CN102146257B - Formaldehyde-resistance odor-removing total-effect environmental-friendly water-borne wood white paint and preparation technology thereof - Google Patents
Formaldehyde-resistance odor-removing total-effect environmental-friendly water-borne wood white paint and preparation technology thereof Download PDFInfo
- Publication number
- CN102146257B CN102146257B CN 201110123392 CN201110123392A CN102146257B CN 102146257 B CN102146257 B CN 102146257B CN 201110123392 CN201110123392 CN 201110123392 CN 201110123392 A CN201110123392 A CN 201110123392A CN 102146257 B CN102146257 B CN 102146257B
- Authority
- CN
- China
- Prior art keywords
- white paint
- percent
- formaldehyde
- agent
- emulsion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses a formaldehyde-resistance odor-removing total-effect environmental-friendly waterborne wood white paint and a preparation technology thereof. The wood white paint comprises the following components in percentage: 25 to 30 percent of formaldehyde removing emulsion, 10 to 15 percent of core-shell pure acrylic acid emulsion and polyurethane modified acrylic acid emulsion, 3 to 5 percent of bamboo carbon powder, 1 to 3 percent of nano TiO2 photocatalyst, 15 to 25 percent of calcium carbonate and pigment and filler, 0.1 to 0.3 percent of delustering powder, 0.1 to 0.2 percent of antifoaming agent, 0.5 to 1.5 percent of dispersing agent, 0.2 to 0.5 percent of anti-sedimentation agent and 18 to 38 percent of water and auxiliaries. The preparation technology comprises the following steps of: firstly adding the core-shell pure acrylic acid emulsion and the polyurethane modified acrylic acid emulsion into a dispersing cylinder and dispersing at an intermediate speed; then uniformly adding micron active bamboo carbon powder; after dispersing for 15 to 30 minutes at a high speed, adding the formaldehyde removing emulsion, scratch resistance wax additive, the water, the dispersing agent, the delustering agent, the antifoaming agent, the anti-sedimentation agent and other components; after dispersing for 40 minutes at an intermediate speed, sampling and detecting the fineness and the viscosity of a finished product; and carrying out filtering, canning and packaging on the finished product.
Description
Technical field
The present invention relates to a kind of aqueous wooden ware white paint; The present invention be more particularly directed to the environment-friendly water-based woodenware white paint of a kind of anti-formaldehyde smell-clearing full-effective, the invention still further relates to the preparation method of the environment-friendly water-based woodenware white paint of a kind of this anti-formaldehyde smell-clearing full-effective.
Background technology
The woodwork coating of domestic existing main flow mainly comprises following several, polyurethane woodware coating (PU), acid cure alkyd amino woodwork coating (Acidcuring), nitrocellulose woodenware coating (NC), UV solidified carpentry coating (UV), water-borne coatings (Waterborne) and several big classifications of polyester woodwork coating (PE).Wherein the polyurethane coating ratio is the highest, next is nitro, UV, alkyd, water-based and polyester lacquer successively.In furniture woodwork coating field, pyroxylin(e)finish is being replaced by water-borne coatings gradually.Water-based system will concentrate on the vinylformic acid single-component.In UV and the dual-component polyurethane.At furniture exporter face, China's policies and regulations do not stipulate clearly that wood furniture can not use solvent based coating at present, but the U.S., European Union and Japan have all put into effect the relevant laws and regulations that limit and ban use of the solvent-borne type woodwork coating.
The solvent-borne type woodwork coating in use owing to the release of organic substance, has brought Health hazard for wood furniture producer and user.
Summary of the invention
The objective of the invention is in order to overcome weak point of the prior art, provide a kind of prescription simple, can effectively anti-formaldehyde, the environment-friendly water-based woodenware white paint of full effect of clean flavor.
Another object of the present invention provides the preparation method of the environment-friendly water-based woodenware white paint of a kind of this anti-formaldehyde smell-clearing full-effective.
In order to achieve the above object, the present invention adopts following scheme:
The environment-friendly water-based woodenware white paint of a kind of anti-formaldehyde smell-clearing full-effective is characterized in that percentage composition is composed of the following components by weight:
The environment-friendly water-based woodenware white paint of aforesaid a kind of anti-formaldehyde smell-clearing full-effective, it is characterized in that described color stuffing by weight percentage composition comprise the filler of 10-15% pigment and 2-5%.
Wherein said pigment can be shades of colours such as Pigment white, Pigment blue, Pigment Yellow 73, Pigment green.Can be independent a kind of, also can be the mixture of multiple pigment.
The environment-friendly water-based woodenware white paint of aforesaid a kind of anti-formaldehyde smell-clearing full-effective is characterized in that described filler is SiO
2
The environment-friendly water-based woodenware white paint of aforesaid a kind of anti-formaldehyde smell-clearing full-effective is characterized in that described defoamer is the water-based high effective antifoaming agent.The water-based high effective antifoaming agent that described water-based high effective antifoaming agent is model AC-900 is organic-silicon-modified compound defoamer.Belong to the commercially available prod.
The environment-friendly water-based woodenware white paint of aforesaid a kind of anti-formaldehyde smell-clearing full-effective is characterized in that described flatting silica is diatomite.Described diatomaceous characteristic: have characteristics such as porosity is big, absorptivity is strong, chemical property is stable, wear-resisting, heat-resisting, can provide excellent surface property for coating, increase-volume, thickening and raising sticking power.Control film coated surface gloss that can be balanced increases wear resistance and the mar-resistance of filming, and dries, deodorizing and can also purify air sound insulation, waterproof and characteristics heat insulation, that permeability is good.
The environment-friendly water-based woodenware white paint of aforesaid a kind of anti-formaldehyde smell-clearing full-effective is characterized in that described anti-settling agent is polyamide wax.
The environment-friendly water-based woodenware white paint of aforesaid a kind of anti-formaldehyde smell-clearing full-effective is characterized in that described auxiliary agent is siccative, tensio-active agent, auxiliary rheological agents, film coalescence aid, the mixture more than 4 kinds in the mould inhibitor.
The environment-friendly water-based woodenware white paint of aforesaid a kind of anti-formaldehyde smell-clearing full-effective is characterized in that described siccative is dibutyl tin laurate, and its content is 0.03-0.08%; Described tensio-active agent is that its content of fluorocarbon surfactant is 0.02-0.5%; Described auxiliary rheological agents is that its content of tributyl phosphate is 0.6-0.9%; Described film coalescence aid is 0.8-1.5% for Yi Bingchunan content; Described mould inhibitor is that its content of 3-iodo-2 propargyl butyl carbamates is 0.1-0.3%; Described active film coalescence aid is vinylformic acid double cyclopentenyl oxygen ethyl ester, and its content is 1-5%; Wherein said content is weight percentage.
The preparation method of the environment-friendly water-based woodenware white paint of the anti-formaldehyde smell-clearing full-effective of the present invention is characterized in that comprising following processing step:
At first in disperseing cylinder, add nucleocapsid pure acrylic acid emulsion and polyurethane-modified acrylic acid emulsion and carry out the middling speed dispersion, evenly sneak into bamboo charcoal powder afterwards, after high speed dispersion 15-30 minute, add aldehydes removal emulsion and scratch resistance wax assistant, water, dispersion agent, flatting silica, defoamer, anti-settling agent and other component, middling speed was disperseed after 40 minutes, and sampling detects finish fineness and viscosity, filtered, tinning, packing.
Aforesaid preparation method is characterized in that the speed that described middling speed is disperseed is 600-800r/min; The speed of described high speed dispersion is 1000-1500r/min.
Aforesaid preparation method is characterized in that described finish fineness is 35-50 μ m, and described finished product viscosity is 30-60mm
2/ s.
Dispersion agent described in the present invention is Henkel KGaA 5040 dispersion agents, has good thermotolerance, mutual solubility, efficient height, and stable viscosity prevents the coating precipitation, coagulates wadding.Keep good, nontoxic, the no burn into of glossiness not have special odor.
Aldehydes removal emulsion described in the present invention is LG-DOW chemical industry 3030 emulsions.Have superpower aldehydes removal effect, can effectively decompose formaldehyde in the coating.
Bamboo charcoal powder described in the present invention is specification: (1000 ~ 4000 order) is many as coating class Industrial products raw material.Because the specific surface area of bamboo charcoal increases by geometric progression after the super-fine processing, specific functions such as the absorption of bamboo charcoal, decomposition are also strengthened synchronously.
In the present invention's prescription:
1. preferred water-based aldehydes removal emulsion and high-performance emulsion binder system
The selection PARA FORMALDEHYDE PRILLS(91,95) has adsorption and can carry out formulating of recipe with the emulsion of formaldehyde generation irreversible chemical reaction.The surface of formaldehyde reaction emulsion or inner residual a large amount of active groups (as amino, carboxyl, epoxy group(ing) etc., all can with formaldehyde generation irreversible chemical reaction).Formaldehyde reaction emulsion and ordinary emulsion all have the ability of certain elimination formaldehyde in indoor air.The mechanism that ordinary emulsion is eliminated formaldehyde is the adsorption of emulsion film PARA FORMALDEHYDE PRILLS(91,95), and this effect is reversible; And reactive emulsion has the elimination formaldehyde ability more much better than than ordinary emulsion.
The water-borne wood coating system of present domestic formation is mainly based on the pure acrylic acid emulsion, the cold assembly emulsion of modified acrylic acid-polyurethane, binder systems for use such as urethane synthesis modification ACRYLIC EMULSION and polyurethane dispersions.Each binder systems for use has outstanding merits and demerits.Based on the extensive collection to emulsion binder system market information and sample, the highly sophisticated products that compile advantage emulsion both domestic and external manufacturing enterprise, experimental design method and Recipe optimization by the advanced person, every performance of comprehensive assessment product, and is analyzed contrast and screened, therefrom optimize binder systems for use and the sample of several optimums, for the further composite test of test mixing provides concrete advantage base-material sample.
2. mix composite high-performance emulsion binder system and reach maximum synergistic effect
Selection and collocation blend to present binder systems for use, form the base-material compound system, obtain synergistic effect, not only make the relative merits of different binder systems for use reach the effect that remedies mutually, obtain breaking through in some performances simultaneously, reach a performance on the equal base-material technical foundation and break through.The polyurethane-modified acrylic acid binder systems for use that body series is selected for use will select for use the aliphatic polyurethane modified acroleic acid as a basic base-material, the composite pure acrylic acid emulsion system of going up, give full play to the advantage of the outstanding chemical resistance of the outstanding mechanical mechanics property of aliphatic polyurethane system, anti-yellowing property and vinylformic acid system, by the DOE experiment research of science, determine compound proportion, component concentration and the Recipe optimized the most.Its outstanding discovery is, not only allow two individual system reach the synergistic effect of a mutual supplement with each other's advantages, remedied weak tendency and shortcoming separately simultaneously, thereby when allowing the chemical-resistant of paint film and antiblocking effect satisfy the basic demand of industry standard, its mechanical property, anti-yellowing property etc. all rise to a higher aspect.
3. creatively introduce the clean aldehyde of the bamboo charcoal component of distinguishing the flavor of only, the optimization of C system reaches clean flavor effect
There is microvoid structure in bamboo charcoal, has greater porosity (macrovoid, mesopore and micropore) and high-specific surface area, and obnoxious flavoures such as PARA FORMALDEHYDE PRILLS(91,95), volatile solvent have good physical absorption effect, and the application in coating is more and more.Certainly, physisorption has certain limitation, mainly shows two aspects: the one, there is saturation ratio, and the 2nd, adsorptive power is relevant with temperature.Therefore, removing obnoxious flavoures such as formaldehyde in the room air and volatile solvent by physical adsorption, is practical, effective scheme to a certain extent.
The emulsion building-up process has been used various latex resist technologies, and the difference of technology causes the difference of combined coefficient simultaneously, has often seen in some tastes greatly even has had irritating auxiliary agent and monomer, and the smell of base-material emulsion is comparatively stimulated; After being made into the coating finished product, still long-term release of taste makes the human consumer be difficult to accept.By with supplier's cooperative development, avoid in the base-material raw material, adding the composition that contains irritating smell, simultaneously by adjusting process with improve combined coefficient, by adopting additional process to reduce the residual quantity of the free monomer in the finished product, the smell of finished product reaches minimum the most at last.On the basis of this advantage emulsion, by adding preferred low smell, zero VOC(organic volatile component) coating composition, make finished product have irritating smell because adding the auxiliary agent of a large amount of stimulation tastes in avoiding filling a prescription.In order to reach the minimum technical requirements of product odour, replacement has also been cancelled some conventional paint additives, and adopted the clean flavor technical formula platform of our company's uniqueness, jumped out traditional formula system framework, make storage and the stability of formula for a product be subjected to great challenge, but also make the smell of product absolutely arrive clean flavor requirement.
4. add special auxiliary agent, improve the surperficial scratch resistance effect of water-miscible paint
The more solvent type coating of compactness of the dried paint film of water-borne wood coating low, cause the surperficial scratch resistance effect of paint film generally on the low side, usually stay together significantly scar because some shaggy hard objects streak fast at smooth coating surface easily in use, thereby destroyed the aesthetic feeling of coating surface.This prescription is when composite emulsion basis makes paint film reach the physical and chemical performance an of the best, add a kind of special scratch resistance auxiliary agent, thereby the resistance to marring of coating surface is improved greatly, the scratch resistance effect can match in excellence or beauty with solvent-borne type paint film effect, has improved the durable effect of water-borne wood coating greatly.
In sum, beneficial effect of the present invention:
1. the present invention adopts up-to-date preparation method for coating and advanced water-base resin system, added the natural radioactivity bamboo charcoal factor, the formaldehyde that energy active adsorption and decomposition chamber inner decoration material discharge, purify various volatile injurant matter such as benzene class, ester class, ketone, can build the lasting pure and fresh living environment of air, can not produce irritating smell after construction process or construction, household's health redoubles one's care.This aqueous wooden ware white paint paint film is plentiful, strong covering power; Its priming paint has good filling properties and sanding property energy, and finish paint has excellent scratch resistance and anti-yellowing property.
2. product of the present invention adopts clean flavor paint technology, has reduced in the Lacquered Tin Plate Can and the amount of the pungency volatile matter of construction process, and the VOC of product reduces greatly simultaneously.The TVOC of white paint product is reduced to 150g/L, is significantly less than the 250g/L that HJ/T201-2005 requires.The environmental-protecting performance of high-performance water-based woodwork coating has been given prominence in the raising of these performances more.
3. product of the present invention is by advantage latex composite compounding technology, remedied traditional defective that contains the alkali resistance difference of urethane composition, improved the chemical resistance of paint film, complete every chemicals-resistant test that requires by HG/T3828-2006 makes the use of this product have the advantage of weather resistance more.
4. to carry out technology by the base-material that screens various advantage technologies composite in the present invention, given play to synergy, improve the mechanical property of paint film greatly, the wear resistance loss of white paint product is not more than 0.022g(750g/500r), be lower than the standard of the 0.030g that sets among the HG/T3828-2006, this standard is the standard of indoor solvent-borne type woodwork coating equally.
5. product satisfies industry standard: HG/T3828-2006 " indoor water-borne wood coating " industry standard.Meet environmental protection standard " environmental labelling product technical requirements: water-borne coatings " HJ/T201-2005.
6. the effective volatile injurant matter in the decontamination chamber of product of the present invention.Has excellent scratch resistance performance.Paint film is plentiful.Has excellent anti-yellowing property.
Embodiment
Below in conjunction with embodiment the present invention is described further:
Embodiment 1
The environment-friendly water-based woodenware white paint of the preparation anti-formaldehyde smell-clearing full-effective of 100kg the present invention, composed of the following components:
At first in disperseing cylinder, add nucleocapsid pure acrylic acid emulsion and polyurethane-modified acrylic acid emulsion and carry out the middling speed dispersion, the speed that wherein said middling speed is decomposed is 600-800r/min, evenly sneak into micron order active bamboo powder afterwards, high speed dispersion 15-30 minute, the speed of wherein said high speed dispersion is 1000-1500r/min, add aldehydes removal emulsion and scratch resistance wax assistant, water, dispersion agent, matting agent, defoamer, anti-settling agent and other component, middling speed was disperseed after 40 minutes, sampling detects finish fineness and viscosity, if finish fineness reaches 35-50 μ m, viscosity is 30-60mm
2Be salable product during/s, filter then, tinning, packing.
Embodiment 2
The environment-friendly water-based woodenware white paint of the preparation anti-formaldehyde smell-clearing full-effective of 100kg the present invention, composed of the following components:
At first in disperseing cylinder, add nucleocapsid pure acrylic acid emulsion and polyurethane-modified acrylic acid emulsion and carry out the middling speed dispersion, the speed that wherein said middling speed is decomposed is 600-800r/min, evenly sneak into micron order active bamboo powder afterwards, high speed dispersion 15-30 minute, the speed of wherein said high speed dispersion is 1000-1500r/min, add aldehydes removal emulsion and scratch resistance wax assistant, water, dispersion agent, matting agent, defoamer, anti-settling agent and other component, middling speed was disperseed after 40 minutes, sampling detects finish fineness and viscosity, if finish fineness reaches 35-50 μ m, viscosity is 30-60mm
2Be salable product during/s, filter then, tinning, packing.
Embodiment 3
The environment-friendly water-based woodenware white paint of the preparation anti-formaldehyde smell-clearing full-effective of 100kg the present invention, composed of the following components:
At first in disperseing cylinder, add nucleocapsid pure acrylic acid emulsion and polyurethane-modified acrylic acid emulsion and carry out the middling speed dispersion, the speed that wherein said middling speed is decomposed is 600-800r/min, evenly sneak into micron order active bamboo powder afterwards, high speed dispersion 15-30 minute, the speed of wherein said high speed dispersion is 1000-1500r/min, add aldehydes removal emulsion and scratch resistance wax assistant, water, dispersion agent, matting agent, defoamer, anti-settling agent and other component, middling speed was disperseed after 40 minutes, sampling detects finish fineness and viscosity, if finish fineness reaches 35-50 μ m, viscosity is 30-60mm
2Be salable product during/s, filter then, tinning, packing.
Embodiment 4
The environment-friendly water-based woodenware white paint of the preparation anti-formaldehyde smell-clearing full-effective of 100kg the present invention, composed of the following components:
At first in disperseing cylinder, add nucleocapsid pure acrylic acid emulsion and polyurethane-modified acrylic acid emulsion and carry out the middling speed dispersion, the speed that wherein said middling speed is decomposed is 600-800r/min, evenly sneak into micron order active bamboo powder afterwards, high speed dispersion 15-30 minute, the speed of wherein said high speed dispersion is 1000-1500r/min, add aldehydes removal emulsion and scratch resistance wax assistant, water, dispersion agent, matting agent, defoamer, anti-settling agent and other component, middling speed was disperseed after 40 minutes, sampling detects finish fineness and viscosity, if finish fineness reaches 35-50 μ m, viscosity is 30-60mm
2Be salable product during/s, filter then, tinning, packing.
Embodiment 5
The environment-friendly water-based woodenware white paint of the preparation anti-formaldehyde smell-clearing full-effective of 100kg the present invention, composed of the following components:
At first in disperseing cylinder, add nucleocapsid pure acrylic acid emulsion and polyurethane-modified acrylic acid emulsion and carry out the middling speed dispersion, the speed that wherein said middling speed is decomposed is 600-800r/min, evenly sneak into micron order active bamboo powder afterwards, high speed dispersion 15-30 minute, the speed of wherein said high speed dispersion is 1000-1500r/min, add aldehydes removal emulsion and scratch resistance wax assistant, water, dispersion agent, matting agent, defoamer, anti-settling agent and other component, middling speed was disperseed after 40 minutes, sampling detects finish fineness and viscosity, if finish fineness reaches 35-50 μ m, viscosity is 30-60mm
2Be salable product during/s, filter then, tinning, packing.
Claims (9)
1. environment-friendly water-based woodenware white paint of anti-formaldehyde smell-clearing full-effective is characterized in that percentage composition is composed of the following components by weight:
Wherein said aldehydes removal emulsion is LG-DOW chemical industry 3030 emulsions.
2. the environment-friendly water-based woodenware white paint of a kind of anti-formaldehyde smell-clearing full-effective according to claim 1, it is characterized in that described color stuffing by weight percentage composition comprise the filler of 10-15% pigment and 2-5%.
3. the environment-friendly water-based woodenware white paint of a kind of anti-formaldehyde smell-clearing full-effective according to claim 2 is characterized in that described filler is SiO
2
4. the environment-friendly water-based woodenware white paint of a kind of anti-formaldehyde smell-clearing full-effective according to claim 1 is characterized in that described flatting silica is diatomite.
5. the environment-friendly water-based woodenware white paint of a kind of anti-formaldehyde smell-clearing full-effective according to claim 1 is characterized in that described anti-settling agent is polyamide wax.
6. the environment-friendly water-based woodenware white paint of a kind of anti-formaldehyde smell-clearing full-effective according to claim 1 is characterized in that described auxiliary agent is siccative, tensio-active agent, auxiliary rheological agents, the mixture in film coalescence aid or the mould inhibitor more than 4 kinds.
7. the environment-friendly water-based woodenware white paint of a kind of anti-formaldehyde smell-clearing full-effective according to claim 6 is characterized in that described siccative is dibutyl tin laurate, and its content is 0.03-0.08%; Described tensio-active agent is that its content of fluorocarbon surfactant is 0.02-0.5%; Described auxiliary rheological agents is that its content of tributyl phosphate is 0.6-0.9%; Described film coalescence aid is 0.8-1.5% for Yi Bingchunan content; Described mould inhibitor is that its content of 3-iodo-2 propargyl butyl carbamates is 0.1-0.3%; Wherein said content is weight percentage.
8. the preparation method of the environment-friendly water-based woodenware white paint of any anti-formaldehyde smell-clearing full-effective of claim 1 to 7 is characterized in that comprising following processing step:
At first in disperseing cylinder, add nucleocapsid pure acrylic acid emulsion and polyurethane-modified acrylic acid emulsion and carry out the middling speed dispersion, evenly sneak into bamboo charcoal powder afterwards, after high speed dispersion 15-30 minute, add aldehydes removal emulsion, water, dispersion agent, flatting silica, defoamer, anti-settling agent and other component, middling speed was disperseed after 40 minutes, and sampling detects finish fineness and viscosity, filter, tinning, packing, the speed that described middling speed is disperseed is 600-800r/min; The speed of described high speed dispersion is 1000-1500r/min.
9. preparation method according to claim 8 is characterized in that described finish fineness is 35-50 μ m, and described finished product viscosity is 30-60mm
2/ s.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110123392 CN102146257B (en) | 2011-05-13 | 2011-05-13 | Formaldehyde-resistance odor-removing total-effect environmental-friendly water-borne wood white paint and preparation technology thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110123392 CN102146257B (en) | 2011-05-13 | 2011-05-13 | Formaldehyde-resistance odor-removing total-effect environmental-friendly water-borne wood white paint and preparation technology thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102146257A CN102146257A (en) | 2011-08-10 |
| CN102146257B true CN102146257B (en) | 2013-08-21 |
Family
ID=44420738
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110123392 Expired - Fee Related CN102146257B (en) | 2011-05-13 | 2011-05-13 | Formaldehyde-resistance odor-removing total-effect environmental-friendly water-borne wood white paint and preparation technology thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102146257B (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104817961B (en) * | 2014-05-16 | 2017-04-05 | 紫荆花涂料（上海）有限公司 | A kind of anti-formaldehyde aqueous wooden ware bottom surface unification varnish and its compound method |
| CN104030604B (en) * | 2014-06-26 | 2016-03-30 | 中山蓝海洋水性涂料有限公司 | True mineral varnish of a kind of weather-proof anti-soil of environment-friendly type and preparation method thereof |
| CN105400258B (en) * | 2015-12-28 | 2018-03-23 | 河北晨阳工贸集团有限公司 | A kind of heat preservation environment protection woodcare paint |
| CN107201129B (en) * | 2016-05-20 | 2019-08-27 | 南京长江涂料有限公司 | A kind of room-temperature self crosslinking type PUA-SiO2Hybridisation emulsion and preparation method thereof |
| CN107779081A (en) * | 2017-11-22 | 2018-03-09 | 广西超盛网络科技有限责任公司 | A kind of special-purpose aqueous coating of wood furniture |
| CN108219559A (en) * | 2017-12-26 | 2018-06-29 | 深圳光天建材有限公司 | Multi-functional environment-protection water nano diatom ooze and preparation method thereof |
| CN108219614A (en) * | 2018-01-05 | 2018-06-29 | 吕跃文 | Aqueous one-component negative oxygen ion woodware white paint and preparation method thereof |
| CN109929435A (en) * | 2019-03-21 | 2019-06-25 | 苏州蓝沃奇纳米科技有限公司 | Plant is self-cleaning to remove aldehyde Essence, preparation method and self-cleaning coat |
| CN111073515B (en) * | 2019-12-25 | 2021-07-23 | 广东伊思曼新材料科技股份有限公司 | Plant-based water-based art paint and preparation method thereof |
| CN111849329B (en) * | 2020-07-10 | 2021-11-02 | 东南大学 | In-situ-regulated water-based super-amphiphobic coating and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101993655A (en) * | 2010-10-28 | 2011-03-30 | 华南理工大学 | Ultraviolet cured waterborne wood lacquer and preparation method thereof |
| CN102002310A (en) * | 2009-09-03 | 2011-04-06 | 澳达树熊涂料(惠州)有限公司 | High-adaptability environment-friendly water-borne wood coating |
-
2011
- 2011-05-13 CN CN 201110123392 patent/CN102146257B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102002310A (en) * | 2009-09-03 | 2011-04-06 | 澳达树熊涂料(惠州)有限公司 | High-adaptability environment-friendly water-borne wood coating |
| CN101993655A (en) * | 2010-10-28 | 2011-03-30 | 华南理工大学 | Ultraviolet cured waterborne wood lacquer and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 张旭,刘蔽蔽,王代民.净醛内墙乳胶漆的研制.《上海建材》.2009,(第1期),第18-19页. * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102146257A (en) | 2011-08-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102146257B (en) | Formaldehyde-resistance odor-removing total-effect environmental-friendly water-borne wood white paint and preparation technology thereof | |
| CN102146255B (en) | Formaldehyde-resistance odor-removing total-effect environmental-friendly waterborne wood varnish and preparation technology thereof | |
| CN102676035B (en) | High-glossiness, scratch-resistant, wear-resistant and environment-friendly waterborne wood varnish and preparation method thereof | |
| CN103193444B (en) | Silicic acid mud interior wall decorating material and preparation method thereof | |
| CN102558987B (en) | Reinforced formaldehyde-decomposed dope and preparation method thereof | |
| CN105176220B (en) | Synthetic emulsion diatom interiro wall latex paint and preparation method thereof | |
| CN101831223B (en) | Formaldehyde-removal non-yellowing mould-proof white wood lacquer | |
| CN104804579A (en) | Interior wall paint for sleep improvement | |
| CN102337064A (en) | Algae clay mineral environmentally-friendly inner wall coating | |
| CN102757698B (en) | Low-VOC (Volatile Organic Compounds) nitrolacquer | |
| CN105056272A (en) | Air purifying agent containing plant extracts | |
| CN103483999B (en) | A kind of children special-purpose environmental protection light top coat top coat with antibacterial functions and preparation method thereof | |
| CN104087140B (en) | Children special-purpose environmental protection dull finishing coat with antibacterial functions and preparation method thereof | |
| CN103073706B (en) | Water-like air-purifying oily polyurethane finishing paint and preparation method thereof | |
| CN102140302A (en) | Shock-resistant plant essential oil woodware paint | |
| CN104726025A (en) | Negative ion furniture paint | |
| CN103756378B (en) | A kind of stable type diatom liquid coating | |
| CN109852160A (en) | Multifunctional inner wall coating material and its preparation method and application | |
| CN107383982A (en) | A kind of negative ion putty powder and preparation method thereof | |
| CN100366689C (en) | Nanometer bactericidal negative ion nitrocellulose lacquer as woodenware finish | |
| CN107384140A (en) | A kind of anion environmental protection health paint and preparation method thereof | |
| CN105400258B (en) | A kind of heat preservation environment protection woodcare paint | |
| CN101768390B (en) | Aqueous transparent pigment dispersion and preparation method thereof | |
| CN107699009A (en) | Finish materials, finish materials preparation method | |
| CN114045075A (en) | Anti-formaldehyde coating and preparation method and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130821 Termination date: 20210513 |