium and nano-tourmaline powder cobalt-60γray radiation treatment, irradiation dose: 20Mrad；Irradiation temperature: 20 DEG C；In nitrogen
Under protection；
Step 2: preparing high molecular material powder
The copolymer of 20 parts of ethene-vinyl acetate, 10 parts of acrylic copolymer and 5 parts of native cellulose are mixed
It closes uniform；
Step 3: preparation chlorination C60 negative ion powder
C60 negative ion powder is subjected to chlorination[1]
Step 4: preparing coating
Each component is sufficiently mixed in parts by weight, with blender uniform stirring 25 minutes, revolving speed 1200r/min was obtained
To coating one.
Embodiment two
A kind of C60 anion shell powder interior wall paint, the coating is with natural or artificial breeding conch meal for basic material
Material, while nano-titanium dioxide and nano-tourmaline powder and macromolecule powdery material with cobalt-60γray radiation treatment is added
Material comprising component be calculated by weight as:
A kind of preparation method of C60 anion shell powder interior wall paint, comprising the following steps:
Step 1: needing nano-titanium dioxide and nano-tourmaline powder being surface modified processing first, by nano-silica
Change titanium and nano-tourmaline powder cobalt-60γray radiation treatment, irradiation dose: 20Mrad；Irradiation temperature: 20 DEG C；In nitrogen
Under protection；
Step 2: preparing high molecular material powder
The copolymer of 20 parts of ethene-vinyl acetate, 10 parts of acrylic copolymer and 5 parts of native cellulose are mixed
It closes uniform；
Step 3: preparation chlorination C60 negative ion powder
C60 negative ion powder is subjected to chlorination[1]
Step 4: preparing coating
Each component is sufficiently mixed in parts by weight, with blender uniform stirring 25 minutes, revolving speed 1200r/min was obtained
To coating two.
Embodiment three
A kind of C60 anion shell powder interior wall paint, the coating is with natural or artificial breeding conch meal for basic material
Material, while nano-titanium dioxide and nano-tourmaline powder and macromolecule powdery material with cobalt-60γray radiation treatment is added
Material comprising component be calculated by weight as:
A kind of preparation method of C60 anion shell powder interior wall paint, comprising the following steps:
Step 1: needing nano-titanium dioxide and nano-tourmaline powder being surface modified processing first, by nano-silica
Change titanium and nano-tourmaline powder cobalt-60γray radiation treatment, irradiation dose: 20Mrad；Irradiation temperature: 20 DEG C；In nitrogen
Under protection；
Step 2: preparing high molecular material powder
The copolymer of 20 parts of ethene-vinyl acetate, 10 parts of acrylic copolymer and 5 parts of native cellulose are mixed
It closes uniform；
Step 3: preparation chlorination C60 negative ion powder
C60 negative ion powder is subjected to chlorination[1]
Step 4: preparing coating
Each component is sufficiently mixed in parts by weight, with blender uniform stirring 25 minutes, revolving speed 1200r/min was obtained
To coating three.
Example IV
A kind of C60 anion shell powder interior wall paint, the coating is with natural or artificial breeding conch meal for basic material
Material, while nano-titanium dioxide and nano-tourmaline powder and macromolecule powdery material with cobalt-60γray radiation treatment is added
Material comprising component be calculated by weight as:
A kind of preparation method of C60 anion shell powder interior wall paint, comprising the following steps:
Step 1: needing nano-titanium dioxide and nano-tourmaline powder being surface modified processing first, by nano-silica
Change titanium and nano-tourmaline powder cobalt-60γray radiation treatment, irradiation dose: 20Mrad；Irradiation temperature: 20 DEG C；In nitrogen
Under protection；
Step 2: preparing high molecular material powder
The copolymer of 20 parts of ethene-vinyl acetate, 10 parts of acrylic copolymer and 5 parts of native cellulose are mixed
It closes uniform；
Step 3: preparation chlorination C60 negative ion powder
C60 negative ion powder is subjected to chlorination[1]
Step 4: preparing coating
Each component is sufficiently mixed in parts by weight, with blender uniform stirring 25 minutes, revolving speed 1200r/min was obtained
To coating four.
Embodiment five
A kind of C60 anion shell powder interior wall paint, the coating is with natural or artificial breeding conch meal for basic material
Material, while nano-titanium dioxide and nano-tourmaline powder and macromolecule powdery material with cobalt-60γray radiation treatment is added
Material comprising component be calculated by weight as:
A kind of preparation method of C60 anion shell powder interior wall paint, comprising the following steps:
Step 1: needing nano-titanium dioxide and nano-tourmaline powder being surface modified processing first, by nano-silica
Change titanium and nano-tourmaline powder cobalt-60γray radiation treatment, irradiation dose: 20Mrad；Irradiation temperature: 20 DEG C；In nitrogen
Under protection；
Step 2: preparing high molecular material powder
The copolymer of 20 parts of ethene-vinyl acetate, 10 parts of acrylic copolymer and 5 parts of native cellulose are mixed
It closes uniform；
Step 3: preparation chlorination C60 negative ion powder
C60 negative ion powder is subjected to chlorination[1]
Step 4: preparing coating
Each component is sufficiently mixed in parts by weight, with blender uniform stirring 25 minutes, revolving speed 1200r/min was obtained
To colored paint five.
Embodiment six
A kind of C60 anion shell powder interior wall paint, the coating is with natural or artificial breeding conch meal for basic material
Material, while nano-titanium dioxide and nano-tourmaline powder and macromolecule powdery material with cobalt-60γray radiation treatment is added
Material comprising component be calculated by weight as:
A kind of preparation method of C60 anion shell powder interior wall paint, comprising the following steps:
Step 1: needing nano-titanium dioxide and nano-tourmaline powder being surface modified processing first, by nano-silica
Change titanium and nano-tourmaline powder cobalt-60γray radiation treatment, irradiation dose: 20Mrad；Irradiation temperature: 20 DEG C；In nitrogen
Under protection；
Step 2: preparing high molecular material powder
The copolymer of 20 parts of ethene-vinyl acetate, 10 parts of acrylic copolymer and 5 parts of native cellulose are mixed
It closes uniform；
Step 3: preparation chlorination C60 negative ion powder
C60 negative ion powder is subjected to chlorination[1]
Step 4: preparing coating
Each component is sufficiently mixed in parts by weight, with blender uniform stirring 25 minutes, revolving speed 1200r/min was obtained
To colored paint six.
Experimental example one
Material to be tested: coating one, coating two, coating three, coating four, colored paint five, colored paint six.
The purifying formaldehyde efficiency of each coating is detected by routine experiment.Experimental result is as shown in table 1, meets Building wood
Expect I category alignment request of industrial technology, purification efficiency >=75%.
1 purifying formaldehyde efficiency experimental result record sheet of table
| Experimental material | Coating one | Coating two | Coating three | Coating four | Colored paint five | Colored paint six |
| Inspection result | 83.3% | 84.2% | 84.9.% | 84.6% | 85.1% | 85.8% |
Experimental example two
Material to be tested: coating one, coating two, coating three, coating four, colored paint five, colored paint six.
Content of volatile organic compound (VOC) is carried out to each coating by routine experiment and free formaldehyde content detects.
Volatile organic compounds (VOC) and free formaldehyde are not detected in six groups of coating of experimental result, meet relevant regulations.
Although the embodiments of the present invention have been disclosed as above, but its institute not only in the description and the implementation
Column use.It can be applied to various suitable the field of the invention completely.For those skilled in the art, can hold
It changes places and realizes other modification.Therefore without departing from the general concept defined in the claims and the equivalent scope, the present invention is simultaneously
It is not limited to specific details.
Claims (5)
1. a kind of C60 anion shell powder interior wall paint, which is characterized in that the coating is with natural or artificial breeding conch meal
For basic material, while nano-titanium dioxide and nano-tourmaline powder and high score with cobalt-60γray radiation treatment is added
Sub- pulverulent material comprising component be calculated by weight as:
The partial size of shell powder is 500-1500 mesh.
2. a kind of C60 anion shell powder interior wall paint, which is characterized in that the coating is with natural or artificial breeding conch meal
For basic material, while nano-titanium dioxide and nano-tourmaline powder and high score with cobalt-60γray radiation treatment is added
Sub- pulverulent material comprising component be calculated by weight as:
The partial size of shell powder is 800 mesh.
3. a kind of C60 anion shell powder interior wall paint, which is characterized in that the coating is with natural or artificial breeding conch meal
For basic material, while nano-titanium dioxide and nano-tourmaline powder and high score with cobalt-60γray radiation treatment is added
Sub- pulverulent material comprising component be calculated by weight as:
The partial size of shell powder is 1000 mesh.
4. a kind of C60 anion shell powder interior wall paint according to claim 1 to 3, which is characterized in that further include 20-80
The phytochrome of part.
5. a kind of preparation method of C60 anion shell powder interior wall paint described in -4 according to claim 1, which is characterized in that
The following steps are included:
Step 1: needing nano-titanium dioxide and nano-tourmaline powder being surface modified processing first, by nano-titanium dioxide
And nano-tourmaline powder cobalt-60γray radiation treatment, irradiation dose: 20Mrad；Irradiation temperature: 20 DEG C；In nitrogen protection
Under；
Step 2: preparing high molecular material powder
By the copolymer of 20-50 parts of ethene-vinyl acetate, 10-40 parts of acrylic copolymer and 5-20 parts of natural fiber
Element is uniformly mixed；
Step 3: preparation chlorination C60 negative ion powder
C60 negative ion powder is subjected to chlorination；
Step 4: preparing coating
Each component is sufficiently mixed in parts by weight, with blender uniform stirring 25min, revolving speed 1200r/min.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811586348.8A CN109705637A (en) | 2018-12-25 | 2018-12-25 | A kind of C60 anion shell powder interior wall paint and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811586348.8A CN109705637A (en) | 2018-12-25 | 2018-12-25 | A kind of C60 anion shell powder interior wall paint and preparation method thereof |
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| CN109705637A true CN109705637A (en) | 2019-05-03 |
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| CN103627261A (en) * | 2013-12-06 | 2014-03-12 | 吉林日禾科技开发有限公司 | Dry powder type shell powder interior wall coating material and preparation method thereof |
| CN103980744A (en) * | 2014-03-28 | 2014-08-13 | 广西万家康科技股份有限公司 | Special dry powder type ecologic shell powder interior wall coating for children's rooms |
| CN103979958A (en) * | 2013-02-13 | 2014-08-13 | 鹤山市龙腾科技有限公司 | Nano far-infrared superconductive composite negative ion energy material |
| CN106318007A (en) * | 2015-07-06 | 2017-01-11 | 山东花瓣雨涂料科技有限公司 | Formaldehyde-removal latex paint capable of releasing negative oxygen ions and preparation method thereof |
| CN107418264A (en) * | 2017-08-22 | 2017-12-01 | 杭州纳巍负离子科技有限公司 | Fullerene negative ion dry powder paint and application method |
-
2018
- 2018-12-25 CN CN201811586348.8A patent/CN109705637A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103979958A (en) * | 2013-02-13 | 2014-08-13 | 鹤山市龙腾科技有限公司 | Nano far-infrared superconductive composite negative ion energy material |
| CN103627261A (en) * | 2013-12-06 | 2014-03-12 | 吉林日禾科技开发有限公司 | Dry powder type shell powder interior wall coating material and preparation method thereof |
| CN103980744A (en) * | 2014-03-28 | 2014-08-13 | 广西万家康科技股份有限公司 | Special dry powder type ecologic shell powder interior wall coating for children's rooms |
| CN106318007A (en) * | 2015-07-06 | 2017-01-11 | 山东花瓣雨涂料科技有限公司 | Formaldehyde-removal latex paint capable of releasing negative oxygen ions and preparation method thereof |
| CN107418264A (en) * | 2017-08-22 | 2017-12-01 | 杭州纳巍负离子科技有限公司 | Fullerene negative ion dry powder paint and application method |
Non-Patent Citations (1)
| Title |
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Application publication date: 20190503 |