CN108744844A - A kind of gel beads and preparation method thereof with antibacterial function of removing formaldehyde - Google Patents
A kind of gel beads and preparation method thereof with antibacterial function of removing formaldehyde Download PDFInfo
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- CN108744844A CN108744844A CN201810547210.0A CN201810547210A CN108744844A CN 108744844 A CN108744844 A CN 108744844A CN 201810547210 A CN201810547210 A CN 201810547210A CN 108744844 A CN108744844 A CN 108744844A
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- cyclodextrin
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/007—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by irradiation
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/40—Liliopsida [monocotyledons]
- A01N65/44—Poaceae or Gramineae [Grass family], e.g. bamboo, lemon grass or citronella grass
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8668—Removing organic compounds not provided for in B01D53/8603 - B01D53/8665
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/708—Volatile organic compounds V.O.C.'s
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/91—Bacteria; Microorganisms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/06—Polluted air
Abstract
It the invention discloses a kind of gel beads with antibacterial function of removing formaldehyde, particularly belongs to indoor exhaust air and administers field, including spherical gel beads nucleome, the functional aquagel and crosslinking agent that are coated on outside gel beads nucleome;The functional aquagel is in terms of parts by weight, including following component:10~16 parts of photocatalyst, 5~10 parts of nano silver, 20~30 parts of gel, 3~5 parts of 5~10 parts of natural pigment, 10~15 parts of plants essential oil and emulsifier;The gel beads nucleome is made of at least one of graphene, bentonite, volcanic ash and chitosan material.The present invention is with slow releasing function, long action time and except the good advantage of useless effect.
Description
Technical field
The invention belongs to indoor exhaust airs to administer field, specially a kind of gel beads and its system with antibacterial function of removing formaldehyde
Preparation Method.
Background technology
Indoor decoration pollution refers to that the oxygen that harmful health is mixed into room air, formaldehyde, benzene, ammonia and volatility are organic
The phenomenon that gases such as object.It is well known that being fitted up to indoor particulate matter, a variety of environmental problems can be brought, such as:It uses
Building materials containing poisonous and harmful substances can have an impact indoor air quality;It will produce various dust in fitment process, discard
Object and noise pollution, these can all seriously affect people's lives.There are many source of indoor decoration pollution, wherein having suitable one
Partially due to caused by material used in fitment process is improper, including the volatile organic matters gas such as formaldehyde, benzene, dimethylbenzene
Body.However the pernicious gas volatilized in finishing material then can cause one as removed not in time to the health for the personnel of moving in
Fixed harm.
Occur a variety of improvement products for being directed to formaldehyde or benzene homologues on the market.Due to newly-decorated indoor meeting sustained release
Go out pernicious gas, therefore how to extend the hot spot paid close attention at research staff except useless action time to the maximum extent.
Invention content
The present invention provides a kind of gel beads with antibacterial function of removing formaldehyde, which has slow releasing function so that
Time is long and except the good advantage of useless effect.
To achieve the above object, the present invention provides the following technical solutions:
A kind of gel beads with antibacterial function of removing formaldehyde, including spherical gel beads nucleome, it is coated on gel beads nucleome
External functional aquagel and crosslinking agent;The functional aquagel is in terms of parts by weight, including following component:Photocatalyst
10~16 parts, 5~10 parts of nano silver, 20~30 parts of gel, 5~10 parts of natural pigment, 10~15 parts of plants essential oil and emulsification
3~5 parts of agent;The gel beads nucleome is made of at least one of graphene, bentonite, volcanic ash and chitosan material.
Wherein, the photocatalyst in functional aquagel and nano silver have the function of antibacterial, decomposing formaldehyde, as long as interior has
Illumination, you can persistently play a role.Also, plants essential oil is volatilizable into air, can not only improve indoor air quality,
Antibacterial effect can also be played.
Gel beads nucleome is located at the middle part of functional aquagel, and the gel beads can be prevented to be squeezed and deform.It coagulates simultaneously
Glue bead nucleome is made of the strong material of antibacterial, adsorption capacity, can assist adsorbing indoor exhaust gas or harmful substance, to reach pair
The effect of waste gas pollution control and treatment.
Preferably, the crosslinking agent is any one in glutaraldehyde, formaldehyde, epoxychloropropane, beta-cyclodextrin, or
Their mixture.
Preferably, in dance glue, konjac glucomannan, sodium alginate, Aloe Vera Gel and Arabic gum of the gel selected from a white Ji
Any one.
Preferably, the natural pigment is selected from any one of Gardenia Yellow and curcumin.
Preferably, the plants essential oil is selected from mulberry leaf essential oil, Lavender, pine tree essence oil, Essential Oil from Flos Sophorae Immaturus, orange peel essence
At least one of oil and oil of Cymbopogon winterianus.
Preferably, the emulsifier is selected from lecithin, solidifying fragrant at least one of body and palm vegetable wax.
Preferably, the functional aquagel is in terms of parts by weight, including following component:13 parts of photocatalyst, nano silver 7
Part, 5 parts of the dance glue of a white Ji, 3 parts of konjac glucomannan, 6 parts of sodium alginate, 7 parts of Aloe Vera Gel, 3 parts of Arabic gum, 3 parts of Gardenia Yellow, mulberry
8 parts of leaf essential oil, 12 parts of Lavender, 4 parts of pine tree essence oil, 3 parts of oil of Cymbopogon winterianus coagulate 1 part of 3 parts of perfume body and palm vegetable wax.Institute
It states gel beads nucleome to be made by bentonite, volcanic ash and chitosan are uniformly mixed, the crosslinking agent is beta-cyclodextrin.
The present invention also provides a kind of preparation method of the gel beads with antibacterial function of removing formaldehyde, which includes
Following preparation process:
(1) preparation of gel beads nucleome
(1.1) by bentonite, volcanic ash and chitosan in mass ratio 2:1:1 uniformly mixing, is added after pure water constantly
Stirring is poured into after spherical die and is heated to hardening to get to gel beads nucleome to colloidal;
(2) preparation of functional aquagel
(2.1) preset weight number proportioning is pressed by photocatalyst, nano silver, the dance glue of a white Ji, konjac glucomannan, sodium alginate, reed
Luxuriant growth glue, Arabic gum, Gardenia Yellow, mulberry leaf essential oil, Lavender, pine tree essence oil, oil of Cymbopogon winterianus coagulate perfume body and palm
Vegetable wax is uniformly mixed, and under 40~60 DEG C of water bath condition, is stirred 70~90min, is obtained functional aquagel;
(3) the gel beads nucleome being prepared is immersed in beta-cyclodextrin cyclodextrin, obtaining adsorption has β-ring paste
The gel beads nucleome of smart cyclodextrin;
(4) there is the gel beads nucleome of beta-cyclodextrin cyclodextrin to be immersed in functional aquagel adsorption, fully inhale
To get to the gel beads with antibacterial function of removing formaldehyde after attached crosslinking.
Preferably, further including step (5) after step (4), step (5) is in the above preparation method:Will
To gel beads be repeated in step (3) and step (4), obtain crosslinking adsorption multi-layer functional aquagel gel beads.
Preferably, in step (3), gel beads nucleome be immersed in the time in beta-cyclodextrin cyclodextrin be 200~
400min;In step (4), adsorption has the gel beads nucleome of beta-cyclodextrin cyclodextrin to be immersed in functional aquagel
Time is 300~400min.
Beneficial effects of the present invention are:
(1) photocatalyst in functional aquagel and nano silver have the function of antibacterial, decomposing formaldehyde, as long as there is light in interior
According to, you can persistently play a role.Also, plants essential oil is volatilizable into air, can not only improve indoor air quality,
Antibacterial effect can be played.
(2) gel beads nucleome is located at the middle part of functional aquagel, and the gel beads can be prevented to be squeezed and deform.Simultaneously
Gel beads nucleome is made of the strong material of antibacterial, adsorption capacity, can assist adsorbing indoor exhaust gas or harmful substance, to reach
To the effect of waste gas pollution control and treatment.
Specific implementation mode
Embodiment 1
The present embodiment provides a kind of technical solutions:
A kind of gel beads with antibacterial function of removing formaldehyde, including spherical gel beads nucleome, it is coated on gel beads nucleome
External functional aquagel and beta-cyclodextrin.
Above-mentioned functional aquagel is in terms of parts by weight, including following component:13 parts of photocatalyst, 7 parts of nano silver, a white Ji it
Wave 5 parts of glue, 3 parts of konjac glucomannan, 6 parts of sodium alginate, 7 parts of Aloe Vera Gel, 3 parts of Arabic gum, 7 parts of Gardenia Yellow, mulberry leaf essential oil 8
Part, 4 parts of Lavender, 2 parts of pine tree essence oil, 1 part of oil of Cymbopogon winterianus coagulate 1 part of 3 parts of perfume body and palm vegetable wax.
Above-mentioned gel beads nucleome is uniformly mixed by bentonite, volcanic ash and chitosan and is made.
The preparation method of above-mentioned gel beads is as follows:
(1) preparation of gel beads nucleome
(1.1) by bentonite, volcanic ash and chitosan in mass ratio 2:1:1 uniformly mixing, is added after pure water constantly
Stirring is poured into after spherical die and is heated to hardening to get to gel beads nucleome to colloidal.
(2) preparation of functional aquagel
(2.1) preset weight number proportioning is pressed by photocatalyst, nano silver, the dance glue of a white Ji, konjac glucomannan, sodium alginate, reed
Luxuriant growth glue, Arabic gum, Gardenia Yellow, mulberry leaf essential oil, Lavender, pine tree essence oil, oil of Cymbopogon winterianus coagulate perfume body and palm
Vegetable wax is uniformly mixed, and under 40~60 DEG C of water bath condition, is stirred 70~90min, is obtained functional aquagel.
(3) the gel beads nucleome being prepared is immersed in beta-cyclodextrin cyclodextrin, continues 300min, obtain surface suction
Gel beads nucleome with beta-cyclodextrin cyclodextrin.
(4) there is the gel beads nucleome of beta-cyclodextrin cyclodextrin to be immersed in functional aquagel adsorption, continue
350min until abundant cross-linking to get to the gel beads with antibacterial function of removing formaldehyde.
(5) obtained gel beads are repeated in step (3) and step (4), obtain crosslinking adsorption multi-layer functionality water-setting
The gel beads of glue.
Embodiment 2
A kind of gel beads with antibacterial function of removing formaldehyde, including spherical gel beads nucleome, it is coated on gel beads nucleome
External functional aquagel and beta-cyclodextrin.
Above-mentioned functional aquagel is in terms of parts by weight, including following component:10 parts of photocatalyst, 5 parts of nano silver, a white Ji it
Wave 4 parts of glue, 5 parts of konjac glucomannan, 8 parts of sodium alginate, 6 parts of Aloe Vera Gel, 5 parts of Arabic gum, 6 parts of Gardenia Yellow, mulberry leaf essential oil 7
Part, 3 parts of Lavender, 2 parts of pine tree essence oil, 1 part of oil of Cymbopogon winterianus coagulate 1 part of 3 parts of perfume body and palm vegetable wax.
Above-mentioned gel beads nucleome is uniformly mixed by bentonite, volcanic ash and chitosan and is made.
The preparation method is the same as that of Example 1 for above-mentioned gel beads.
Embodiment 3
A kind of gel beads with antibacterial function of removing formaldehyde, including spherical gel beads nucleome, it is coated on gel beads nucleome
External functional aquagel and beta-cyclodextrin.
Above-mentioned functional aquagel is in terms of parts by weight, including following component:16 parts of photocatalyst, 10 parts of nano silver, a white Ji
3 parts of dance glue, 4 parts of konjac glucomannan, 2 parts of sodium alginate, 6 parts of Aloe Vera Gel, 5 parts of Arabic gum, 10 parts of Gardenia Yellow, mulberry leaf essential oil
6 parts, 1 part of Lavender, 4 parts of pine tree essence oil, 1 part of oil of Cymbopogon winterianus coagulates 3 parts of 2 parts of body of perfume and palm vegetable wax.
Above-mentioned gel beads nucleome is uniformly mixed by bentonite, volcanic ash and chitosan and is made.
The preparation method is the same as that of Example 1 for above-mentioned gel beads.
Comparative example 1
A kind of gel beads with antibacterial function of removing formaldehyde, including spherical gel beads nucleome, it is coated on gel beads nucleome
External functional aquagel and glutaraldehyde.
Above-mentioned functional aquagel is in terms of parts by weight, including following component:13 parts of photocatalyst, 7 parts of nano silver, a white Ji it
Wave 5 parts of glue, 3 parts of konjac glucomannan, 6 parts of sodium alginate, 7 parts of Aloe Vera Gel, 3 parts of Arabic gum, 7 parts of Gardenia Yellow, mulberry leaf essential oil 8
Part, 4 parts of Lavender, 2 parts of pine tree essence oil, 1 part of oil of Cymbopogon winterianus coagulate 1 part of 3 parts of perfume body and palm vegetable wax.
Above-mentioned gel beads nucleome is uniformly mixed by bentonite, volcanic ash and chitosan and is made.
The preparation method is the same as that of Example 1 for above-mentioned gel beads.
Comparative example 2
A kind of gel beads with antibacterial function of removing formaldehyde, including spherical gel beads nucleome, it is coated on gel beads nucleome
External functional aquagel and beta-cyclodextrin.
Above-mentioned functional aquagel is in terms of parts by weight, including following component:13 parts of photocatalyst, 7 parts of nano silver, a white Ji it
Wave 5 parts of glue, 3 parts of konjac glucomannan, 6 parts of sodium alginate, 7 parts of Aloe Vera Gel, 3 parts of Arabic gum, 7 parts of Gardenia Yellow, mulberry leaf essential oil 8
Part, 4 parts of Lavender, 2 parts of pine tree essence oil, 1 part of oil of Cymbopogon winterianus coagulate 1 part of 3 parts of perfume body and palm vegetable wax.
Above-mentioned gel beads nucleome is uniformly mixed by bentonite and volcanic ash and is made.
Comparative example 3
A kind of gel beads with antibacterial function of removing formaldehyde, including spherical gel beads nucleome, it is coated on gel beads nucleome
External functional aquagel and beta-cyclodextrin.
Above-mentioned functional aquagel is in terms of parts by weight, including following component:5 parts of the dance glue of a white Ji, 3 parts of konjac glucomannan, sea
6 parts of mosanom, 7 parts of Aloe Vera Gel, 3 parts of Arabic gum, 7 parts of Gardenia Yellow, 8 parts of mulberry leaf essential oil, 4 parts of Lavender, pine tree
2 parts of essential oil, 1 part of oil of Cymbopogon winterianus coagulate 1 part of 3 parts of perfume body and palm vegetable wax.
Above-mentioned gel beads nucleome is uniformly mixed by bentonite, volcanic ash and chitosan and is made.
Above-mentioned gel beads nucleome is uniformly mixed by bentonite and volcanic ash and is made.
Comparative example 4
A kind of gel beads with antibacterial function of removing formaldehyde, including spherical gel beads nucleome, it is coated on gel beads nucleome
External functional aquagel and beta-cyclodextrin.
Above-mentioned functional aquagel is in terms of parts by weight, including following component:13 parts of photocatalyst, 7 parts of nano silver, a white Ji it
Wave 5 parts of glue, 3 parts of konjac glucomannan, 6 parts of sodium alginate, 7 parts of Aloe Vera Gel, 3 parts of Arabic gum, 7 parts of Gardenia Yellow, coagulate 3 parts of body of perfume with
And 1 part of palm vegetable wax.
Above-mentioned gel beads nucleome is uniformly mixed by bentonite, volcanic ash and chitosan and is made.
Test case 1
Decoration company holds consultation with cell, chooses and waits for decorating house with 24 sets of building building with cell, is randomly divided into 8 groups,
Number is A~H.10 are placed respectively in A~C groups house that just finishing has been completed to be made of the component that Examples 1 to 3 is provided
Gel beads, place gel made of the component that 10 are provided comparative example 1~4 in D~G groups house that just finishing has been completed
Pearl, H groups compare group, air conditions statistics such as the following table 1 in measuring chamber after 36 hours:
1 room air situation statistical form of table
Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art,
It still can be with technical scheme described in the above embodiments is modified, or is carried out to which part technical characteristic etc.
With replacing, all within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in this
Within the protection domain of invention.
Claims (10)
1. a kind of gel beads with antibacterial function of removing formaldehyde, which is characterized in that including spherical gel beads nucleome, be coated on it is solidifying
Functional aquagel outside glue bead nucleome and crosslinking agent;
The functional aquagel is in terms of parts by weight, including following component:
10~16 parts of photocatalyst, 5~10 parts of nano silver, 20~30 parts of gel, 5~10 parts of natural pigment, plants essential oil 10~15
3~5 parts of part and emulsifier;
The gel beads nucleome is made of at least one of graphene, bentonite, volcanic ash and chitosan material.
2. a kind of gel beads with antibacterial function of removing formaldehyde according to claim 1, which is characterized in that the crosslinking agent
It is any one in glutaraldehyde, formaldehyde, epoxychloropropane, beta-cyclodextrin or their mixture.
3. a kind of gel beads with antibacterial function of removing formaldehyde according to claim 1, which is characterized in that the gel choosing
Any one in the dance glue of a confession Ji, konjac glucomannan, sodium alginate, Aloe Vera Gel and Arabic gum.
4. a kind of gel beads with antibacterial function of removing formaldehyde according to claim 1, which is characterized in that the natural colour
Element is selected from any one of Gardenia Yellow and curcumin.
5. a kind of gel beads with antibacterial function of removing formaldehyde according to claim 1, which is characterized in that the plant essence
Oil is selected from least one of mulberry leaf essential oil, Lavender, pine tree essence oil, Essential Oil from Flos Sophorae Immaturus, orange peel essential oil and oil of Cymbopogon winterianus.
6. a kind of gel beads with antibacterial function of removing formaldehyde according to claim 1, which is characterized in that the emulsifier
Selected from lecithin, solidifying fragrant at least one of body and palm vegetable wax.
7. according to a kind of any gel beads with antibacterial function of removing formaldehyde of claim 1~6, which is characterized in that
The functional aquagel is in terms of parts by weight, including following component:13 parts of photocatalyst, 7 parts of nano silver, the dance glue of a white Ji
5 parts, 3 parts of konjac glucomannan, 6 parts of sodium alginate, 7 parts of Aloe Vera Gel, 3 parts of Arabic gum, 7 parts of Gardenia Yellow, 8 parts of mulberry leaf essential oil smokes
4 parts of clothing grass essential oil, 2 parts of pine tree essence oil, 1 part of oil of Cymbopogon winterianus coagulate 1 part of 3 parts of perfume body and palm vegetable wax;
The gel beads nucleome is uniformly mixed by bentonite, volcanic ash and chitosan and is made, and the crosslinking agent is beta-cyclodextrin.
8. a kind of preparation method of the gel beads with antibacterial function of removing formaldehyde, which is characterized in that including following preparation process:
(1) preparation of gel beads nucleome
(1.1) by bentonite, volcanic ash and chitosan in mass ratio 2:1:1 uniformly mixing, is stirred continuously after pure water is added
To colloidal, pours into after spherical die and be heated to hardening to get to gel beads nucleome;
(2) preparation of functional aquagel
(2.1) preset weight number is pressed to match photocatalyst, nano silver, the dance glue of a white Ji, konjac glucomannan, sodium alginate, Aloe Vera Gel,
Arabic gum, Gardenia Yellow, mulberry leaf essential oil, Lavender, pine tree essence oil, oil of Cymbopogon winterianus coagulate perfume body and palm vegetable wax
It is uniformly mixed, under 40~60 DEG C of water bath condition, stirs 70~90min, obtain functional aquagel;
(3) the gel beads nucleome being prepared is immersed in beta-cyclodextrin cyclodextrin, obtaining adsorption has beta-cyclodextrin ring
The gel beads nucleome of dextrin;
(4) the gel beads nucleome of beta-cyclodextrin cyclodextrin is immersed in functional aquagel adsorption, fully absorption is handed over
To get to the gel beads with antibacterial function of removing formaldehyde after connection.
9. preparation method according to claim 8, which is characterized in that further include step (5), step after step (4)
(5) it is:Obtained gel beads are repeated in step (3) and step (4), obtain the solidifying of crosslinking adsorption multi-layer functional aquagel
Glue bead.
10. preparation method according to claim 8, which is characterized in that in step (3), gel beads nucleome is immersed in β-
Time in cyclodextrin cyclodextrin is 200~400min;In step (4), adsorption has the gel of beta-cyclodextrin cyclodextrin
Pearl nucleome is immersed in the time in functional aquagel as 300~400min.
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CN109401629A (en) * | 2018-11-19 | 2019-03-01 | 巴洛克木业(中山)有限公司 | Remove aldehyde UV cured coating application timber apron |
CN111744345A (en) * | 2020-07-24 | 2020-10-09 | 浙江立居环保科技有限公司 | Slow-release aldehyde-removing gel and preparation method thereof |
CN112088907A (en) * | 2020-10-23 | 2020-12-18 | 山西纳安生物科技股份有限公司 | Gel antibacterial bead and preparation method thereof |
CN112275128A (en) * | 2020-08-13 | 2021-01-29 | 江苏卓高环保科技有限公司 | Korean pine seed nano-catalyst composite formaldehyde-removing functional liquid with fragrance slow-release function and preparation method thereof |
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CN111744345A (en) * | 2020-07-24 | 2020-10-09 | 浙江立居环保科技有限公司 | Slow-release aldehyde-removing gel and preparation method thereof |
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CN117138515A (en) * | 2023-11-01 | 2023-12-01 | 常州绿养源环保科技股份有限公司 | Environment-friendly sterilization formaldehyde-removing composition and preparation method thereof |
CN117138515B (en) * | 2023-11-01 | 2024-02-23 | 常州绿养源环保科技股份有限公司 | Environment-friendly sterilization formaldehyde-removing composition and preparation method thereof |
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