CN109745856A - It is a kind of for eliminating the spray of pollutants in air - Google Patents

It is a kind of for eliminating the spray of pollutants in air Download PDF

Info

Publication number
CN109745856A
CN109745856A CN201910101697.4A CN201910101697A CN109745856A CN 109745856 A CN109745856 A CN 109745856A CN 201910101697 A CN201910101697 A CN 201910101697A CN 109745856 A CN109745856 A CN 109745856A
Authority
CN
China
Prior art keywords
parts
air
spray
pollutants
eliminating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910101697.4A
Other languages
Chinese (zh)
Inventor
向小洪
林凤云
邱妍川
韦丽佳
刘阳
江尚飞
谢阳
刘巧
马潋
张慧梅
刘艺萍
张天竹
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chongqing Medical and Pharmaceutical College
Original Assignee
Chongqing Medical and Pharmaceutical College
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chongqing Medical and Pharmaceutical College filed Critical Chongqing Medical and Pharmaceutical College
Priority to CN201910101697.4A priority Critical patent/CN109745856A/en
Publication of CN109745856A publication Critical patent/CN109745856A/en
Pending legal-status Critical Current

Links

Landscapes

  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

The invention belongs to air sterillization sterilization technology fields, it specifically discloses a kind of for eliminating the spray of pollutants in air, including following component: 20-30 parts of ethyl alcohol, 2-5 parts of photochemical catalyst, 5-10 parts of plant extracts, 5-10 parts of gelatin, 2-5 parts of aromatic, 0.5-1 parts of surfactant and 50-70 parts of deionized water.Photochemical catalyst and plant extracts are applied in combination this programme, and photochemical catalyst and plant extracts cladding are got up with gelatin, and after spray sprinkling, due to the auxiliary of particle water, photochemical catalyst energy moment is attached to body surface, forms photo-catalyst film, not easily to fall off;Photochemical catalyst and plant extracts can be firmly bonded in film simultaneously, the slow release under the control of gelatin, to extend its action time, the poisonous and harmful substance that the finishing materials such as plate discharge in room air can be constantly eliminated, has good eradicating efficacy for volatile organic matters such as formaldehyde, benzene, sulfur dioxide (TVOC) etc..

Description

It is a kind of for eliminating the spray of pollutants in air
Technical field
The invention belongs to air sterillization sterilization technology fields, specifically disclose a kind of for eliminating the spray of pollutants in air Mist agent.
Background technique
In recent years, with the development of economy and society, city makes rapid progress, people's living standard is gradually increased, but empty Gas pollution is increasingly severe, and there is a large amount of pollutants in air.Air pollutants are by gaseous material, volatility object Air pollution owner caused by the mixture of matter, half volatile substance and particulate matter (PM), in people's daily life environment If caused by use, construction and decoration (spray painting, finishing material, construction material etc.) as vehicle exhaust, fossil fuel etc., mainly Include the volatile organic matters such as oxygenatedchemicals, nitrogenous compound (total volatile organism TVOC), sulfur dioxide, PM2.5, Formaldehyde, benzene etc..Other than welding, air pollution also results in many diseases, at present people by air pollution effect and The disease incidence of the diseases such as caused visual impairment, respiratory disease, cranial nerve be impaired, pneumonia and cancer is also in the trend of rising.
Currently, having many air fresheners or the air purifying preparation for eliminating formaldehyde on the market, but prevalent effects are not It is that very well, effect is not also lasting.
Summary of the invention
The purpose of the present invention provide it is a kind of for eliminating the spray of pollutants in air, it is net to solve existing air Agent is bad to the clean-up effect of pollutants in air, the problem that action time is not grown.
In order to achieve the above object, base case of the invention are as follows: it is a kind of for eliminating the spray of pollutants in air, Ingredient including following parts by weight: 20-30 parts of ethyl alcohol, 2-5 parts of photochemical catalyst, 5-10 parts of plant extracts, 5-10 parts of gelatin, 2-5 parts of aromatic, 0.5-1 parts of surfactant and 50-70 parts of deionized water.
The working principle and beneficial effect of this base case are:
Photochemical catalyst and plant extracts are applied in combination this programme, and with gelatin by photochemical catalyst and plant extracts packet It covers, after spray sprinkling, due to the auxiliary of particle water, photochemical catalyst energy moment is attached to body surface, forms photocatalyst Film, it is not easily to fall off;Photochemical catalyst and plant extracts can be firmly bonded in film simultaneously, slowly be released under the control of gelatin It puts, to extend its action time, can constantly eliminate the poisonous and harmful substance that the finishing materials such as plate discharge in room air, There is good eradicating efficacy for volatile organic matters such as formaldehyde, benzene, sulfur dioxide (TVOC) etc..
Photochemical catalyst and plant extracts have the synergistic effect mutually promoted in this spray, can effectively eliminate in air Pollutant, play purification air, disinfection and sterilization and other effects.
Further, the plant extracts includes take drugs 1-2 parts of grass, 1-2 parts of aloe, 1-2 parts of pomegranate leaf, 1-2 parts of bracketplant With 1-2 parts of schefflera.
The effective component extracting from above-mentioned several plant can effectively purify air by the synergistic effect between them, Disinfection and sterilization.Wherein, grass of taking drugs can convert oxygen and carbon dioxide for the nicotine for generation of smoking in air, moreover it is possible to absorb cigarette Taste peculiar smell, disinfection and sterilization;Aloe can absorb the nocuousness such as formaldehyde, carbon dioxide, sulfur dioxide, the nicotine in air well Substance, especially PARA FORMALDEHYDE PRILLS(91,95) have good absorption effect, and can also kill the aerial microorganism of floating, adsorb dust; Pomegranate leaf can purify the sulfur dioxide in air, reduce the lead content in air;Bracketplant and schefflera can will be in air The harmful substances such as carbon monoxide, hyponitric acid, nicotine, formaldehyde absorb and decompose the innocuous substances such as saccharogenesis and amino acid, and Duplicator can be decomposed, the benzene that printer is discharged, in addition, the volatile component in bracketplant has significant sterilizing function.
Further, the photochemical catalyst is nano-titanium dioxide.Nano-titanium dioxide itself has nontoxic feature, at present It is widely used in the industries such as cosmetics, suncream, food, it is extremely intimate with human contact, therefore, using nano-titanium dioxide As photochemical catalyst, nano-titanium dioxide will not be floated in the sky, cause dust pollution, will not influence human health.
Further, the aromatic be peppermint extracting solution, Jasmine extracting solution, lavender extracting solution, tea extract and The combination of one or more of Rosa Damascana.The addition of aromatic, can cover the smell of nano-titanium dioxide, and people can also Different fragrance is selected according to the hobby of oneself.
It is walked the present invention also provides a kind of for eliminating the preparation method of the spray of pollutants in air, including as follows It is rapid:
(1) preparation of plant extracts: taking the fresh sample of plant, is ground into juice after clean wash with distilled water, will After juice is dry, it is extracting solution with ethyl alcohol, obtains distillate by distillation, after distillate is concentrated, freeze-drying obtains plant Extract;
(2) by step (1) plant extracts and nano-titanium dioxide be added in 20% gelatin solution, be dispersed with stirring 5 DEG C are cooled to after uniformly immediately, gelatine microsphere is made hereinafter, being centrifuged;
(3) gelatine microsphere, aromatic, surfactant and the ethyl alcohol in step (2) are added in deionized water, stirring point It dissipates uniformly up to spray.
Plant extracts and nano-titanium dioxide are wrapped up with gelatin, gelatine microsphere is made, is then added in water and makes At spray, the rate of release of plant extracts and nano-titanium dioxide can be preferably controlled, when extending the effect of effective component Between, to improve the function of the purification air and disinfection of this spray.
Further, the plant extracts of the step (1) will be through pulverization process at nanometer grade powder, partial size 300- 400nm., can be preferably by gelatin coatings after plant extracts is ground into nanometer grade powder, dispersion effect is more preferable, while its grain The specific surface area of son increases, and the function and effect for purifying air are stronger.
Further, in the step (1) when distillation, 2% aqueous citric acid solution is added, the pH value for adjusting distillate is 3.5- 4.5。
In distillation, the pH value of distillate is controlled within the scope of 3.5-4.5, the effective component of plant can be made better It is dissolved in ethanol solution, improves the content of effective component in the plant extracts finally obtained.
Further, being dispersed with stirring in the step (2) and (3) is all made of water bath sonicator dispersion, bath temperature 50-60 ℃.Water bath sonicator dispersion can accelerate rate of dispersion, stir more uniform;By bath temperature control within the scope of 50-60 DEG C, it can make Gelatin is obtained preferably to dissolve.
Specific embodiment
It is further described below by specific embodiment:
Embodiment 1:
It is a kind of for eliminating the spray of pollutants in air, the ingredient including following parts by weight: 25 parts of ethyl alcohol, light are urged 5 parts of agent, 10 parts of plant extracts, 10 parts of gelatin, 5 parts of aromatic, 1 part of surfactant and 70 parts of deionized water.Wherein, it plants Object extract includes 2 parts of grass of taking drugs, 2 parts of aloe, 2 parts of pomegranate leaf, 2 parts of bracketplant and 2 parts of schefflera, and photochemical catalyst is nano-silica Change titanium, aromatic is Jasmine extracting solution.
The preparation method of the above-mentioned spray for eliminating pollutants in air includes the following steps:
(1) preparation of plant extracts: take take drugs grass, aloe, pomegranate leaf, bracketplant and schefflera plant fresh sample, Be ground into juice after clean wash with distilled water, by juice it is dry after, be extracting solution with ethyl alcohol, with 2% aqueous citric acid solution tune Section pH value is 3.5-4.5, obtains distillate by distillation, and after distillate is concentrated, freeze-drying obtains plant extracts, plant Extract is through pulverization process at nanometer grade powder, partial size 300nm;
(2) by step (1) plant extracts and nano-titanium dioxide be added in 20% gelatin solution, water bath sonicator Dispersion, bath temperature are 60 DEG C, are cooled to 0-5 DEG C (it is cooling that ice water can be used) after being dispersed with stirring uniformly immediately, centrifugation is made bright Glue microballoon;
(3) gelatine microsphere, aromatic, surfactant and the ethyl alcohol in step (2) are added in deionized water, stirring point It dissipates uniformly up to spray.
Embodiment 2:
It is a kind of for eliminating the spray of pollutants in air, the ingredient including following parts by weight: 30 parts of ethyl alcohol, light are urged 4 parts of agent, 8 parts of plant extracts, 7 parts of gelatin, 3 parts of aromatic, 0.8 part of surfactant and 60 parts of deionized water,.Wherein, Plant extracts includes 1 part of grass of taking drugs, 2 parts of aloe, 2 parts of pomegranate leaf, 2 parts of bracketplant and 1 part of schefflera, and photochemical catalyst is nanometer two Titanium oxide, aromatic are lavender extracting solution.
The preparation method of the above-mentioned spray for eliminating pollutants in air includes the following steps:
(1) preparation of plant extracts: take take drugs grass, aloe, pomegranate leaf, bracketplant and schefflera plant fresh sample, Be ground into juice after clean wash with distilled water, by juice it is dry after, be extracting solution with ethyl alcohol, with 2% aqueous citric acid solution tune Section pH value is 3.5-4.5, obtains distillate by distillation, and after distillate is concentrated, freeze-drying obtains plant extracts, plant Extract is through pulverization process at nanometer grade powder, partial size 400nm;
(2) by step (1) plant extracts and nano-titanium dioxide be added in 20% gelatin solution, water bath sonicator Dispersion, bath temperature are 55 DEG C, are cooled to 0-5 DEG C after being dispersed with stirring uniformly immediately, are centrifuged and gelatine microsphere is made;
(3) gelatine microsphere, aromatic, surfactant and the ethyl alcohol in step (2) are added in deionized water, stirring point It dissipates uniformly up to spray.
Embodiment 3:
It is a kind of for eliminating the spray of pollutants in air, the ingredient including following parts by weight: 20 parts of ethyl alcohol, light are urged 2 parts of agent, 5 parts of plant extracts, 5 parts of gelatin, 2 parts of aromatic, 0.5 part of surfactant and 50 parts of deionized water.Wherein, it plants Object extract includes 1 part of grass of taking drugs, 1 part of aloe, 1 part of pomegranate leaf, 1 part of bracketplant and 1 part of schefflera, and photochemical catalyst is nano-silica Change titanium, aromatic is Rosa Damascana.
The preparation method of the above-mentioned spray for eliminating pollutants in air includes the following steps:
(1) preparation of plant extracts: take take drugs grass, aloe, pomegranate leaf, bracketplant and schefflera plant fresh sample, Be ground into juice after clean wash with distilled water, by juice it is dry after, be extracting solution with ethyl alcohol, with 2% aqueous citric acid solution tune Section pH value is 3.5-4.5, obtains distillate by distillation, and after distillate is concentrated, freeze-drying obtains plant extracts, plant Extract is through pulverization process at nanometer grade powder, partial size 350nm;
(2) by step (1) plant extracts and nano-titanium dioxide be added in 20% gelatin solution, water bath sonicator Dispersion, bath temperature are 50 DEG C, are cooled to 0-5 DEG C after being dispersed with stirring uniformly immediately, are centrifuged and gelatine microsphere is made;
(3) gelatine microsphere, aromatic, surfactant and the ethyl alcohol in step (2) are added in deionized water, stirring point It dissipates uniformly up to spray.
Comparative example 1:
This comparative example the difference from embodiment 1 is that: in this comparative example do not contain nano-titanium dioxide.
Comparative example 2:
This comparative example the difference from embodiment 1 is that: in this comparative example do not contain plant extracts.
Test:
At one in newly-decorated house, formaldehyde, benzene,toluene,xylene, TVOC etc. five is carried out to the new decorating house Pollutant Indexs measure finds wherein formaldehyde and TVOC two referring to GB/T18883-2002 (national Indoor Air Quality standards) Item index exceeding standard most serious, formaldehyde 0.9mg/m3, TVOC 2.5mg/m3.It will be in 1-3 of the embodiment of the present invention and comparative example 1-2 Homemade spray, by 2g/m3Fountain height, apply (each room in 5 different rooms of the new decorating house respectively The finishing time it is the same, the difference in room will not impact testing result), it is then right after different time sections after use The amount of formaldehyde and TVOC are detected, and testing result is as shown in table 1 below.
To guarantee to be relatively isolated from sealing between each room tested during the test.
Testing result (the unit: mg/m of table 1 embodiment 1-3 and comparative example 1-23)
Conclusion:
The data as described in table 1 analyze the spray it is found that compared to the spray in comparative example 1-2, in embodiment 1-3 There is the removal effect become apparent to formaldehyde in air and TVOC, after use after 3 days, the content of formaldehyde in room air is low In 0.1mg/m3, the content of TVOC is lower than 0.6mg/m3, meet the regulation in national Indoor Air Quality standards, reaching can live Environment.
What has been described above is only an embodiment of the present invention, and the common sense such as well known characteristic do not describe excessively herein in scheme. It should be pointed out that for those skilled in the art, without departing from the structure of the invention, several changes can also be made Shape and improvement, these also should be considered as protection scope of the present invention, these all will not influence the effect and patent that the present invention is implemented Practicability.

Claims (8)

1. a kind of for eliminating the spray of pollutants in air, it is characterised in that: the ingredient including following parts by weight: ethyl alcohol 20-30 parts, 2-5 parts of photochemical catalyst, 5-10 parts of plant extracts, 5-10 parts of gelatin, 2-5 parts of aromatic, surfactant 0.5-1 Part and deionized water 50-70 parts.
2. according to claim 1 a kind of for eliminating the spray of pollutants in air, it is characterised in that: the plant Extract includes 1-2 parts of grass of taking drugs, 1-2 parts of aloe, 1-2 parts of pomegranate leaf, 1-2 parts of bracketplant and 1-2 parts of schefflera.
3. according to claim 2 a kind of for eliminating the spray of pollutants in air, it is characterised in that: the light is urged Agent is nano-titanium dioxide.
4. according to claim 3 a kind of for eliminating the spray of pollutants in air, it is characterised in that: the fragrance Agent is one or more of peppermint extracting solution, Jasmine extracting solution, lavender extracting solution, tea extract and Rosa Damascana Combination.
5. a kind of for eliminating the spray of pollutants in air described in any one of -4 according to claim 1, feature exists In: preparation method includes the following steps:
(1) preparation of plant extracts: taking the fresh sample of plant, juice is ground into after clean wash with distilled water, by juice It is extracting solution with ethyl alcohol after drying, obtains distillate by distillation, after distillate is concentrated, freeze-drying obtains plant extract Object;
(2) by step (1) plant extracts and nano-titanium dioxide be added in 20% gelatin solution, be dispersed with stirring uniformly It is cooled to 5 DEG C immediately afterwards and gelatine microsphere is made hereinafter, being centrifuged;
(3) gelatine microsphere, aromatic, surfactant and the ethyl alcohol in step (2) are added in deionized water, are dispersed with stirring Even spray to obtain the final product.
6. according to claim 5 a kind of for eliminating the spray of pollutants in air, it is characterised in that: the step (1) plant extracts will be through pulverization process, partial size 300-400nm.
7. according to claim 6 a kind of for eliminating the spray of pollutants in air, it is characterised in that: the step (1) in when distillation, 2% aqueous citric acid solution is added, the pH value for adjusting distillate is 3.5-4.5.
8. according to claim 7 a kind of for eliminating the spray of pollutants in air, it is characterised in that: the step (2) being dispersed with stirring and in (3) is all made of water bath sonicator dispersion, and bath temperature is 50-60 DEG C.
CN201910101697.4A 2019-01-31 2019-01-31 It is a kind of for eliminating the spray of pollutants in air Pending CN109745856A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910101697.4A CN109745856A (en) 2019-01-31 2019-01-31 It is a kind of for eliminating the spray of pollutants in air

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910101697.4A CN109745856A (en) 2019-01-31 2019-01-31 It is a kind of for eliminating the spray of pollutants in air

Publications (1)

Publication Number Publication Date
CN109745856A true CN109745856A (en) 2019-05-14

Family

ID=66407241

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910101697.4A Pending CN109745856A (en) 2019-01-31 2019-01-31 It is a kind of for eliminating the spray of pollutants in air

Country Status (1)

Country Link
CN (1) CN109745856A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110496509A (en) * 2019-08-29 2019-11-26 浙江九片田科技有限公司 A kind of manufacture craft of high-efficiency formaldehyde scavenging agent
CN111659253A (en) * 2020-05-14 2020-09-15 广东中检检测技术有限公司 Photocatalytic aerosol spray for vehicle

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005245766A (en) * 2004-03-04 2005-09-15 Uchu Kankyo Hozen Center:Kk Composition, deodorization material using the same, antibacterial material, coating material, feed additive
CN101642582A (en) * 2009-08-27 2010-02-10 浙江富来森炭材料有限公司 Material with multi-functional long-acting slow-release effective components
CN105056274A (en) * 2015-08-31 2015-11-18 保护伞环保科技成都有限公司 Method for preparing air freshener
CN105251341A (en) * 2015-11-10 2016-01-20 南京润中生物技术有限公司 Air purification spray for removing indoor fitment pollution and preparation method thereof
CN107511059A (en) * 2017-09-22 2017-12-26 太仓弘杉环保科技有限公司 A kind of nano titanium oxide herb extract aldehyde remover
CN107821458A (en) * 2017-10-30 2018-03-23 胡国剑 It is a kind of except air-atomizing agent of formaldehyde and preparation method thereof
CN107865975A (en) * 2017-09-01 2018-04-03 南通香佳纺织科技有限公司 Microcapsules room air freshener that a kind of pinke needle oil compounds with Lavender and preparation method thereof
CN108786442A (en) * 2018-06-10 2018-11-13 杭州传扬环保科技有限公司 A kind of jet printing type environmental protection formaldehyde purifying agent and preparation method thereof

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005245766A (en) * 2004-03-04 2005-09-15 Uchu Kankyo Hozen Center:Kk Composition, deodorization material using the same, antibacterial material, coating material, feed additive
CN101642582A (en) * 2009-08-27 2010-02-10 浙江富来森炭材料有限公司 Material with multi-functional long-acting slow-release effective components
CN105056274A (en) * 2015-08-31 2015-11-18 保护伞环保科技成都有限公司 Method for preparing air freshener
CN105251341A (en) * 2015-11-10 2016-01-20 南京润中生物技术有限公司 Air purification spray for removing indoor fitment pollution and preparation method thereof
CN107865975A (en) * 2017-09-01 2018-04-03 南通香佳纺织科技有限公司 Microcapsules room air freshener that a kind of pinke needle oil compounds with Lavender and preparation method thereof
CN107511059A (en) * 2017-09-22 2017-12-26 太仓弘杉环保科技有限公司 A kind of nano titanium oxide herb extract aldehyde remover
CN107821458A (en) * 2017-10-30 2018-03-23 胡国剑 It is a kind of except air-atomizing agent of formaldehyde and preparation method thereof
CN108786442A (en) * 2018-06-10 2018-11-13 杭州传扬环保科技有限公司 A kind of jet printing type environmental protection formaldehyde purifying agent and preparation method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
慢生活工坊: "《空气净化植物栽培》", 30 April 2015, 福建科学技术出版社 *
绀户朝冶著: "《微胶囊化工艺学》", 30 June 1989, 轻工业出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110496509A (en) * 2019-08-29 2019-11-26 浙江九片田科技有限公司 A kind of manufacture craft of high-efficiency formaldehyde scavenging agent
CN111659253A (en) * 2020-05-14 2020-09-15 广东中检检测技术有限公司 Photocatalytic aerosol spray for vehicle

Similar Documents

Publication Publication Date Title
CN105435280B (en) A kind of preparation method of high-efficiency plant deodorant
CN110327763A (en) Environmentally-frieindoor indoor air cleanser
CN108465121A (en) A kind of plant essence extracting solution eliminating smell agent and preparation method thereof
CN113057184A (en) Composite plant liquid deodorant and preparation method thereof
CN104189934A (en) Chemical type deodorant for waste transfer station and preparation method thereof
CN108771961B (en) Biological enzyme formaldehyde removing agent and application thereof
CN107486005A (en) A kind of indoor formaldehyde odor scavenging agent
CN112107984A (en) Plant type sterilization deodorant and preparation method thereof
CN110876811A (en) Water-soluble plant extract deodorant and preparation method thereof
CN108144417A (en) Multiple-effect, environmentally-friendly eliminating smell agent and preparation method and application
CN109745856A (en) It is a kind of for eliminating the spray of pollutants in air
CN109091696A (en) A kind of plant type air freshener and preparation method thereof
CN106922752B (en) Air disinfectant and preparation method thereof
CN103623679B (en) Anion air purifying preparation
CN107648980A (en) A kind of method of environmental purifying agent and Environment control
KR102227273B1 (en) Car cleaning composition containing graphene with enhanced cleaning and coating functions
CN109569245A (en) A kind of natural plant environment-friendly deodorant agent and preparation method thereof
CN105727718B (en) In-vehicle exposure scavenger
CN112844004A (en) Spray type air purifying agent and preparation method thereof
CN115043723A (en) Application of zinc itaconate and preparation process of zinc itaconate-containing deodorant
KR20040021077A (en) A composite of paint having multi-function
CN108854424A (en) A kind of composition capable of purifying air
CN104857843A (en) Biological enzyme air purifying agent, preparation method and application thereof
CN107158442A (en) Standby air freshener of a kind of utilization swamp mahogany leather and preparation method thereof
CN105412967A (en) Novel plant deodorant

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20190514