CN107384140A - A kind of anion environmental protection health paint and preparation method thereof - Google Patents

A kind of anion environmental protection health paint and preparation method thereof Download PDF

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Publication number
CN107384140A
CN107384140A CN201710700667.6A CN201710700667A CN107384140A CN 107384140 A CN107384140 A CN 107384140A CN 201710700667 A CN201710700667 A CN 201710700667A CN 107384140 A CN107384140 A CN 107384140A
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CN
China
Prior art keywords
environmental protection
protection health
parts
anion environmental
anion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201710700667.6A
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Chinese (zh)
Inventor
杨卓舒
纪勇
段晓
张军华
马春羽
甄瑞成
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hebei Zhuoda Building Materials Research Institute Co Ltd
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Hebei Zhuoda Building Materials Research Institute Co Ltd
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Priority to CN201710700667.6A priority Critical patent/CN107384140A/en
Publication of CN107384140A publication Critical patent/CN107384140A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C09D163/10Epoxy resins modified by unsaturated compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D201/00Coating compositions based on unspecified macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02Emulsion paints including aerosols
    • C09D5/024Emulsion paints including aerosols characterised by the additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/38Boron-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/09Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098Metal salts of carboxylic acids

Abstract

The invention provides a kind of anion environmental protection health paint, the anion environmental protection health paint is made up of 0.5 7wt% anionic additives, 93 99.5wt% coating base materials.The present invention a kind of anion environmental protection health paint by nano-tourmaline, nano titanium oxide, ultra-fine calcium stearate, superfine talcum powder reasonable disposition, improve anion induces effect;And the raw material composition for providing anionic additive is simple, industrialized production of being more convenient for, meanwhile, anion environmental protection health paint reduces radioactivity possibility, more environmentally-friendly health existing for tourmaline by adding effective radiation shield agent.

Description

A kind of anion environmental protection health paint and preparation method thereof
Technical field
The present invention relates to a kind of coating and preparation method, especially a kind of anion environmental protection health paint and its preparation side Method.
Background technology
With the enhancing that the growth in the living standard of people and health environment-friendly are realized, the choosing to the material of household living-- room decoration Material and use propose higher requirement.Increasingly how to meet the requirement of people on the indoor hardware fitting of furniture in competition Become the problem of all big enterprises pay the utmost attention to.
Negative oxygen ion is widely present in the Nature, in content high local such as forest, seashore, waterfall area.Although nothing Color is tasteless, and function is but very surprising, so that turning into " air vitamin " by medical field.Negative oxygen ion can pass through blood and nerveous system System enters in human body, and the organism physiology activity to people has an impact.Such as when negative oxygen ion enters brain, can be big by adjusting The function of cortex, play and improve sleep quality, the effect of reducing blood pressure;After negative oxygen ion enters human respiratory tract, it can make Bronchial smooth muscle relaxes, and improves cardiorespiratory system function, improves operating efficiency;It is tired that negative oxygen ion can then reduce human body in blood Labor, improve human body reaction, improve body immunity.Negative oxygen ion can also play purification to the oil smoke in air, second-hand-cigarette and make With so as to prevent the respiratory diseases such as pneumonia, tracheitis, and mitigating negative effect caused by smoking.
Therefore, negative oxygen ion is the indispensable material of human body, and human body needs 13,000,000,000 negative oxygen ions, but city daily The negative oxygen ion that people can only but obtain 2,000,000,000 or so daily is obtainable just less particularly in general room, is primarily due to Caused by the reason for present air pollution is increasingly severe, and the negative oxygen ion in air is fewer and fewer.
At present, CN102702834A discloses a kind of anion environmental protection health paint, is added by 0.2-1.5wt% anions Agent and 98.5-99.8wt% coating base material composition, the anionic additive, are made up of following components by mass parts:Coral Stone 10-15 parts;Tourmaline 10-15 parts;Opal 30-50 parts;Serpentine 15-20 parts;Medical stone 2-4 parts;Strange ice stone 10-15 Part;Hokutolite 2-4 parts;Doctor king stone 2-4 parts;Shell 3-6 parts;Di-iron trioxide 2-4 parts;Alundum (Al2O3) 2-4 parts;Zirconium oxide 2- 4 parts;Basic zirconium phosphate 2-4 parts.Although the coating can produce negative aeroion, wherein anionic additive constituent is excessively multiple It is miscellaneous, it is unfavorable for large-scale production.And raw materials tourmaline has trace-level activity, too high levels are known from experience to people produces wound Evil.
The content of the invention
For the deficiencies in the prior art, it is an object of the invention to provide a kind of anion environmental protection health paint and its Preparation method, anion environmental protection health paint of the invention can not only can more produce air ion, and provide anion and add The raw material of agent is added to form simple, industrialized production of being more convenient for, and more environmentally friendly health.
In order to realize the object of the invention, the present invention is achieved through the following technical solutions:
A kind of anion environmental protection health paint, the anion environmental protection health paint by 0.5-7wt% anionic additives, 93-99.5wt% coating base material forms.
The anion environmental protection health paint is made up of 3wt% anionic additives, 97wt% coating base materials.
The anionic additive includes following component:It is nano-tourmaline, nano titanium oxide, ultra-fine calcium stearate, super Fine and smooth stone flour.
The anionic additive is made up of by mass fraction following components:Nano-tourmaline 15-30 parts, nanometer titanium dioxide Titanium 20-40 parts, ultra-fine calcium stearate 15-25 parts, superfine talcum powder 15-25 parts.
Preferably, the anionic additive is made up of by mass fraction following components:Part, nanometer two of nano-tourmaline 20 30 parts of titanium oxide, 20 parts of ultra-fine calcium stearate, 20 parts of superfine talcum powder.
Described anion environmental protection health paint preparation method, comprises the following steps:
(1) nano-tourmaline, nano titanium oxide, ultra-fine calcium stearate, ultra-fine cunning are weighed according to each component mass fraction Stone flour, it is well mixed, by sieving and dries, anionic additive is made.
(2) anionic additive is mixed with the coating base material.
Sieving is sieved using 200 mesh filter clothes in the step (1).
Conventional coating, such as epoxy-based lacquers, nitrate paint, unsaturated polyester varnish, ethene lacquer can be selected in the coating base material, or Person directly selects commercial coating.
Beneficial effects of the present invention:The present invention anionic additive not only by nano-tourmaline, nano titanium oxide, The reasonable disposition of ultra-fine calcium stearate, superfine talcum powder, improve anion induces effect, can produce it is more bear from Son, and the raw material composition for providing anionic additive is simple, industrialized production of being more convenient for, meanwhile, anion environmental protection coating passes through Effective radiation shield agent is added, reducing radioactivity existing for tourmaline may;More environmentally-friendly health.
Embodiment
The present invention is further elaborated below by way of specific embodiment.
Embodiment 1
The anion environmental protection health paint of the present embodiment is prepared,
(1) weigh:
(2) nano-tourmaline, nano titanium oxide, ultra-fine calcium stearate, superfine talcum powder are well mixed, by 200 Mesh sieve and drying, anionic additive is made.
(3) anionic additive is mixed according to the ratio of percentage by weight 3% with commercial coating base material;It can be prepared by this The anion environmental protection coating of invention.
Conventional coating ethene lacquer can be selected in the coating base material.
Embodiment 2
The anion environmental protection health paint of the present embodiment is prepared,
(1) weigh:
(2) nano-tourmaline, nano titanium oxide, ultra-fine calcium stearate, superfine talcum powder are mixed by above-mentioned mass fraction Close uniformly, through sieving (200 mesh) and drying, anionic additive is made.
(3) anionic additive is mixed according to the ratio of percentage by weight 5% with commercial coating base material;It can be prepared by this The anion environmental protection coating of invention.
The coating base material selects ippon multiple-effect five in one interiro wall latex paint.
Embodiment 3
The anion environmental protection health paint of the present embodiment is prepared,
(1) weigh:
(2) nano-tourmaline, nano titanium oxide, ultra-fine calcium stearate, superfine talcum powder are well mixed, through sieving (200 mesh) and dry, anionic additive is made.
(3) anionic additive is mixed according to the ratio of percentage by weight 6% with commercial coating base material;It can be prepared by this The anion environmental protection coating of invention.
The coating base material selects the how happy scholar's exterior wall paint of conventional commercial coating.
Comparative example:
(1) 15 parts of astroies are weighed;15 parts of tourmaline;50 parts of opal;20 parts of serpentine;4 parts of medical stone;Strange ice stone 15 parts;4 parts of hokutolite;4 parts of Doctor king stone;6 parts of shell;4 parts of di-iron trioxide;4 parts of alundum (Al2O3);4 parts of zirconium oxide;Basic zirconium phosphate 4 parts, it is well mixed, through drying of sieving, anionic additive is made.
(2) anionic additive is mixed according to the ratio of percentage by weight 1% with commercial coating base material;It can be prepared by pair The anion environmental protection coating of ratio.
Table 1 is with reference to professional standard《Function of purifying indoor air coating material purifying property》Method of testing, to implement Example 1, embodiment 2, embodiment 3 and comparative example have carried out purifying formaldehyde performance test.
Table 2 be embodiment and comparative example brushing after coated plate, to testing result (25 DEG C of temperature, the humidity of harmful substance 75%RH, coated plate standard area are 200mm*400mm, minute 100s)
As can be seen from the above Examples and Comparative Examples, anion adds in the anionic additive in comparative example and embodiment Add agent component difference, content different, from the performance test results table of sample coating it can be found that coating property corresponding to comparative example Typically, the negative ion amount of release is relatively fewer, and the negative ion amount of corresponding release is substantially more in embodiment, especially implements Example 1, meanwhile, it is also undesirable to the adsorption effect of pernicious gas in comparative example, illustrate in the present invention anionic additive component and Content realizes that the release of a large amount of anions and effectively absorption pernicious gas have very crucial meaning to coating.
A kind of anion environmental protection health paint of the present invention passes through nano-tourmaline, nano titanium oxide, ultra-fine stearic acid The reasonable disposition of calcium, superfine talcum powder, improve anion induces effect, can produce more anions, and provides negative The raw material composition of ionic additive is simple, industrialized production of being more convenient for, meanwhile, anion environmental protection coating is by adding effective spoke Screener is penetrated, reducing radioactivity existing for tourmaline may;More environmentally-friendly health.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto, Any one skilled in the art is in the technical scope of present disclosure, the change or replacement that can readily occur in, It should all be included within the scope of the present invention.Therefore, protection scope of the present invention should be with the protection model of claims Enclose and be defined.

Claims (7)

  1. A kind of 1. anion environmental protection health paint, it is characterised in that the anion environmental protection health paint by 0.5-7wt% bear from Sub- additive, 93-99.5wt% coating base material composition.
  2. 2. anion environmental protection health paint according to claim 1, it is characterised in that the anion environmental protection health paint It is made up of 3wt% anionic additives, 97wt% coating base materials.
  3. 3. anion environmental protection health paint according to claim 1 or 2, it is characterised in that the anionic additive bag Include following component:Nano-tourmaline, nano titanium oxide, ultra-fine calcium stearate, superfine talcum powder.
  4. 4. anion environmental protection health paint according to claim 1, it is characterised in that the anionic additive presses quality Number is made up of following components:Nano-tourmaline 15-30 parts, nano titanium oxide 20-40 parts, ultra-fine calcium stearate 15-25 parts, Superfine talcum powder 15-25 parts.
  5. 5. anion environmental protection health paint according to claim 1, it is characterised in that the anionic additive presses quality Number is made up of following components:20 parts of nano-tourmaline, 30 parts of nano titanium oxide, 20 parts of ultra-fine calcium stearate, extra fine talc 20 parts of powder.
  6. 6. according to any described anion environmental protection health paint preparation methods of claim 1-5, it is characterised in that including as follows Step:
    (1) nano-tourmaline, nano titanium oxide, ultra-fine calcium stearate, superfine talcum powder are weighed according to each component mass fraction, It is well mixed, by sieving and dries, anionic additive is made;
    (2) anionic additive is mixed with the coating base material.
  7. A kind of 7. preparation method of anion environmental protection health paint according to claim 6, it is characterised in that the step (1) sieving is sieved using 200 mesh filter clothes in.
CN201710700667.6A 2017-08-16 2017-08-16 A kind of anion environmental protection health paint and preparation method thereof Withdrawn CN107384140A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
CN201710700667.6A CN107384140A (en) 2017-08-16 2017-08-16 A kind of anion environmental protection health paint and preparation method thereof

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Publication Number Publication Date
CN107384140A true CN107384140A (en) 2017-11-24

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108264849A (en) * 2018-01-26 2018-07-10 佛山市邦韵建材有限公司 A kind of coating of decomposing formaldehyde release anion
CN109762408A (en) * 2019-01-23 2019-05-17 李永东 A kind of antibacterial, the preparation method of fungus resistance negative ion paint

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102702834A (en) * 2012-01-12 2012-10-03 上海韬鸿化工科技有限公司 Healthy anion coating
CN103627261A (en) * 2013-12-06 2014-03-12 吉林日禾科技开发有限公司 Dry powder type shell powder interior wall coating material and preparation method thereof
CN103980744A (en) * 2014-03-28 2014-08-13 广西万家康科技股份有限公司 Special dry powder type ecologic shell powder interior wall coating for children's rooms
CN104497692A (en) * 2015-01-15 2015-04-08 宁波保税区韬鸿化工科技有限公司 Negative ion coating
CN105038366A (en) * 2015-08-27 2015-11-11 保护伞环保科技成都有限公司 Air-purification internal wall putty

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102702834A (en) * 2012-01-12 2012-10-03 上海韬鸿化工科技有限公司 Healthy anion coating
CN103627261A (en) * 2013-12-06 2014-03-12 吉林日禾科技开发有限公司 Dry powder type shell powder interior wall coating material and preparation method thereof
CN103980744A (en) * 2014-03-28 2014-08-13 广西万家康科技股份有限公司 Special dry powder type ecologic shell powder interior wall coating for children's rooms
CN104497692A (en) * 2015-01-15 2015-04-08 宁波保税区韬鸿化工科技有限公司 Negative ion coating
CN105038366A (en) * 2015-08-27 2015-11-11 保护伞环保科技成都有限公司 Air-purification internal wall putty

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108264849A (en) * 2018-01-26 2018-07-10 佛山市邦韵建材有限公司 A kind of coating of decomposing formaldehyde release anion
CN109762408A (en) * 2019-01-23 2019-05-17 李永东 A kind of antibacterial, the preparation method of fungus resistance negative ion paint

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Application publication date: 20171124

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